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1.
One of the more prominent architectural elements of the Nankai subduction margin, offshore southwest Japan, is an out‐of‐sequence thrust fault (megasplay) that separates the inner accretionary prism from the outer prism. The inner prism (hanging wall of the megasplay) is dominated by mudstone, which is enigmatic when the sedimentary facies is compared to coeval deposits in the Shikoku Basin (i.e. inputs from the subducting Philippine Sea plate) and to coarser‐grained turbidite sequences from the Quaternary trench wedge. Clay mineral assemblages amplify the mismatches of sedimentary facies. Mudstones from the inner prism are uniformly depleted in smectite, with average bulk values of 23–24 wt%, whereas the Shikoku Basin deposits show progressive decreases in proportions of smectite over time, from averages of 46–48 wt% at 10 Ma to 17–21 wt% at 1 Ma. Plate‐boundary reconstructions for the Philippine Sea region provide one solution to the conundrum. Between 15 Ma and 10 Ma, the Pacific plate subducted near the NanTroSEIZE transect, and a trench‐trench‐trench triple junction migrated to the northeast. Accretion during that period involved sediments that had been deposited on the Pacific plate. Motion of the Philippine Sea plate changed from 10 Ma to 6 Ma, resulting in sinistral slip along the proto‐Nankai Trough. Sediments accreted during that period probably had been deposited near the triple junction, with a hybrid detrital provenance. Renewed subduction of the Philippine Sea plate at 6 Ma led to reorganization of watersheds near the Izu–Honshu collision zone and gradual incision of large submarine canyons on both sides of the colliding Izu arc. Accreted Pliocene mudstones share more of an affinity to the triple junction paleoenvironment than they do to Shikoku Basin. These differences between subducting Shikoku Basin strata and accreted Pacific plate sediments have important implications for interpretations of frictional properties, structural architecture, and diagenetic fluid production.  相似文献   

2.
REE geochemistry of surface sediments in the Chukchi Sea   总被引：4，自引：0，他引：4  
Rare earth elements (including the lanthanides and Y) have analogical chemical properties and low solubility, and they are not easy to transfer and take inter-element fractionation during geological processes such as weathering, disintegration, transporta…  相似文献   

3.
High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are re-ported to reconstruct a history of East Asian monsoon evolution. Variations in Illite, chlorite, and kaolinite contents indicate a strong glacial-interglacial cyclicity, while changes in smectite content present a higher frequency cyclicity. The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea. Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands. Illite and chlorite originated mainly from the Mekong and Red rivers. Kaolinite was provided mainly by the Pearl River. Spectral analysis of the kaolin-ite/(illite chlorite) ratio displays a strong eccentricity period of 100 ka, implying the ice sheet-forced win-ter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka, and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well, implying the tropical-forced summer monsoon evolution. The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity, with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere, with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation. The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons, respectively, implying their diplex and self-contained forcing mechanism.  相似文献   

4.
欧亚东边缘的双向板块汇聚及其对大陆的影响   总被引：1，自引：1，他引：0       下载免费PDF全文
自3 Ma至现今,在欧亚东缘太平洋、菲律宾海板块以较大速率朝NWW方向运动,并沿海沟向欧亚大陆俯冲;同时欧亚板块以较小速率朝SEE方向移动,构成双方向的板块汇聚格局.沿日本岛弧东侧,海洋板片以较小的倾角插入欧亚大陆下面,在浅部产生的挤压变形扩展到日本海东边缘.琉球岛弧的中、北部,菲律宾海俯冲板片的倾角较大,其西南段由NE向转变为EW向,正经历活动的海沟后退与弧后扩张.台湾是3种板块汇聚的交点:欧亚沿马尼拉海沟向东俯冲,吕宋弧与台湾碰撞,使台湾岛陆壳东西向缩短与隆升,形成年轻的造山带,菲律宾海板块沿琉球海沟的西南段向北俯冲到欧亚下面.位于南海与菲律宾海之间的菲律宾群岛是宽的变形过渡带,两侧被欧亚向东、菲律宾海向西俯冲夹击,中间是大型左旋走滑断层.总体上,现今时期的太平洋、菲律宾海板块的西向俯冲运动所产生的变形主要分布在俯冲板片内部及岛弧,未扩散到弧后地区,可能这种俯冲运动产生的水平应力较小,不能阻挡欧亚大陆的向东移动,对大陆内部的现今构造没有明显的影响.  相似文献   

5.
The Indonesian Throughflow (ITF) links upper ocean waters of the west Pacific and Indian Ocean, modulates heat and fresh water budgets between these oceans, and in turn plays an important role in global climate change. The climatic phenomena such as the East Asian monsoon and El Niño-Southern Oscillation (ENSO) exert a strong influence on flux, water properties and vertical stratification of the ITF. This work studied sediments of Core SO18462 that was retrieved from the outflow side of the ITF in the Timor Sea in order to investigate response of the ITF to monsoon and ENSO activities since the last glacial. Based on Mg/Ca ratios and oxygen isotopes in shells of planktonic foraminiferal surface and thermocline species, seawater temperatures and salinity of both surface and thermocline waters and vertical thermal gradient of the ITF outflow were reconstructed. Records of Core SO18462 were then compared with those from Core 3cBX that was recovered from the western Pacific warm pool (WPWP). The results displayed that similar surface waters occurred in the Timor Sea and the WPWP during the last glacial. Since ～16 ka, an apparent difference in surface waters between these two regions exists in salinity, indicated by much fresher waters in the Timor Sea than in the WPWP. In contrast, there is little change in difference of sea surface temperatures (SSTs). With regard to thermocline temperature (TT), it increased until ～11.5 ka since the last glacial, and then remained an overall unchanged trend in the WPWP but continuously decreased in the Timor Sea towards the late Holocene. Since ～6 ka, thermocline waters have tended to be close to each other in between the Timor Sea and the WPWP. It is indicated that intensified precipitation due to East Asian monsoon and possible ENSO cold phase significantly freshened surface waters over the Indonesian Seas, impeding the ITF surface flow and in turn having enhanced thermocline flow during the Holocene. Consequently, thermocline water of the ITF outflow was cooling and thermocline was shoaling towards the late Holocene. It is speculated that, in addition to strengthening of East Asian winter monsoon, increasing ENSO events during the late Holocene likely played an important role in influencing thermocline depth of the ITF outflow.  相似文献   

6.
The sedimentation rate of the sediment drift in the southeast of Dongsha Islands is as high as 49 cm/ka in the last 1.05 Ma. Although the sedimentation rate changes with time, the contents of rare elements of the sediments remain almost the same, indicating that the source area of the sediments has been constant with time. On the triangular diagrams of La-Th-Sc and Th-Sc-Zr/10, the samples from the southeast of Dongsha Islands fall within the continental island arc field, overlapping the samples from Taiwan, while the samples from the Pearl River, those from the west of the Philippines that contain volcanic material, are separated from them. This indicates that the sediments from the southeast of Dongsha Islands have a close relationship to those from Taiwan in terms of provenance. In fact, the sediments on the northern slope of the South China Sea were derived from northeast direction, as well as from Taiwan, most probably transported from Taiwan through Penghu channel into the South China Sea. The terrigenous part of the deep-sea sediments in the north of the South China Sea was provided by different sources.  相似文献   

7.
High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 190 ka during late Quaternary from core MD01-2393 off the Mekong River in the southern South China Sea are reported to reconstruct a history of East Asian monsoon evolution. The dominating clay mineral components indicate a strong glacial-interglacial cyclicity, with high glacial illite, chlorite, and kaolinite contents and high interglacial smectites content. The provenance analysis indicates the direct input of clay minerals via the Mekong River drainage basin. Illite and chlorite derived mainly from the upper reach of the Mekong River, where physical erosion of meta-sedimentary rocks is dominant. Kaolinite derived mainly from active erosion of inhered clays from reworked sediments in the middle reaches. Smectites originated mainly through bisiallitic soils in the middle to lower reaches of the Mekong River. The smectites/(illite+chlorite) and smectites/kaolinite ratios are determined as mineralogical indicato  相似文献   

8.
226Ra profiles have been measured in the western Indian Ocean as part of the 1977–1978 Indian Ocean GEOSECS program. These profiles show a general increase in deep and bottom water Ra concentration from the Circumpolar region to the Arabian Sea. A deep Ra maximum which originates in the Arabian Sea and in the Somali basin at about 3000 m depth spreads southward into the Mascarene basin and remains discernible in the Madagascar and Crozet basins. In the western Indian Ocean, the cold Antarctic Bottom Water spreads northward under the possibly southward-flowing deep water, forming a clear benthic front along the Crozet basin across the Southwest Indian Ridge into the Madagascar and Mascarene basins. The Antarctic Bottom Water continues to spread farther north to the Somali basin through the Amirante Passage at 10°S as a western boundary current. The benthic front and other characteristic features in the western Indian Ocean are quite similar to those observed in the western Pacific where the benthic front as a distinctive feature was first described by Craig et al. [15]. Across the Mid-Indian Ridge toward the Ceylon abyssal plain near the triple junction, Ra profiles display a layered structure, reflecting the topographic effect of the mid-ocean ridge system on the mixing and circulation of the deep and bottom waters. Both Ra and Si show a deep maximum north of the Madagascar basin. Linear relationships between these two elements are observed in the deep and bottom water with slopes increasing northward. This suggests a preferential input of Ra over Si from the bottom sediments of the Arabian Sea and also from the flank sediments of the Somali basin.  相似文献   

9.
The Hakusan volcano, central Japan, is located in a region where two subducting plates (the Pacific Plate and the Philippine Sea Plate) overlap near the junction of four plates adjacent to the Japanese Islands (the Pacific Plate, the Philippine Sea Plate, the Eurasia Plate, and the North American Plate). The Hakusan volcano consists of products from four major volcanic episodes: Kagamuro, Ko‐hakusan, and Shin‐Hakusan I and II. To date the eruption events of the Hakusan volcano we applied thermoluminescence and fission track methods. 238U(234U)–230Th disequilibrium and 206Pb/238U methods were applied to date the zircon crystallization ages for estimating the magma residence time before the eruptions. The eruption ages we obtained are ca 250 ka for Kagamuro, ca 100 ka and ca 60 ka for Ko‐Hakusan, ca 50 ka for Shin‐Hakusan I, and <10 ka for Shin‐Hakusan II. They are concordant with previous reports based on K–Ar dating. Some of the pyroclastic rocks, possibly originating from Shin‐Hakusan II activities, are dated to be ca 36 ka or 50 ka, and belong to the Shin‐Hakusan I activity. The zircon crystallization ages show several clusters prior to eruption. The magma residence time was estimated for each volcanic activity by comparing the major crystallization events and eruption ages, and we found a gradual decrease from ca. 500 ky for the Kagamuro activity to ca. 5 ky for the Shin‐Hakusan II activity. This decrease in residence time may be responsible for the decrease in volume of erupted material estimated from the current topography of the region. The scale of volcanic activity, which was deduced from the number of crystallized zircons, is more or less constant throughout the Hakusan volcanic activity. Therefore, the decrease in magma residence time is most likely the result of stress field change.  相似文献   

10.
We calculated statistical average of thermal data to speculate regional thermal structure of the forearc area of the Japanese Islands. The three thermal statistical averages show a difference of a high thermal regime in the western part of forearc inner zone and a low in the Kanto forearc outer zone. The Kanto zone marks 18 K km−1 for mean geothermal gradient, 44 mW m−2 for mean heat flow, while the western inner zone shows 27 K km−1 for mean geothermal gradient, 63 mW m−2 for mean heat flow. The geothermal gradients of the Nobi Plain and the Osaka Plain in the western inner zone are 29 and 36 K km−1, respectively, while the value of the Kanto Plain in the Kanto zone is 21 K km−1. Taking account of the effect of accumulation of sediments, we see the difference in the thermal regime between the plains and conclude that the difference is significant. Heat flux in the crust depends on the volume of granite rich in radioactive elements. There are few granitic rocks in the Kanto zone, while granitic rocks are dominant in the western inner zone. The heat flow of 20 mW m−2 is attributed to the granitic rocks of about 8 km in thickness. There are two oceanic plate subductions of the Pacific plate and the Philippine Sea plate under the Kanto zone, while only the Philippine Sea plate has been subducting under the western inner zone. The model simulation based on thermal and subduction model shows a heat flow ranging 50-60 mW m−2 in the southwest Japan forarc area and a low value of about 20 mW m−2 in the northeast Japan forearc area. The heat flux from the cooling oceanic lithosphere depends on the age of plate. The Shikoku Basin, a part of the Philippine Sea plate, off the western inner zone is 15-30 Ma, while the Pacific plate off the Kanto zone is 122-132 Ma. Theoretically, heat flux values of 15 and 50 Ma oceanic plates range 60-120 mW m−2 and those of 122-132 Ma could be about 10 mW m−2. If the heat flux contribution from the Philippine Sea plate under the Kanto zone is smaller than the plate under the western inner zone, there could be a thermal regime difference in order of several tens of mW m−2. Conclusively, the cause of the difference of heat flux could be the uneven granitic rocks distribution and/or the difference of heat flux between the two subducting plate.  相似文献   

11.
The Neogene sediments of Gansu Group from northwestern China contain eolian and fluvial deposits.The origins of these sediments are very important for exploring the onset of Asian inland aridification,the pattern of paleo-atmospheric circulation,and the regional tectonics and geomorphic evolution during the Miocene.Here we present detrital-zircon age spectra of typical eolian and fluvial deposits from highlands and subsidence basin,and compare them with those of surrounding eroded mountain(such as the West Qinling Mountains and Liupan Mountains)materials and Quaternary loess derived from the Asian inlands.The results reveal that(1)the detrital-zircon age spectrum of the Miocene eolian sample is remarkably different from the eroded materials of the West Qinling Mountains and the Miocene fluvial deposits from Tianshui region,but very similar to the Quaternary loess deposits.This indicates that the provenance of Miocene eolian sediments is similar with the Quaternary loess,and thus further confirms the previous conclusions that the distribution of Asian arid lands and the pattern of atmospheric circulation during the Miocene are broadly similar with the Quaternary.(2)The detrital-zircon age spectrum of the fluvial deposits(with age about 11.5 Ma)from Tianshui region is different from the eroded materials of West Qinling Mountains,but similar with that of the Liupan Mountains to the east,which may suggest that the Liupan Mountains have already been exhumed by11.5 Ma.  相似文献   

12.
大地震(特别是8级以上的大地震)的发生必须满足2个基本条件:一个是震源附近要有超过岩石弹性极限的高应力背景;另一个是该处的岩石具有发生地震的能力,即在大地震孕育所需的时间尺度(几千年以上)内岩石能长期保持弹性。为考察第1个条件,分析了中国周边三大板块的作用力。认为太平洋板块在海沟附近的俯冲方式所产生的水平力分量较小,而且海沟离中国大陆较远,因此它对中国的地震影响不大;菲律宾海板块对台湾的碰撞使台湾及福建沿海地区为高应力区,但由于碰撞边界的长度只有200km左右,其影响范围不大;印度板块向北推挤是产生中国西部及华北高应力区的最主要原因,文中较详细分析了它的作用,并据此尝试性划分了3个对中国具有强烈影响的地震带。根据岩石的流变性质和地质形成时代把地质体分成了刚性、次刚性和较柔性3类。初步计算了刚性地块的弹性持续时间至少在1Ma以上,而柔性地块的弹性持续时间最多为1ka。因此,8级大地震的位置与刚性地块密切相关  相似文献   

13.
Pb, Nd and Sr isotope compositions of oceanic basalts have been used to identify recycled components of continent derivation in the mantle. The isotopic compositions of Sr, Nd and Pb, together with U, Pb, Sm, Nd, Rb, and Sr abundances have been determined for back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins, in addition to basalts from South Sandwich Islands, Ascension, St. Helena and Tristan da Cunha. Comparisons made between the isotopic compositions of South Sandwich Islands basalts and Atlantic MORB glasses permit the identification of recycled components of continent derivation in the source of the island arc basalts. Recycled Sr of continent derivation is also recognisable in back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins. However, contemporary reinjection of material with the isotopic structures similar to those identified as a component of island arc and back-arc regions cannot be the sole or dominant influence on the fine structure observed in MORB glasses from the Atlantic Ocean, nor the isotopic compositions of Tristan da Cunha, St. Helena and Ascension basalts. Recycled materials are likely to have been responsible for the generation of these heterogeneities only if they have been stored in the mantle for periods of time exceeding 109 years.  相似文献   

14.
中国大陆及邻近海域的Rayleigh波群速度分布   总被引：11，自引：5，他引：11       下载免费PDF全文
利用Rayleigh波群速度资料反演得到中国大陆及其临近海域的(70°E-145°E,10°N-55°N)15-120s周期的群速度分布图像. 塔里木盆地在15s处清楚地显示为低速,在16-33s左右没有显示,但在36-5s显示为高速,说明塔里木盆地有较深的根. 青藏高原块体是44s至120s图像中最为突出的低速块体,南面与印度板块的分界线以及与北面的塔里木盆地、柴达木盆地的分界清晰,其块体中西部的速度低于东部. 泰国清迈附近存在一尺度为1000km左右的低速带,可能是青藏高原块体的物质向东南方向迁移造成上地幔物质上涌的结果. 南北地震带表现为强烈的速度梯度带,西面为低速,东面为高速. 中国南海的中央、日本海中央、菲律宾海表现为海洋性地壳. 菲律宾海的图像与地形及地震带完全吻合. 环绕菲律宾海及日本海存在400km左右宽的低速带,可能是岩浆活动带.  相似文献   

15.
Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.  相似文献   

16.
Concentrations of rare earth elements (REE), Y, Th and Sc were recently determined in marine sediments collected using a box corer along two onshore-offshore transects located in the Strait of Sicily (Mediterranean Sea). The REE + Y were enriched in offshore fine-grained sediments where clay minerals are abundant, whereas the REE + Y contents were lower in onshore coarse-grained sediments with high carbonate fractions. Considering this distribution trend, the onshore sediments in front of the southwestern Sicilian coast represent an anomaly with high REE + Y concentrations (mean value 163.4 μg g−1) associated to high Th concentrations (mean value 7.9 μg g−1). Plot of shale-normalized REE + Y data of these coastal sediments showed Middle REE enrichments relative to Light REE and Heavy REE, manifested by a convexity around Sm-Gd-Eu elements. These anomalies in the fractionation patterns of the coastal sediments were attributed to phosphogypsum-contaminated effluents from an industrial plant, located in the southern Sicilian coast.  相似文献   

17.
The El Niño–Southern Oscillation (ENSO) is a climatic phenomenon that affects socio-economical welfare in vast areas in the world. A continuous record of Holocene ENSO related climate variability of the Indo-Pacific Warm pool (IPWP) is constructed on the basis of stable oxygen isotopes in shells of planktic foraminifera from a sediment core in the western Pacific Ocean. At the centennial scale, variations in the stable oxygen isotope signal (δ18O) are thought be a representation of ENSO variability, although an imprint of local conditions cannot be entirely excluded. The record for the early Holocene (10.3–6 ka BP) shows, in comparison with the mid- to late Holocene, small amplitude variations in the δ18O record of up to 0.3‰ indicating relatively stable and warm sea surface conditions. The mid- to late Holocene (6–2 ka BP) exemplified higher variability in δ18O and thus in oceanic IPWP conditions. Climatically, we interpret this change (5.5–4.2 ka BP) as a phenomenon induced by variability in frequency and/or intensity changes of El Niño. In the period 4.2–2 ka BP we identified several periods, centred on 1.9, 2.1, 2.7, 3.3, 3.7 and 4.2 ka BP, with in general heavy δ18O values. During these periods, the IPWP was relocated to a more eastward position, enhancing the susceptibility for El Niño-like conditions at the core site. Over the last 2000 yr precipitation increased in the area as a response to an increase in Asian monsoon strength, resulting in a freshening of the surface waters. This study corroborates previous findings that the present-day ENSO activity started around 5.5 ka BP.  相似文献   

18.
We performed U–Th radioactive disequilibrium analyses of carbonate nodules and sediment samples recovered from methane seep sites off Joetsu, of the eastern margin of Japan Sea, to decipher the active period of the methane seep. The carbonates contain 230Th, part of which is located in detritus such as silicate and organics, at the time of precipitation. The initial 230Th renders accurate dating with U–Th radioactive disequilibrium method difficult. We assessed the feasibility of correction using radioactive disequilibrium data of ambient sediment to overcome this difficulty. A (230Th/232Th)–(234U/232Th) isochron drawn by three chips divided from a carbonate nodule (PC05-04-50) passed through data points of local sediments. We conclude that the problem of initial 230Th can be resolved by measurements of local sediments. Results show that carbonate nodules include local sediment as impurities. Furthermore, the results of trace element analyses such as Rb, Zr, Nb, REE, Pb, and Th also support the idea.In all, 18 carbonate samples were dated with correction of initial 230Th using the mean value of local sediment in this study. The U–Th correction ages show 12–35ka with an isochron age of 26 ± 3ka. Results indicate that during the time interval of U–Th ages, from 12ka to 35ka, environmental conditions must have been favorable for enhanced methane flux through sediment. The extensive methane flow period at 20ka accords with the lowest-stand sea level during the last glacial age. Results of this study also suggest that U–Th ages of carbonate are useful as a reliable chronometer with regard to methane seep activation. In order to acquire U–Th ages of carbonate at methane seep sites, however, it is important to evaluate the amount of initial 230Th accurately using the value of sediment.  相似文献   

19.
The abundance and distribution of rare earth elements (REE) and their signatures in the Vigo Ria were studied from 50 samples of surface sediments and related to the geological formation in its watershed. The total amount of REE in the Ria is heterogeneous. It ranges from 220 mg kg−1 in the southern middle Ria margin in the vicinity of the Galiñeiro geological shore complex, which contains REE-enriched minerals, to 2 mg kg−1 near the Ria mouth due to dilution with high levels of carbonated biogenic particles (31% of Ca). Rare earth elements of the Ria sediments are considerably enriched in light-REE relative to heavy-REE (a LREE/HREE ratio of 9.7±1.6) and also show a slightly negative Eu-anomaly. Low European shale normalised REE patterns were distinguished in the innermost sediments of Vigo Ria, but were not correlated with Al. This suggests a minor contribution of REE from upstream freshwater inputs to the sediments in the middle Vigo Ria zone. Normalised REE ratios in the middle Ria imply that fine particles enriched in REE may be exported from the Ria to shelf mud patches and REE can be useful as sediment tracers of Ria input on the shelf.  相似文献   

20.
Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents (ΣREE), LREE/HREE ratio and cerium anomaly (δCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio <1, δCe >0.85, ΣREE <400 μg/g, LREE/HREE ratio ≈4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio >1, δCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio ≈6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or ɛNd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to ɛNd values. Terrigenous clay minerals of type I with the ɛNd values of ™8 to ™6 originate mainly from North American fluvial deposits. Those of type II with the ε Nd values of ™9 to ™7 are mainly from the East Asia and North American fluvial deposits. Those of type III with ε Nd values of ™6 to ™3 could come from the central and eastern Pacific volcanic islands. Those of type IV with ε Nd values of ™13 to ™12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.  相似文献   

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