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考虑了相变过程中生成相晶核的真实形状,对1956年Cahn给出的颗粒边界成核情况下成核长大型相变的相变体积分数计算公式进行了修正;当初始实验数据是成核率、长大率时,两种相变体积分数计算公式的计算结果差别很大. 当初始实验数据是相变体积分数随时间变化的实验点时,两种相变体积分数计算公式所给出的计算结果的差别主要由拟合误差所致. 无论从哪种实验数据开始计算,两种不同的计算模型给出的生成相的颗粒大小都存在很大区别,这将影响对俯冲带流变结构的认识. 相似文献
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本文研究了橄榄石原位相变实验中加载、加热路径上的相变及其对确定相变动力学参数的影响.利用文献［1］所给出的退火后先加温后加压,且相对低温条件下实验结果确定出的Ni2SiO4橄榄石相变动力学参数,计算了加载、加热路径上所发生的相变对确定成核率、长大率及相变体积分数的影响.结果表明,退火后先加压后加温,且相对高温条件下的实验数据受到加热路径上成核的影响.根据这样的实验数据得到的成核率会明显高于实际温压条件下的成核率.尤其是当多数实验都是高温实验时,根据这些成核率数据所确定的成核率参数会严重偏离其真值,从而严重影响对俯冲带颗粒粒度及俯冲带流变结构的计算.尽管目前有很多关于Mg2SiO4橄榄石长大率的实验数据,也有通过对挤碰物理图像的分析对(Mg0.89Fe0.11)2SiO4橄榄石成核率的估算,但只有文献［2］通过退火后先加压后加温的原位实验得到了Mg2SiO4橄榄石的相变成核率,且属于高温实验.根据本文的研究结果,我们认为亟需补充退火后先加温后加压或相对低温的实验数据以得到正确的地幔橄榄石成核率参数. 相似文献
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混合矿物体系表面吸附反应动力学研究 总被引：4，自引：0，他引：4
通过Pb2 ,Zn2 ,Ag 离子与混合矿物体系中表面吸附反应动力学实验研究表明 ,吸附离子与矿物表面吸附反应动力学主要受离子在溶液中扩散速率控制 ,可用复合二级反应动力学方程拟合得到较好的结果 .在近中性溶液中被交换的离子K 和Na 可用一级反应动力学方程较好拟合 .Ca2 的浓度变化符合扩散 交换反应动力学方程 .K ,Na ,Ca2 离子释放总量远大于吸附离子在溶液中减少量说明K ,Na ,Ca2 离子释放主要由于氢离子的交换反应 ;而Pb2 ,Zn2 ,Ag 离子与矿物之间吸附反应在常温下仍以表面反应为主 ,并未进入矿物晶格与K ,Na ,Ca2 离子发生交换反应 相似文献
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通过讨论地球空间已有稳定核素内质子数与中子数的分布趋势，介绍了稳定核素的趋势分析方法及其有关周期性分布方程形式，给出了理论方程曲线与地球空间稳定核素实验数据分布点的对比结果，进而给出了稳定核素极限值和元素周期表中化学元素极限，以及其与正负粒子对的可能对应关系方程，包括位于电子中微子层面附近的粒子质量量级初步估计.随后通过建立真空物质能量状态的二个假设，及基于等效Binet方程，给出了与Einstein狭义相对论有关结论相融合的物质粒子以光速及超光速运动的质量及能量方程；作为推论，对这些方程与暗物质及暗能量的可能对应关系予以了初步探讨. 相似文献
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正演计算是反演研究的基础,为了实现基于三维弹性波方程的全波形反演成像,发展准确、高效、低数值频散的三维正演模拟方法至关重要.为此,本文将修正保辛分部龙格-库塔格式与优化有限差分算子结合,发展了用于数值求解三维弹性波方程的修正时空优化保辛方法(MTSOS).新方法使用二级龙格-库塔格式达到了三阶时间精度,且更适用于求解非均匀介质情况下的弹性波方程,数值频散误差小于同精度保辛分部龙格-库塔(SPRK)方法的误差,提高了计算精度.波场模拟结果表明,三维MTSOS方法可以精确给出数值模拟结果,能够清晰模拟地震波传播过程中产生的各种震相、有效压制数值频散. 相似文献
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提出了一个新的太阳宇宙线日 -地传输的数学模型 ,它包括日冕粒子分布源和行星际传播方程 .根据对太阳宇宙线耀斑黑子群特征和耀斑相的观测 ,提出了多极性黑子湮没的两阶段日冕传输过程和传输方程 ,得到了与观测特征一致的日冕粒子分布源 .日冕传输的第一阶段 ,和太阳耀斑脉冲相的时间相当 ,加速粒子通过扩散很快均匀地分布在耀斑区 ,形成所谓快传播区 .第二阶段 ,加速粒子向快传播区以外的日冕区扩散并向行星际空间逃逸 ,形成慢传播过程 .日冕传输模型的数值结果和日冕传输的观测特征符合 .太阳宇宙线的行星际传播采用三维正交均匀各向异性方程描述 .最后把模型的数值结果与 1 997年 9月 2 4日事件的SOHO（SolarandHeliosphericObservatory）观测资料作了比较 .能较好地符合 . 相似文献
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逆时偏移作为一种高精度偏移方法已成为复杂构造成像的重要技术,描述纵波独立传播的延拓方程是各向异性介质逆时偏移的一个关键问题.在对VTI介质几个经典相速度近似公式回顾的基础上,针对常用于描述纯P波的Harlan近似公式在各向异性参数ε较大情况下近似精度较低的问题,本文对Harlan公式中的非椭圆项进行了修正,在非椭圆项前添加了一个与各向异性参数ε有关的修正系数,得到了三种改进型Harlan公式,并以近似精度最高的改进式为基础,推导了TTI介质纯P波方程.针对该伪微分方程,本文利用伪谱法和有限差分法联合实现波场延拓,对于常密度二阶方程,基于中心网格实现;对于一阶应力-速度方程则基于旋转交错网格实现.通过数值试验分析了TTI介质纯P波一阶应力-速度方程的近似精度,并以一阶纯P波方程为基础进行了TTI介质逆时偏移数值模拟试验.结果表明,本文给出的方法能够较准确地描述TTI介质纯P波波场特征,可以应用至各向异性介质逆时偏移. 相似文献
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Shigehiko Tateno Kei Hirose Nagayoshi Sata Yasuo Ohishi 《Physics of the Earth and Planetary Interiors》2007,160(3-4):319-325
Phase relations in Mg0.5Fe0.5SiO3 and Mg0.25Fe0.75SiO3 were investigated in a pressure range from 72 to 123 GPa on the basis of synchrotron X-ray diffraction measurements in situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). Results demonstrate that Mg0.5Fe0.5SiO3 perovskite is formed as a single phase at 85–108 GPa and 1800–2330 K, indicating a high solubility of FeO in (Mg,Fe)SiO3 perovskite at high pressures. Post-perovskite appears coexisting with perovskite in Mg0.5Fe0.5SiO3 above 106 GPa at 1410 K, the condition very close to the post-perovskite phase transition boundary in pure MgSiO3. The coexistence of perovskite and post-perovskite was observed to 123 GPa. In addition, post-perovskite was formed coexisting with perovskite also in Mg0.25Fe0.75SiO3 bulk composition at 106–123 GPa. In contrast to earlier experimental and theoretical studies, these results show that incorporation of FeO stabilizes perovskite at higher pressures. This could be due to a larger ionic radius of Fe2+ ion, which is incompatible with a small Mg2+ site in the post-perovskite phase. 相似文献
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Lin-Gun Liu 《Earth and Planetary Science Letters》1978,40(3):401-406
Gehlenite (Ca2Al2SiO7) has been found to transform to a new phase at pressures greater than 100 kbar and at about 1000°C, using a diamond-anvil pressure cell coupled with laser heating. The atoms of the new phase appear to be arranged in a perovskite-related structure similar to that described for Na2Ti3O7. The structure probably consists of layers of (Al2SiO7)4−, which are built up from blocks of edge-sharing (Al, Si)O6 octahedra and these blocks are joined by common octahedra corners. A small cubic unit cell with a = 3.719 ± 0.004 Å indexes completely the strong lines of the powder diffraction pattern, and a superlattice with a = 14.88 ± 0.02 Å satisfies all the observed weak lines in addition to the strong ones. However, the cell may be pseudocubic. The small cell contains a half of the gehlenite formula while the large cell contains 32 gehlenite formulae. Hence the molar volume for the new phase of Ca2Al2SiO7 is calculated to be 61.96 ± 0.20 cm3 at atmospheric pressure and room temperature. The new sodium titanate-type structure is probably more closely packed than an ordinary perovskite-type structure in which all octahedral corners are shared. This view is strongly supported by the very great density of this new phase, which is about 8% denser than the equivalent mixture of CaAl2O4 (calcium ferrite type) plus CaSiO3 (cubic perovskite type). The new phase is probably the most closely packed silicate known. Mg2SiO4 (spinel) was found to transform to an assemblage containing MgSiO3 (perovskite) plus MgO (periclase) at P-T conditions equivalent to the upper part of the lower mantle. By reacting with MgO, the perovskite modification of both MgSiO3 and MgSiO3 · xAl2O3 may adopt the sodium titanate structure at the still greater depths of the lower mantle. If the sodium titanate structures of Mg2(Al2Si)O7 and Mg2(MgSi2)O7 are present in the deep part of the lower mantle, MgO does not exist as a separate phase at the mantle-core boundary. This might be an obstacle to the possibility of dissolving these oxides (specifically the FeO component) in the molten Fe in the outer core as suggested by geophysical and geochemical studies of the earth's interior. The mechanism for developing the chemical plumes in the deep mantle proposed by Anderson does not appear to be consistent with studies of phase transformations in Ca-Al-rich compounds as outlined in this paper. 相似文献
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Tibor Gasparik 《Physics of the Earth and Planetary Interiors》1997,100(1-4):197-212
Numerical modeling of mantle convection by Liu (1994, Science, 264: 1904–1907) favors a two-layer convection, if the results are reinterpreted for the correct phase relations in (Mg,Fe)2SiO4. The resulting chemical isolation of the upper and lower mantle suggests a highly differentiated and layered upper mantle to account for the discrepancy between the observed compositions of mantle xenoliths and the cosmic abundances of elements. It is shown that a layered upper mantle with a hidden reservoir can have a structure consistent with the observed seismic velocity profiles and an average bulk composition corresponding to the cosmic abundances. The evolution of the upper mantle and the origin of komatiites are discussed in the context of the proposed model. 相似文献
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在保证低频自由振荡信号分辨率,又不对高频自由振荡信号产生抑制效应的前提下,利用张家口地震台体应变观测资料,采用功率谱密度估计方法,获得2011年3月11日日本9.0级大地震激发的0S2-0S74基频球型振荡和17个谐频球型振荡（3S2、5S3、2S10、2S12、3S9、11S1、7S10、5S13、4S18、5S14、14S4、4S24、1S38、7S18、14S8、9S19、5S30）,并与地球初步参考模型（PREM）的理论自由振荡周期进行对比,发现与实测振荡周期基本一致。 相似文献
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准确估计低频自由振荡及谱线分裂是约束地球内部结构和改进地球模型的重要手段.本文利用四个不同台站的超导重力观测数据系统研究了日本Mw9.0大地震激发的低于1.5 mHz自由振荡及谱线分裂.研究结果表明:(1)选取适当的数据长度,超导重力观测数据可以检测出低于1.5 mHz除1S1以外的所有自由振荡;(2)除0S2、0S3、0S0、2S1、3S1、1S2和0T2外,重点探测出3S2、0S4和1S4谱线分裂的所有谱峰;(3)与PREM模型理论频率相比,0S0观测频率平均向右偏移0.354×10-3mHz,说明PREM理论模型中地幔底部参数与真实地球可能存在微小偏差;(4)3S2的谱线分裂率r为1.485267,比PREM理论谱线分裂宽度约宽50%,表明PREM中地球内核中部介质参数可能存在一定误差,需要进一步改善.另外,quasi-0T2的r为1.254206,比PREM理论谱线分裂宽度约宽25%. 相似文献
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本文基于VTI介质拟声波方程,利用散射积分原理,在Born近似下导出了速度与各向异性参数的敏感核函数,同时结合作者前期研究提出的矩阵分解算法实现了一种新的VTI介质多参数全波形反演方法.矩阵分解算法通过对核函数-向量乘进行具有明确物理含义的向量-标量乘分解累加运算实现目标函数一阶方向或二阶方向的直接求取,从而避免了庞大核函数矩阵与Hessian矩阵的存储,该方法同时可以大大降低常规全波形反演在计算二阶方向时的庞大计算量.为了克服不同参数对波场影响程度的不同,本文利用作者前期在VTI介质射线走时层析成像研究中提出的分步反演策略实现了多参数联合全波形反演.理论模型实验表明,本文提出的基于Born敏感核函数的各向异性矩阵分解全波形反演方法可以获得较好的多参数反演结果. 相似文献
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Frank N. Bruscato Assistant Professor J. Roger McHenry Research Chemist 《Journal of Hydrology》1970,10(4):406-417
A series of Co-60 compounds, considered as potentially useful tracers of groundwater movement, were prepared and evaluated in soil column and batch studies. The compounds were: potassium hexacyanocobaltate (III), K3Co(CN)6; potassium ethylenediamminetetraacetato-cobaltate (III), KCo(EDTA); ammonium 12-tungstodicobaltoate (III), (NH4)8[Co(II)Co(II)W12O42] · 20 H2O; chloraquotetrammine cobalt (III) chloride, [Co(NH3)4(H2O)Cl]Cl2; and sodium hexanitrocobaltate (III), Na3Co(NO2)6. The performance of K3 60Co(CN)6 and K 60Co EDTA were dependent on their environment and more especially on the type and amount of clay present. The EDTA cobalt complex cannot be used in soils that are basic or where a large fraction of the clay is saturated with Na+ and/or Ca++. Of the other radioactive tracers tested, none were suitable for groundwater tracing because of instability in aqueous solution (Na3Co(NO2)6), variable anionic structure under acid conditions ((NH3)8[Co(II)Co(II)W12O42] · 20 H2O), or preferential uptake by the clay fraction ([Co(NH3)4(H2O)Cl]Cl2). 相似文献
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甚长周期VP型垂直摆倾斜仪对某些地球物理信号有特殊的敏感性,除了在观测小地震、慢地震等方面有优势之外,还可有效应用于低频地球自由振荡信号的探测.利用安置在武汉大学珞珈山的我国自行研制的VP型垂直摆倾斜仪在2011日本Mw9.0级大地震之后不同长度的观测数据,联合EEMD方法、自回归估计(AR)方法和bootstrap法,本文不仅检测到该地震激发的频率小于4.7 mHz的零阶球型振荡(0S2至0S38)和环型振荡(0T4至0T35)几乎所有振型以及15个谐频振型,还检测到5个其频率低于1mHz的低阶球型多线态(0S2、2S1、0S3、0S4和1S2)的部分或全部谱峰分裂现象,并给出了所有检测结果的精度评估.此外,本文分析了某些球型和环型振荡之间的耦合效应,结果表明耦合效应将显著影响地球自由振荡信号的相关参数. 相似文献
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断层带摩擦稳定性转换及其对应的微破裂特征对于地震成核条件和慢地震机理研究具有重要的意义.本文利用双轴实验装置研究了硬石膏断层带摩擦稳定性的转换及其对应的应变变化、微破裂特征,并分析了实验标本的微观结构.实验结果表明,σ2和加载点速度对断层滑动稳定性具有显著影响.在低σ2条件下,硬石膏断层带出现不稳定滑动,变形以局部化的脆性破裂和摩擦为主;随σ2的增加,断层由不稳定滑动向稳定滑动转换,断层带变形方式逐渐转变为分布式的破裂.在低σ2条件下,硬石膏断层带在较低加载点速度下表现为速度强化且滑动稳定,在中等加载点速度下表现为速度弱化并伴有准周期性的黏滑,在较高加载点速度下又有转向速度强化的趋势,σ2的提高使得速度弱化的范围逐渐减少,滑动趋于稳定.上述两次转换对应不同的微破裂特征,在较高速度下从速度弱化转换为速度强化时,断层滑动伴有能量较小但频度很高的微破裂活动,而在较低速度下从速度弱化转换为速度强化时,断层滑动伴有间歇性的微破裂,这与断层带的微观结构特征有较好的对应关系,表明其转换机制是不同的. 相似文献
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Larissa F. Dobrzhinetskaya Harry W. Green Matthew Weschler Mark Darus Young-Chung Wang Hans-Joachim Massonne Bernhard St ckhert 《Earth and Planetary Science Letters》2003,210(3-4):399-410
A focused ion beam of Ga ions is a relatively new technique that has been developed for microelectronic industries. Now researchers of the Earth sciences find it to be a promising tool for studying various geological materials. Using the FIB technique and an FEI Strata DB 235 dual beam system, we have successfully prepared several electron-transparent foils, which crossed μm-sized diamonds included in host minerals such as zircon and garnet from quartzofeldspathic rocks of the Saxonian Erzgebirge, Germany. Scanning and transmission electron microscopy applied to these foils revealed that the diamonds contain crystalline nanometric inclusions. These inclusions consist of minerals of known stoichiometries such as SiO2 and Al2SiO5, whereas others are characterized by different combinations of Si, K, P, Ti, and Fe in the presence of oxygen (stoichiometries are not clear at this stage of research). One suite of inclusions is assumed to be represented by archerite, KH2PO4, which is known to be stable at pressures of 4–22 GPa, and one nanocrystal containing Pb, oxygen and carbon is interpreted to be PbxOy or PbCO3. Along with solid crystalline inclusions, the diamonds contain cavities filled by liquid/gas that escaped during sample preparation. These are associated with dislocations of diamond growth. Our data are consistent with the concept of diamond crystallization from a COH-rich multicomponent supercritical fluid and suggest that the composition of such a fluid is more consistent with a local crustal source rather than that of a mantle origin. 相似文献