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1.
Based on the study of Beijing PM10 bioreactivity with the newly developed plasmid DNA assay method, and analysis for trace elements of PM10, the cause of plasmid DNA damage by PM10 was investigated. The study showed that plasmid DNA oxidative damages by PM10 are of difference in different seasons at various areas. The concentrations of TM50 of PM10 in whole samples respectively collected at urban and comparison sites during winter were 900 μg mL−1 and 74 μg mL−1, while those in their corresponding soluble fractions were 540 μg mL−1 and 86 μg mL−1. In contrast, TM50 contents of PM10 from summer whole samples at urban areas and comparison sites were 116 μg mL−1 and 210 μg mL−1, whereas those in their soluble fractions were 180 μg mL−1 and 306 μg mL−1. The difference of bioreactivity of Beijing PM10 resulted from the variation of trace elements. The oxidative damage of plasmid DNA caused by Pb, Zn, As in PM10 (whole sample) was relatively strong. TM50 and Mn, V, Zn display stronger correlation in the soluble fraction. It implies that Zn could be the major trace element in Beijing PM10 which contributes to oxidative damage to plasmid DNA.  相似文献   

2.
The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions.  相似文献   

3.
Trace metal clean sampling and analysis techniques were used to examine the temporal patterns of Hg, Cu, and Zn concentrations in shallow ground water, and the relationships between metal concentrations in ground water and in a hydrologically connected river. Hg, Cu, and Zn concentrations in ground water ranged from 0.07 to 4.6 ng L−1, 0.07 to 3.10 μg L−1, and 0.17 to 2.18 μg L−1, respectively. There was no apparent seasonal pattern in any of the metal concentrations. Filtrable Hg, Cu, and Zn concentrations in the North Branch of the Milwaukee River ranged from below the detection limit to 2.65 ng Hg L−1,0.51 to 4.30 μg Cu L−1, and 0.34 to 2.33 μg Zn L−1. Thus, metal concentrations in ground water were sufficiently high to account for a substantial fraction of the filtrable trace metal concentration in the river. Metal concentrations in the soil ranged from 8 to 86 ng Hg g−1, 10 to 39 μg Cu g−1, and 15 to 84 μg Zn g−1. Distribution coefficients, KD, in the aquifer were 7900,22,000, and 23,000 L kg−1 for Hg, Cu, and Zn, respectively. These values were three to 40 times smaller than KD values observed in the Milwaukee River for suspended particulate matter.  相似文献   

4.
The concentration and areal distribution of selected trace metals (Cu, Zn, Pb, Cd, Mo, Ni, Mn and Hg) in surficial sediments of Saint John Harbour, New Brunswick, Canada, were studied to determine the extent of anthropogenic input and to estimate the effects of dumping dredged material in the outer harbour. Hg and Cd are of especial concern, since the disposal of dredge material containing these two elements is regulated under the Ocean Dumping Control Act.The concentrations of all metals are low: Cu 16, Zn 53, Pb 24, Cd 0.16, Mo 3, Ni 16, Mn 296 and Hg 0.04 μg g?1. Hg and Cd levels in sediments are well below the permissible limits of 0.75 and 0.6 μg g?1, respectively, set by the Ocean Dumping Control Act.The mean concentrations of trace elements are similar to the low mean values in the unpolluted Bay of Fundy. There is an overall decline in concentrations of metals in the sediments from the inner to the outer harbour. Comparison of the metal levels in the sediments from different areas within the harbour indicate that there is a detectable anthropogenic input in the Courtenay Bay area. Trace metal levels at the dumpsite are significantly lower than in the Courtenay Bay area, where the bulk of the dredged material originates.  相似文献   

5.
Mineralogy and geochemistry of the four main workable coal seams (No.6, No.7, No.8, and No.11) of Late Permian age from the Songzao Coalfield, Chongqing, Southwest China, were examined using in- ductively coupled plasma-mass spectrometry (ICP-MS), X-ray fluorescence spectrometry (XRF), cold-vapor absorption spectrometry (CV-AAS), ion-selective electrode (ISE), scanning electron mi- croscopy equipped with an energy-dispersive X-ray spectrometer (SEM-EDX), and X-ray diffraction analysis (XRD). The results showed that the main workable No.8 Coal that accounts for about 60% of the total coal reserves in the Songzao Coalfield was not enriched in hazardous trace elements. The No.11 Coal has high concentrations of alkaline elements, Be (9.14 μg/g), Sc (12.9 μg/g), Ti (9508 μg/g), Mn (397 μg/g), Co (23.7 μg/g), Cu (108 μg/g), Zn (123 μg/g), Ga (32 μg/g), Zr (1304 μg/g), Nb (169 μg/g), Hf (32.7 μg/g), Ta (11.4 μg/g), W (24.8 μg/g), Hg (0.28 μg/g), Pb (28.1 μg/g), Th (24.1 μg/g), and rare earth elements (509.62 μg/g). The concentration of Nb and Ta in the No. 11 Coal is higher than the industrial grade, and their potential utilization should be further studied. Besides pyrite, quartz, calcite, and clay minerals, trace minerals including chalcopyrite, marcasite, siderite, albite, mixed-layer clay minerals of illite and smectite, monazite, apatite, anatase, chlorite, and gypsum were found in the No.11 Coal. It should be noted that alabandite of hydrothermal origin and anatase occurring as cement were identi- fied in coal. In addition, the clayey microbands derived from alkaline volcanic ashes were identified in the coal. The dominant compositions of these clayey microbands were mixed-layer clay minerals of illite and smectite, which were interlayered with organic bands. The modes of occurrence of alkaline volcanic ash bands indicate that the volcanic activities were characterized by the multiple eruptions, short time interval and small scale for each eruption during peat accumulation. The alkaline volcanic ashes were the dominant factors for the enrichment of alkaline elements, Nb, Ta, Zr, Hf, and rare earth elements, and the sulfide minerals are the main carriers of Ga, Cu, and Hg in the No. 11 Coal.  相似文献   

6.
城市布局规模与大气环境影响的数值研究   总被引：8，自引：0，他引：8       下载免费PDF全文
为探索城市建设对局地及周边大气环境的影响,本文采用典型代表性天气条件,以北京主城区及其东部发展带小城镇群的发展变化为例,设计算例进行数值模拟.分析结果表明：城镇群建设发展通过地气的相互作用对局地环境产生显著影响,在本文选择的夏日晴好天气条件下,就1980～2004年城市区域布局状况,模拟域内北京城市用地增加19%,城市区域平均气温增加1.91℃,植被覆盖率减少20%,城市区域平均比湿减少3.3 g·kg-1,并且城市发展的格局规模不同,对城市气象环境的影响程度也不同. 此外,由于地气多因子的相互影响和反馈作用,城建规模的变化对周边的环境也存在显著的影响,城建规模越大,对周边的影响越大．例如, (1) 北京主城区的存在对周边小城镇午间14:00近地面温度影响最大可达到1.2℃,混合层高度可增高150 m左右; (2) 城市建设在影响周边气象环境的同时,也改变了城市污染物的输送扩散能力,北京主城区的存在使周边小城镇PM10的允许排放总量减小18.02 t·d-1,同时,随着周边小城镇城市规模的扩大,影响主城区PM10逐渐由净的输出转变为净的收入,小城镇群的存在对主城区PM10净收支的贡献率达到0.192 t·d-1.  相似文献   

7.
The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.  相似文献   

8.
The concentration levels of Cd (25 ng l?1), Cu (0.45 μg l?1), Ni (0.48 μg l?1), Fe (0.2–7.0 μg l?1), Pb (40 ng l?1) and Zn (0.80 μg l?1) have been determined in the Danish Sounds and in the Kattegat. Different sampling techniques have been used and analyses have been carried out separately by two different investigators, both using freon-extraction followed by determination by atomic absorption spectrometry (a.a.s.). Except for iron, found mainly in the particulate phase, the metals are found predominantly in a dissolved and labile (extractable) form. The results are compared with trace metal levels found in the two main water masses entering the Kattegat—the North Sea and the Baltic Sea.  相似文献   

9.
Instrumental neutron activation analysis was used for the determination of more than 20 trace and minor elements in water and silt samples (suspended load) of the river Aare. The samples were collected at four different locations along the river between its source and the lake of Bienne. The principal results are: 1. The concentrations of all elements investigated are much lower than WHO-limits for drinking water. 2. Human activities are responsible for an increase of some elements along the river. 3. The concentrations of dissolved trace elements are generally anticorrelated with the water flow rate. 4. The concentrations of the trace elements in particulates (in μg/l) are correlated with the flow rate of water. Except for Ca?Sr there are no significant interelement correlations for all four sampling stations.  相似文献   

10.
Measurement results of PM10 (particulate matter with diameters below 10 μm) concentrations performed at four stations in central Poland (2007–2010) were analyzed in terms of levels and distributions of concentrations, the number of exceedances of the limit values and the causes of these exceedances. PM10 levels were similar at suburban and rural stations, except of one station located in the vicinity of a busy street. The median of PM10 concentration ranged from 26 μg/m3 at suburban station to 44 μg/m3 at Warsaw Kerb station. Seasonal variability analysis of PM10 concentration revealed an additional maximum beyond the usual autumn-winter one. This maximum occurred in April at all stations, and corresponded to seasonal wildfires activity and dust activation in Eastern Europe. Cluster analysis of back-trajectories revealed that PM10 concentrations depend on the direction of advection of the incoming air; the highest values are registered for air of regional and southern origins, while the lowest are for the airmasses coming from the north and northwest direction.  相似文献   

11.
The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.  相似文献   

12.
Glacial meltwater and sediment at the source of the River Rhône have been analyzed to determine: 1. the partitioning of Al, Cd, Co, Cu, Cr. Fe, Mn, Ni, Pb and Zn between the water and particulate phase. 2. the particle size ranges which affect the dissolved trace metal ion composition of the meltwater and 3. the availability (potential release) of the ten trace metal ions from the sediment. Greater than 80% of the total Cd, Cu, Mn, Ni and Zn were found to be in operationally-defined (0.4 μm) dissolved forms. Fe and Al in the meltwater are primarily associated with particles in the size range 0.4–8 μm, while Cd. Cu, Mn, Ni and Zn occur with particles smaller than 0.1 μm. For the sediment, Cu, Ni and Pb were significantly present as exchangeable forms; only Cu, Ni, Pb and Zn were determined as organicallybound forms.  相似文献   

13.

Satellite images are used extensively in studying the urban heat island (UHI) phenomenon. We evaluated the suitability of thermal infrared (TIR) data from the HJ-1B satellite for detecting UHI using a case study in Beijing. Two modified algorithms for retrieving the land surface temperature (LST) from HJ-1B data were tested. The results were compared with LST images derived from a Landsat TM thermal band and the MODIS LST output. The spatial pattern of UHI generated using HJ-1B data matched well with that produced using TM and MODIS data. Of the two algorithms, the mono-window algorithm performed better but further tests are necessary. With more frequent coverage than TM and higher spatial resolution than MODIS, the HJ-1B TIR data present a unique opportunity to study thermal environments in cities in China and neighboring countries.

  相似文献   

14.
Satellite images are used extensively in studying the urban heat island (UHI) phenomenon. We evaluated the suitability of thermal infrared (TIR) data from the HJ-1B satellite for detecting UHI using a case study in Beijing. Two modified algorithms for retrieving the land surface temperature (LST) from HJ-1B data were tested. The results were compared with LST images derived from a Landsat TM thermal band and the MODIS LST output. The spatial pattern of UHI generated using HJ-1B data matched well with that produced using TM and MODIS data. Of the two algorithms, the mono-window algorithm performed better but further tests are necessary. With more frequent coverage than TM and higher spatial resolution than MODIS, the HJ-1B TIR data present a unique opportunity to study thermal environments in cities in China and neighboring countries.  相似文献   

15.
Major hurricanes Emily and Wilma hit the Mexican Caribbean in 2005. Changes in trace metals in the seagrass Thalassiatestudinum prior to (May 2004, 2005) and following passage of these hurricanes (May, June 2006) were determined at four locations along a ∼130 km long stretch of coast. Before the hurricanes, essential metals were likely limiting and concentrations of potentially toxic Pb were high in a contaminated lagoon (27.5 μg g−1) and near submarine springs (6.10 μg g−1); the likely sources were inland sewage disposal or excessive boat traffic. After the hurricanes, Pb decreased to 2.0 μg g−1 in the contaminated lagoon probably through flushing. At the northern sites, essential Fe increased >2-fold (from 26.8 to 68.3 μg g−1 on average), possibly from remobilization of anoxic sediments or upwelling of deep seawater during Wilma. Thus, hurricanes can be beneficial to seagrass beds in flushing toxic metals and replenishing essential elements.  相似文献   

16.
Using wet digested method and ICP mass spectrometer, we analyzed the concentration of five trace elements (Cd, Mn, P, Zn and Pb) for the tree rings from both urban and suburbs of Xi’an. At the urban sampling site, one Chinese mahogany (Toona sinensis) disc and one phoenix tree (Firmiana simplex) disc were sampled from a steelworks in Xi’an City. At the suburb site, a Chinese mahogany disc was collected from a village in the south of the City. In addition, some soils near the roots of the sampled trees were ...  相似文献   

17.
Concentrations of 13 trace elements (V, Mn, Cr, Co, Cu, Zn, Se, Mo, Ag, Cd, Hg, Tl and Pb) were determined in muscle of bony fishes collected from coastal areas of the Caspian Sea (Kazakhstan, Azerbaijan, Turkmenistan and Iran). In all the fishes, Zn concentration was highest, followed by Cu, Se, Mn and Co, while levels of toxic elements (Ag, Cd, Cd, Tl and Pb) were relatively low. Concentrations of several elements were significantly varied between the species in each sampling area. For most of the trace elements examined, the concentrations decreased significantly with body weight of fishes. In contrast, a positive correlation with body weight was found for Co, Se and Pb concentrations in one fish species, and Hg in 2 fish species. Geographical difference in the concentrations of trace elements was examined using the Caspian roach collected from five stations of Iranian coastal waters. The concentrations of Co, Mo, Ag, Cd and Tl were higher in fishes from western stations than those from eastern stations, whereas the opposite trend was observed for Hg, indicating that local sources of trace metal pollution may be present in the Iranian coastal areas of the Caspian Sea. Levels of trace elements in Caspian fishes were relatively low in comparison to those of other regions, but Zn and Hg levels in some specimens exceeded the guideline values for food.  相似文献   

18.
Concentrations of heavy metals were determined in nearshore marine sediments and fish tissue from Sea Lots area on the west coast, at Caroni Lagoon National Park, and in the Point Lisas harbor, Trinidad. The most dominant metals found in sediments were Al, Fe and Zn with mean concentrations highest at Sea Lots (Al-39420 μg/g; Fe-45640 μg/g; Zn-245 μg/g), when compared to sediments from Point Lisas (Al-11936 μg/g; Fe-30171 μg/g; Zn-69 μg/g) and Caroni (Al-0400 μg/g; Fe-19000 μg/g; Zn-32 μg/g), High concentration of Cu, Al, Fe and Zn were also detected in fish tissue from Point Lisas and Caroni. Metal concentrations in fish tissue showed significant correlation with sediment metals concentration, which suggests that tissue levels are influenced by sediment concentration. Of the metals, only Zn, Hg and Cu had a bioaccumulation factor (BAF) greater than one, which suggests a high bioaccumulation potential for these metals.  相似文献   

19.
The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.  相似文献   

20.
Vertical profiles of dissolved and particulate Mn, Fe, Ni, Cu, Zn, Cd, Pb, and (234)Th were determined in the Hung-Tsai Trough off southwestern Taiwan during 19-23 November, 2004. Except in the case of Cd, the distribution coefficient (K(d)) of the trace elements showed a negative correlation with the suspended particle concentration. Based on the average K(d) values, the general sequence of particle affinities for the eight trace elements is, from highest to lowest, Fe>Mn≈Pb>Zn≈Th>Cd≈Cu≈Ni. The trace metal data was coupled with the particle removal flux estimated from (234)Th/(238)U disequilibrium to investigate metal removal by particle sinking from the euphotic layer. The residence time of trace elements with respect to particle removal from the euphotic layer was estimated. A negative correlation between the residence time and the distribution coefficient for the trace metals was found.  相似文献   

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