Solution Chemistry and the 36~(th) International Conference on Solution Chemistry (36 ICSC) in Xining,China          下载免费PDF全文

Toshio YAMAGUCHI 《盐湖研究》2019,(2)

<正>Solution chemistry covers a broad and interdisciplinary area in chemistry,physics,biology,pharmaceutical,and medical sciences,as well as various application fields. With the advent of new theories,analytical methods,computers,and technology,the research area of solution chemistry has now been widely and deeply  相似文献   

Transformation between surface spherical harmonic expansion of arbitrary high degree and order and double Fourier series on sphere     

Toshio Fukushima 《Journal of Geodesy》2018,92(2):123-130

In order to accelerate the spherical harmonic synthesis and/or analysis of arbitrary function on the unit sphere, we developed a pair of procedures to transform between a truncated spherical harmonic expansion and the corresponding two-dimensional Fourier series. First, we obtained an analytic expression of the sine/cosine series coefficient of the \(4 \pi \) fully normalized associated Legendre function in terms of the rectangle values of the Wigner d function. Then, we elaborated the existing method to transform the coefficients of the surface spherical harmonic expansion to those of the double Fourier series so as to be capable with arbitrary high degree and order. Next, we created a new method to transform inversely a given double Fourier series to the corresponding surface spherical harmonic expansion. The key of the new method is a couple of new recurrence formulas to compute the inverse transformation coefficients: a decreasing-order, fixed-degree, and fixed-wavenumber three-term formula for general terms, and an increasing-degree-and-order and fixed-wavenumber two-term formula for diagonal terms. Meanwhile, the two seed values are analytically prepared. Both of the forward and inverse transformation procedures are confirmed to be sufficiently accurate and applicable to an extremely high degree/order/wavenumber as \(2^{30}\,{\approx }\,10^9\). The developed procedures will be useful not only in the synthesis and analysis of the spherical harmonic expansion of arbitrary high degree and order, but also in the evaluation of the derivatives and integrals of the spherical harmonic expansion.  相似文献   

Oxygen isotope speedometry in granulite facies garnet recording fluid/melt–rock interaction (Sør Rondane Mountains,East Antarctica)     

Fumiko Higashino  Daniela Rubatto  Tetsuo Kawakami  Anne‐Sophie Bouvier  Lukas P. Baumgartner 《Journal of Metamorphic Geology》2019,37(7):1037-1048

In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ¹⁸O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ¹⁸O = ~15‰) to the rim (δ¹⁸O = ~11‰) suggests that the ¹⁸O/¹⁶O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the ¹⁸O/¹⁶O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ¹⁸O value of the garnet rim, together with the previously reported low δ¹⁸O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ¹⁸O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   

Long-term variations of North Pacific Tropical Water along the 137°E repeat hydrographic section     

Toshiya Nakano  Tomoyuki Kitamura  Shusaku Sugimoto  Toshio Suga  Masafumi Kamachi 《Journal of Oceanography》2015,71(3):229-238

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Groundwater flow system in Bengal Delta,Bangladesh revealed by environmental isotopes     

Ratan K. Majumder  M. A. Halim  B. B. Saha  Reo Ikawa  Toshio Nakamura  Makoto Kagabu  Jun Shimada 《Environmental Earth Sciences》2011,64(5):1343-1352

A total number of 328 groundwater samples are analysed to evaluate the groundwater flow systems in Bengal Delta aquifers, Bangladesh using environmental isotope (²H, ¹⁸O, ¹³C, ³H, and ¹⁴C) techniques. A well-defined Local Meteoric Water Line (LMWL) δ²H = 7.7 δ¹⁸O + 10.7 ‰ is constructed applying linear correlation analyses to the monthly weighted rainfall isotopic compositions (δ¹⁸O and δ²H). The δ¹⁸O and δ²H concentrations of all groundwater samples in the study area are plotted more or less over the LMWL, which provides compelling evidence that all groundwaters are derived from rainfall and floodwater with a minor localized evaporation effects for the shallow groundwaters. Tritium concentration is observed in 40 samples out of 41 with values varying between 0.3 and 5.0 TU, which represents an evidence of young water recharge to the shallow and intermediate aquifers. A decreasing trend of ¹⁴C activity is associated with the heavier δ¹³C values, which indicates the presence of geochemical reactions affecting the ¹⁴C concentration along the groundwater flow system. Both vertical and lateral decrease of ¹⁴C activity toward down gradient show the presence of regional groundwater flow commencing from the unconfined aquifers, which discharges along the coastal regions. Finally, shallow, intermediate, and deep groundwater flow dynamics has revealed in the Bengal Delta aquifers, Bangladesh.  相似文献   

Decadal seesaw of the Central and Subtropical Mode Water formation associated with the Kuroshio Extension variability   总被引：1，自引：1，他引：0  

Eitarou?OkaEmail author  Bo?Qiu  Shinya?Kouketsu  Kazuyuki?Uehara  Toshio?Suga 《Journal of Oceanography》2012,68(2):355-360

Available Argo profiling float data from 2002 to 2011 were analyzed to examine the effect of the Kuroshio Extension (KE) current system variability on the formation of the Central Mode Water. Just north of the upstream portion of the KE at 140–152°E, formation of a lighter variety of the Central Mode Water in winter was active during the unstable period of the upstream KE in 2006–2009 and was reduced when the upstream KE was in the stable period of 2002–2005 and 2010–2011. This decadal formation variability is out of phase with that of the Subtropical Mode Water just south of the KE.  相似文献   

Holocene paleolimnological changes in Lake Skallen Oike in the Syowa Station area of Antarctica inferred from organic components in a sediment core (Sk4C-02)     

Genki I. Matsumoto  Yukinori Tani  Koji Seto  Tomoko Tazawa  Masumi Yamamuro  Takahiro Watanabe  Toshio Nakamura  Tetsuo Takemura  Satoshi Imura  Hiroshi Kanda 《Journal of Paleolimnology》2010,44(2):677-693

Antarctic climate changes influence environmental changes at both regional and local scales. Here we report Holocene paleolimnological changes in lake sediment core Sk4C-02 (length 378.0 cm) from Lake Skallen Oike in the Soya Kaigan region of East Antarctica inferred from analyses of sedimentary facies, a range of organic components, isotope ratios of organic carbon and nitrogen, and carbon-14 dating by Tandetron accelerator mass spectrometry. The sediment core was composed of clayish mud (378.0–152.5 cm) overlain by organic sediments (152.5 cm-surface). The age of the surface and the core bottom were 150 (AD1950-1640) and ca. 7,030 ± 73 calibrated years before present (cal BP), respectively, and the mean sedimentation rate was estimated to be 0.55 mm/year. Multi-proxy analyses revealed that the principal environmental change in the core is a transition from marine to lacustrine environments which occurred at a depth of 152.5 cm (ca. 3,590 cal BP). This was caused by relative sea level change brought about by ongoing retreat of glaciers during the mid-Holocene warming of Antarctica, and ongoing isostatic uplift which outpaced changes in global (eustatic) sea level. The mean isostatic uplift rate was calculated to be 2.8 mm/year. The coastal marine period (378.0–152.5 cm, ca. 7,030–3,590 cal BP) was characterized by low biological production with the predominance of diatoms. During the transition period from marine to freshwater conditions (152.5-approximately 135 cm, ca. 3,590–3,290 cal BP) the lake was stratified with marine water overlain by freshwater, with a chemocline and an anoxic (sulfidic) layer in the bottom of the photic zone. Green sulfur bacteria and Cryptophyta were the major photosynthetic organisms. The Cryptophyta appeared to be tolerant of the moderate salinity and stratified water conditions. The lacustrine period (approximately 135 cm-surface, ca. 3,290 cal BP-present) was characterized by high biological production by green algae (e.g. Comarium clepsydra and Oedegonium spp.) with some contributions from cyanobacteria and diatoms. Biological production during this period was 8.7 times higher than during the coastal marine period.  相似文献   

The role of the intra-daily SST variability in the Indian monsoon variability and monsoon-ENSO–IOD relationships in a global coupled model     

Pascal Terray  Kakitha Kamala  Sébastien Masson  Gurvan Madec  A. K. Sahai  Jing-Jia Luo  Toshio Yamagata 《Climate Dynamics》2012,39(3-4):729-754

The impact of diurnal SST coupling and vertical oceanic resolution on the simulation of the Indian Summer Monsoon (ISM) and its relationships with El Ni?o-Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD) events are studied through the analysis of four integrations of a high resolution Coupled General Circulation Model (CGCM), but with different configurations. The only differences between the four integrations are the frequency of coupling between the ocean and atmosphere for the Sea Surface Temperature (SST) parameter (2 vs. 24?h coupling) and/or the vertical oceanic resolution (31 vs. 301 levels) in the CGCM. Although the summer mean tropical climate is reasonably well captured with all the configurations of the CGCM and is not significantly modified by changing the frequency of SST coupling from once to twelve per day, the ISM–ENSO teleconnections are rather poorly simulated in the two simulations in which SST is exchanged only once per day, independently of the vertical oceanic resolution used in the CGCM. Surprisingly, when 2?h SST coupling is implemented in the CGCM, the ISM–ENSO teleconnection is better simulated, particularly, the complex lead-lag relationships between the two phenomena, in which a weak ISM occurs during the developing phase of an El Ni?o event in the Pacific, are closely resembling the observed ones. Evidence is presented to show that these improvements are related to changes in the characteristics of the model’s El Ni?o which has a more realistic evolution in its developing and decaying phases, a stronger amplitude and a shift to lower frequencies when a 2-hourly SST coupling strategy is implemented without any significant changes in the basic state of the CGCM. As a consequence of these improvements in ENSO variability, the lead relationships between Indo-Pacific SSTs and ISM rainfall resemble the observed patterns more closely, the ISM–ENSO teleconnection is strengthened during boreal summer and ISM rainfall power spectrum is in better agreement with observations. On the other hand, the ISM–IOD teleconnection is sensitive to both SST coupling frequency and the vertical oceanic resolution, but increasing the vertical oceanic resolution is degrading the ISM–IOD teleconnection in the CGCM. These results highlight the need of a proper assessment of both temporal scale interactions and coupling strategies in order to improve current CGCMs. These results, which must be confirmed with other CGCMs, have also important implications for dynamical seasonal prediction systems or climate change projections of the monsoon.  相似文献   

Impact of intra-daily SST variability on ENSO characteristics in a coupled model   总被引：1，自引：1，他引：0  

Sébastien Masson  Pascal Terray  Gurvan Madec  Jing-Jia Luo  Toshio Yamagata  Keiko Takahashi 《Climate Dynamics》2012,39(3-4):681-707

This paper explores the impact of intra-daily Sea Surface Temperature (SST) variability on the tropical large-scale climate variability and differentiates it from the response of the system to the forcing of the solar diurnal cycle. Our methodology is based on a set of numerical experiments based on a fully global coupled ocean–atmosphere general circulation in which we alter (1) the frequency at which the atmosphere sees the SST variations and (2) the amplitude of the SST diurnal cycle. Our results highlight the complexity of the scale interactions existing between the intra-daily and inter-annual variability of the tropical climate system. Neglecting the SST intra-daily variability results, in our CGCM, to a systematic decrease of 15% of El Ni?o—Southern Oscillation (ENSO) amplitude. Furthermore, ENSO frequency and skewness are also significantly modified and are in better agreement with observations when SST intra-daily variability is directly taken into account in the coupling interface of our CGCM. These significant modifications of the SST interannual variability are not associated with any remarkable changes in the mean state or the seasonal variability. They can therefore not be explained by a rectification of the mean state as usually advocated in recent studies focusing on the diurnal cycle and its impact. Furthermore, we demonstrate that SST high frequency coupling is systematically associated with a strengthening of the air-sea feedbacks involved in ENSO physics: SST/sea level pressure (or Bjerknes) feedback, zonal wind/heat content (or Wyrtki) feedback, but also negative surface heat flux feedbacks. In our model, nearly all these results (excepted for SST skewness) are independent of the amplitude of the SST diurnal cycle suggesting that the systematic deterioration of the air-sea coupling by a daily exchange of SST information is cascading toward the major mode of tropical variability, i.e. ENSO.  相似文献   

IOD and ENSO impacts on the extreme stream-flows of Citarum river in Indonesia     

Netrananda Sahu  Swadhin K. Behera  Yosuke Yamashiki  Kaoru Takara  Toshio Yamagata 《Climate Dynamics》2012,39(7-8):1673-1680

Extreme stream-flow events of Citarum River are derived from the daily stream-flows at the Nanjung gauge station. Those events are identified based on their persistently extreme flows for 6 or more days during boreal fall when the seasonal mean stream-flow starts peaking-up from the lowest seasonal flows of June–August. Most of the extreme events of high-streamflows were related to La Ni?a conditions of tropical Pacific. A few of them were also associated with the negative phases of IOD and the newly identified El Ni?o Modoki. Unlike the cases of extreme high streamflows, extreme low streamflow events are seen to be associated with the positive IODs. Nevertheless, it was also found that the low-stream-flow events related to positive IOD events were also associated with El Ni?o events except for one independent event of 1977. Because the occurrence season coincides the peak season of IOD, not only the picked extreme events are seen to fall under the IOD seasons but also there exists a statistically significant correlation of 0.51 between the seasonal IOD index and the seasonal streamflows. There also exists a significant lag correlation when IOD of June–August season leads the streamflows of September–November. A significant but lower correlation coefficient (0.39) is also found between the seasonal streamflow and El Ni?o for September–November season only.  相似文献