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1.
In Switzerland the geological storage in the Opalinus Clay formation is the preferred option for the disposal of spent fuel (SF) and high-level radioactive waste (HLW). The waste will be encapsulated in steel canisters and emplaced into long tunnels that are backfilled with bentonite. Due to uncertainties in the depth of the repository and the associated stress state, a concrete liner might be used for support of emplacement tunnels.Numerical reactive transport calculations are presented that investigate the influence of a concrete liner on the adjacent barrier materials, namely bentonite and Opalinus Clay. The geochemical setup was tailored to the specific materials foreseen in the Swiss repository concept, namely MX-80 bentonite, low-pH concrete (ESDRED) and Opalinus Clay. The heart of the bentonite model is a new conceptual approach for representing thermodynamic properties of montmorillonite which is formulated as a multi-component solid solution comprised of several end-members.The presented calculations provide information on the extent of pH fronts, on the sequence and extent of mineral phase transformations, and on porosity changes on cement–clay interfaces. It was found that the thickness of the zone containing significant mineralogical alterations is at most a few tens of centimeters thick in both the bentonite and the Opalinus Clay adjacent to the liner. Near both interfaces, bentonite–concrete liner and concrete liner–Opalinus Clay, the precipitation of minerals causes a reduction in the porosity. The effect is more pronounced and faster at the concrete liner–Opalinus Clay interface. The simulations reveal that significant pH-changes (i.e. pH > 9) in bentonite and Opalinus Clay are limited to small zones, less than 10 cm thick at the end of the simulations. It is not to be expected that the zone of elevated pH will extend much further at longer times.  相似文献   

2.
Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.  相似文献   

3.
Inorganic industrial waste landfills have the potential to contaminate subsurface groundwater supplies through migration of leachates down to the water table and into groundwater aquifers, despite the use of compacted low permeability clay or polyethene liners. This paper aims the removal of Cu2+ and Zn2+ in the leachate from an industrial waste landfill using natural materials (natural zeolite, expanded vermiculite, pumice, illite, kaolinite, and bentonite) as a liner material. Cu2+ and Zn2+ concentrations for all treatments decreased during the process. Of all the different natural materials, natural zeolite, expanded vermiculite and pumice, with bentonite, were effective in removing Cu2+ and Zn2+ present in the leachate. However, the use of illite and kaolinite with bentonite as liner materials could be of disadvantage in Cu2+ and Zn2+ removal from leachate. The adsorption kinetic models were also tested for the validity. The second order kinetics with the high correlation coefficients best described adsorption kinetic data.  相似文献   

4.
The target of this study is the evaluation of repair mortar contribution to the dynamic behavior of Kaisariani Monastery in Athens, by using the tools of finite element analysis and fragility curves. Three types of mortars (concrete) are designed in order to simulate the Hagia Sophia historic mortar, by using different binding material: lime/metakaolin, hydraulic lime, lime/cement. In the developed model the mechanical characteristics of the designed mortars are used. In addition, fragility curves were developed and their results indicated that for the current situation of Kaisariani Monastery and for peak ground acceleration (PGA) value ≥0.24 g, the probability of occurrence of serious damage is 59%. For PGA=0.36 g an overall failure happened. For PGA=0.40 and by using restoration mortar up to 15% of the total bed joint the failure percentage reduces in the range of 12–30%. Better protection is reported for lime/cement mix design followed by hydraulic lime and lime/metakaolin.  相似文献   

5.
This study was performed to propose a suitable treatment for waste foundry sand (WFS) before persistent disposal. It was observed that solidification/stabilization (S/S), which is the common pre‐treatment method because of its comparatively easy and inexpensive applicability, can treat WFS including dissolved organic carbon (DOC) above hazardous landfilling limits. Regular sand was partially replaced with WFS with a ratio of 0–90 wt% in order to prepare three different kinds of mortar samples, where Portland limestone cement (PLC) alone, calcium lime (CL) alone, and PLC together with CL were contained as binders. Leaching behaviors of all S/S products were analyzed according to the TS EN 12457‐4 leaching test. The treatment efficiency was assessed to reduce the DOC content to the levels under the European landfill acceptance criteria. Furthermore, heavy metals (Ni, Zn, Cr), fluoride (F?), total dissolved solids leachability, and total organic carbon content were analyzed in order to investigate the pre‐treatment ability and to determine whether S/S products can be disposed of in a landfill site with municipal wastes or in a separate landfill site. The results showed that S/S of WFS is an efficient pre‐treatment technique before its disposal in a landfill and provides economical advantages compared to hazardous waste landfilling.  相似文献   

6.
Gypsum rocks are widely exploited in the world as industrial minerals. The purity of the gypsum rocks (percentage in gypsum mineral in the whole rock) is a critical factor to evaluate the potential exploitability of a gypsum deposit. It is considered than purities higher than 80% in gypsum are required to be economically profitable. Gypsum deposits have been studied with geoelectrical methods; a direct relationship between the electrical resistivity values of the gypsum rocks and its lithological composition has been established, with the presence of lutites being the main controlling factor in the geoelectrical response of the deposit. This phenomenon has been quantified in the present study, by means of a combination of theoretical calculations, laboratory measurements and field data acquisition. Direct modelling has been performed; the data have been inverted to obtain the mean electrical resistivity of the models. The laboratory measurements have been obtained from artificial gypsum-clay mixture pills, and the electrical resistivity has been measured using a simple electrical circuit with direct current power supply. Finally, electrical resistivity tomography data have been acquired in different evaporite Tertiary basins located in North East Spain; the selected gypsum deposits have different gypsum compositions. The geoelectrical response of gypsum rocks has been determined by comparing the resistivity values obtained from theoretical models, laboratory tests and field examples. A geoelectrical classification of gypsum rocks defining three types of gypsum rocks has been elaborated: (a) Pure Gypsum Rocks (>75% of gypsum content), (b) Transitional Gypsum Rocks (75–55%), and (c) Lutites and Gypsum-rich Lutites (<55%). From the economic point of view, the Pure Gypsum Rocks, displaying a resistivity value of >800 ohm.m, can be exploited as industrial rocks. The methodology used could be applied in other geoelectrical rock studies, given that this relationship between the resistive particles embedded within a conductive matrix depends on the connectivity of the matrix particles.  相似文献   

7.
Spatial variation of the surface micro‐relief in a Sharkey clay soil was investigated. The micro‐relief measurements of the soil surface were obtained using an automated infrared laser system and evaluated with methods of Fourier analysis. The authors illustrate the spectral technique with a simple example and then use the technique to interpret the surface micro‐relief patterns of soil samples subjected to three simulated rainstorm intensities. The periodicity of the soil surface micro‐relief in the longitudinal direction was 80–120 mm. The periodic surface micro‐relief patterns immediately following the rainstorm are shown to be an early manifestation of the cracking pattern. Published in 2006 by John Wiley & Sons, Ltd.  相似文献   

8.
Sands belonging to Kamalapuram Formation of Paleocene-Eocene age are deposited in Cauvery basin as incised valley fill during a regressive cycle. Here we attempt to quantify the influence of diagenesis on pore-filling materials using rock physics template constrained by geohistory modelling. Primarily, porosity–velocity and acoustic impedance – the ratio of P-wave and S-wave velocity (VP/Vs) cross-plots are used as rock physics templates. Rock physics template has efficiently quantified pore-filling materials namely; contact cement and non-contact cement. The estimated contact cement and non-contact cement are correlated with conventional petrophysical logs within the selected depth interval. Further, this correlation is used to interpret the composition of pore-filling materials. Shallower depth intervals (I and II) exhibit moderate non-contact cement (4–5%) and insignificant contact cement (1–2% approx.) depositions. However, deeper interval (III) records a significant amount of pore-filling materials amounting average of 12% non-contact cement and 4% contact cement. Pore-filling materials demonstrate a positive correlation with the depth of burial. The fluid response is substantially affected by the degree of diagenesis, composition and spatial distribution of pore-filling materials. Shallower depth intervals (1770–1786 m and 1858–1878 m) are relatively more sensitive to fluid changes as it is affected by insignificant contact cement. The depth interval 1770–1786 m shows class II (oil) and class III (gas) amplitude variation with offset anomalies. The sand occurring in depth interval 1858–1878 m demonstrates class IIP (oil) and II (gas) anomaly. The deeper interval (2118–2170 m) is comparatively stiffer and demonstrates class I amplitude variation with offset (oil and gas sand) anomaly.  相似文献   

9.
The bulk of eroded soils measured at the outlets of plots, slopes and watersheds are suspended sediments, splash‐induced sheet erosion. It is depending on rainfall intensity and antecedent soil moisture contents and contributes to a significant proportion of soil loss that usually is ignored in soil erosion and sediment studies. A digital image processing method for tracing and measuring non‐suspended soil particles detached/transported by splash/runoff was therefore used in the present study. Accordingly, fine mineral pumice grains aggregated with white cement and coloured with yellow pigment powder, with the same size, shape and specific gravity as those of natural soil aggregates, called synthetic color‐contrast aggregates, were used as tracers for detecting soil particle movement. Subsequently, the amount of non‐suspended soil particles detached and moved downward the slope was inferred with the help of digital image processing techniques using MATLAB R2010B software (Mathworks, Natick, Massachusetts, USA). The present study was conducted under laboratory conditions with four simulated rainfall intensities between 30–90 mm h‐1, five antecedent soil moisture contents between 12–44 % v v‐1 and a slope of 30%, using sandy loam soils taken from a summer rangeland in the Alborz Mountains, Northern Iran. A range of total transported soil between 90.34 and 1360.93 g m‐2 and net splash erosion between 36.82 and 295.78 g m‐2were observed. The results also showed the sediment redeposition ratio ranging from 87.27% [sediment delivery ratio (SDR) = 12.73%] to 96.39% (SDR = 3.61%) in various antecedent soil moisture contents of rainfall intensity of 30 mm h‐1 and from 80.55% (SDR = 19.45%) to 89.42% (SDR = 10.58%) in rainfall intensity of 90 mm h‐1. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

10.
Nowadays,the preservation of natural resources,the reuse,and the recycling of waste and by-products in the cement industry are gaining increasing attention in a sustainable development project.In this perspective,many studies focus on finding solutions in order to propose environmentally friendly materials.Nowadays the sediments represent a way to preserve the natural resources by their reuse as a secondary raw material in multiple applications(concrete,roads,landscaped mound,etc.).However,they commonly contain contaminants,organic matter(5%-30%),high water content(50%-200%),and relatively small particle size(Dmax≤300 mm).Therefore to improve the mechanical properties of this material as well as its physiochemical ones,specific methods of characterization and appropriate treatment techniques(calcination,chemical treatment,etc.)are required.This article presents a bibliographical review of the efficient use of sediments in cementitious matrix.It details experimental tests that must be performed to ensure the durability of sediment-based structure and assess their environmental impact under prescribed conditions.  相似文献   

11.
The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

12.
Spatially discontinuous permafrost conditions frequently occur in the European Alps. How soils under such conditions have evolved and how they may react to climate warming is largely unknown. This study focuses on the comparison of nearby soils that are characterised by the presence or absence of permafrost (active‐layer thickness: 2–3 m) in the alpine (tundra) and subalpine (forest) range of the Eastern Swiss Alps using a multi‐method (geochemical and mineralogical) approach. Moreover, a new non‐steady‐state concept was applied to determine rates of chemical weathering, soil erosion, soil formation, soil denudation, and soil production. Long‐term chemical weathering rates, soil formation and erosion rates were assessed by using immobile elements, fine‐earth stocks and meteoric 10Be. In addition, the weathering index (K + Ca)/Ti, the amount of Fe‐ and Al‐oxyhydroxides and clay minerals characteristics were considered. All methods indicated that the differences between permafrost‐affected and non‐permafrost‐affected soils were small. Furthermore, the soils did not uniformly differ in their weathering behaviour. A tendency towards less intense weathering in soils that were affected by permafrost was noted: at most sites, weathering rates, the proportion of oxyhydroxides and the weathering stage of clay minerals were lower in permafrost soils. In part, erosion rates were higher at the permafrost sites and accounted for 79–97% of the denudation rates. In general, soil formation rates (8.8–86.7 t/km2/yr) were in the expected range for Alpine soils. Independent of permafrost conditions, it seems that the local microenvironment (particularly vegetation and subsequently soil organic matter) has strongly influenced denudation rates. As the climate has varied since the beginning of soil evolution, the conditions for soil formation and weathering were not stable over time. Soil evolution in high Alpine settings is complex owing to, among others, spatio‐temporal variations of permafrost conditions and thus climate. This makes predictions of future behaviour very difficult. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

13.
Declines of acidic deposition levels by as much as 50% since 1990 have led to partial recovery of surface waters in the northeastern USA but continued depletion of soil calcium through this same period suggests a disconnection between soil and surface water chemistry. To investigate the role of soil‐surface water interactions in recovery from acidification, the first regional survey to directly relate soil chemistry to stream chemistry during high flow was implemented in a 4144‐km2 area of the Catskill region of New York, where acidic deposition levels are among the highest in the East. More than 40% of 95 streams sampled in the southern Catskill Mountains were determined to be acidified and had inorganic monomeric aluminum concentrations that exceeded a threshold that is toxic to aquatic biota. More than 80% likely exceeded this threshold during the highest flows, but less than 10% of more than 100 streams sampled were acidified in the northwestern portion of the region. Median Oa horizon soil base saturation ranged from 50% to 80% at 200 sites across the region, but median base saturation in the upper 10 cm of the B horizon was less than 20% across the region and was only 2% in the southern area. Aluminum is likely to be interfering with root uptake of calcium in the mineral horizon in approximately half the sampled watersheds. Stream chemistry was highly variable over the Catskill region and, therefore, did not always reflect the calcium depletion of the B horizon that our sampling suggested was nearly ubiquitous throughout the region. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

14.
Grout continuity and the location of the bentonite seal and sand pack in PVC-cased monitoring wells can be evaluated with cased-hole geophysical density logs. This method relies upon density contrasts among various completion conditions and annular materials. Notably, the lack of annular material behind pipe (i.e., void space) creates a low-density zone that is readily detected by borehole density measurements.
Acoustic cement bond logging has typically been applied to the evaluation of cement in the annular space of completed oil and gas production wells, and in some cases to ground water monitoring wells. These logs, however, can only be obtained in the fluid-filled portion of the borehole, and their interpretation is severely hindered by the presence of the micro-annulus between casing and cement. The influence of the micro-annulus on cement bond logs can be mitigated in steel-cased wells by pressurizing the wellbore during acquisition of the log, but this procedure is not feasible in PVC-cased monitoring wells. The micro-annulus does not affect cased-hole density logs or their interpretation.
Empirical measurements made in the laboratory with density probes provide information on their depths of investigation and response to specific completion conditions. These empirical data, and general knowledge of the density of annular completion materials (sand, bentonite, cement), are used to support interpretations of cased-hole density logs acquired in the field. Three field examples demonstrate the applicability of geophysical density logs to the evaluation of PVC-cased monitoring well completions.  相似文献   

15.
The numerical simulation of long‐term large‐scale (field to regional) variably saturated subsurface flow and transport remains a computational challenge, even with today's computing power. Therefore, it is appropriate to develop and use simplified models that focus on the main processes operating at the pertinent time and space scales, as long as the error introduced by the simpler model is small relative to the uncertainties associated with the spatial and temporal variation of boundary conditions and parameter values. This study investigates the effects of various model simplifications on the prediction of long‐term soil salinity and salt transport in irrigated soils. Average root‐zone salinity and cumulative annual drainage salt load were predicted for a 10‐year period using a one‐dimensional numerical flow and transport model (i.e. UNSATCHEM) that accounts for solute advection, dispersion and diffusion, and complex salt chemistry. The model uses daily values for rainfall, irrigation, and potential evapotranspiration rates. Model simulations consist of benchmark scenarios for different hypothetical cases that include shallow and deep water tables, different leaching fractions and soil gypsum content, and shallow groundwater salinity, with and without soil chemical reactions. These hypothetical benchmark simulations are compared with the results of various model simplifications that considered (i) annual average boundary conditions, (ii) coarser spatial discretization, and (iii) reducing the complexity of the salt‐soil reaction system. Based on the 10‐year simulation results, we conclude that salt transport modelling does not require daily boundary conditions, a fine spatial resolution, or complex salt chemistry. Instead, if the focus is on long‐term salinity, then a simplified modelling approach can be used, using annually averaged boundary conditions, a coarse spatial discretization, and inclusion of soil chemistry that only accounts for cation exchange and gypsum dissolution–precipitation. We also demonstrate that prediction errors due to these model simplifications may be small, when compared with effects of parameter uncertainty on model predictions. The proposed model simplifications lead to larger time steps and reduced computer simulation times by a factor of 1000. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

16.
This paper examines the weathering processes that have combined to produce the distribution of soil‐regolith (SR) thickness across the Triassic Sherwood Sandstone Group outcrop (750 km2) in Nottinghamshire, UK. Archive borehole logs (n = 282) taken across the outcrop showed that SR thickness had mean and median depths of ~1·8 and 1·5 m, respectively. Cores were taken from a forested site to depths ~3 m for geochemical analysis. At this site the SR thickness was ~1·7 m. Analysis of the loss of elements, compared to bedrock using mass balance calculations (τ) showed that all the calcite and gypsum cement had been removed to depths of >3 m. Thus the major difference between the SR and the underlying saprolite was that the former exists as loose sand as opposed to a semi‐durable rock. Scanning electron microscopy (SEM) analysis of core samples suggested that the non‐durable rock or saprolite had greater cementation of clay particles. We propose that the mechanism through which the clay cement (and other interlocking grain bonds) was eased apart was through freeze–thaw processes associated with the summer ‘active layer development (ALD)’ during the last glacial activity in the UK. We tested this theory by developing a Monte Carlo simulation based on a simplified version of the Stefan equation. Current Arctic datasets of air and ground temperatures were obtained to provide reasonable starting conditions for input variables. These were combined with known data for thermal conductivity, bulk density and moisture content of the Sherwood Sandstone regolith. Model predictions (n = 1000) of the distribution of SR thickness accurately reflect the observed distribution thickness from the borehole logs. This is strong evidence that freeze–thaw and ‘ALD’ processes are major factors in determining the thickness of SR across this outcrop. British Geological Survey © NERC 2012  相似文献   

17.
Soil water systems have been severely degraded in coal‐mined and subsiding land, where a shallow groundwater table is also present. The present paper discussed the effects of fly ash (FA) and coal gangue (CG) as filling materials on the hydraulic properties and water content distribution in a profile for the purpose of rehabilitating subsided lands. The saturated water content, water characteristic curve, and water diffusivity of local soil, FA, CG, and a mixture of FA and CG (“mixed filling”) were characterized. A column experiment was conducted to investigate the changes of water content in profiles reconstructed from the combination of soil and filling materials, including soil only, FA, CG, and a mixture of FA and CG, which were used to fill the lower part of the reconstructed profile. The mixture of FA and CG was found to possess similar hydraulic properties to those of the soil, particularly high water‐holding capacity and permeability. Moreover, the volumetric water contents in the whole profile containing the mixture of FA and CG were consistent with those of the profile reconstructed with soil only. As a result, it is recommended to adopt the mixture of FA and CG for reconstructing the lower profile of the land to alleviate or rehabilitate subsided land in coal mines.  相似文献   

18.
Soil macropore networks are subsurface connected void spaces caused by processes such as fracture of soils, micro‐erosion and fauna burrows. Axial X‐ray computed tomography (CT) scanning provides a convenient means of recording the spatial structure of soil macropore networks. The objective of this study were to (1) based on CT technique and GIS digitized image method, construction a new technique for tracing, visualizing and measuring the soil macropore networks and (2) investigate the effects of farming activities on soil macropore networks characteristics. Our technique uses left‐turning and nine‐direction judgment methods, a combination of the layer‐by‐layer analysis method and the up‐down tracking algorithm. The characteristics for the overall structure patterns of macropores, the spatial distribution of the macropore networks and each single macropore network can be conveniently identified by our technique. Eight undisturbed soil columns from fields with two distinct land uses (under cultivation and not been cultivated) and four different depths (0–20, 20–40, 40–60 and 60–80 cm) were investigated. The soil columns were scanned using X‐ray CT at a voxel resolution of 0.075 × 0.075 × 3.000 mm. Results indicate that farming activities can destroy the initial structure of macropores, and those remaining are mainly small‐sized and medium‐sized networks with lower extension and hydraulic conductivity. The network properties show a significant difference between upper and lower layer. The results can provide beneficial reference to further research centered on non‐equilibrium flow prediction and chemical transport modeling in field soils. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

19.
To determine how soil frost changes flowpaths of runoff water along a hillslope, a transect consisting of four soil profiles directed towards a small stream in a mature forest stand was investigated at Svartberget, near Vindeln in northern Sweden. Soil temperature, unfrozen water content, groundwater level and snow depth were investigated along the transect, which started at the riparian peat, and extended 30 m upslope into mineral soils. The two, more organic‐rich profiles closest to the stream had higher water retention and wetter autumn conditions than the sandy mineral soils further upslope. The organic content of the soil influenced the variation in frost along the transect. The first winter (1995–96) had abnormally low snow precipitation, which gave a deep frost down to 40–80 cm, whereas the two following winters had frost depths of 5–20 cm. During winter 1995–96, the two organic profiles close to the stream had a shallower frost depth than the mineral soil profile higher upslope, but a considerably larger amount of frozen water. The fraction of water that did not freeze despite several minus degrees in the soil was 5–7 vol.% in the mineral soil and 10–15 vol.% in the organic soil. From the measurements there were no signs of perched water tables during any of the three snowmelt periods, which would have been strong evidence for changed water flowpaths due to soil frost. When shallow soil layers became saturated during snowmelt, especially in 1997 and 1998, it was because of rising groundwater levels. Several rain on frozen ground events during spring 1996 resulted in little runoff, since most of the rain either froze in the soil or filled up the soil water storage. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

20.
While soil moisture patterns can be interesting traits to investigate spatio‐temporal heterogeneity of catchments relevant for various physical processes of soil–atmosphere interaction and soil water redistribution, many of the existing methods to capture spatial patterns are time consuming, expensive or need site‐specific calibration. In this study we present a quick and inexpensive supplementary field method for classifying soil wetness in wet environments. The seven wetness classes are based on qualitative indicators, which one can touch, hear or see on the soil surface. To counter critics that such qualitative methods are considerably affected by subjectivity, we performed systematic testing of the method by taking qualitative measurements in the field with 20 non‐expert raters. We then analyzed these in terms of degree of agreement and assessed the results against gravimetric sampling and time domain reflectometry measurements. In 70% of all classifications raters agreed on the wetness class assigned to the marked sampling locations and in 95% they were not off by more than one wetness class. The seven quantitative wetness classes agreed with gravimetric and time domain reflectometry measurements, although intermediate to wet classes showed an overlap of their range whereas the driest classes showed considerable spread. Despite some potential to optimize the method, it has been shown to be a reliable supplement to existing quantitative techniques for assessing soil moisture patterns in wet environments. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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