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1.
Luminescence and ESR dating methods of quartz sediment are based on the natural resetting of the signal by light exposure (optical bleaching). When the bleaching is incomplete, a residual dose (DeR) is added to the post-depositional dose accumulated since the deposit and hence the age is overestimated.Insufficient bleaching is usually linked to the environment and conditions of transport/deposition of the quartz grains affecting the light exposure duration. Indeed, each transportation mode – fluvial, marine or aeolian – is associated to specific conditions of light exposure, depending mainly to the location of grains in the transport agent during the transport phase, the opacity of the transport environment and the velocity of the transport.The present study attempts to discriminate the modes of transport/deposition providing a satisfying reset of the ESR signals of quartz grains. For this purpose, we investigated bleaching rates and ESR residual doses of aluminum centers from “present-day” aeolian, fluvial and marine sediments sampled in various sedimentary environments. The bleaching efficiency evaluation in these different environments may help for a better understanding of the resetting phenomenon for quartz signals which represents presently the main difficulty for ESR dating.The results show that the residual doses are small enough to allow an ESR dating of the main part of the sediment transported in almost all the context examined in this study. The smallest residual doses are obtained from quartz grains within the range of 100–200 μm and transported in clear water. Some limits for the application of optically bleached quartz ESR dating appears nevertheless, mainly when the residual dose and the dose accumulated after the deposit are quite similar, i.e. for Upper Pleistocene samples.  相似文献   

2.
As part of a chronological study of the famous Upper Pleistocene Nussloch (Germany) loess sequence, three samples were collected to check the applicability of palaeodosimetric dating methods (OSL and ESR) to quartz grains. The ESR-multicentre method showed a partial bleaching of the ESR centers in aeolian sands. This partial bleaching was also observed by OSL. Laminated loess seemed to be sufficiently bleached but showed a large scatter of the doses, which we ascribed to heterogeneous responses of the luminescent grains to the SAR protocol. Ages could nevertheless be calculated for the three samples and were found to be somewhat older than the IRSL and 14C ages obtained for the same layers of the laminated loess.  相似文献   

3.
Electron spin resonance (ESR) dating of optically bleached quartz grains was performed on three sediment samples collected from the Middle Palaeolithic site of Cuesta de la Bajada (Spain). A standard multiple grain and multiple aliquot additive dose procedure was employed, and both the Al and Ti centres were measured as part of the multiple centres approach.ESR age estimates obtained for the three samples indicate that the Al centre provides a maximum possible chronology, as the Ti centres show that the Al signal was likely not systematically reset to its residual level during sediment transport. A direct comparison between ESR ages based on the Ti centres and single grain optically stimulated luminescence (OSL) ages from samples collected nearby shows broadly consistent results. The Ti-H centre also appears to provide suitable chronologies for at least two of the three Middle Pleistocene samples studied here. Surprisingly, the only sample showing consistent ESR ages between the Al and Ti centres appears to be overestimated in comparison with the Ti-centre and OSL ages derived from the other two samples. This indicates either incomplete bleaching of both the Al and Ti centres for this sample, or unexpected impacts of other sources of De uncertainty, such as multi-grain averaging effects. The ESR dating results overall indicate that the archaeological sequence of Cuesta de la Bajada CB-3 is most likely correlated to either MIS 7 or 9.  相似文献   

4.
Sediments attributed to flooding events of River Danube concerning the bleaching of the optical stimulated luminescence (OSL) signal were investigated. It is demonstrated that the OSL signal in both quartz and feldspar is not completely but differentially bleached in the sediment grains. Partial bleaching of the samples is clearly indicated by the scatter of equivalent dose determined for several individual single aliquots. It is also shown that residual ages in feldspars are significantly higher than those calculated for quartz. It is furthermore demonstrated that analysing measurement-time dependent equivalent dose estimates is not a suitable method to identify partial bleaching in the investigated sediment grains. However, the transport and deposition process of the investigated samples was probably disturbed by an artificial input of sediment, and this case study may thus not be representative of undisturbed high flood events in the past.  相似文献   

5.
The present work reports the first numerical ages obtained for the two highest fluvial terraces (Qt1 and Qt2) of the Alcanadre River system (Northeastern Spain) representing the earliest remnants of Quaternary morphosedimentary fluvial activity in the Ebro basin. ESR dating method was applied to optically bleached quartz grains and both the Al and Ti centers were measured, in accordance with the Multiple Center approach. The results are overall in good agreement with the existing preliminary chronostratigraphic framework and our interpretation indicate that terraces Qt1 and Qt2 have an ESR age of 1276 ± 104 ka and 817 ± 68 ka, respectively. These data provide some chronological insights on the beginning of the fluvial sedimentary processes in a scenario of incision maintained over Quaternary in the Ebro Basin. These are among the first numerical ages obtained for such high terraces in the Iberian Peninsula.Our results demonstrate the interest of using the Multiple Center approach in ESR dating of quartz, since the two centers provide complementary information, i.e. an independent dose control. The overall apparent consistency between the ESR age estimates and the existing preliminary chronostratigraphic framework may be considered as an empirical evidence that the Ti–Li center may actually work for Early Pleistocene deposits, whereas the Ti–H center shows some clear limitations instead. Finally, these results demonstrate the interest of using ESR method to date Early Pleistocene fluvial terraces that are usually beyond the time range covered by the OSL dating method.  相似文献   

6.
The electron spin resonance (ESR) dating of tills using germanium-doped (Ge) paramagnetic centers in quartz has advantages over other dating techniques, as quartz is common, processing is easy, and the technique has the potential for dating features several hundreds of thousands years old. ESR dating of moraines is based on the supposition that either subglacial comminution or exposure to sunlight resets the signal. However, actual dating suggests that a signal that is initially present cannot be bleached to zero by grinding alone. We found that grinding coarse samples (0.5–1 mm in diameter) to the mean grain size of fine sand (0.125–0.193 mm) reduced the signal intensity to 53–69% of its original value. From the value of the signal difference, one can devise a correction factor for ESR ages of subglacial sediment. Polymineralic grains are commonly present in till. Exposure of them to sunlight for several days can reduce the signal intensity to 7–8% of its original value within 1–2 mm thick of the sediment surface. However, within 5–8 mm of the sediment surface, exposure to sunlight for over one week only reduced the signal intensity to mean plateau values of 42–50% of the initial value. Mixing upper and lower layers of the samples during exposure to sunlight changed the signal intensity. This suggests that the amount of bleaching varies spatially. Sediments initially deposited at the margins of ice caps or ice sheets and subsequently overridden may have been sufficiently exposed to sunlight to allow ESR dating of moraines. The purity of the quartz and the grain size have significant impacts on signal intensity; intensive purification and the use of a uniform fine sand fraction are thus recommended.  相似文献   

7.
Usually, multiple-grain aliquots are used for electron spin resonance (ESR) dating of sediments. However, this approach excludes the ability of detecting insufficient bleaching, as would be the case when measuring several single aliquots or single grains. In this paper, we present preliminary results of single-grain ESR dating experiments on three different sedimentary deposits (fluvial, fluvio-aeolian and desert aeolian), ranging in age between 100 ka and 2 Ma. Titanium-related impurity centres (Ti–Li and Ti–H) were measured in a Q-band ESR spectrometer for estimating equivalent doses (De) of individual quartz grains (0.5–1 mm). Both additive and regenerative dose methods were used. The resulting De plots show a large scatter in De—from 100 Gy to more than 600 Gy—for the fluvial sample, probably reflecting different bleaching histories of the grains. On the contrary, a clear plateau can be observed in De for sands with a strong aeolian component. Preliminary single-grain ESR ages are in relatively good agreement with independent estimates, the best results being obtained for the desert aeolian sample (200 ka). It is concluded that ESR has a promising potential for estimating large naturally accumulated doses of well-bleached sediments. Nevertheless, the method is challenged by several experimental difficulties, such as long measurement times, excessive errors, and presumably a complex interrelationship between Ti–Li and Ti–H components.  相似文献   

8.
The quartz Al centre has been used in pioneering studies for ESR dating of sediments. Acceptable age estimates could be obtained for a range of deposits using this centre after estimating the residual level. To inspect the feasibility and reliability of ESR dating of windblown sediments, six loess samples from the loess–paleosol sequences of Luochuan profile on central Loess Plateau, China, were dated by ESR with regeneration method using the quartz Al centre measured at 115 K. The samples were exposed to sunlight for 430 h. Only about 25% signal intensity was bleached. According to our preliminary results, ESR age estimates increased with the depth along the loess profile, however, the ESR age of each sample is only about a half of the reference age of the corresponding strata. For example, the ESR age of a sample from the top of L8 loess near B/M boundary (a known age of 780 ka) yields an age of only 385 ka. It seems that ESR dating using quartz Al centre with dose regeneration protocol may have the potential for dating of loess and other aeolian deposits, but the studies on the nature of the quartz Al centre and experiment protocols have to be studied further.  相似文献   

9.
Little work has been undertaken on combined dating of sedimentary quartz grains using electron spin resonance (ESR) and optically stimulated luminescence (OSL) techniques in Australia. This study aims to assess the suitability of a combined ESR and OSL dating approach for establishing improved chronologies of Middle-Late Pleistocene deposits within the Naracoorte Cave Complex (NCC), South Australia. Here, we apply ESR and OSL dating in tandem to a series of samples collected from three different NCC sites: Whale Bone, Specimen and Alexandra cave. ESR quartz dating focuses on the multi-centre (MC) approach, which involves comparative evaluations of Al and Ti centre signals, while paired luminescence dating focuses on single-grain OSL analysis and includes examination of multi-grain averaging effects. The comparative ESR-OSL dating results exhibit broad agreement for deposits spanning 50–150 thousand years, with either the Ti–H or Al centre ages overlapping with paired OSL ages at 2σ in nearly all cases. MC ESR evaluations (Al v Ti–Li v Ti–H age assessments) indicate incomplete resetting of the bleachable Al centre signal for a small number of samples. Two-thirds of samples exhibit Ti–Li ages that are significantly older than corresponding Al centre ages, which is unexpected from a bleaching kinetics perspective and may indicate a broader reliability issue for Ti–Li palaeodose evaluation with these particular samples. Our findings: (i) support the applicability of both palaeodosimetric dating methods in this depositional setting; (ii) highlight the merits of applying combined ESR-OSL analyses in tandem, and; (iii) provide one of the first reliable evaluations of quartz ESR MC dating for samples with natural dose ranges as low as only a few tens of Gy. These results show that the Whale Bone, Specimen and Alexandra cave sites are temporally related and can be used to derive multi-site reconstructions of faunal assemblages and palaeoenvironmental history.  相似文献   

10.
When electron spin resonance (ESR) is applied to sedimentary quartz, dealing with the poor bleachability of the signals is particularly challenging. In this study, we used both the single-grain optically stimulated luminescence (OSL) and the single aliquot ESR dating of quartz from deep sand deposits preserving a Stone Age archaeological sequence to combine the advantages of the two methods: good bleaching behaviour and extended age range. Using the youngest samples at each sampling site we were able to calculate the mean ESR residual age from the difference between the OSL ages and the apparent ESR ages. Focusing mainly on the single aliquot regenerative dose (SAR) protocol here, we were able to calculate the mean ESR residual age for the Ti and Al centres, including the non-bleachable signal component for the latter. For the NP site, residual ages of 209 ± 13 ka and 695 ± 23 ka were calculated for the two centres, whereas for the ZS site 268 ± 39 ka and 742 ± 118 ka were determined. These residual ages are significant and cannot be neglected. Thus, the residual age was subtracted from the apparent ESR ages. The validity of the residual subtraction method was tested through a comparison of the oldest OSL age from each site with the residual subtracted ESR age. For both NP and ZS sites, the residual subtracted Ti and Al ages were consistent with the OSL age within 2-σ uncertainty, and therefore confirm the robustness of the subtraction method. Within the NP sequence, we were able to locate the end of the Early Stone Age at 590 ± 86 ka, and this provides a maximum age for the transition to the Middle Stone Age in this part of south-central Africa.  相似文献   

11.
In this study we report on optical stimulated luminescence (OSL) ages of quartz extracted from a sedimentary record in the N-Oman mountain range. Equivalent dose (DE) distributions derived from single aliquot measurements (SAR) of small aliquots (ca. 200 grains) were investigated to test whether the skewness and broadness of the dose distribution can be used as criteria for the identification of insufficient bleaching. Furthermore, the methods proposed by Lepper and McKeever [2002 An objective methodology for dose distribution analysis. Radiation Protection Dosimetry 101 (1–4), 349-352]. Singhvi [Juyal, N., Chamyal, L.S., Bhandari, S., Bushan, R., Singhvi, A.K., in press. Continental record of the southwest monsoon during the last 130 ka: evidence from the southern margin of the Thar Desert, India. Quaternary Science Review] and Fuchs and Lang [2001 Fuchs, M., Lang, A., 2001. OSL dating of coarse-grain fluvial quartz using single-aliquot protocols on sediments from NE Peloponnese, Greece. Quaternary Science Review 20, 783–787.] to derive DE's from insufficiently bleached sediments were compared. At first, the investigations were carried out on artificially bleached, irradiated and mixed quartz material from the Oman study area to simulate insufficiently bleached sediments. Then, the various statistical methods for identifying insufficient bleaching and DE derivation were applied to the natural samples from the study area, where 18 samples were measured. For the identification of insufficient bleaching the preferential parameter is the broadness of a distribution. For DE calculation, both the Singhvi method and the Fuchs and Lang method produce similar results, which are consistent with the stratigraphic order. A drawback of both methods is their sensitivity to low outliers. The Lepper and McKeever method was not applied to the natural samples, due to limitations in its application to a small number of aliquots and due to the ambiguous identification of the rising limb of the dose distributions.  相似文献   

12.
The bleaching and subsequent mortality of branching and massive corals on artificial and natural reefs in the central atolls of Maldives in 1998 are examined with respect to sea surface temperature (SST) anomalies. SST normally peaks in April-May in Maldives. The UK Meteorological Office's Global sea-Ice and SST data set version 2.3 b shows that in 1998 monthly mean SST was 1.2-4 S.D. above the 1950-1999 average during the warmest months (March-June), with the greatest anomaly in May of +2.1 degrees C. Bleaching was first reported in mid-April and was severe from late April to mid-May with some recovery evident by late-May. At least 98% of branching corals (Acroporidae, Pocilloporidae) on artificial structures deployed on a reef flat in 1990 died whereas the majority of massive corals (Poritidae, Faviidae, Agariciidae) survived the bleaching. The pre-bleaching coral community on the artificial reefs in 1994 was 95% branching corals and 5% massives (n = 1589); the post-bleaching community was 3% branching corals and 97% massives (n = 248). Significant reductions in live coral cover were seen at all natural reefs surveyed in the central atolls, with average live coral cover decreasing from about 42% to 2%, a 20-fold reduction from pre-bleaching levels. A survey of recruitment of juvenile corals to the artificial structures 10 months after the bleaching event showed that 67% of recruits (> or = 0.5 cm diameter) were acroporids and pocilloporids and 33% were from massive families (n = 202) compared to 94% and 6%, respectively, in 1990-1994 (n = 3136). Similar post-bleaching dominance of recruitment by branching corals was seen on nearby natural reef (78% acroporids and pocilloporids; 22% massives). A linear regression of April mean monthly SST against year was highly significant (p < 0.001) and suggests a rise of 0.16 degree C per decade. If this trend continues, by 2030 mean April SST in the central atolls will normally exceed the anomaly level at which corals appear there are susceptible to mass bleaching.  相似文献   

13.
The optically stimulated luminescence (OSL) signals from quartz have been widely used to estimate the equivalent dose (De) of environment radiation after the deposition of mineral grains. However, the usage of quartz is often limited due to the lower saturation behavior compared with feldspar. Saturation limits among quartz (defining the upper dating range) vary significantly. It is important to better understand the reason for various dose saturation behaviors of the quartz OSL signals. In this study, coarse quartz grains were extracted from the Taklimakan Desert and the Hunshandake sandy land in north China and the dose saturation behavior of quartz OSL signals were studied. Our results suggest that the quartz grains produce very different aliquot-specific dose response curves, showing the significant variability in dose saturation characteristics for OSL signals. Laboratory dosing, optical bleaching and heating experiments were designed to simulate their effects on the dose saturation behavior for the quartz OSL. The results demonstrate that cycles of dosing and optical bleaching have insignificant impact on the OSL dose growth curves, while the heating to high temperature (above 400 °C) can significantly change the dose saturation characteristics for the quartz OSL. Such results suggest that the different heating history of quartz might be an important factor for the variability in dose saturation characteristics for OSL signals. Additionally, the quartz grains from the Hunshandake sandy land exhibit lower dose saturation level for OSL signals, compared with that from the Taklimakan Desert. This can be explained that the quartz grains from Hunshandake sandy land are mainly of igneous origin, while the quartz grains from Taklimakan Desert are mainly of metamorphic origin.  相似文献   

14.
Optical dating of liquefied sand structures formed during major earthquakes in Upper Assam, northeast of India, has been carried out to constrain the timing of prehistoric earthquakes in this seismically active region. The bleaching of source material and of the same material during the creation of a liquefaction feature was tested using quartz extracted from 21 samples associated with two different liquefaction structures in Upper Assam. Due to the poor sensitivity of quartz from this region, a sensitisation procedure was used in our SAR protocol to reduce the scatter in optical ages. Various internal consistency tests of the measurement protocol and the excellent reproducibility of the OSL ages indicate that the dose estimates from the quartz are accurate and the optical ages reliable. The preliminary OSL ages indicate that the liquefaction features were formed between 1430 AD and 1630 AD. This study demonstrates that using OSL, ‘direct dating’ of prehistoric earthquakes may be possible, if sand blows from liquefied dykes are preserved.  相似文献   

15.
第四纪沉积物ESR年代学研究进展   总被引：6，自引：1，他引：5       下载免费PDF全文
在缺少第四纪火山活动的区域,沉积物成为第四纪地质构造和地貌、环境演化等方面研究的主要年代学测量对象.对于老于200ka的沉积物,电子自旋共振(ESR)是潜在的测量方法之一.ESR信号中心会在光晒退或热事件的作用下衰减或"回零".对于第四纪沉积物而言,在最后一次埋藏事件发生之前,只存在阳光晒退作用,因此了解各ESR信号中...  相似文献   

16.
Five Plio-Pleistocene to Holocene aeolian quartz samples from the coastal dune deposits of the Wilderness-Knysna area (South Africa) previously dated by OSL were selected for ESR dating. Samples were processed following the Multiple Centre approach and using the Multiple Aliquot Additive dose method. Aluminium (Al) and Titanium (Ti) signals were systematically measured in all samples.Our study shows that ESR results obtained for Middle Pleistocene to Holocene samples may be strongly impacted by (i) the presence of a significant high frequency noise in the ESR spectra acquired for the Ti signals and (ii) the choice of the fitting function employed. In particular, if not taken into account, very noisy spectra can lead to a significant overestimation of the true ESR intensity measured for the Ti–H signal. These sources of uncertainty are however not sufficient to remove the ESR age overestimations. Consequently, our results indicate that the Al and Ti ESR signals of these quartz samples have not been fully reset during their aeolian transport.While this work contributes to improve our understanding of the ESR method applied to quartz grains, and especially of the potential and limitations of the Ti signals, it also provides additional baseline data to illustrate the existing variability among quartz samples of different origins or sedimentary context. Our results are consistent with previous studies by confirming that the Ti–H signal shows the best potential for the evaluation of low dose values (<100 Gy for these samples), whereas it becomes inappropriate for the higher dose range, and the Ti–Li–H (option D sensu Duval and Guilarte, 2015) should be used instead.Beyond the methodological outcome, this ESR dating study also provides a useful addition to the existing chronology of the aeolian deposits in this region. In particular, new (and possibly) finite numerical age results were obtained for the two oldest samples, constraining the aeolianite landward barrier dune and the coversand formations to the MIS 10-8 and Pliocene, respectively.  相似文献   

17.
The optically stimulated luminescence (OSL) signals from quartz consist of several physically distinct components, which are commonly referred to as fast, medium and slow components. In this study, the OSL components of quartz from the Taklimakan Desert and the Hunshandake sandy land in north China are investigated. Our results show that the relative contributions of OSL components to the bulk OSL signal can be significantly different among quartz grains from both deserts. Laboratory dosing, optical bleaching and heating experiments are used to test their effects on the relative contributions of quartz OSL components. It is found that cycles of dosing and optical bleaching have insignificant impact on the relative contributions of quartz OSL components, while heating to high temperature (500 °C) can significantly enhance the contribution of the fast component to the bulk OSL signals, especially for quartz samples from the Taklimakan Desert. Such results suggest that the different heating history of natural quartz grains plays an important role in controlling OSL components. Additionally, the quartz grains from the Hunshandake sandy land can easily be distinguished from those of the Taklimakan Desert, by using a ternary plot of fast-medium-slow components. The quartz grains from the Hunshandake sandy land exhibit a much stronger fast component than those from the Taklimakan Desert. This can be explained by that the quartz grains from the Hunshandake sandy land are mainly of igneous origin, while most of the quartz grains from the Taklimakan Desert are of low grade metamorphic origin.  相似文献   

18.
《Quaternary Geochronology》2008,3(1-2):143-149
Experimental results from ESR dose recovery tests using Ti-related absorption lines in sedimentary quartz will be presented and discussed. The tests were performed on two Late Pleistocene Australian dune sands with a known burial dose based on OSL measurements. The regenerative dose technique (after thermal annealing) was used to detect any differences between ESR estimates of the natural dose, and ESR estimates of an equal laboratory gamma-dose. The studied absorption lines show consistent results with regard to the laboratory dose, but inconsistencies regarding the recovery of the natural dose. Line-shape changes between the natural and artificially induced ESR signals are a matter of concern. These changes are probably the result of the different relative abundance of Ti–H and Ti–Li centres in the naturally irradiated and artificially irradiated sample.  相似文献   

19.
Abstract Electron spin resonance (ESR) analyses of quartz grains in fault gouge were performed for a core sample taken from the Nojima Fault that moved during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake). Distribution of radiation-induced defects in the gouge at a depth of 389.4 m was measured by extracting quartz grains from seven discrete positions within 30 mm of the fault plane on the granite side. The decrease in E'1 and Al centers was observed within 2 mm of the fault plane, suggesting partial annealing due to faulting. Partial annealing even at that depth suggested that conventional ESR dating, which is based on the hypothesis of complete annealing during faulting, was not applicable. Theoretical calculations of the temperature rise and of the thermal annealing of defects have been made by assuming a simple annealing model of heat generation on the fault plane. Thermal energy was calculated to have been approximately 8 MJ/m2 to explain the profile of the heat-affected region. Thermal energy was much larger than the one estimated from hydrothermal solution, and corresponded to the frictional heat calculated for a normal stress of 20 MPa, a displacement of 2 m, and a frictional coefficient of 0.2.  相似文献   

20.
In the quest for extending the upper age limit of optically stimulated luminescence (OSL) dating of quartz, it was shown that violet stimulated luminescence (VSL) may be a promising candidate. However, difficulties in the application of the single aliquot regenerative dose (SAR) protocol for VSL has been reported in previous studies. In this study, a set of experiments was carried out to investigate the behaviour of the VSL signal under different measurement conditions with the aim to improve the SAR VSL protocol in terms of passing the procedural tests of the SAR protocol, i.e., recycling ratio, recuperation and dose recovery. The validity of an optimised SAR protocol was then evaluated on four coarse-grained quartz samples from Sardinia, for which previously reported OSL and post-IR IRSL ages are available. Our result showed that all measured aliquots meet the recuperation, recycling ratio and dose recovery criteria, indicating that the proposed protocol is suitable for the studied samples. The obtained VSL and reference ages agree within uncertainty (2σ) for most of the samples except one sample with a largest expected equivalent dose of ∼320 Gy, for which the VSL significantly (∼50%) underestimates despite satisfactory dose recovery result. This underestimation is most likely due to trapping sensitivity change between the natural and all subsequent regenerated VSL signals induced by the first preheating in the SAR procedure, which is likely dose dependent. To minimise sensitivity change, the sensitivity-corrected multiple aliquot regenerative dose (SC-MAR) protocol was applied. The SC-MAR protocol yields VSL ages in agreement with reference ages for two samples (1σ); the other two samples show overestimation. We show that the observed age overestimation can be explained by incomplete resetting of the natural signal after 7 days SOL2 exposure used for the SC-MAR procedure. Bleaching experiments confirm variable bleaching behaviour among different samples. However, it is unclear whether this different bleaching behaviour arises from measuring samples with different bleaching histories, mineralogical compositions, or VSL source trap properties.  相似文献   

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