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1.
The frequency of nuclear aberrations and neutral red retention time of hemocytes in the mollusk Lamellidens marginalis were recorded under exposure to sublethal concentrations of sodium arsenite in order to examine the sensitivity and effectiveness of these inexpensive assays for screening the toxicity of As3+ in a freshwater ecosystem. A dose and time dependent increase in the density of micronucleated and binucleated hemocytes and gill cells was indicative of the pronounced genotoxic effect of arsenic on this animal. The disruption of intrahemocyte homeostasis imposed by this natural toxicant was evident from a dose and time dependent reduction in the lysosomal stability of the hemocytes of the animal. The tested parameters are indicative of arsenic toxicity in L. marginalis in the freshwater systems of the arsenic affected geographical areas of West Bengal, India. 相似文献
2.
Increased hazard of arsenic toxicity at many provinces of India causing extensive contamination of their wetlands. To illustrate the consequences of the arsenic menace on the aquatic fauna, a nutritionally important freshwater catfish Clarias batrachus (Linn.) was subjected to the stress of sublethal concentration (1 mg/L; 5% of 96‐h LC50 value) of sodium meta‐arsenite. The alterations induced by the arsenic salt on certain biomolecules (proteins, free amino acids (FAA), and protease activities) in five tissue components (muscle, liver, brain skin, and gills) of the fish using biochemical techniques were estimated. Significant (p < 0.01) decrease in the concentration of proteins in all the tissues (19.74–44.84% in muscles; 3.17–49.39% in liver; 10.05–36.16% in brain; 12.62–52.01% in skin and 7.34–61.69% in gills), and significant (p < 0.01) increase in FAA (6.84–269.89% in muscles; 125.89–358.03% in liver; 1.07–152.90% in brain; 29.31–401.62% in skin and 38.53–165.07% in gills), and protease activities (43.59–183.33% in muscles; 19.52–131.90% in liver; 8.85–46.72% in brain; 33.33–261.53% in skin and 25.39–50.79% in gills) of the exposed fish were observed. This increase in amino acids and enzyme activity point out toward breakdown of protein leading to their depletion. 相似文献
3.
Jin‐Jing Lee Cheng‐Shin Jang Sheng‐Wei Wang Chin‐Ping Liang Chen‐Wuing Liu 《水文研究》2008,22(16):3029-3041
This study characterized the redox conditions in arsenic‐affected groundwater aquifers of the Lanyang plain, Taiwan. Discriminant analysis was adopted to delineate three redox zones (oxidative, transitional and reductive zones) in different aquifers and yielded 92·3% correctness on groundwater quality data. Arsenic is mainly distributed in the reductive zone, and arsenic distribution in the shallow aquifer is mainly affected by surface activities. According to PHREEQC modelling results, possible mechanisms for arsenic release to groundwater in Lanyang plain are explored. Arsenic released to groundwater in the oxidative zone (zone 1) is primarily caused by the oxidations of arsenic‐bearing pyrite minerals, and arsenate is the predominant species. While the reductive dissolution of Fe‐oxides are responsible for the high arsenic concentration found in the transitional and reductive zones (zones 2 and 3), arsenite is the predominant species. The reduction potential of groundwater rises as the depths and zones increase. Some sulphates may be reduced to form sulphide ions, which then react with arsenic to form arseno‐sulphide deposits (such as realgar, orpiment) and then slightly lower groundwater arsenic concentrations. A conceptual diagram which summarized the possible release processes of arsenic in different redox zones along groundwater flow in Lanyang plain is postulated. Arsenic‐bearing pyrite and arsenopyrite (FeAsS) are oxidized as they are exposed to the infiltrated oxygenated rainwater, releasing soluble arsenate Fe(II) and SO42? into zone 1. The dissolution of arsenic‐rich Fe‐oxides due to the onset of reducing conditions in zones 2 and 3 is responsible for the mobility of arsenic and likely to be the primary mechanism of arsenic release to groundwater in the Lanyang plain Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
4.
In natural waters arsenic normally occurs in the oxidation states +III (arsenite) and +V (arsenate). The removal of As(III) is more difficult than the removal of As(V). Therefore, As(III) has to be oxidized to As(V) prior to its removal. The oxidation in the presence of air or pure oxygen is slow. The oxidation rate can be increased by ozone, chlorine, hypochlorite, chlorine dioxide, or H2O2. The oxidation of As(III) is also possible in the presence of manganese oxide coated sands or by advanced oxidation processes. Arsenic can be removed from waters by coprecipitation with Fe(OH)3, MnO2 or during water softening. Fixed‐bed filters have successfully been applied for the removal of arsenic.The effectiveness of arsenic removal was tested in the presence of adsorbents such as FeOOH, activated alumina, ferruginous manganese ore, granular activated carbon, or natural zeolites. Other removal technologies are anion exchange, electrocoagulation, and membrane filtration by ultrafiltration, nanofiltration or reverse osmosis. 相似文献
5.
Jessica Leber M. Moshiur Rahman Kazi M. Ahmed Brian Mailloux Alexander van Geen 《Ground water》2011,49(1):111-123
Arsenic in groundwater has been a concern in South and Southeast Asia for more than a decade. We explore here the possibility that hydrogeologic factors recently shown to influence the distribution of arsenic might also affect the level of contamination of shallow (<20 m) wells with microbial pathogens. A total of 96 shallow tube wells in two nearby villages of Bangladesh were surveyed during the wet and dry seasons, along with 55 deeper wells in neighboring villages. One of the two villages is located in a particularly sandy environment where recharge is rapid and shallow wells contain little arsenic. Shallow aquifers in the other village are capped with an impermeable clay layer, recharge is an order of magnitude slower, and arsenic levels are high. The fecal indicator E. coli was detected in 43% of shallow wells, compared with 12% of deeper wells. More shallow wells contained E. coli during the wet season (61%) than during the dry season (9%). In the wet season, a higher proportion of shallow wells in the village with low arsenic levels (72%) contained E. coli compared with the village having high arsenic levels (43%). Differences in arsenic and E. coli distributions between the two sites are likely due to the differences in permeability of near‐surface sediments although differences in average well‐depth between the two villages (9 ± 4 vs. 15 ± 3 m) may play a role as well. Hydrogeologic conditions that favor high levels of fecal contamination but low levels of arsenic in shallow groundwater should be taken into account during arsenic mitigation throughout South and Southeast Asia. 相似文献
6.
Adsorption and oxidative transformation processes critically affect the mobility and toxicity of arsenic (As) in the environment. In this study, the detoxification of arsenite through adsorption and oxidation by pyrolusite was systematically investigated. Disappearance of aqueous As(III) in the solution can be efficiently achieved using pyrolusite. The As(III) oxidative transformation product arsenate or As(V) was obtained both in the solution and on the pyrolusite surface. The arsenic species adsorbed on pyrolusite exist in two forms: As(III) and As(V). Furthermore, over 64.8% of the adsorbed As cannot be desorbed. They were fixed more stably in the structure of the mineral to achieve a safer removal. Lower As(III) initial concentration increased As(III) detoxification rates. Elevating the reaction pH from 4.5 to 7.9 elicited a slight effect on the disappearance rate of As(III). Efficient As(III) detoxification can be achieved by pryrolusite within the studied pH range. The addition of low‐molecular‐weight carboxylic acids decreased the detoxification rate of As(III) through competition for active sites on pyrolusite. Co‐existing divalent metal ions, such as Ca2+, Ni2+, and Mn2+, also decreased the detoxification rate of As(III). However, the trivalent ion Cr3+ largely increased the detoxification rate through co‐precipitation and adsorption processes. 相似文献
7.
Deepak Jhajharia Yagob Dinpashoh Ercan Kahya Vijay P. Singh Ahmad Fakheri‐Fard 《水文研究》2012,26(3):421-435
In the present study, the trends in the reference evapotranspiration (ETO) estimated through the Penman‐Monteith method were investigated over the humid region of northeast (NE) India by using the Mann‐Kendall (MK) test after removing the effect of significant lag‐1 serial correlation from the time series of ETO by pre‐whitening. During the last 22 years, ETO has been found to decrease significantly at annual and seasonal time scales for 6 sites in NE India and NE India as a whole. The seasonal decreases in ETO have, however, been more significant in the pre‐monsoon season, indicating the presence of an element of a seasonal cycle. The decreases in ETO are mainly attributed to the net radiation and wind speed, which are also corroborated by the observed trends in these two parameters at almost all the times scales over most of the sites in NE India. The steady decrease in wind speed and decline in net radiation not only balanced the impact of the temperature increases on ETO, but may have actually caused the decreases in ETO over the humid region of northeast India. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
8.
Jatin Srivastava Dinesh Shukla Vishal Chand Ram Naraian Harish Chandra Anant R. Nautiyal 《洁净——土壤、空气、水》2010,38(8):771-774
The presence of arsenic (As) in water is of great public concern. Arsenic exists in three common valence states viz., As(0) metalloid arsenic, As(III) (arsenite) and As(V) (arsenate). Arsenite [As(III)] is the most toxic form among arsenicals which, predominates in anaerobic conditions, generally in flooded soils and in the water with high BOD. Experiments were conducted to investigate the effect of As(III) on the mycorrhization in vetiver (Vetiveria zizanioides (L.) Nash) grass in hydroponics. Studies showed significant alteration in the mycorrhizal colonization in the roots of vetiver exposed to higher concentrations of As(III) starting from 1.0, 2.0, 3.0, 4.0 to 5.0 mg/L prepared in 5% Hoagland nutrient solution without addition of phosphate ions. Considerable reduction in the mycorrhizal intensity (M) was observed in all the treatment sets as compared to the control suggesting a negative impact of the As(III) on the mycorrhizal association. Simultaneously, the study also showed that, As(III) is toxic to the vetiver plants having mycorrhizal association however plants with non‐mycorrhizal (cleansed) roots were found to be able to survive for a longer period exposed to As(III). 相似文献
9.
This paper deals with kinetics and equilibrium studies on the adsorption of arsenic species from simulated groundwater containing arsenic (As(III)/As(V), 1:1), Fe, and Mn in concentrations of 0.188, 2.8, and 0.6 mg/L, respectively, by Ca2+ impregnated granular activated charcoal (GAC‐Ca). Effects of agitation period and initial arsenic concentration on the removal of arsenic species have also been described. Although, most of the arsenic species are adsorbed within 10 h of agitation, equilibrium reaches after ～24 h. Amongst various kinetic models investigated, the pseudo second order model is more adequate to explain the adsorption kinetics and film diffusion is found to be the rate controlling step for the adsorption of arsenic species on GAC‐Ca. Freundlich isotherm is adequate to explain the adsorption equilibrium. However, empirical polynomial isotherm gives more accurate prediction on equilibrium specific uptakes of arsenic species. Maximum specific uptake (qmax) for the adsorption of As(T) as obtained from Langmuir isotherm is 135 µg/g. 相似文献
10.
Temporal variation of diatom benthic propagules in a monsoon-influenced tropical estuary 总被引：2，自引：0，他引：2
Temporal variations in the diatom benthic propagule (DBP) community and their role in the phytoplankton community in a monsoon-affected tropical estuary, Zuari estuary, Goa (India) are presented. The DBP from the sediments was enumerated using an extinction dilution method (most probable number method), which allows estimation of resting stages through examination of germinated vegetative cells in culture. The DBP community was dominated by planktonic species belonging to the genera Skeletonema, Fragilariopsis, Thalassiosira, and Chaetoceros. Benthic propagules (BPs) of Skeletonema costatum and Fragilariopsis sp. were dominant throughout the year. Between these two species, only S. costatum showed a linear relationship between the BP and planktonic cells, indicating that this species is particularly important in coupling of pelagic and benthic ecosystems. During the onset and restart of monsoon after an intermittent break, water column was stratified, with a low-salinity layer arising from riverine discharge and precipitation at the surface and relatively cold, saline, low-oxygen waters at the bottom. Stratification favored blooming of S. costatum and Fragilariopsis sp. in nutrient-rich surface and bottom waters, respectively. The decline in these blooms ensuing nitrate depletion and salinity change resulted in an increased abundance of BP. Chaetoceros bloom was observed during the monsoon break as well as during non-monsoon period and on both the occasions the decline in bloom was coupled with freshwater discharge. During the non-monsoon season, Thalassiosira blooms were encountered subsequent to high nitrate inputs. These findings suggest that in such shallow tropical regions, physical processes during monsoon (freshwater discharge) and non-monsoon seasons (currents, waves and tides) cause resuspension of diatom BP. Since light is not a limiting factor for germination in such regions, the blooming of resuspended BP depends on nutrient availability. 相似文献
11.
Munawar Sultana Taslin Jahan Mou Santonu Kumar Sanyal Farzana Diba Zahid Hayat Mahmud Anowar Khasru Parvez M. Anwar Hossain 《Ground water》2017,55(5):736-746
Arsenotrophic bacteria contribute to the nutrient cycling in arsenic (As) affected groundwater. This study employed a culture‐independent and ‐dependent investigation of arsenotrophic microbiomes in As affected groundwater samples collected from Madhabpur, Sonatengra, and Union Porishod in Singair Upazila, Manikganj, Bangladesh. Total As contents, detected by Atomic Absorption Spectrophotometry (AAS) of the samples, were 47 µg/L (Madhabpur, SNGW‐1), 53 µg/L (Sonatengra, SNGW‐2), and 12 µg/L (Union porishod, SNGW‐3), whereas the control well (SNGW‐4; depths >150 m) showed As content of 6 µg/L. Denaturing Gradient Gel Electrophoresis (DGGE) analysis of the amplified 16S rRNA gene from As‐affected groundwater samples revealed the dominance of aerobic bacteria Pseudomonas within heterogeneous bacterial populations. DGGE of heterotrophic enrichments supplemented with arsenite [As (III)] for 4 weeks showed the dominance of Chryseobacterium, Flavobacterium, and Aquabacterium, whereas the dominant genera in that of autotrophic enrichments were Aeromonas, Acinetobacter, and Pseudomonas. Cultured bacteria retrieved from both autotrophic and heterotrophic enrichments were distinguished into nine genotypes belonging to Chryseobacterium, Acinetobacter, Escherichia, Pseudomonas, Stenotrophomonas, Janibacter, Staphylococcus, and Bacillus. They exhibited varying range of As(III) tolerance from 4 to 27 mM. As(III) transformation potential was confirmed within the isolates with oxidation rate as high as 0.143 mM/h for Pseudomonas sp. Sn 28. The arsenotrophic microbiome specifies their potential role in groundwater As‐cycling and their genetic information provide the scientific basis for As‐bioremediation. 相似文献
12.
Radioarsenic was used to identify various chemical forms of arsenic, accumulated as arsenate from food or water, in a three-step food chain consisting of an autotroph, a grazer and a carnivore. Differential extraction procedures carried out on tissues from these organisms suggest that organic forms of arsenic in marine food webs are derived from an in vivo synthesis by primary producers and are efficiently transferred along a marine food chain. The muscle tissue of the carnivorous shrimp which represented the highest trophic level in this food chain could not itself form organic arsenic; in this case arsenate taken up from water was converted largely to arsenite. 相似文献
13.
Research interest in speciation of arsenic stems from its species dependent behavior in the environment and in living organisms. The complexity of the matrix to be analyzed and low concentrations of target arsenic species that may be labile or difficult to chromatogram, indicate that a suitable pre‐treatment methodology is required. This study investigated the usefulness of chelation solvent extraction – high performance liquid chromatography (CSE‐HPLC) for the speciation of arsenic in water. It involved reacting arsenic with the chelant known for its affinity towards arsenic, followed by extraction, separation, and identification of the arsenic‐chelant‐arsenic complex. Arsenic species having different physicochemical properties were investigated. Species, such as, As2O3, As3O5, KH2AsO4, Na2HAsO4, and NaAsO2 were detected as a group of closely eluted peaks with different retention times and spectral properties, whereas, the organic arsenic species CH3Na2AsO3, o‐arsanilic acid, roxarson and triphenyl arsine separated quite well on the EnviroseP‐CM HPLC column. Key method parameters, such as, type of HPLC column, composition of mobile phase and organic solvents affecting peak resolution and sensitivity were optimized. Real environmental matrices contaminated with arsenic were analyzed under varying wavelengths (λmax = 190, 210, 220, 234, 244, and 282 nm), with good precision. Different arsenic species were detected in these samples with excellent background and signal‐to‐noise ratios demonstrating the robustness of the method. The detection limit, reproducibility, selectivity, accuracy, and dynamic range of the calibration curves were evaluated. 相似文献
14.
Abstract The resolution of the freshwater and saline water aquifers in a coastal terrain (Mahanadi Basin, India) is updated. We analysed electrical borehole log data at four sites and compared the water resistivity regime of the freshwater and saline water zones obtained from electrical borehole logging, with the resistivity regime obtained by interpreting vertical electrical sounding (VES) data. The multilayer VES data interpretation is modified to a simple model, containing only the freshwater zone and the saline water zone. The composite geophysical parameters of the freshwater and saline water zones, in particular the resistivity and longitudinal unit conductance regime, are identified. The resolution obtained from the composite geophysical data analyses is very clear and convincing. The composite longitudinal unit conductance regime of the saline water zones is very high compared to that of the freshwater zones. This makes the identification of the two aquifers easy and increases its reliability. A technique which enables analysis of composite geophysical data of freshwater and saline water zones at VES sites in the vicinity of the borehole log sites is proposed. The significance of longitudinal unit conductance in resolving the freshwater and saline water aquifers is illustrated graphically. The proposed technique is validated by correlating the longitudinal unit conductance and resistivity with the total dissolved solids. The efficiency of the technique is validated by carrying out discriminant function analysis. Citation Hodlur, G. K., Dhakate, R., Sirisha, T. & Panaskar, D. B. (2010) Resolution of freshwater and saline water aquifers by composite geophysical data analysis methods. Hydrol. Sci. J. 55(3), 414–434. 相似文献
15.
16.
Damir Viličić Tarzan Legović Vera Žutić 《Aquatic Sciences - Research Across Boundaries》1989,51(1):31-46
We present a fine vertical distribution of physico-chemical parameters and phytoplankton density around the halocline (freshwater/seawater interface) in the Krka estuary on the East coast of the Adriatic Sea. Suspended matter, surfactant activity, surface active aggregates, particulate organic carbon and phaeophytin all show largest concentrations in the 20–50 cm thick interface layer. The highest concentration of chlorophyll-a is found on the upper boundary of the interface and it is a consequence of majority of viable freshwater phytoplankton cells that accumulate there. The phytoplankton accumulates selectively in the interface: larger size fractions accumulate faster than smaller ones. In particular, nanoplanakton accumulates the least. The visible interface is also populated by dead phytoplankton cells. Most of the freshwater phytoplankton dies and decomposes in the interface, as revealed by a small chlorophyll-a/phaeophytin ratio, and it represents the main source of surface active dissolved and particulate organic matter. Marine flagellates migrate and divide in the interface, while some species likeProrocentrum micans andSyracosphera sp. are also found in the upper freshwater layer. 相似文献
17.
Ultrahigh‐temperature (UHT) granulite facies rocks from the Achankovil Shear Zone area and the southern domain of the Madurai Granulite Block in South India contain monazite useful for in situ microprobe U–Pb dating. The UHT rocks examined consist of garnet + cordierite (retrograde) + quartz + mesoperthite + biotite + plagioclase + Fe‐Ti oxides ± orthopyroxene ± sillimanite and accessory zircon and monazite. Sillimanite occurs only as inclusions in garnet. Microstructural observations suggest garnet, orthopyroxene, spinel and mesoperthite are products of peak metamorphism. Post‐peak formation of cordierite ± orthopyroxene ± quartz and cordierite + spinel + Fe‐Ti oxides assemblages is also observed. Geothermobarometry on orthopyroxene and garnet‐orthopyroxene bearing assemblages suggest peak UHT conditions of T = 940–1040°C and P = 8.5–9.5 kbar. This was followed by a retrograde stage of 3.5–4.5 kbar and 720 ± 60°C, estimated from garnet‐cordierite assemblages. A small population of rounded, probably detrital, monazites in these rocks yield ages from Meso‐ to Neoproterozoic indicating a heterogeneous source. The youngest associated spot ages are 660–600 Ma suggesting protolith deposition up to ca 600 Ma. In contrast, the vast majority of monazites that crystallized during the latest metamorphic event show late Neoproterozoic to Cambrian ages. Probability‐density plots of monazite age data show a ‘peak’ between 533 and 565 Ma, but this peak need not reflect a particular thermal event. Collating ages from homogenous metamorphic monazites associated with minerals stable at peak P‐T conditions suggests peak metamorphism in these rocks occurred at 580–600 Ma. Together with a re‐evaluation of available data from adjacent granulite blocks in southern India, these data suggest the main metamorphic event coinciding with the suturing of India with the Gondwana amalgam probably occurred 580–600 Ma. The 500–550 Ma ages commonly reported in previous studies might represent post‐peak thermal events. 相似文献
18.
Sejuti Naha Biswas Nallamuthu Godhantaraman Ranjit K. Sarangi Bhaskar D. Bhattacharya Santosh K. Sarkar Kamala K. Satpathy 《洁净——土壤、空气、水》2013,41(4):333-339
An intense monospecies bloom of the centric diatom Hemidiscus hardmannianus (Greville) Mann. (Bacillariophyceae) occurred in the coastal waters of Sundarban mangrove wetland, India on 22 July, 2010. The species was abruptly flourished (mean density 8.86 × 106 cells/L) resulting intense green coloration of water. The greatest impoverishment of diversity and density of phytoplankton, micro‐ and mesozooplankton community was observed during the bloom. The phytoplankton community showed an extreme reduction in diversity (12 species to one) and sharp decrease in standing stock (12.84 × 103 to 8.86 × 106 cells/L) during this period. The late bloom condition coincided with sudden and huge arrival of a clupoid fish Hilsa ilisha which forms the most potential fisheries in Sundarban deltaic region. An attempt has been made to correlate the satellite remote sensing‐derived information to the bloom conditions. The MODIS‐Aqua derived chlorophyll and TMI satellite derived sea surface temperature and wind speed maps have been interpreted. 相似文献
19.
Inorganic arsenic is a carcinogen and consumption in low dose may lead to cancer. We estimated the cancer risk of the participants from arsenic endemic regions of West Bengal, India. The probable cancer risk was estimated following the assessment of daily inorganic arsenic intake through drinking water and diets of 20 participants for three consecutive years who had been using low arsenic water in the Indian context (median arsenic concentration in the study Years-I, II and III were 22, 16, 13 µg/l respectively). Probable cancer risk of the population was 2.80 × 10?4, 2.94 × 10?4, 3.12 × 10?4 in the three respective study years (Year-I, II and III); just higher than the US EPA risk level of concern. The arsenic species content of the paired raw, cooked rice and urine was estimated in the as is taken basis. The major diet component, rice contained 72–86% inorganic arsenic whereas urine contains 70% organic arsenic on an average. The cancer risk assessment has been proposed to be modified by inclusion of urine arsenic release, considering the fact of arsenic release through urine. The risk became 1.28 × 10?5, 1.13 × 10?5, 1.01 × 10?5 in the study Year-I, II and III respectively, considering urinary arsenic release, attributed the consideration of urine arsenic release into probable cancer risk estimation. 相似文献