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1.
Abstract

Trends in rainfall series were investigated at 16 stations in Ghana over the period 1960–2005. Time series were first de-correlated using an effective pre-whitening methodology and then submitted to the resampling-based Mann-Kendall test. Field significances were assessed using the regional average Kendall statistic. Although no significant changes were observed in annual rainfall, the analysis reveals: (a) a reduction in the number of wet season days totalling less than 20 mm of rainfall, between latitudes 6° and 9.5°N; (b) a delay (about 0.5 d year‐1) in the wet season onset at several locations throughout the country; and (c) a lengthening (about 0.1 d year‐1) of rainless periods during the wet season in the south and centre of Ghana. All these changes, which remained insignificant at more than half of the individual stations, were found to be regionally significant at the 95% confidence level. The results highlight the importance of evaluating regional significance when investigating climate trends.

Editor Z.W. Kundzewicz

Citation Lacombe, G., McCartney, M., and Forkuor, G., 2012. Drying climate in Ghana over the period 1960–2005: evidence from the resampling-based Mann-Kendall test at local and regional levels. Hydrological Sciences Journal, 57 (8), 1594–1609.  相似文献   

2.
The development of intense agriculture in semiarid areas modifies intensity and spatial distribution of groundwater recharge by summing irrigation return flow to limited rainfall infiltration. Environmental tracers provide key information, but their interpretation is complicated by more complex groundwater flow patterns. In multilayered aquifers, the real origin of the groundwater samples is hard to assess because of local mixing processes occurring inside long‐screened boreholes. We use environmental tracers (14C, 13C, 2H, 18O, 3H) to investigate the long‐term evolution of recharge in the five‐layer Campo de Cartagena aquifer in South‐Eastern Spain, in addition to high‐resolution temperature loggings to identify the depth of origin of groundwater. Despite the complex background, this methodology allowed a reliable interpretation of the geochemistry and provided a better understanding of the groundwater flow patterns. The tritium method did not give good quantitative results because of the high variability of the recharge signal but remained an excellent indicator of recent recharge. Nonetheless, both pre‐anthropization and post‐anthropization recharge regime could be identified and quantified by radiocarbon. Before the development of agriculture, recharge varied from 17 mm.year‐1 at the mountain ranges to 6 mm.year‐1 in the plain, whereas the mean annual rainfall is about 300 mm. In response to the increase of agricultural activity, recharge fluxes to the plain were amplified and nowadays reach up to 210 mm.year‐1 in irrigated areas. These values are strengthened by global water budget and local unsaturated zone studies. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

3.
Groundwater extraction is rampant in many developing countries and urban areas whereas the natural recharge is decreasing due to covering of Earth's surface for various developmental activities. This leads to declining levels of groundwater and deterioration in groundwater quality. Artificial recharge with rain water harvesting techniques offers an excellent scope to arrest this degradation. This paper presents a study that analyzes the influence of rain water harvesting (RWH) on groundwater storage and quality. Chennai City, India is selected as study area, as major RWH implementation has taken place during 2002–2003 due to Government legislation. Preliminary analysis of groundwater levels were done spatially and temporally. Groundwater table contours were drawn using the GIS software for pre‐ (1999–2000) and post‐RWH (2009–2010) periods. The groundwater levels follow a decreasing trend before implementation of RWH where as a positive increasing trend takes place after construction of RWH structures. “Groundwater Estimation Committee (GEC)” norms of Government of India were used to estimate the change in storage during pre‐ and post‐RWH periods, which are found to be 1.76 × 106 and 32.77 × 106 m3, respectively. The results show that the implementation of RWH has increased the groundwater storage considerably. Also, the influence of RWH on groundwater quality is found to be encouraging in some parts of the studied area.  相似文献   

4.
Deuterium and oxygen‐18 are common environmental tracers in water used to investigate hydrological processes such as evaporation and groundwater recharge, and to trace moisture source. In this study, we collected event precipitation from 01 January 2010 to 28 February 2011 at a site in Changsha, Yangtze River Basin to estimate the influence of moisture source and atmospheric conditions on stable isotope compositions. The local meteoric water line, established as δD = (8.45 ± 0.13) δ18O + (17.7 ± 0.9) (r2 = 0.97, n = 189), had a higher slope and intercept than global meteoric water line. Temperature–δ18O exhibited complex correlations, with positive correlations during Nov.–Apr. superior to during Jun.–Sep., which was attributed to distinctive moisture sources, but vague the overall period; amount effect examined throughout the year. Linear regressions between δ18O and δD value in different precipitation event size classes revealed progressively decreasing slope and intercept values with decreasing precipitation amount and increasing vapour pressure deficit, indicating that small rainfall events (0–5 mm) were subject to secondary evaporation effects during rainwater descent. In contrast, snowfall and heavy precipitation events exhibited high slope and intercepts for the regression equation between δ18O and δD. High concentrations of heavy isotopes were associated with precipitation events sourced from remote westerly air masses, degenerated tropical marine air masses from the Bay of Bengal (BoB), and inland moisture in the pre‐monsoon period, as determined from backward trajectories assessed in the HYSPLIT model. Meanwhile, low concentrations of heavy isotopes were found to correspond with remote maritime moisture from BoB, the South China Sea, and the west Pacific at three different air pressures in summer monsoon and post‐monsoon using HYSPLIT and records of typhoon paths. These findings suggest that stable isotope compositions in precipitation events are closely associated with the meteorological conditions and respond sensitively to moisture source in subtropical monsoon climates. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

5.
Changing fire regimes and prescribed‐fire use in invasive species management on rangelands require improved understanding of fire effects on runoff and erosion from steeply sloping sagebrush‐steppe. Small (0·5 m2) and large (32·5 m2) plot rainfall simulations (85 mm h–1, 1 h) and concentrated flow methodologies were employed immediately following burning and 1 and 2 years post‐fire to investigate infiltration, runoff and erosion from interrill (rainsplash, sheetwash) and rill (concentrated flow) processes on unburned and burned areas of a steeply sloped sagebrush site on coarse‐textured soils. Soil water repellency and vegetation were assessed to infer relationships in soil and vegetation factors that influence runoff and erosion. Runoff and erosion from rainfall simulations and concentrated flow experiments increased immediately following burning. Runoff returned to near pre‐burn levels and sediment yield was greatly reduced with ground cover recovery to 40 per cent 1 year post‐fire. Erosion remained above pre‐burn levels on large rainfall simulation and concentrated flow plots until ground cover reached 60 per cent two growing seasons post‐fire. The greatest impact of the fire was the threefold reduction of ground cover. Removal of vegetation and ground cover and the influence of pre‐existing strong soil‐water repellency increased the spatial continuity of overland flow, reduced runoff and sediment filtering effects of vegetation and ground cover, and facilitated increased velocity and transport capacity of overland flow. Small plot rainfall simulations suggest ground cover recovery to 40 per cent probably protected the site from low‐return‐interval storms, large plot rainfall and concentrated flow experiments indicate the site remained susceptible to elevated erosion rates during high‐intensity or long duration events until ground cover levels reached 60 per cent. The data demonstrate that the persistence of fire effects on steeply‐sloped, sandy sagebrush sites depends on the time period required for ground cover to recover to near 60 per cent and on the strength and persistence of ‘background’ or fire‐induced soil water repellency. Published in 2009 by John Wiley & Sons, Ltd.  相似文献   

6.
Soil and vadose zone profiles are used as an archive of changes in groundwater recharge and water quality following changes in land use in an area of the Loess Plateau of China. A typical rain‐fed loess‐terrace agriculture region in Hequan, Guyuan, is taken as an example, and multiple tracers (chloride mass balance, stable isotopes, tritium and water chemistry) are used to examine groundwater recharge mechanisms and to evaluate soil water chloride as an archive for recharge rate and water quality. Results show that groundwater recharge beneath natural uncultivated grassland, used as a baseline, is about 94–100 mm year?1 and that the time it takes for annual precipitation to reach water table through the thick unsaturated zone is from decades to hundreds of years (tritium free). This recharge rate is 2–3 orders of magnitude more than in the other semiarid areas with similar annual rainfall but with deep‐rooted vegetation and relatively high temperature. Most of the water that eventually becomes recharge originally infiltrated in the summer months. The conversion from native grassland to winter wheat has reduced groundwater recharge by 42–50% (50–55 mm year?1 for recharge), and the conversion from winter wheat to alfalfa resulted in a significant chloride accumulation in the upper soil zone, which terminated deep drainage. The paper also evaluates the time lag between potential recharge and actual recharge to aquifer and between increase in solute concentration in soil moisture and that in the aquifer following land‐use change due to the deep unsaturated zone. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

7.
This paper describes the application of environmental isotopes and injected tracer techniques in estimating the contribution of storms as well as annual precipitation to groundwater recharge and its circulation, in the semi‐arid region of Bagepalli, Kolar district, Karnataka. Environmental isotopes 2H, 18O and 3H were used to study the effect of storms on the hydrological system, and an isotope balance was used to compute the contribution of a storm component to the groundwater. Some of the groundwater samples collected during the post‐storm periods were highly depleted in stable isotope content with higher deuterium excess relative to groundwater from the pre‐storm periods. Significant variation in deuterium excess in groundwater from the same area, collected in two different periods, indicates the different origin of air masses. The estimated recharge component of a storm event of 600 mm to the groundwater was found to be in the range of 117–165 mm. There was no significant variation in environmental tritium content of post‐storm and pre‐storm groundwater, indicating the fast circulation of groundwater in the system. After completion of the environmental isotope work, an injected radiotracer 3H technique was applied to estimate the direct recharge of total precipitation to the groundwater. The estimated recharge to the groundwater is 33 mm of the 550 mm annual precipitation during 1992. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

8.
Submarine groundwater discharges (SGD) were investigated in a marine watershed in south‐eastern Korea using water budget analysis and a 222Rn mass balance model. Multi‐layered TOPMODEL added hydrological assumption was used to estimate groundwater components in the water budget analysis. Field observations of soil moisture, rainfall, runoff and groundwater fluctuations were used for calibration and validation of the hydrologic model. Based on observed hydrological data and terrain analyses, parameters for the hydrologic model were delineated and used to describe several hydrologic responses in the watershed. SGD estimations by 222Rn mass balance method were also performed at Il‐Gwang bay in July, 2010, and May, June, July and Nov. 2011. The estimated groundwater through hydrologic modeling and water balance analysis was 1.3x106 m3/year, which rapidly increased during typhoon season due to heavy rainfall and permeable geologic structure. The estimated groundwater was approximately 3.7–27.1% of SGD as evaluated by 222Rn mass balance method ranges 3.44 and 17.45 m3m?2year?1. Even though SGD is predominantly influenced by tide fluctuation, the head gradient (difference) from hydrologic processes associated with heavy rainfalls can also have extra significant influences. Comprehensive understanding of SGD evaluation can be improved through a simultaneous application of both these approaches. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

9.
We examined the fire‐induced changes in groundwater recharge rate. This aspect is particularly important in the case of large forested areas growing over a coastal aquifer affected by saltwater intrusion. In the Ravenna coastal area (Italy), pine forests grow on coastal dune belts, overlying a sandy unconfined aquifer, which is strongly affected by marine ingression. Three groundwater profiles across the forest and perpendicular to the coastline were monitored for groundwater level, physical, and chemical parameters. The aims were to define groundwater quality, recharge rate, freshwater volume, and highlight change, which occurred after a forest fire with reference to pre‐fire conditions. Analytical solutions based on Darcy Law and the Dupuit Equation were applied to calculate unconfined flow and compare recharge rates among the profiles. The estimated recharge rates increased in the partially and completely burnt areas (219 and 511 mm year?1, respectively) compared with the pristine pine forest area (73 mm year?1). Although pre‐fire conditions were similar in all monitored profiles, a post‐fire decrease in salinity was observed across the burnt forest, along with an increase in infiltration and freshwater lens thickness. This was attributed to decrease canopy interception and evapotranspiration caused by vegetation absence after the fire. This research provided an example of positive forest fire feedback on the quantity and quality of fresh groundwater resources in a lowland coastal aquifer affected by saltwater intrusion, with limited availability of freshwater resources. The fire provided an opportunity to evaluate a new forest management approach and consider the restoration and promotion of native dune herbaceous vegetation.  相似文献   

10.
The American cranberry (Vaccinium macrocarpon Ait.) is an important part of the cultural heritage and economy of Southeastern Massachusetts, yet water quality concerns and wetland protection laws challenge its commercial production. Here, we report inputs and outputs of water, nitrogen (N), and phosphorus (P) for a 2.12‐ha cranberry bed over a 2‐year period from 2013 to 2015. Water‐budget analysis indicated that precipitation contributed 40%, floodwater 37%, irrigation 15%, and groundwater 8% of water inputs to the cranberry bed. Minor annual variation in surface water discharge (~90 mm·year?1 or 3%) contrasted with large decreases in net (= outputs ? inputs) nutrient export, from 16.2 to 9.1 kg N·ha?1·year?1 for total (dissolved + suspended particulate) nitrogen (TN) and from 3.34 to 1.47 kg P·ha?1·year?1 for total phosphorus (TP) between Years 1 and 2. Annual variation in net TN and TP export was tied to decreases in spring and summer nutrient export and controlled by the combined effects of fertilizer management, soil biogeochemistry, and hydrology. The relatively high spring TN export in Year 1 was associated with coincident increases in soil temperature and rainfall. A second factor was the timing of fertilizer application, which occurred 1 day prior to a major summer storm (i.e., third largest daily rainfall since 1926) and was responsible for up to 15% and 9% of the Year 1 TN and TP export, respectively. Nutrient budgets, which balanced water and fertilizer inputs with water, fruit, and vegetative outputs, were consistent with the burial of 21.6 kg N·ha?1·year?1 and 7.27 kg P·ha?1·year?1. Field measurements indicated that burial would increase TN and TP in the shallow (0–5 cm) rooting zone by 14% and 6%, respectively, which seemed plausible based on the relatively young age of the bed (4–5 years) and new root growth patterns in Vaccinium plants.  相似文献   

11.
Post‐wildfire runoff was investigated by combining field measurements and modelling of infiltration into fire‐affected soils to predict time‐to‐start of runoff and peak runoff rate at the plot scale (1 m2). Time series of soil‐water content, rainfall and runoff were measured on a hillslope burned by the 2010 Fourmile Canyon Fire west of Boulder, Colorado during cyclonic and convective rainstorms in the spring and summer of 2011. Some of the field measurements and measured soil physical properties were used to calibrate a one‐dimensional post‐wildfire numerical model, which was then used as a ‘virtual instrument’ to provide estimates of the saturated hydraulic conductivity and high‐resolution (1 mm) estimates of the soil‐water profile and water fluxes within the unsaturated zone. Field and model estimates of the wetting‐front depth indicated that post‐wildfire infiltration was on average confined to shallow depths less than 30 mm. Model estimates of the effective saturated hydraulic conductivity, Ks, near the soil surface ranged from 0.1 to 5.2 mm h?1. Because of the relatively small values of Ks, the time‐to‐start of runoff (measured from the start of rainfall), tp, was found to depend only on the initial soil‐water saturation deficit (predicted by the model) and a measured characteristic of the rainfall profile (referred to as the average rainfall acceleration, equal to the initial rate of change in rainfall intensity). An analytical model was developed from the combined results and explained 92–97% of the variance of tp, and the numerical infiltration model explained 74–91% of the variance of the peak runoff rates. These results are from one burned site, but they strongly suggest that tp in fire‐affected soils (which often have low values of Ks) is probably controlled more by the storm profile and the initial soil‐water saturation deficit than by soil hydraulic properties. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

12.
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13.
The present work examines the possible use of major ion chemistry and multivariate statistical techniques as a rapid and relatively cost‐effective method of identifying the extent of groundwater and surface water (GW–SW) interaction in an urban setting. The original hydrogeochemical dataset consists of groundwater (n = 114), stream water (n = 42) and drain water (n = 24) samples, collected twice in a year for the pre‐ and post‐monsoon seasons, for three successive years along an 8 km reach of the Delhi segment of River Yamuna, India. The dynamic and similar seasonal changes of hydro‐geochemical facies and major ion trends of river, drain and groundwater samples indicate the existence of an empirical relationship between GW and SW. Results of both R‐ and Q‐mode factor and cluster analyses highlight multi‐scale control of the fluid exchange distributions, with distinct seasonal alteration in mode and extent of GW–SW interaction, namely, the influence of the mixing zones between urban river and groundwater and the pattern of groundwater flow through the river bed. Hierarchical cluster analysis (HCA) of sampling locations efficiently illustrates different groups that comprise samples severely influenced by contaminated surface water downstream and the upstream fresh water samples. These results substantiate the strong exchange processes between GW and SW all along the stretch. The study shows that the combination of an empirical and statistical relationship between different ionic species and sampling locations can provide greater confidence in identifying the extent of GW–SW interaction/exchange processes. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

14.
In much of western United States destructive floods after wildfire are frequently caused by localized, short‐duration convective thunderstorms; however, little is known about post‐fire flooding from longer‐duration, low‐intensity mesoscale storms. In this study we estimate and compare peak flows from convective and mesoscale floods following the 2012 High Park Fire in the ungaged 15.5 km2 Skin Gulch basin in the northcentral Colorado Front Range. The convective storm on 6 July 2012 came just days after the wildfire was contained. Radar data indicated that the total rainfall was 20–47 mm, and the maximum rainfall intensities (upwards of 50 mm h?1) were concentrated over portions of the watershed that burned at high severity. The mesoscale storm on 9–15 September 2013 produced 220–240 mm of rain but had maximum 15‐min intensities of only 25–32 mm h?1. Peak flows for each flood were estimated using three independent techniques. Our best estimate using a 2D hydraulic model was 28 m3 s?1 km?2 for the flood following the convective storm, placing it among the largest rainfall‐runoff floods per unit area in the United States. In contrast, the flood associated with the mesoscale flood was only 6 m3 s?1 km?2, but the long‐duration flood caused extensive channel incision and widening, indicating that this storm was much more geomorphically effective. The peak flow estimates for the 2013 flood had a higher relative uncertainty and this stemmed from whether we used pre‐ or post‐flood channel topography. The results document the extent to which a high and moderate severity forest fire can greatly increase peak flows and alter channel morphology, illustrate how indirect peak flow estimates have larger errors than is generally assumed, and indicate that the magnitude of post‐fire floods and geomorphic change can be affected by the timing, magnitude, duration, and sequence of rainstorms. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

15.
S. Lallahem  J. Mania 《水文研究》2006,20(7):1585-1595
Chalk crops out from a wide belt around the Paris basin, France, covering an area of about 70 000 km2. In this region, the chalk presents the most important unconfined aquifer because of its extent and the size of its resources ((11–12) × 109 m3 year?1). The assessment of underground outflow depends on the vertical feeding, the infiltration and the hydrometry. This paper analyses the regional structural map, interprets the groundwater reaction under rainfall, explains the water circulation in such media where the reservoir geometry plays an essential role on aquifer response, and determines different aquifer physical parameters. Attempts are made to identify the rapid transfer of groundwater at the level of faults and their important fissures. Based on a quantitative study of the seasonal and interannual piezometry fluctuations, it is noted that the mode and the piezometric chronology events are controlled by major parameters of geological and hydrogeologic contexts, aquifer hydraulic characteristics, the position of upstream and downstream basin limits, groundwater depth and replenishment time. This paper ends with determination of groundwater physical parameters of the diffusivity (T/S, T and S) values by examination of the groundwater replenishments periods. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

16.
Evaporation dominates the water balance in arid and semi‐arid areas. The estimation of evaporation by land‐cover type is important for proper management of scarce water resources. Here, we present a method to assess spatial and temporal patterns of actual evaporation by relating water balance evaporation estimates to satellite‐derived radiometric surface temperature. The method is applied to a heterogeneous landscape in the Krishna River basin in south India using 10‐day composites of NOAA advanced very high‐resolution radiometer satellite imagery. The surface temperature predicts the difference between reference evaporation and modelled actual evaporation well in the four catchments (r2 = 0·85 to r2 = 0·88). Spatial and temporal variations in evaporation are linked to vegetation type and irrigation. During the monsoon season (June–September), evaporation occurs quite uniformly over the case‐study area (1·7–2·1 mm day?1), since precipitation is in excess of soil moisture holding capacity, but it is higher in irrigated areas (2·2–2·7 mm day?1). In the post‐monsoon season (December–March) evaporation is highest in irrigated areas (2·4 mm day?1). A seemingly reasonable estimate of temporal and spatial patterns of evaporation can be made without the use of more complex and data‐intensive methods; the method also constrains satellite estimates of evaporation by the annual water balance, thereby assuring accuracy at the seasonal and annual time‐scales. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
In this study, we examined the year 2011 characteristics of energy flux partitioning and evapotranspiration of a sub‐alpine spruce forest underlain by permafrost on the Qinghai–Tibet Plateau (QPT). Energy balance closure on a half‐hourly basis was H + λE = 0.81 × (Rn ? G ? S) + 3.48 (W m?2) (r2 = 0.83, n = 14938), where H, λE, Rn, G and S are the sensible heat, latent heat, net radiation, soil heat and air‐column heat storage fluxes, respectively. Maximum H was higher than maximum λE, and H dominated the energy budget at midday during the whole year, even in summer time. However, the rainfall events significantly affected energy flux partitioning and evapotranspiration. The mean value of evaporative fraction (Λ = λE/(λE + H)) during the growth period on zero precipitation days and non‐zero precipitation days was 0.40 and 0.61, respectively. The mean daily evapotranspiration of this sub‐alpine forest during summer time was 2.56 mm day?1. The annual evapotranspiration and sublimation was 417 ± 8 mm year?1, which was very similar to the annual precipitation of 428 mm. Sublimation accounted for 7.1% (30 ± 2 mm year?1) of annual evapotranspiration and sublimation, indicating that the sublimation is not negligible in the annual water balance in sub‐alpine forests on the QPT. The low values of the Priestley–Taylor coefficient (α) and the very low value of the decoupling coefficient (Ω) during most of the growing season suggested low soil water content and conservative water loss in this sub‐alpine forest. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

18.
A high groundwater level is highly relevant to the slope instability. Drainage tunnel is an effective method for groundwater level control, but its effect on landslide hydrogeological characteristics is rarely discussed. This study analysed the changes of the landslide hydrogeological characteristics under the effect of a drainage tunnel by real-time monitoring of rainfall, groundwater level, and surface displacement. The trend and mutation of groundwater level are analysed by the Mann–Kendall test and the Mann–Kendall mutation test. The memory effect of groundwater in the landslide area was analysed using autocorrelation analysis. The response characteristics of groundwater level to rainfall were evaluated using cross-correlation analysis and mutual information theory. Variations of groundwater levels were further investigated based on hydrograph analysis. Results showed that the groundwater level had a downward trend from 2016 to 2017. The significant downward trend of groundwater levels began in August 2016. The memory effect of groundwater levels was longer under the effect of the drainage tunnel. Before the construction of the drainage tunnel, the response time of groundwater to rainfall was less than 3 hr and rainfall can generate dramatic groundwater level variations. After the drainage tunnel was completed, time lags can be observed in the groundwater response, and the variation of groundwater levels was smaller than before. A strong correlation was found between groundwater levels and the landslide movement. This study demonstrated that the drainage tunnel had effectively controlled the groundwater level in the landslide and ensured the stability of the landslide.  相似文献   

19.
The goal of this study was to test hollow‐fiber ultrafiltration as a method for concentrating in situ bacteria and viruses in groundwater samples. Water samples from nine wells tapping a shallow sandy aquifer in a densely populated village in Bangladesh were reduced in volume approximately 400‐fold using ultrafiltration. Culture‐based assays for total coliforms and Escherichia coli, as well as molecular‐based assays for E. coli, Bacteroides, and adenovirus, were used as microbial markers before and after ultrafiltration to evaluate performance. Ultrafiltration increased the concentration of the microbial markers in 99% of cases. However, concentration factors (CF = post‐filtration concentration/pre‐filtration concentration) for each marker calculated from geometric means ranged from 52 to 1018 compared to the expected value of 400. The efficiency was difficult to quantify because concentrations of some of the markers, especially E. coli and total coliforms, in the well water (WW) collected before ultrafiltration varied by several orders of magnitude during the period of sampling. The potential influence of colloidal iron oxide precipitates in the groundwater was tested by adding EDTA to the pre‐filtration water in half of the samples to prevent the formation of precipitates. The use of EDTA had no significant effect on the measurement of culturable or molecular markers across the 0.5 to 10 mg/L range of dissolved Fe2+ concentrations observed in the groundwater, indicating that colloidal iron did not hinder or enhance recovery or detection of the microbial markers. Ultrafiltration appears to be effective for concentrating microorganisms in environmental water samples, but additional research is needed to quantify losses during filtration.  相似文献   

20.
A recent study assessing the state‐of‐the‐practice of in situ thermal remediation technologies (e.g., electrical resistive heating [ERH], conductive heating, steam‐based heating, in situ large‐diameter auger soil mixing with steam/hot air injection, and radio‐frequency heating) identified 182 applications in the 1988 to 2007 period and summarized the geologic settings in which these technologies were applied, chemicals treated, design parameters, and operating conditions. That study concluded that documentation for less than 8% of those applications contained sufficient data to assess the effect remediation had on groundwater quality. Consequently, post‐treatment data were collected at five ERH sites, with emphasis on assessing reductions in dissolved groundwater concentrations and mass discharge (mass flux) to the aquifer. For each site, dissolved groundwater concentrations and hydraulic conductivities were determined across a vertical transect oriented perpendicular to groundwater flow and at the downgradient edge of the treatment zone. Dissolved concentration and mass discharge reductions ranged from about less than 10× to 100×, with post‐treatment groundwater concentrations ranging from about 101 to 104μg/L and mass discharges ranging from about 10–1 to 102 kg/y. The primary factors differentiating sites with greater and lesser dissolved concentration and mass discharge reductions were the adequacy of pre‐treatment source zone delineation, the extent to which the treatment zone encompassed the source zone, and the duration of treatment at the design operating temperature. The results suggest that ERH systems are capable of reducing groundwater concentrations to 10 to 100 μg/L levels and lower in some settings, but only if the source zone is adequately delineated and fully encompassed by the treatment system, and the treatment system is operated for a sufficiently long period of time.  相似文献   

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