Insights into agricultural influences and weathering processes from major ion patterns          下载免费PDF全文

Robert van Geldern  Peter Schulte  Michael Mader  Alfons Baier  Johannes A.C. Barth  Tobias R. Juhlke  Kern Lee 《水文研究》2018,32(7):891-903

Karst areas and their catchments pose a great challenge for protection because fast conduit flow results in low natural attenuation of anthropogenic contaminants. Studies of the hydrochemistry of karst sources and river solutes are an important tool for securing and managing water resources. A study of the geochemical downriver evolution of the Wiesent River and its tributaries, located in a typical karst terrain, revealed unexpected downstream decreases of nitrate with maximum mean values of 30 mg/L at the source to minimum values of 18 mg/L near the river mouth. This trend persisted over the length of the river even though increased agricultural activities are evident in the downstream section of the catchment. This pattern is caused by fertilizer inputs via diffusive and fast conduits flow from karst lithology in the upstream area that may have reached the river's source even from beyond the hydrological catchment boundaries. Further downstream, these influences became diluted by tributary inputs that drain subcatchments dominated by claystone and sandstone lithologies that increased potassium and sulphate concentrations. Our findings indicate that bedrock geology remains the dominant control on the major ion chemistry of the Wiesent River and that agricultural influences are strongest near the headwaters despite increased land use further downstream, due to long‐term storage and accumulation in karst aquifers. This feature may not be unique to the Wiesent River system, as carbonates cover significant portions of the Earth's surface and subsequent work in other river systems could establish whether such patterns are ubiquitous worldwide.  相似文献   

3-D assessment of peak-metamorphic conditions by Raman spectroscopy of carbonaceous material: an example from the margin of the Lepontine dome (Swiss Central Alps)   总被引：2，自引：0，他引：2  

Michael Wiederkehr  Romain Bousquet  Martin A. Ziemann  Alfons Berger  Stefan M. Schmid 《International Journal of Earth Sciences》2011,100(5):1029-1063

This study monitors regional changes in the crystallinity of carbonaceous matter (CM) by applying Micro-Raman spectroscopy to a total of 214 metasediment samples (largely so-called Bündnerschiefer) dominantly metamorphosed under blueschist- to amphibolite-facies conditions. They were collected within the northeastern margin of the Lepontine dome and easterly adjacent areas of the Swiss Central Alps. Three-dimensional mapping of isotemperature contours in map and profile views shows that the isotemperature contours associated with the Miocene Barrow-type Lepontine metamorphic event cut across refolded nappe contacts, both along and across strike within the northeastern margin of the Lepontine dome and adjacent areas. Further to the northeast, the isotemperature contours reflect temperatures reached during the Late Eocene subduction-related blueschist-facies event and/or during subsequent near-isothermal decompression; these contours appear folded by younger, large-scale post-nappe-stacking folds. A substantial jump in the recorded maximum temperatures across the tectonic contact between the frontal Adula nappe complex and surrounding metasediments indicates that this contact accommodated differential tectonic movement of the Adula nappe with respect to the enveloping Bündnerschiefer after maximum temperatures were reached within the northern Adula nappe, i.e. after Late Eocene time.  相似文献   

Kinematics and significance of a poly-deformed crustal-scale shear zone in central to south-eastern Madagascar: the Itremo–Ikalamavony thrust     

Giese  Jörg  Schreurs  Guido  Berger  Alfons  Herwegh  Marco 《International Journal of Earth Sciences》2017,106(6):2091-2108

International Journal of Earth Sciences - Across the crystalline basement of Madagascar, late Archaean rocks of the Antananarivo Block are tectonically overlain by Proterozoic, predominantly...  相似文献   

Late Quaternary history of the Vakinankaratra volcanic field (central Madagascar): insights from luminescence dating of phreatomagmatic eruption deposits     

Daniel Rufer  Frank Preusser  Guido Schreurs  Edwin Gnos  Alfons Berger 《Bulletin of Volcanology》2014,76(5):1-20

The Quaternary Vakinankaratra volcanic field in the central Madagascar highlands consists of scoria cones, lava flows, tuff rings, and maars. These volcanic landforms are the result of processes triggered by intracontinental rifting and overlie Precambrian basement or Neogene volcanic rocks. Infrared-stimulated luminescence (IRSL) dating was applied to 13 samples taken from phreatomagmatic eruption deposits in the Antsirabe–Betafo region with the aim of constraining the chronology of the volcanic activity. Establishing such a chronology is important for evaluating volcanic hazards in this densely populated area. Stratigraphic correlations of eruption deposits and IRSL ages suggest at least five phreatomagmatic eruption events in Late Pleistocene times. In the Lake Andraikiba region, two such eruption layers can be clearly distinguished. The older one yields ages between 109?±?15 and 90?±?11 ka and is possibly related to an eruption at the Amboniloha volcanic complex to the north. The younger one gives ages between 58?±?4 and 47?±?7 ka and is clearly related to the phreatomagmatic eruption that formed Lake Andraikiba. IRSL ages of a similar eruption deposit directly overlying basement laterite in the vicinity of the Fizinana and Ampasamihaiky volcanic complexes yield coherent ages of 68?±?7 and 65?±?8 ka. These ages provide the upper age limit for the subsequently developed Iavoko, Antsifotra, and Fizinana scoria cones and their associated lava flows. Two phreatomagmatic deposits, identified near Lake Tritrivakely, yield the youngest IRSL ages in the region, with respective ages of 32?±?3 and 19?±?2 ka. The reported K-feldspar IRSL ages are the first recorded numerical ages of phreatomagmatic eruption deposits in Madagascar, and our results confirm the huge potential of this dating approach for reconstructing the volcanic activity of Late Pleistocene to Holocene volcanic provinces.  相似文献   

Adaptive growth reduction in response to fish kairomones allows mosquito larvae (Culex pipiens) to reduce predation risk     

Jonas Jourdan  Jasmin Baier  Rüdiger Riesch  Sven Klimpel  Bruno Streit  Ruth Müller  Martin Plath 《Aquatic Sciences - Research Across Boundaries》2016,78(2):303-314

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On the consequences of a long-term perspective for coastal management     

Erik M. Horstman  Kathelijne M. Wijnberg  Alfons J. Smale  Suzanne J.M.H. Hulscher 《Ocean & Coastal Management》2009,52(12):593-611

The potential impacts of climate change on coastal zones combined with the ever increasing number of people living in these areas, motivate a more long-term perspective in coastal management. To explore whether such a perspective raises the need for developing coastal management strategies at larger spatial scales, this paper presents a case study for the dune-protected Holland coast. Long-term (200 years) coastal management strategies are set-up at different levels of spatial aggregation, accounting for specific characteristics of the coast itself and for types of land use in the hinterland. Using a combination of multi-criteria analysis and cost-benefit analysis the new coastal management strategies are compared to the long-term continuation of present coastal management practice. It appears that the large uncertainties that inevitably accompany a long-term perspective do not preclude the comparison of long-term coastal management strategies. Additionally, it appears that a long-term perspective favors solutions for coastal defense enhancement that are more spatially extended and alongshore uniform than those emerging from continuing today's coastal management practice for two centuries.  相似文献   

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta     

Kim Vermonden  Marion A. A. Hermus  Marije van Weperen  Rob S. E. W. Leuven  Gerard van der Velde  Alfons J. P. Smolders  Jan G. M. Roelofs  A. Jan Hendriks 《水文研究》2009,23(21):3110-3120

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Mineralisation of amethyst-bearing geodes in Ametista do Sul (Brazil) from low-temperature sedimentary brines: evidence from monophase liquid inclusions and stable isotopes     

H. Albert Gilg  Yves Krüger  Heinrich Taubald  Alfons M. van den Kerkhof  Martin Frenz  Giulio Morteani 《Mineralium Deposita》2014,49(7):861-877

Fluid inclusion studies in combination with hydrogen, oxygen and sulphur isotope data provide novel insights into the genesis of giant amethyst-bearing geodes in Early Cretaceous Paraná continental flood basalts at Amestita do Sul, Brazil. Monophase liquid inclusions in colourless quartz, amethyst, calcite, barite and gypsum were analysed by microthermometry after stimulating bubble nucleation using single femtosecond laser pulses. The salinity of the fluid inclusions was determined from ice-melting temperatures and a combination of prograde and retrograde homogenisation temperatures via the density maximum of the aqueous solutions. Four mineralisation stages are distinguished. In stage I, celadonite, chalcedony and pyrite formed under reducing conditions in a thermally stable environment. Low δ³⁴S_V-CDT values of pyrite (?25 to ?32?‰) suggest biogenic sulphate reduction by organotrophic bacteria. During the subsequent stages II (amethyst, goethite and anhydrite), III (early subhedral calcite) and IV (barite, late subhedral calcite and gypsum), the oxidation state of the fluid changed towards more oxidising conditions and microbial sulphate reduction ceased. Three distinct modes of fluid salinities around 5.3, 3.4 and 0.3 wt% NaCl-equivalent characterise the mineralisation stages II, III and IV, respectively. The salinity of the stage I fluid is unknown due to lack of fluid inclusions. Variation in homogenisation temperatures and in δ¹⁸O values of amethyst show evidence of repeated pulses of ascending hydrothermal fluids of up to 80–90 °C infiltrating a basaltic host rock of less than 45 °C. Colourless quartz and amethyst formed at temperatures between 40 and 80 °C, while the different calcite generations and late gypsum precipitated at temperatures below 45 °C. Calculated oxygen isotope composition of the amethyst-precipitating fluid in combination with δD values of amethyst-hosted fluid inclusions (?59 to ?51?‰) show a significant ¹⁸O-shift from the meteoric water line. This ¹⁸O-shift, high salinities of the fluid inclusions with chloride-sulphate composition, and high δ³⁴S values of anhydrite and barite (7.5 to 9.9?‰) suggest that sedimentary brines from deeper parts of the Guaraní aquifer system must have been responsible for the amethyst mineralisation.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987114000395     

Alfons van den Kerkhof  Andreas Kronz  Klaus Simon 《地学前缘(英文版)》2014,5(5):683-695

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.  相似文献   

Interannual and decadal variability in zooplankton communities of the southeast Bering Sea shelf     

Jeffrey M. Napp  Christine T. Baier  Richard D. Brodeur  Kenneth O. Coyle  Naonobu Shiga  Kathy Mier 《Deep Sea Research Part II: Topical Studies in Oceanography》2002,49(26)

The southeastern Bering Sea shelf ecosystem is an important fishing ground for fin- and shellfish, and is the summer foraging grounds for many planktivorous seabirds and marine mammals. In 1997 and 1998, Northern Hemisphere climate anomalies affected the physical and biological environment of the southeastern Bering Sea shelf. The resulting anomalous conditions provided a valuable opportunity to examine how longer-term climate change might affect this productive ecosystem. We compared historical and recent zooplankton biomass and species composition data for the southeastern Bering Sea shelf to examine whether or not there was a response to the atmosphere–ocean–ice anomalies of 1997 and 1998. Summer zooplankton biomass (1954–1994) over the southeastern shelf did not exhibit a decline as previously reported for oceanic stations. In addition, zooplankton biomass in 1997 and 1998 was not appreciably different from other years in the time series. Spring concentrations of numerically abundant copepods (Acartia spp., Calanus marshallae, and Pseudocalanus spp.), however, were significantly higher during 1994–1998 than 1980–1981; spring concentrations of Metridia pacifica and Neocalanus spp. were not consistently different between the two time periods. Neocalanus spp. was the only taxon to have consistent differences in stage composition between the two time periods—CV copepodites were much more prevalent in May of the 1990s than early 1980s. Since relatively high zooplankton concentrations were observed prior to 1997, we do not attribute the high concentrations observed in the summers of 1997 and 1998 directly to the acute climate anomalies. With the present data it is not possible to distinguish between increased production (control from below) and decreased predation (control from above) to explain the recent increase in concentrations of the species examined.  相似文献