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1.
岩石的超高压状态参数对研究地球动力学问题和岩石爆破工程问题具有十分重要的意义.本实验应用平面波炸药透镜驱动飞板撞击靶板产生超高压冲击波,并用探针测量冲击波在岩石试件中的传播速度和粒子速度,再由 Rankine-Hugoniot 方程得到岩石的密度与压力之间的关系.所研究的岩石为石灰岩和花岗岩.实验的最高压力超过70GPa.得到两种岩石的超高压状态方程是:石灰岩————=3.22+0.016p;花岗岩————=3.20+0.024p.其中的单位为 g/cm3,p 的单位为 GPa. 相似文献
2.
岩石相变关系对限定地球内部物质成分和动力学关系有着重要意义.利用光探针在14~39 GPa压力区间对热压烧结的辉长岩样品进行了冲击波加载实验.从16 GPa开始,D-u线斜率发生明显变化,说明样品内发生了相变.利用原始的Hugoniot曲线结合地震波状态方程（Seismic Equation of State）得到了Birch-Murnaghan型的等熵压缩线和相变能.结合前人的实验结果,得到了辉长岩的Grü neisen参数γ0,约为2.3.计算得到相变后的矿物集合体在零压下的密度为3.41 g·cm-3.根据以上参数分析得出,在此压力段辉长岩相变主要由长石的分解反应和石英的高压相变控制. 相似文献
3.
0.4～5.0GPa和室温～500℃下NaCl溶液的电导率 总被引：2，自引：0，他引：2
NaCl-H_2O体系是地质上最基本的二元系.对高压(>0.5 GPa)下NaCl溶液电导率测量很少.测量了0.4～5.0 GPa和室温～500℃时 0.01 mol/L NaCl溶液的电导率.结果表明,在 0.4 GPa下,0.01 mol/L NaCl溶液的电导率为 Quist和Marshall(1968)的结果吻合的较好.NaCl溶液的电导率随温度升高而增大,当压力≤1.5 GPa时,随压力升高变化很小.当压力在 1.5 GPa以上时,NaCl溶液的电导率随压力升高迅速增大.高压下电导率随压力的迅速增大可能在许多地质过程(如热液条件下的矿床形成)以及其他领域上都具有重要意义. 相似文献
4.
在密闭体系中, 400~700℃和1~3 GPa的条件下进行了褐煤加水的模拟实验, 分析了实验产物中芳烃的演化特征, 并讨论了高压高温对有机质的演化的影响. 实验结果表明, 高压抑制了液态烃的裂解, 压力升高有利于有机质降解产物的环化、聚合和芳构化; 温度升高, 芳烃的成熟度增加, 压力增加会抑制或延迟油气的生成和有机质成熟, 并且温度越低, 抑制作用越明显. 高压对有机质热演化的影响是非线性的. 该研究结果不仅加深了对俯冲带地幔有机质稳定性的认 识, 而且对认识深层油气成藏及保存也有启示意义. 相似文献
5.
大地电磁(MT)资料显示,青藏高原地壳及地幔中普遍存在着高导层.作为大陆造山带中古洋盆岩石圈残片,蛇绿岩套的电导率测量可为了解古洋盆地区地壳及地幔的电性结构提供极其有用的信息.本研究中,我们在压力为1 GPa或3 GPa下,用交流阻抗谱法测量了采自西藏南部地区的蚀变辉长岩、玄武岩、角闪橄榄岩及方辉橄榄岩四个样品的阻抗谱,并进一步得出样品的电导率,不同样品电导率与温度之间的关系满足Arrhenius关系式.在实验温度范围内,蛇绿岩套电导率的对数logσ位于-6.0~-0.5 S/m之间,且随着温度的增高,不同样品电导率增大约4~5.5个量级.样品在未脱水的情况下,低温段的活化焓变化范围在0.4~0.6 eV之间,高温段的活化焓变化范围为1.7~2.6 eV之间.同时,我们研究了样品中结构水含量及铁含量对实验电导率的影响,验证了样品电导率与铁含量之间呈正比关系.当对样品结构水含量进行归一化后,相同温度下各样品的电导率随铁含量的增加而增大,而对样品铁含量归一化后,相同温度下各样品的电导率随样品中水含量的增加而增大.将实验电导率与藏南地区大地电磁结果进行了对比,发现本研究中各样品高温段实验电导率结果均落在大地电磁结果范围内. 相似文献
6.
7.
在压力4.0到17.5GPa、温度1200℃到1400℃范围,研究了模拟地幔岩成分中的辉石-石榴子石相转变。相转变大多出现在14～16GPa压力范围,单相铝亏损的石榴子石(镁铁榴石)在16GPa压力以上变得稳定。根据本实验和其他最近实验资料计算了地幔岩的矿物组合、密度、地震波速随深度的变化。所得到的密度和地震波速度剖面在550Km深度范围和根据地震观测所建立的模型相吻合。如果证实在550km到650km之间存在有一高密度、高速度梯度带确定,则可能表明镁铁榴石有新的相转变和或存在某种程度的化学不均匀性。 相似文献
8.
《地球物理学进展》2016,(4)
弹性常数是矿物最重要的物性参数之一,它能为矿物结构的稳定性研究提供很有价值的信息,了解弹性性质与压力之间的关系是认识地球内部动力学过程及性质的基础.本文采用密度泛函理论中的PBEsol泛函对HgS同质异象体高压下的结构、弹性性质(弹性常数、零压下的体积模量及其一阶偏导)进行了研究,分析了HgS的弹性模量和焓随压强的变化情况,并据此得到相变压强.研究表明,β-HgS在约2.2~2.5 GPa时相变为α-HgS,随着压强进一步增加,α-HgS大概在12~21 GPa逐渐从辰砂结构转变为岩盐结构.通过与前人的研究结果对比发现,采用PBEsol得到的HgS晶格参数与实验值更接近,优于前人基于PBE计算的结果,但是本文基于PBEsol和前人基于PBE计算的弹性常数C_(ij),体积模量和焓与实验都存在不同程度的偏差,并且这两种泛函计算的结果之间也存在差异,这说明在实际应用中,对无法通过实验获得的高压弹性性质,最好选择不同泛函理论计算弹性常数C_(ij)、体积模量和焓并慎重分析. 相似文献
9.
应用超声波反射-透射法,在最高压力为1.0 GPa（室温）,最高温度为700℃（1.0 GPa）的条件下对新疆东准噶尔地区的卡拉麦里花岗岩带和野马泉岩体的典型花岗岩类岩石（碱长花岗岩、碱性花岗岩、花岗闪长岩、二长花岗岩和石英闪长岩）的纵波速度（VP）和横波速度（VS）进行了测量.结果显示,在常温、压力0.4~1.0 GPa条件下,东准噶尔地区花岗岩类岩石的VP和VS均随压力呈线性增加,说明在这个压力段岩石中的微裂隙已基本闭合.室温、1.0 GPa时花岗岩类岩石的VP是5.79~6.84 km·s-1,VS是3.26~3.85 km·s-1.依据压力与VP及压力与VS的线性关系,拟合得到常温常压下花岗岩类岩石的纵波和横波压力系数分别是0.1568~0.4078 km/（s·GPa）和0.0722~0.3271 km/（s·GPa）,VP0和VS0分别是5.62~6.47 km·s-1和3.15~3.75 km·s-1.恒压1.0 GPa、室温到700℃条件下,花岗岩类岩石的VP和VS均随温度的升高呈线性降低,温度系数分别为（-3.41~-4.96）×10-4 km/（s·℃）和（-0.88~-3.22）×10-4 km/（s·℃）.利用实验获得的花岗岩类岩石的VP0、VS0及温度系数和压力系数,结合东准噶尔地区的地热资料,建立了VP和VS随深度变化的剖面.将获得的VP和VS-深度剖面与该区地球物理探测结果对比,发现东准噶尔地区的碱长花岗岩、碱性花岗岩、二长花岗岩和部分花岗闪长岩的VP和VS与该区上地壳速度吻合很好,同时这几种岩石的平均泊松比也与上地壳泊松比一致,因此我们认为这几种类型的岩石是该区上地壳的重要组成部分.另外,石英闪长岩的VP和VS均符合中地壳的速度,可能为中地壳中的一种岩石. 相似文献
10.
《中国科学:地球科学》2016,(5)
同系温度为晶体材料的绝对温度(T)与其熔点(T_m)的比值,是对比晶体流变强度的重要参数之一.橄榄石(Mg,Fe)_2Si O_4的熔点随含铁量和含水量的增加而降低,随压力增加而升高,高压下橄榄石的相变可导致熔点随压力发生不连续变化.本文对前人的铁橄榄石(Fe2Si O_4)熔融实验结果进行校正,确定铁橄榄石-γ相Fe2Si O_4-熔体的三联点位于6.4GPa和1793K.然后使用广义混合律建立了常压至6.4GPa,无水橄榄石的固相线和液相线与含铁量和压力的关系.橄榄石T/T_m随深度的变化可用于定性对比具有不同热状态和橄榄石成分的上地幔流变强度,T/T_m=0.5的深度界定了上地幔从半脆性变形到完全塑性变形的转换深度.克拉通岩石圈地幔的橄榄石T/T_m显著低于造山带和伸展盆地,一直到岩石圈-软流圈边界才与周围地幔趋于一致(T/T_m0.66),表明克拉通的岩石圈强度较高.此外,使用T/T_m分析橄榄石的变形实验结果,发现含水量对橄榄石组构的影响与压力密切相关,但是水对橄榄石流变强度的弱化作用及其与橄榄石同系温度的关系尚需进一步研究.低于6.4GPa(200km),T/T_m控制了橄榄石[100]和[001]位错滑移的转变.在上地幔10~-(12)~10~-(15)s~(-1)的应变速率和低应力条件下,橄榄石[100](010)位错滑移系(A型组构)的稳定域为T/T_m0.55~0.60.T/T_m0.55~0.60时,[001]位错滑移更易于发生,低T/T_m使橄榄石的主控位错滑移系转变为[001](100),形成C型组构.这与天然变形的橄榄岩普遍发育橄榄石A型组构,而超高压变质带中经历了深俯冲的橄榄岩发育橄榄石C型组构一致.而[001](010)位错滑移系(B型组构)受T/T_m和应力的共同影响.因此,橄榄石的同系温度建立了将变形实验结果外延到上地幔流变的桥梁.克拉通地区的上地幔地震波各向异性需要一个四层模型来拟合:上层为残留的A型组构,中间为B型组构,岩石圈-软流圈边界为新生的A型或B型组构,以及Lehmann不连续面之下以扩散蠕变为主的软流圈地幔.对橄榄石组构转变机制的认识是通过地震波各向异性追踪上地幔含水量的分布和地幔流动的关键. 相似文献
11.
Large olivine samples were hot-pressed synthesized for shock wave experiments. The shock wave experiments were carried out at pressure range between 11 and 42 GPa. Shock data on olivine sample yielded a linear relationship between shock wave velocity D and particle velocity u described by D=3.56(?0.13)+2.57(?0.12)u. The shock temperature is determined by an energy relationship which is approximately 790°C at pressure 28 GPa. Due to low temperature and short experimental duration, we suggest that no phase change occurred in our sample below 30 GPa and olivine persisted well beyond its equilibrium boundary in metastable phase. The densities of metastable olivine are in agreement with the results of static compression. At the depth shallower than 410 km, the densities of metastable olivine are higher than those of the PREM model, facilitating cold slab to sink into the mantle transition zone. However, in entire mantle transition zone, the shock densities are lower than those of the PREM model, hampering cold slab to flow across the "660 km" phase boundary. 相似文献
12.
Abstract Melting experiments have been carried out on an olivine andesite of Mt Yakushi-Yama from the Miocene Setouchi volcanic belt in northeastern Shikoku, Japan. This andesite has been characterized by a low ratio of FeO*/Mg° (= 0.78). Phase relations have been determined within the pressure range of 2.8 to 19.3 kbar at 1000-1300°C under anhydrous and water-saturated conditions. At pressures less than 8.8 kbar, olivine is a liquidus phase. Orthopyroxene appears on the liquidus at 9.3 kbar under the anhydrous conditions. The multiple saturation point rises up to 17.5 kbar for water-saturated experiments. The andesite melt coexists with olivine and orthopyroxene just below the liquidus at 8.8–9.3 kbar and 1230°C for dry conditions, and at 17.5 kbar and 1060°C under water-saturated conditions. These experimental results indicate that the Yakushi-Yama olivine andesite magma could coexist with a harzburgitic mantle at depths between about 30 and 60 km, and at temperatures between 1060 and 1230°C. Experimental data also suggest a possibility that a high magnesian andesite magma would be generated by a direct partial melting of the uppermost harzburgitic mantle under anhydrous conditions. 相似文献
13.
The study of viscosity in sub-liquidus heterogeneous media, which includes kimberlite magma at the pressures and temperatures that prevail in the mantle, is an urgent task. We have conducted experiments in the serpentine–olivine, serpentine–CaCO3?olivine, and native kimberlite–olivine systems at a pressure of 4 GPa and temperatures of 1400?1600°С in a BARS high-pressure device using the technique of a falling Pt pellet. The samples were examined after experiments to find fine-grained chilled mass of crystals where the Pt pellet was observed at the time of chilling. The concentration of the solid phase was varied in the experiments between 10 and 50 wt %. We showed that when 50 wt % of olivine grains has been introduced, it was not possible to detect the motion of the Pt pellet, while when the concentration of olivine xenocrysts reached 10 wt %, the Pt pellet very rapidly descended to the bottom of the reaction volume. Viscosity was calculated using the Stokes method. We found that the viscosity of a homogeneous kimberlite melt at 4 GPa and 1600°С is below 2 Pa s, with the viscosity of a melt that contained up to 10 wt % of the solid phase being approximately constant. A kimberlite melt that contained 30 wt % of the solid phase had a viscosity on the order of 100 Pa s, while with 50 wt % of the solid phase the relative viscosity of an ultrabasic system increased to reach values over 1000 Pa s. 相似文献
14.
Olivine flow mechanisms at 8 GPa 总被引：1，自引：0，他引：1
Li Li Paul Raterron Donald WeidnerJiuhua Chen 《Physics of the Earth and Planetary Interiors》2003,138(2):113-129
The mechanisms responsible for high-temperature olivine deformation are investigated at a pressure of 8 GPa and temperatures up to 1780 K. San Carlos olivine specimens of different average grain sizes (0.5 and 5 μm) were deformed simultaneously between hard-alumina pistons during relaxation experiments. These experiments are carried out in a multi-anvil high-pressure apparatus coupled with synchrotron X-ray radiation. The different grain-size specimens experienced identical P-T-stress condition at any given time. A new method for measuring strains and strain rates (≥10−6 s−1) of specimens at high pressure is documented. This method uses time-resolved in situ X-ray imaging and an image-analysis computation. The microstructures of run products, recovered after being quenched at different temperatures were characterized by transmission electron microscopy (TEM). We find that high-temperature olivine flow is grain-size insensitive at 8 GPa, which suggests that dislocation creep dominates olivine deformation at high pressure. This result is confirmed by the TEM investigation of our deformed specimens in which we find evidences of the activation of olivine dislocation slip systems. Specimen microstructures are consistent with dynamic recrystallization as an assisting process in olivine deformation during the high-pressure experiments. Extrapolation of our results to the low stress level and large grain size expected in the mantle suggests that dislocation creep assisted by dynamic recrystallization may also dominate natural olivine deformation in the upper mantle. 相似文献
15.
The aim of this study is to compare the experimentally shock-induced features with those in naturally shocked chondrites and
to test the feasibility of experimentally calibrating naturally induced features in shocked H- and L-chondrites. Samples of
the Jilin chondrite (H5) were experimentally shock-loaded at the following peak pressures: 12, 27, 39, 53, 78, 83, 93 and
133 GPa respectively. Chondritic melts were first obtained at P>78 GPa and more than 60% melting was achieved at P~133 GPa.
No high-pressure phases were observed in any of the shocked samples, neither in the deformed nor in the molten regions. Textural
relations and mineral assemblages of the shocked samples are comparable to those encountered in the heavily shocked H-chondrite
Yanzhuang but differ considerably from those found in heavily shocked L6 chondrites. Shock melt veins in L6 chondrites contain
high-pressure polymorphs of olivine and pyroxene and high pressure liquidus phases. Scaling from shock experiments on millimeter-sized
samples to natural shock features on kilometer-sized asteroids poses considerable problems in quantifying the P-T conditions
during natural shock events on asteroids. 相似文献
16.
在温度750～1600 K和压力10～20 GPa条件下,借助于Kawai-5000多面顶砧高温高压设备,就位测量了(Mg0.9Fe0.1) SiO3 顽火辉石的电导率.实验结果显示,顽火辉石的电导率在高温区以小极化子机制为主,在低温区以质子导电为主,因为实验后的样品中有一定的水含量.另外,X射线衍射实验表明压力（20 GPa）诱发了顽火辉石向林伍德石的相变,这是我们首次在顽火辉石的电导率实验中观测到林伍德石含水相变,而且含水林伍德石的电导率与已有的实验结果相当一致. 相似文献
17.
《Acta Geochimica》2015,(1)
Carbonate melts are important active metasomatic agents and efficient transport agents; their thermodynamic properties at high temperatures and pressures are therefore of considerable interest for various geochemica applications. However, due to the extreme challenges in relevant experiments, current knowledge of even the density of carbonate melts is limited. In this study, we provide high quality volumetric data of Ca CO3-melt from firs principles at high temperatures and pressures(up to3,500 K and 60 GPa). The accuracy of these data is demonstrated through comprehensive comparison with available experimental data and a thorough discussion of the predictability of the re-scaling method proposed in this study. Based on the simulations, an equation of state has been established that is critical to relevant highly disputed questions such as the decomposition and solidification boundaries of Ca CO3 melts, the latter of which is briefly discussed in this study with a newly derived ab initio melting curve to high pressures. 相似文献
18.
Yuki Asahara Motohiko Murakami Yasuo Ohishi Naohisa Hirao Kei Hirose 《Earth and Planetary Science Letters》2010,289(3-4):479-485
We extended the pressure range of sound velocity measurements for liquid water to 25 GPa and 900 K along the melting curve using a laser heated diamond anvil cell with a combined system of Brillouin scattering and synchrotron X-ray diffraction. Experimental pressure and temperature were obtained by solving simultaneous equations: the melting curve of ice and the equation of state for gold. The sound velocities obtained in liquid water at high pressures and melting temperatures were converted to density using Murnaghan's equation of state by fitting a parameter of the pressure derivative of bulk modulus at 1 GPa. The results are in good agreement with the values predicted by a previously reported equation of state for water based on sound velocity measurements. The equation of state for water obtained in this study could be applicable to water released by dehydration reactions of dense hydrous magnesium silicate phases in cold subducting slabs at lower mantle conditions, although the validity of Murnaghan's equation of state for water should be evaluated in a wider pressure and temperature ranges. The present velocity data provides the basis for future improvement of the accurate thermodynamic model for water at high pressures. 相似文献
19.
Laboratory measurements of ‘porosity‐free’ intrinsic Vp and Vs in an olivine gabbro of the Oman ophiolite: Implication for interpretation of the seismic structure of lower oceanic crust 
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下载免费PDF全文 In order to determine ‘porosity‐free’ intrinsic ultrasonic compressional (Vp) and shear wave (Vs) velocities and Vp/Vs of an olivine gabbro from the Oman ophiolite, we developed a new experimental system using a piston‐cylinder type high‐pressure apparatus. The new system allowed us to measure velocities at pressures ranging from 0.20 to 1.00 GPa and at temperatures up to 300°C for Vp and 400°C for Vs. At room temperature, the Vp and Vp/Vs increase rapidly with pressure up to 0.40 GPa, while between 0.45 and 1.00 GPa the increase is more gradual. The change in increasing rate is attributed to closure of porosity at pressures above 0.45 GPa. Based on the linear regression of data obtained at higher pressures (0.45–1.00 GPa) and extrapolation to the lower pressures, combined with temperature derivatives of velocities of the sample measured at 1.00 GPa, we determined the intrinsic Vp and Vs of the sample as a function of pressure (P, in GPa) and temperature (T, in °C). The intrinsic velocities can be expressed as Vp (km/s) = 7.004 + 0.096 × P ? 0.00015 × T, and Vs (km/s) = 3.827 + 0.007 × P ? 0.00008 × T. We evaluated the intrinsic Vp and Vs of the olivine gabbro at oceanic crustal conditions and compared them with a velocity depth‐profile of the borehole seismic observatory WP‐2 area in the northwestern Pacific Basin. Although the intrinsic Vp (～7.0 km/s) and Vs (～3.8 km/s) for the olivine gabbro studied are comparable to those of seismic layer 3 in the WP‐2 area, the estimated vertical gradients of intrinsic velocities are significantly smaller than those reported from layer 3. These results suggest that velocity profiles of layer 3 in the WP‐2 area may reflect the presence of a minor porosity in lower oceanic crust, which closes with increasing depth and/or continuous changes in mineralogy of layer 3 rocks. 相似文献
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High-pressure polymorphs of olivine and enstatite are major constituent minerals in the mantle transition zone(MTZ).The phase transformations of olivine and enstatite at pressure and temperature conditions corresponding to the lower part of the MTZ are import for understanding the nature of the 660 km seismic discontinuity.In this study,we determine phase transformations of olivine(MgSi2O4) and enstatite(MgSiO3) systematiclly at pressures between 21.3 and 24.4 GPa and at a constant temperature of 1600℃.The most profound discrepancy between olivine and enstatite phase transformation is the occurency of perovskite.In the olivine system,the post-spinel transformation occures at 23.8 GPa,corresponding to a depth of 660 km.In contrast,perovskite appears at 23 GPa(640 km) in the enstatite system.The ~1 GPa gap could explain the uplifting and/or splitting of the 660 km seismic discountinuity under eastern China. 相似文献