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1.
This study investigated CO2 degassing and related carbon isotope fractionation effects in the Wiesent River that drains a catchment in the karst terrain of the Franconian Alb, Southern Germany. The river was investigated by physico‐chemical and stable isotope analyses of water and dissolved inorganic carbon during all seasons along 65‐km long downstream transects between source and mouth. Calculated pCO2 values at the source were 21 400 ± 2400 µatm. The pCO2 rapidly decreased in the river water and dropped to an average of 1240 ± 330 µatm near the mouth. About 90% of this decrease occurred within the first 6 km of the river. The river was supersaturated with respect to CO2 over its entire course and must have acted as a continuous year‐round CO2 source to the atmosphere. The average CO2 flux from the karst river was estimated with 450 mmol m?2 day?1 with higher fluxes up to 5680 mmol m?2 day?1 at the source. At the source, δ13CDIC values showed no seasonal variations with an average of ?14.2 ± 0.2‰. This indicated that groundwater retained high pCO2 mainly from soil CO2. The contribution of soil CO2 to dissolved inorganic carbon was estimated at 65% to 72%. The downstream CO2 loss caused a positive shift in δ13CDIC values of 2‰ between source and mouth because of the preferential loss of the 12C isotope during degassing. Considering the findings of this study and the fact that carbonate lithology covers a significant part of the earth's surface, CO2 evasion from karst regions might contribute notably to the annual carbon dioxide release from global freshwater systems. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

2.
The water quality along the River Kennet, in the Thames basin of southern England, was examined in terms of the influence of point- and diffuse-nutrient inputs. The river is supplied mainly from a Cretaceous Chalk aquifer and hence the waters are of a calcium bicarbonate type. The nitrate largely comes from agricultural sources, with concentrations decreasing downstream due to plant uptake and probable denitrification. In contrast, soluble reactive phosphorus (SRP) is largely associated with sewage inputs and concentrations increase downstream in line with effluents from major towns such as Newbury and Reading. Adjacent to the river in the lower half of the catchment is the Kennet and Avon Canal and the two are in places hydrologically connected. The canal inputs may influence calcium carbonate (calcite) precipitation and increase suspended sediment and particulate phosphorus concentrations in the river. Monitoring upstream and downstream of Marlborough sewage treatment works (STW) showed that SRP concentrations in the effluent were highly variable due to variable efficiency of P stripping and still sufficiently concentrated to dominate downstream river SRP with potential impacts on stream ecology. Biological recovery in this river following P stripping at STWs is complex and controlling those spikes in SRP that are above a threshold of 100 μg l−1 may be a critical requirement. More stringent effluent targets than are currently recommended may be needed (less than 800 μg RP l−1) to achieve good ecological status in this river depending on SRP concentrations upstream.  相似文献   

3.
Glacial lake outburst floods (GLOF) often have a significant impact on downstream users. Including their effects in hydrological models, identifying past occurrences and assessing their potential impacts are challenges for hydrologists working in mountainous catchments. The regularly outbursting Merzbacher Lake is located in the headwaters of the Aksu River, the most important source of water discharge to the Tarim River, northwest China. Modelling its water resources and the evaluation of potential climate change impacts on river discharge are indispensable for projecting future water availability for the intensively cultivated river oases downstream of the Merzbacher Lake and along the Tarim River. The semi‐distributed hydrological model SWIM was calibrated to the outlet station Xiehela on the Kumarik River, by discharge the largest tributary to the Aksu River. The glacial lake outburst floods add to the difficulties of modelling this high‐mountain, heavily glaciated catchment with poor data coverage and quality. The aims of the study are to investigate the glacier lake outburst floods using a modelling tool. Results include a two‐step model calibration of the Kumarik catchment, an approach for the identification of the outburst floods using the measured gauge data and the modelling results and estimations of the outburst flood volumes. Results show that a catchment model can inform GLOF investigations by providing ‘normal’ (i.e. without the outburst floods) catchment discharge. The comparison of the simulated and observed discharge proves the occurrence of GLOFs and highlights the influences of the GLOFs on the downstream water balance. © 2013 The Authors. Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

4.
Sources and fate of nutrients in a subtropical reservoir   总被引：1，自引：0，他引：1  
This study examined the sources and fate of nutrient inputs from two principal tributaries to the eutrophic subtropical Wivenhoe reservoir: an unregulated river and a dammed river with regular releases, during a period of declining reservoir water levels. Nutrient budgets were constructed over a period of 6 years, and combined with short-term data on nutrient concentrations and forms, and δ15N stable isotope data. Our study found that over a 6 year period, there was net retention of phosphorus (P) in the reservoir, with 60% of inputs retained. Most of the P input load came from the unregulated river, with an agricultural catchment, during periods of high flow. During one event half of the total TP load from the unregulated river in the study period was delivered in only 12 days. Much of the P was dissolved inorganic P (DIP) and was derived from high P concentrations in soils and sediments. This highlights the importance of appropriate catchment management practices to reduce P losses from terrestrial systems because retention of P in reservoir sediments reduces the availability of this nutrient for agricultural production. In contrast, there was negligible retention of nitrogen (N). The unregulated river was an important source of N derived from N fixation in the river and adjacent soils, while the source from the dammed river was mostly reprocessed N. The high retention of P relative to N is consistent with relatively higher accumulation of P in sediments.  相似文献   

5.
1INTRODUCTIONTileillinoisRiver,oneofthemajortributariestotheMississippiRiverinthecentralUnitedStates,hasadrainageareaof75,156kmZthatcoversportionsof1llinois,Indiana,andWisconsin(Figllre1).Asaresultofrepeatedlevelingbyglaciers,mostofthe1llinoisRiverwatershedisflatandcoveredwithfineloesssoil,makingitoneofthebestagriculturalregionsinNorthAmerica.Morethan80percentoftheIllinoisRiverbasinispresentlyusedforagricultUralpurposes.IllinoisagricultUrestartedtoexpandveryrapidlyinthe19thcentury,g…  相似文献   

6.
Alluvial fans at tributary junctions modulate sediment flux through river networks, by buffering the mainstem channel from disturbance in the tributaries. Buffering occurs through the storage (and release) of sediment in fans. Here, we use an extensive historic dataset to characterise the ways in which fan buffering can change as sediment supply varies. In New Zealand's East Coast region, sediment supply and fluvial transport are prolific by global standards. We reconstruct how tributary-junction fans in this region have responded to sediment generated by deforestation and extreme storms. The dynamics of five fans along the Tapuaeroa River are examined for the period 1939–2015. In response to major sediment loading, fans aggraded by up to 12 m and prograded by up to 170 m. Net sediment accumulation ranged from near zero to 1.5×106 m3. Fan size, gradient, sediment storage and buffering were influenced by both upstream and downstream controls. Key upstream (tributary) influences were sediment supply and stream power; downstream (mainstem) influences included distal confinement and, importantly, the nature of fan interaction with the mainstem, which aggraded by up to 6 m. The fans' ability to buffer the Tapuaeroa River from change in the tributaries was largely governed by this downstream interaction: as the mainstem aggraded, it increasingly curtailed fan progradation, thus limiting buffering. Previous studies of tributary-junction fans have related fan morphometry to basin characteristics. However, we find that fan slope and area can vary considerably at decadal, annual or even monthly timescales. Consequently, we suggest that such studies could benefit by examining regional histories of disturbance. © 2019 John Wiley & Sons, Ltd.  相似文献   

7.
The aim of this paper is to quantify peakflow attenuation and/or amplification in a river, investigating lateral flow from the intermediate catchment during floods. This is a challenge for the study of the hydrological response of permeable/intermittent streams, and our contribution refers to a modelling framework based on the inverse problem for the diffusive wave model applied in a karst catchment. Knowing the upstream and downstream hydrographs on a reach between two stations, we can model the lateral one, given information on the hydrological processes involved in the intermediate catchment. The model is applied to 33 flood events in the karst reach of the Iton River in French Normandy where peakflow attenuation is observed. The monitored zone consists of a succession of losing and gaining reaches controlled by strong surface‐water/groundwater (SW/GW) interactions. Our results show that despite a high baseflow increase in the reach, peakflow is attenuated. Model application shows that the intensity of lateral outflow for the flood component is linked to upstream discharge. A combination of river loss and overbank flow for highest floods is proposed for explaining the relationships. Our approach differentiates the role of outflow (river loss and overbank flow) and that of wave diffusion on peakflow attenuation. Based on several sets of model parameterization, diffusion is the main attenuation process for most cases, despite high river losses of up to several m3/s (half of peakflow for some parameterization strategies). Finally, this framework gives new insight into the SW/GW interactions during floods in karst basins, and more globally in basins characterized by disconnected river‐aquifer systems.  相似文献   

8.
In most countries worldwide regulatory bodies set effluent discharge limits into rivers and other natural water bodies. These limits specify the maximum permissible concentration of defined pollutants that may be discharged into the water body. This limit is conceptually based on the self-purification (assimilative) capacity of the receiving water. However, this self-purification constant is itself a function of the water's pollutant loading. Umguza River situated south west of Zimbabwe, is fed by tributaries that drain an urban catchment and as such is prone to pollution due to human activities in the catchment. This study investigated the levels of pollution in Umguza River that would affect its self-purification capacity. This was achieved by characterising the spatial distribution of a selected range of water quality parameters as well as determining the self-purification capacity of a stretch of the river. Critical pollutant concentrations were determined for some of the parameters that showed high values along the stretch. The selected parameters of interest were dissolved oxygen, suspended solids, phosphates, nitrates, COD, turbidity, ammonia, pH, alkalinity and temperature. The study was carried out from January 2014 to April 2014. The self-purification capacity was determined using a formula that compares the mass flux of a pollutant upstream and downstream of the selected stretch of the river. Statistical analysis was used to establish relationships between the pollutants and the self-purification capacity of the river. The study found that the levels of ammonia and phosphates were very high compared to the regulated limits (2 mg/l vs 0.5 mg/l; and 8 mg/l vs 0.5 mg/l respectively). It was also found that the self-purification capacity varied significantly across pollutants. It was therefore concluded that a critical pollutant concentration exists above which the river completely loses its natural ability to assimilate and decrease its pollutant load over time. It was also concluded that the self-purification capacity depends on the pollutant of concern in the river. It is recommended that the self-purification capacity of a river be determined before regulatory bodies set effluent discharge limits. It is also recommended that the water quality of water bodies draining pollution prone catchments be monitored regularly, besides just monitoring the discharge points.  相似文献   

9.
《Marine pollution bulletin》2014,87(1-2):575-581
Plastic resin pellets collected at 11 beaches covering the whole Ghanaian coastline were analyzed for polychlorinated biphenyls (PCBs). PCB concentrations (∑13 congeners) were higher in Accra, capital city, and Tema (39–69 ng/g-pellets) than those in rural coastal towns (1–15 ng/g-pellets) which are close to global background, indicating local inputs of PCBs. River sediments were also analyzed for PCBs together with molecular markers. Sedimentary PCBs concentrations were highest at a site (AR02) downstream of an electronic waste (e-waste) scrapyard. At the site (AR02), concentration of linear alkylbenzenes (LABs), a marker of municipal wastewater, was lower than another site (AR03) which is located at the downstream of downtown Accra. This result suggests that PCBs are introduced more to the river from the e-waste site than from activities in downtown Accra. PAHs concentrations were relatively higher in urban areas with strong petrogenic signature. Abundance of triphenylbenzenes suggested plastic combustion near e-waste scrapyard.  相似文献   

10.
Seven longitudinal water temperature tow surveys were conducted to attempt to identify the location of surface and subsurface river water exchanges along the length of the West River at the Cape Bounty Arctic Watershed Observatory, Melville Island, Nunavut, Canada (74°55′ N, 109°35′ W). Water temperature data were collected using a calibrated thermistor with an accuracy of ±0.002 °C (resolution <0.00005 °C) along the river during July 2014 in conjunction with stable water isotope sampling to support the thermal data and to determine the extent of surface water mixing from different sources such as precipitation, snowmelt, and surface/subsurface water contributions to the river. Atmospheric conditions were found to be the main contributor to seasonal temperature variance in the river, whereas tributary inflows and residual channel snow also had important thermal effects to river temperatures. Residual channel snow was a sustained source of cold water during much of the 2014 summer season (June–August) and substantially offset downstream warming. The longitudinal temperature profiles indicate notable changes to the thermal state of the river, which are interpreted to be indicative of subsurface and surface water exchange through inputs of relatively cold or warm water. Broadly, surface inflows were found to provide warmer water relative to the West River, and contributed to downstream warming of the river, along with downstream enrichment of δD and δ18O. Subsurface inflows provided cooler water relative to the river, and contributed to downstream depletion of δD and δ18O and downstream cooling of river temperatures. These results demonstrate that localized changes in river temperature, in conjunction with isotopic tracers, can be used to track channel–slope water interactions in Arctic hydrological systems, work previously limited to alpine and temperate settings.  相似文献   

11.
The Cetina River is a typical karst watercourse in the deep and well‐developed Dinaric karst. The total length of the Cetina River open streamflow from its spring to the mouth is about 105 km. Estimated mean annual rainfall is 1380 mm. The Cetina catchment is built of Triassic, Jurassic, and Cretaceous carbonate strata. The western part of the catchment by the Cetina River is referred to as the ‘direct’ or topographic catchment. It was defined based on surface morphologic forms, by connection between mountain chain peaks. This part of the catchment is almost entirely situated in the Republic of Croatia. The eastern part of the catchment is referred to as the ‘indirect’ catchment, and is mainly situated in Bosnia‐Herzegovina. Water from the ‘indirect’ catchment emerges from the western ‘direct’ catchment in numerous permanent and temporary karst springs. Since 1960, numerous hydrotechnical works have been carried out on the Cetina River and within its catchment. Five hydroelectric power plants (HEPPs), five reservoirs, and three long tunnels and pipelines have been built. Their operation has significantly altered the natural hydrological regime. The Cetina River is divided into two hydrological reaches. In the 65 km upstream, the hydrological regime was redistributed within the year: low flows had increased and high flows had decreased, although the mean annual discharge remained the same. Part of the Cetina watercourse downstream from the Pran?evi?i Reservoir lost the majority of its flow. The mean annual discharges dropped from 100 m3 s?1 to less than 10 m3 s?1 because of the Zaku?ac HEPP development. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

12.
Upland agricultural land management activities such as grazing, vegetation burning, and bare ground restoration impact hydrological elements of headwater catchments, many of which may be important for downstream flood peaks (e.g., overland flow and soil water storage). However, there is poor understanding of how these management practices affect river flow peaks during high magnitude rainfall events. Using the distributed TOPMODEL, spatial configurations of land management were modelled to predict flood response in an upland catchment, which contains different regions operating subsidized agricultural stewardship schemes. Heavy grazing leading to soil compaction and loss of vegetation cover in stewardship regions covering 79.8% of the catchment gave a 42‐min earlier flow peak, which was 82.2% higher (under a 1‐hr 15‐mm storm) than the current simulated hydrograph. Light grazing over the same regions of the catchment had much less influence on river flow peaks (18 min earlier and 32.9% increase). Rotational burning (covering 8.8% of the catchment), most of which is located in the headwater areas, increased the peak by 3.2% in the same rainfall event. Vegetation restoration with either Eriophorum or Sphagnum (higher density) in bare areas (5.8%) of the catchment provided a reduction of flood peak (3.9% and 5.2% in the 15‐mm storm event), whereas the same total area revegetated with Sphagnum in riparian regions delivered a much larger decrease (15.0%) in river flow peaks. We show that changes of vegetation cover in highly sensitive areas (e.g., near‐stream zones) generate large impacts on flood peaks. Thus, it is possible to design spatially distributed management systems for upland catchments, which reduce flood peaks while at the same time ensuring economic viability for upland farmers.  相似文献   

13.
Sediment balances in the Blue Nile River Basin   总被引：2，自引：1，他引：1  
Rapid population growth in the upper Blue Nile basin has led to fast land-use changes from natural forest to agricultural land.This resulted in speeding up the soil erosion process in the highlands and increasing sedimentation further downstream in reservoirs and irrigation canals.At present,several dams are planned across the Blue Nile River in Ethiopia and the Grand Ethiopian Renaissance Dam is currently under construction near the border with Sudan.This will be the largest hydroelectric power plant in Africa.The objective of this paper is to quantify the river flows and sediment loads along the Blue Nile River network.The Soil and Water Assessment Tool was used to estimate the water flows from un-gauged sub-basins.To assess model performance,the estimated sediment loads were compared to the measured ones at selected locations.For the gauged sub-basins,water flows and sediment loads were derived from the available flow and sediment data.To fill in knowledge gaps,this study included a field survey in which new data on suspended solids and flow discharge were collected along the Blue Nile and on a number of tributaries.The comparison between the results of this study and previous estimates of the sediment load of the Blue Nile River at El Deim,near the Ethiopian Sudanese border,show that the sediment budgets have the right order of magnitude,although some uncertainties remain.This gives confidence in the results of this study providing the first sediment balance of the entire Blue Nile catchment at the sub-basin scale.  相似文献   

14.
冉蛟  肖克彦  向蓉  郑丙辉 《湖泊科学》2023,35(6):1960-1969
邛海是云贵高原水域面积>25 km2的11个天然湖泊之一。基于邛海入湖河流与湖区水质监测数据,揭示入湖河流水质特征,并探究其湖区响应。结果表明:2021年,邛海入湖河流水质空间异质性显著,且分为自然型、农业型和城镇型3种类型河流。官坝河等3条自然型河流水质优良,而高仓河等8条城镇型和农业型河流(R4～R11)水质较差,污染物浓度超标严重。2011—2021年,邛海主要入湖河流(官坝河、鹅掌河、小青河)的营养盐浓度呈下降或先增加后下降趋势,水质逐渐改善。流域土地利用变化是导致邛海入湖河流水质空间异质性的主要因素,同时也是河流水质在2011—2021年改善的原因之一。受湖泊水文环境与入湖河流污染类型影响,2017—2021年邛海湖区水环境及其与河流水质响应关系差异性明显:高枧湾水域(L5)水深浅、水环境容量小,主要受纳城镇污水,因而湖区营养盐与叶绿素a浓度高,在2021年达富营养状态;官坝河、鹅掌河与小青河入湖影响区(L1～L3)与小渔村(L4)水域湖水深、水环境容量大,污染物浓度与营养状态指数低,但因汇入的河流污染类型不同,湖区营养水平与河流水质响应存在季节性...  相似文献   

15.
In this paper, we present a methodology to construct a sediment budget for meso‐scale catchments. We combine extensive field surveys and expert knowledge of the catchment with a sediment delivery model. The meso‐scale Mediterranean drainage basin of the Dragonja (91 km2), southwest Slovenia, was chosen as case study area. During the field surveys, sheet wash was observed on sloping agricultural fields during numerous rainfall events, which was found to be the main source of sediment. With the sediment yield model WATEM/SEDEM the estimated net erosion on the hillslopes 4·1 t ha–1 y–1 (91% of inputs). The second source, bank erosion (4·2%; 0·25 t ha–1 y–1) was monitored during several years with erosion pins and photogrammetric techniques. The last source, channel incision, was derived from geomorphological mapping and lichenomery and provided 3·8% (0·17 t ha–1 y–1) of the sediment input. The river transports its suspended sediment mainly during high‐flow events (sampled with automated water samplers). About 27% (1·2 t ha–1 y–1) of the sediment delivered to the channel is deposited on floodplains and low terraces downstream (estimated with geomorphological mapping, coring and cesium‐137 measurements). The sediment transported as bedload disintegrates during transport to the outlet due to the softness of the bedrock material. As a result, the river carries no bedload when it reaches the sea. The results imply a build‐up of sediment in the valleys catchment. However, extreme flood events may flush large amounts of sediment stored in the lower parts of the system. Geomorphological evidence exists in the catchment that such high magnitude, low frequency events have happened in the past. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

16.
OSL (optically stimulated luminescence) sensitivity of quartz has been shown to either (1) record downstream sediment transport related to increased number and duration of light exposure cycles or (2) be a function of source geology, presenting a potential tool to track sediment provenance. To test these competing models this study leverages a suite of modern river samples from an extensional basin system in the Rocky Mountains of western USA (Bear River) and a retroarc foreland basin system in the southern Central Andes of Argentina (Río San Juan) to understand the relationships among quartz luminescence sensitivity, sediment transport distance, and catchment lithologies. We compare our results with petrographic analysis of the river sand composition, and characterization of the lithology and morphometrics of the river catchments. Samples taken along the Bear River and its major tributaries in the Rocky Mountains show a progressive downstream decrease in quartz OSL sensitivity that records variation in sediment provenance and steady contribution of lower OSL sensitivity quartz recycled from Palaeozoic passive margin stratigraphy. Andean river sand samples from the Rio San Juan network exhibit pervasive low sensitivity quartz derived from Andean arc volcanic rocks and recycled Neogene foreland basin strata. These modern river sand data do not show increased sensitivity with transport distance and instead indicates that in these landscapes, quartz OSL sensitivity is an intrinsic property of the source rock. Our study shows that river sands primarily composed of older, recycled low-strained quartz derived from quartzite lithologies exhibit the highest quartz sensitivity values. Moderate quartz OSL sensitivity values are observed in rivers with young igneous quartz derived directly from the volcanic and intrusive rocks. Conversely, microcrystalline quartz in chert lithic grains or polycrystalline quartz found in composite metamorphic lithic grains record the lowest quartz OSL sensitivity values. Determining the controlling factors of quartz sensitivity in river sand provides a current baseline for resolving paleogeographic and paleodrainage histories in the sedimentary record and provides further understanding of how sediments are eroded, transported, and deposited in fluvial systems with diverse tectonic settings and geologic source rocks.  相似文献   

17.
Natural ecosystems in the region of the lower Tarim River in northwestern China strongly deteriorated since the 1950s due to an expanding desertification. As a result, the downstream Tarim River reaches became permanently dry land. This historical evolution in land‐use change is typically the result of the anthropogenic impact on natural ecosystems. On the basis of a spatially distributed hydrological catchment model bidirectionally linked with a fully hydrodynamic MIKE11 river model, land‐use changes characterized by historical changes in leaf area index (LAI) of vegetation, as well as the evolution of irrigated surface areas, can be causally related to changes in water resources (groundwater storage and surface water resources). An increased surface area of irrigated (agricultural) land, together with a majority of inefficient irrigation methods, did lead to a strong increase of water resources consumption of the farmlands located in the upper Tarim River area. Evidently, this evolution influenced available water resources downstream in the Tarim basin. As a result, farmland has been gradually relocated to the upstream regions. This has led to reduced flows from the upper Tarim stream, which subsequently accelerated the dropping of the groundwater level downstream in the basin. This study moreover demonstrates that land surface biomass changes (cumulative LAI) along the lower Tarim River are strongly related to the changes in groundwater storage. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

18.
River discharge in mountainous regions of the world is often dominated by snowmelt, but base flows are sustained primarily by groundwater storage and discharge. Although numerous recent studies have focused on base-flow discharge in mountain systems, almost no work has explicitly investigated the role of karst groundwater in these systems across a full range of flow conditions. We directly measured groundwater discharge from 48 karst springs in the Kaweah River and its five forks in the Sierra Nevada mountains, California, United States. Relationships between spring and river discharge showed that karst aquifers and springs provide significant storage and delayed discharge to the river. Regression models showed that, of all potential seasonal groundwater storage compartments in the river basin, the area of karst (0.1–4.4%) present provides the best explanation of base-flow recession in each fork of the Kaweah River (directly measured contributions from karst springs ranged from 3.5 to 16% during high-flow to 20 to 65% during base-flow conditions). These results show that, even in settings where karst represents a small portion of basin area, it may play an over-sized role in seasonal storage and water resources in mountain systems. Karst aquifers are the single most important non-snow storage component in the Kaweah River basin, and likely provide similar water storage capacities and higher base flows in other mountain river systems with karst when compared with systems without karst.  相似文献   

19.
Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

20.
Diffuse sediment pollution impairs water quality, exerts a key control on the transfer and fate of nutrients and contaminants and causes deleterious impacts on freshwater ecology. A variety of catchment sediment sources can contribute to such problems. Sediment control strategies and effective targeting of mitigation options therefore require robust quantitative information on the key sources of the sediment problem at catchment scale. Recent observations by Catchment Sensitive Farming Officers (CSFO's) in England have highlighted road verges damaged and eroded by passing vehicles, particularly large farm machinery, and livestock herd movement as visually important potential sources of local sediment problems. A study was therefore undertaken to assess the relative importance of damaged road verges as a suspended sediment source in three sub‐catchments of the Hampshire Avon drainage basin, southern UK. Road verge sediment contributions were apportioned in conjunction with those from agricultural topsoils and channel banks/subsurface sources. Time‐integrating isokinetic samplers were deployed to sample suspended sediment fluxes at the outlets of two control sub‐catchments drained by the Rivers Chitterne and Till selected to characterize areas with a low road network density and limited visual evidence of verge damage, as well as the River Sem sub‐catchment used to represent areas where road verge damage is more prevalent. The findings of a sediment source fingerprinting investigation based on a combination of intermittent sampling campaigns spanning the period 22/5/02–27/4/08 suggested that the respective overall mean relative sediment contributions from damaged road verges were 5 ± 3%, 4 ± 2% and 20 ± 2%. Relative inputs from damaged road verges for any specific sampling period in the River Sem sub‐catchment were as high as 33 ± 2%. Reconstruction of historical sources in the same sub‐catchment, based on the geochemical record stored in a floodplain depth profile, suggested that the significance of damaged road verges as a sediment source has increased over the past 15–20 years. The findings provide important information on damaged road verges as a primary source of suspended sediment and imply that catchment sediment control strategies and mitigation plans should consider such verges in addition to those agricultural and channel sources traditionally taken into account when attempting to reduce sediment pressures on aquatic resources. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

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