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1.
The large differences in He and Ar diffusivities in silicate minerals could result in fractionation of the He/Ar ratio during melting of the mantle, producing He/Ar ratios in the primary mantle melts that are higher than those of the bulk mantle. Modeling noble gas diffusion out of the bulk mantle into fast diffusion pathways (such as fractures or melt channels) suggests that significant (order of magnitude) He/Ar fractionation will occur if the fast diffusion channels are spaced several meters apart and the noble gas residence in these diffusion channels is of the order days to weeks. In addition, the 15% difference in 3He and 4He diffusivities could also produce isotopic fractionation between the melt and its solid source. Modeling the behavior of He and Ar during melting shows that small increases (few %) in 3He/4He should be correlated with larger variations (factor of 5) in 4He/40Ar. However, in order to test this hypothesis the effects of subsequent He–Ar fractionation that occur during degassing have to be corrected. I describe a scheme that can separate He/Ar variations in the primary melt from overprinted fractionation during magmatic degassing. Using the degassing-corrected data, there is a correlation between the primary melt’s 4He/40Ar and 3He/4He in mid-ocean ridge basalts (MORBs). The slope of the correlation is consistent with the models of preferential diffusion of 3He relative to 4He and of 4He relative to 40Ar from the solid mantle into the melt. Diffusive fractionation of noble gases during melting of the mantle can also account for low 4He/40Ar ratios commonly found in residual mantle xenoliths: preferential diffusion of He relative to Ar will produce some regions of the mantle with low 4He/40Ar, the complement of the high 4He/40Ar ratios in basalts. Diffusive fractionation cannot, however, account for differences between the He and Ne isotopic compositions of MORBs compared with ocean island basalts (OIBs); not only are the extremely high 3He/4He ratios of OIBs (up to 50 Ra) difficult to produce at reasonable mantle time and lengthscales, but also the Ne isotopic compositions of MORBs and OIBs do not lie on a single mass fractionation line, therefore cannot result from diffusive fractionation of a single mantle Ne source. If preferential diffusion of He from the solid mantle into primary melts is a significant process during generation of MORBs, then it is difficult to constrain the He concentration of the mantle: He concentrations in basalts and the He flux to the ocean essentially result from extraction of He from a larger (and unknown) volume of mantle than that that produced the basalts themselves. The He concentration of the mantle cannot be constrained until more accurate estimates of the diffusion contribution are available.  相似文献   

2.
Primordial neon,helium, and hydrogen in oceanic basalts   总被引：3，自引：0，他引：3  
A primordial neon component in neon from Kilauea Volcano and deep-sea tholeiite glass has been identified by the presence of excess20Ne; relative to atmospheric neon the20Ne enrichments are 5.4% in Kilauea neon and about 2.5% in the basalts. The20Ne anomalies are associated with high3He/4He ratios; the ratio in Kilauea helium is 15 times the atmospheric ratio, while mid-ocean ridge basalts from the Atlantic, Pacific, and Red Sea have uniform ratios about 10 times atmospheric. Mantle neon and helium are quite different in isotopic composition from crustal gases, which are highly enriched in radiogenic21Ne and4He. The21Ne/4He ratios in crustal gases are consistent with calculated values based on G. Wetherill's18O (α,n) reaction; the lack of20Ne enrichment in these gases shows that the mantle20Ne anomalies are not radiogenic.21Ne enrichments in Kilauea neon and “high-3He” Pacific tholeiites are much less than in crustal neon, about 2 ± 2% vs. present atmospheric neon, as expected from the much lower4He/Ne ratios.Neon concentrations in two Atlantic tholeiites were found to be only 1–2% of the values obtained by Dymond and Hogan; helium concentrations are slightly greater and our He/Ne ratios are greater by a factor of 150. The large Ne excess relative to solar wind and meteoritic gases is thus not confirmed. Pacific and Atlantic basalts appear to be quite different in He/Ne ratios however, and He and Ne may be inversely correlated. He concentration variations due to diffusive loss can be distinguished from variations due to two-phase partitioning or mantle heterogeneity by the effects on3He/4He ratios. The He isotopic and concentration measurements on “low-3He” basalts are consistent with diffusive loss and dilution of the 3/4 ratio by in-situ radiogenic4He, and may provide a method for dating basalt glasses.Deuterium/hydrogen ratios in Atlantic and Pacific tholeiite glasses are 77% lower than the ratio in seawater. The inverse correlation between deuterium and water content observed by Friedman in erupting Kilauea basalts is consistent with a Rayleigh separation process in which magmatic water is separated from an initial melt with the same D/H ratio as observed in deep-sea tholeiites. The consistency of the D/H ratios in tholeiites containing primordial He and Ne components indicates that these ratios are probably characteristic of primordial or juvenile hydrogen in the mantle.  相似文献   

3.
Helium isotope compositions of the mantle xenoliths and megacrysts in the Cenozoic basalts in the eastern China were measured. The samples were collected from Ludao of Heilongjiang, Huinan and Jiaohe of Jilin, Kuandian of Liaoning, Hannuoba of Hebei, Nüshan of Anhui, Dingan of Hainan. The3He/4He ratios of the mantle xenoliths and megacrysts from the most areas were about 1 × 10-5, and were similar to those of the MORB, thus reflecting the characteristics of the MORB-typed depleted mantle. The3He/4He ratios of the mantle xenoliths from Jiaohe were 4.8×10-6 and the3He/4He ratios of xenoliths from Hannuoba vary from 0.15× 10-6 to 7.4 ×10-6, obviously lower than those of the MORB, and even lower than the atmospheric helium isotope ratios, indicating that the continental mantle was strongly replaced in Jiaohe and Hannuoba areas. The helium isotope compositions of the mantle xenoliths and megacrysts in the same region vary in a very wide range. It is inferred that the mantle xenoliths and megacrysts were from different parts of the continental mantle. There were not necessary origin relations between the mantle xenoliths, megacrysts and their host basalts. An extremely high3He/4He ratio of garnet megacryst from Hannuoba, Hebei was found.  相似文献   

4.
A key requirement for any model of mantle evolution is accounting for the high 3He/4He ratios of many ocean island basalts compared to those of mid-ocean ridge basalts. The early, popular paradigm of primitive, undegassed mantle stored in a convectively isolated lower mantle is incompatible with geophysical constraints that imply whole mantle convection. Thus it has been suggested more recently that domains with high 3He/U ratios have been created continuously from the bulk mantle throughout Earth history. Such models require that the 3He/4He ratio of the convecting mantle was at least as high as the highest values seen in OIB at the time the OIB source was generated. These domains must also be created with sufficient He to impart distinctive He isotopic signatures to ocean island basalts. However, the He isotope evolution of the mantle has not been consistently quantified to determine if such scenarios are plausible.

Here a simple model of the He evolution of the whole mantle is examined. Using a wide range of possible histories of continental extraction and He degassing, the bulk convecting mantle was found to have had 3He/4He ratios as high as those seen in the Iceland hotspot only prior to 3 Ga. Such high 3He/4He ratios can only be preserved if located in domains that are not modified by convective mixing or diffusive homogenisation since that time. Further, there are difficulties in producing, with commonly invoked magmatic processes, domains with sufficiently high 3He/U ratios and enough 3He to be able to impart this signature to ocean island basalts. The results are consistent with models that store such He signatures in the core or a deep layer in the mantle, but are hard to reconcile with models that continuously generate high 3He/4He domains within the mantle.  相似文献   


5.
西藏日喀则地区蛇绿岩的氦同位素研究   总被引：4，自引：0，他引：4       下载免费PDF全文
测定了日喀则地区蛇绿岩组合岩石的稀有气体同位素组成。白朗的玄武岩具有比较均一的He同位素组成 ,3He/ 4He平均值为 5 35 9Ra;变橄岩的He同位素比值范围为 1 10 4～ 3 384Ra,平均为 2 383Ra;从东部的仁布和大竹到西部的下鲁和白朗 ,辉绿岩的3He/ 4He由低变高。采于吉定的新鲜辉绿岩平均高达 31 5 7Ra,该值接近于在夏威夷发现的高比值。分步加热法结果显示高R值的He是在低温步释放的 ,根据这种高R值的He可以推测雅鲁藏布江蛇绿岩的成因环境有地幔柱的作用 ,该构造带很可能出现过裂谷洋盆或未能发育成熟的深大裂谷带  相似文献   

6.
Neon isotopic ratios measured in olivine and basaltic glass from Iceland are the most primitive observed so far in terrestrial mantle-derived samples. Ratios were measured in gas released from olivine and basaltic glass from a total of 10 samples from the Reykjanes Peninsula, Iceland, and one sample from central Iceland. The neon isotopic ratios include solar-like, mid-ocean ridge basalt (MORB)-like and atmospheric compositions. Neon isotopic ratios near the air–solar mixing line were obtained from the total gas released from glass separates from five samples. MORB-like neon isotopic compositions were measured in the total gas released from olivine and glass separates from four samples. Although there is clear evidence for a solar neon component in some of the Icelandic samples, there is no corresponding evidence for a solar helium ratio (320Ra>3He/4He>100Ra). Instead, 3He/4He ratios are mainly between 12±2(Ra) and 29±3(Ra), similar to the range observed in ocean island basalts, indicating that the He–Ne isotopic systematics are decoupled. The mantle source of Icelandic basalts is interpreted to be highly heterogeneous on a local scale to explain the range in observed helium and neon isotopic ratios. The identification of solar-like neon isotopic ratios in some Icelandic samples implies that solar neon trapped within the Earth has remained virtually unchanged over the past 4.5 Ga. Such preservation requires a source with a high [Nesolar]/[U+Th] ratio so that the concentration of solar neon overwhelms the nucleogenic 21Ne* produced from the decay of U and Th in the mantle over time. High [Nesolar]/[U+Th] ratios are unlikely to be preserved in the mantle if it has experienced substantial melting. An essentially undegassed primitive mantle component is postulated to be the host of the solar neon in the Icelandic plume source. Relatively small amounts of this primitive mantle component are likely to mix with more depleted and degassed mantle such that the primitive mantle composition is not evident in other isotopic systems (e.g. strontium and neodymium). The lower mantle plume source is inferred to be relatively heterogeneous owing to being more viscous and less well stirred than the upper mantle. This discovery of near-solar neon isotopic ratios suggests that relatively primitive mantle may be preserved in the Icelandic plume source.  相似文献   

7.
High 4He/3He ratios of 100 000 to 160 000 found at HIMU ocean islands (“high μ,” where μ is the U/Pb ratio) are usually attributed to the presence of recycled oceanic crust in the HIMU mantle source. However, significantly higher 4He/3He ratios are expected in recycled crust after residence in the mantle for periods greater than 1 Ga. In order to better understand the helium isotopic signatures in HIMU basalts, we have measured helium and neon isotopic compositions in a suite of geochemically well-characterized basalts from the Cook–Austral Islands. We observe 4He/3He ratios ranging from 56 000 to 141 000, suggesting the involvement of mantle reservoirs both more and less radiogenic than the mantle source for mid-ocean ridge basalts (MORBs). In addition, we find that the neon isotopic compositions of HIMU lavas extend from the MORB range to compositions less nucleogenic than MORBs. The Cook-Austral HIMU He–Ne isotopic compositions, along with Sr, Nd, Pb, and Os isotopic compositions, indicate that in addition to recycled crust, a relatively undegassed mantle end-member (e.g., FOZO) is involved in the genesis of these basalts. The association of relatively undegassed mantle material with recycled crust provides an explanation for the close geographical association between HIMU lavas and EM (enriched mantle)-type lavas from this island chain: EM-type signatures represent a higher mixing proportion of relatively undegassed mantle material. Mixing between recycled material and relatively undegassed mantle material may be a natural result of entrainment processes and convective stirring in deep mantle.  相似文献   

8.
The ophiolites from the Yarlung Zangbo River (Tibet),Southwestern China,were analysed for the con-tents of helium and neon and their isotopic compositions by stepwise heating. The serpentinites from Bainang showed a high 3He/4He value of 32.66Ra (Ra is referred to the 3He/4He ratio in the present air) in 700 ℃ fraction. At lower temperature,all of the dolerites displayed as very high 3He/4He ratios as ones investigated for hotspots. It was clear that the high 3He/4He ratio was one of immanent characterics in the magma source formed the dolerites,suggesting that there was a large amount of deep mantle fluids in these rocks. In the three-isotope diagram of neon,the data points from the ophiolites of the Yarlung Zangbo River were arranged along the Loihi Line. This is in agreement with the characteristics of he-lium isotopes,revealing that the high-3He plume from deep mantle had played an important role in the formation of the Neo-Tethyan Ocean. The helium isotopic compositions in the basalts were far higher than atomospheric value but lower than the average value of MORB,although there were various de-grees of alteration. The possible reasons were that basaltic magmas  相似文献   

9.
Picrites from the 61 million year old Vaigat Formation of the Nuussuaq Peninsula in West Greenland have 3He/4He ratios trapped in olivine phenocrysts which range up to 30 times the atmospheric ratio. These high values, measured during gas extraction by crushing in vacuum, are similar to the highest magmatic 3He/4He ratios found in young terrestrial volcanic rocks. By analogy with young basalts, in which crushing selectively extracts magmatic helium, any significant cosmogenic 3He appears to be absent in these picrites. Additional evidence for the absence of cosmogenic helium is provided by fusion results on the crushed olivine powders and by a single stepwise crushing experiment, in which only magmatic and radiogenic helium components are resolvable. The West Greenland picrites have Pb, Nd and Sr isotope compositions which overlap those found in picrites from Iceland and in basalts from Loihi Seamount, localities which today also have high 3He/4He ratios. Isotopic variations in He, Pb, Nd and Sr for the West Greenland picrites are interpreted to largely result from interaction of the early Iceland mantle plume with the upper mantle during plume ascent and dispersion beneath the continental lithosphere. The presence of high 3He/4He ratios in West Greenland, and the onset of magmatism across the North Atlantic Volcanic Province near 62 Ma, supports the hypothesis for very rapid dispersion (>1 m/year) of mantle plume head material during the earliest stages of plume impact, as predicted in recent numerical simulations of plume behavior during thermal mantle convection with non-Newtonian rheology.  相似文献   

10.
The geochemical characteristics of mildly alkalic basalts (24–25 Ma) erupted in the southeastern Kerguelen Archipelago are considered to represent the best estimate for the composition of the enriched Kerguelen plume end-member. A recent study of picrites and high-MgO basalts from this part of the archipelago highlighted the Pb and Hf isotopic variations and suggested the presence of mantle heterogeneities within the Kerguelen plume itself. We present new helium and neon isotopic compositions for olivines from these picrites and high-MgO basalts (6–17 wt.% MgO) both to constrain the enriched composition of the Kerguelen plume and to determine the origin of isotopic heterogeneities involved in the genesis of Kerguelen plume-related basalts. The olivine phenocrysts have extremely variable 4He / 3He compositions between MORB and primitive values observed in OIB (∼90,000 to 40,000; i.e., R / Ra ∼8 to 18) and they show primitive neon isotopic ratios (average 21Ne / 21Neext ∼0.044). The neon isotopic systematics and the 4He / 3He ratios that are lower than MORB values for the Kerguelen basalts clearly suggest that the Kerguelen hotspot belongs to the family of primitive hotspots, such as Iceland and Hawaii. The rare gas signature for the Kerguelen samples, intermediate between MORB and solar, is apparently inconsistent with mixing of a primitive component with a MORB-like source, but may result from sampling a heterogeneous part of the mantle with solar 3He / 22Ne and with a higher (U, Th) / 3He ratio compared to typically high R / Ra hotspot basalts such as those from Iceland and Hawaii.  相似文献   

11.
In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10−10 to 2.5×10−7 ccSTP/g by crushing and from 5.4×10−8 to 2.4×10−7 ccSTP/g by melting. 3He/4He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated 20Ne/22Ne and 21Ne/22Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric 20Ne/22Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/3He ratio of these crustal gabbros will generate very radiogenic 4He/3He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.  相似文献   

12.
Abstract Isotopic compositions of He, Ne and Ar were measured on Plio–Quaternary alkaline basalts of Marib–Sirwah and Shuqra volcanic fields in Yemen, south-western Arabian Peninsula. Very high 3He/4He isotope ratios were found in olivine phenocrysts of some Quaternary alkaline basalts in both volcanic fields, located on the margin of the dispersed Afar mantle plume, compared with the Afar–Ethiopian province in the center of the mantle plume. This suggests that the Afar mantle plume source may consist of common component (C or focal zone (FOZO)) with variable primordial 3He/4He ratio rather than high μ mantle (HIMU) component. The three component mixing C as the Afar mantle plume, depleted mantle (DM) as upper mantle and lithospheric mantle with a hybrid enriched mantle I–II (EM I–EM II) characteristics may be adequate to explain He–Sr–Nd–Pb isotope variation for the Afar–Arabian Cenozoic volcanics. The occurrence of high 3He/4He ratios in the Marib–Sirwah volcanic field appears to show that the primitive basaltic magma, derived from the margin of the dispersed trous-like Afar mantle plume during 15–0 Ma, was not by contamination of lithospheric and upper mantle materials in comparison with that from the center of the Afar mantle plume as a result of relatively low thermal anomaly.  相似文献   

13.
Helium (He) and Argon (Ar) isotopic compositions of the Tertiary basic igneous rocks were determined by the high temperature melting extraction method. The selected samples for the studies included al-kaline basalts and diabases from the Jiyang basin,and the surrounding Shanwang and Qixia outcrops in the Shandong Peninsula,eastern China. The results show that the Paleogene basalts and diabases from the Jiyang basin yielded a wide range of P4 PHe abundance of (73.70-804.16)×10 P-8 Pcm P3 P STP·g P-1 P,with P3 PHe/ P4 PHe ratios of 0.374-2.959 Ra,which was lower than the MORB but evidently higher than the con-tinental crust value. The Neogene alkaline basalts from the Jiyang basin,Shanwang and Qixia outcrops have variable P4 PHe abundances ((42.34-286.72)×10-8 Pcm P3 P STP·g-1 P),and "continental crust-like" P3 PHe/ P4 PHe ratios (0.013-0.074 Ra). All of them contain atmospheric-like P40 PAr/ P36 PAr ratio (395.4-1312.7),reflecting the mantle sources with air components. Their low P3 PHe/ P4 PHe ratios are interpreted as the enrichment of the radiogenic P4 PHe mainly inherited from the mantle. He and Ar systematics show the mixing of MORB-type,air and a P4 PHe enriched member in the mantle source,suggesting that these igneous rocks originated from the depleted asthenospheric mantle mixed with an EMI component. Therefore,the present He and Ar isotopes do not support the viewpoints that the Cenozoic igneous rocks of Eastern North China were the products of mantle plume(s) activities.  相似文献   

14.
Helium, volatile fluxes and the development of continental crust   总被引：5，自引：0，他引：5  
Mantle-derived helium has a substantial primordial component and is readily distinguished from radiogenic “crustal” He by its isotopic composition. For some years it has been known to be escaping at mid-ocean ridges and more recently it has been shown to be escaping through the continental lithosphere in tectonically active areas, particularly those undergoing extension or volcanism. The C/3He value observed in ocean ridge basalts and continental gases that contain only mantle He, is close to 109. This is believed to be a typical value for the upper mantle. Other continental gases have ratios that vary widely and are diluted with crustal carbon. The ratio C/4He decreases with time through the production of radiogenic4He, and depends on the C/(U + Th) value. Departures from the average may result from exceptional concentrations of U and Th or from C/He fractionation.There is circumstantial evidence for a steady-state flux of He through the continents that may be estimated from He accumulations in lakes and aquifers. The mantle component of such fluxes is calculated from their3He content. If the mantle component is accompanied by C in the proportion indicated above, and extensional areas make up as little as 10% of the crust at any one time, then about 10% of the present inventory of crustal C would have been added to the crust every Ga by this means. C/K values for the crust and mantle are today very similar, and K may therefore scale as C. K/U and K/Th vary within narrow limits and they may scale with C also.The most plausible means of scavenging He from the mantle is by partial melting: He is expected to enter the first few percent of liquid formed, and the loss of mantle He and C at the surface is associated with the emplacement of basaltic bodies in the lower crust carrying K, U and Th. Some limits are placed on the thickness of basalt added in extensional areas.Mantle-derived CO2 has often been invoked as a means of dehydrating continental crust to produce granulites. However, the amounts of CO2, estimated from mantle He fluxes, entering the crust in those active tectonic areas studied so far appears too small to produce dehydration on a regional scale. The addition of mantle-derived material to the crust in extensional zones is a first-order crustal growth process the importance of which has previously been underestimated.  相似文献   

15.
Helium trapped in the chilled glass rims of Pacific Ocean basalts is highly enriched in 3He; the 3He/4He and 3He/Ne ratios are respectively 10 and 1000 times the atmospheric ratios. We interpret these large enrichments as further evidence that primordial 3He is still present in the interior of the earth. The 3He/4He ratio in basalt glass is the same as the isotope ratio of the “excess helium” in Pacific Ocean deep water, supporting the theory that the atmospheric escape rate of 3He is balanced by a flux of primordial 3He from the mantle.  相似文献   

16.
The distribution and isotopic composition of helium has been measured in a suite of well-characterized one-carat diamonds from the Orapa kimberlite, Botswana. Crushing of the diamonds in vacuo indicates that most of the helium is contained by the matrix (generally greater than 90%), rather than by the inclusions. Step-heating experiments, performed on inclusion-free fragments remaining after crushing, indicate that the3He/4He ratio is variablewithin individual diamonds. The fragments, as small as 10 mg, were heated in two timed steps, both at 2000°C. In every case, lower3He/4He ratios are observed in the first graphitization step (0.05–3 × atmospheric), while the last heating step releases helium with systematically higher3He/4He ratio (30–80 × atmospheric). We suggest that this internal isotopic variability is the result of stepwise graphitization: the first heating step initiates graphitization, which nucleates around defects, and the second heating step graphitizes the relatively defect-free regions of the diamond. The3He/4He ratio measured, using the partial graphitization technique, differs by up to a factor of 100 within a single specimen. The inclusion-free fragments release small quantities of helium below 2000°C, which suggests that helium release is obtained only by graphitization. The3He contents of the monocrystalline diamonds are relatively constant (at 3 × 10−13 cm3 STP/gram) and indicate that most of the isotopic variability is due to radiogenic4He. The variations in4He content are either related to zoning of Th and U in the diamonds (i.e., in-situ decay), to zoning of inherited4He, or to implantation of α-particles from a Th and U rich environment (i.e., kimberlite). Because the Orapa diamonds were mined from roughly 40 m depth in the kimberlite, spallation reactions from cosmic ray interactions are not a significant source of3He. However, calculations based on the age of the kimberlite (90 m.y.) and reasonable Th and U abundances suggest that most of the3He in the Orapa diamonds could be produced by6Li(n, α)T in the diamond. Although this may not be true of all diamonds, nuclear reactions in the crust and mantle (including spallation reactions at the surface) can explain many of the high3He/4He ratios previously reported for diamonds.  相似文献   

17.
Geothermal gases from submarine and subaerial hot springs in Ensenada, Baja California Norte, Mexico, were sampled for determination of gas chemistry and helium, nitrogen and stable carbon isotope composition. The submarine hot spring gas is primarily nitrogen (56.1% by volume) and methane (43.5% by volume), whereas nearby subaerial hot spring gases are predominantly nitrogen (95–99% by volume). The N2/Ar ratios and σ 15N values of the subaerial hot spring gas indicate that it is atmospheric air, depleted in oxygen and enriched in helium. The submarine hot spring gas is most probably derived from marine sediments of Cretaceous age rich in organic matter. CH4 is a major component of the gas mixture (σ 13C = −44.05%0), with only minor amounts of CO2 (σ13C= −10.46%0). The σ15N of N2 is + 0.2%0 with a very high N2/Ar ratio of 160. The calculated isotopic equilibra tion temperature for CH4---CO2 carbon exchange at depth in the Punta Banda submarine geothermal field is approximately 200°C in agreement with other geothermometry estimates. The 3He/4He ratios of the hot spring gases range from 0.3 to 0.6 times the atmospheric ratio, indicating that helium is predominantly derived from the radioactive decay of U and Th within the continental crust. Thus, not all submarine hydrothermal systems are effective vehicles for mantle degassing of primordial helium.  相似文献   

18.
Helium isotopic ratios ranging from 20 to 32 times the atmospheric 3He/4He(RA) have been observed in a suite of 15 basaltic glasses from the Loihi Seamount. These ratios, which are up to four times higher than those of MORB glasses and more than twice those of nearby Kilauea, are strongly suggestive of a primitive source of volatiles supplying this volcanism. The Loihi glasses measured span a broad compositional range, and the 3He/4He ratios were found to be generally lower for the alkali basalts than for the tholeiites. The component with a lower 3He/4He ratio appears to be associated with olivine xenocrysts, within which fluid inclusions are probably the carrier of contaminant helium. One Loihi sample has a much lower isotopic ratio (<5 RA), but a combination of low He concentration, high vesicularity, and presence of cracks lined with clay minerals suggests that the low ratio is due to gas loss and contamination by atmospheric helium.Crushing and melting experiments show that for modest vesicularities (<5% by volume) the Loihi glasses obey a MORB-type partitioning trend, but at higher vesicularities the data show considerably more scatter due to volatile mobilization. The high vesicularities, low extrusion pressure and generally low helium concentrations are consistent with a considerable degree of degassing. Analyses of dunites, plus a correlation between total helium concentrations with xenocryst abundances also suggest that xenocrysts are a significant carrier of contaminating (low 3He/4He) helium.3He/4He ratios from samples of other Hawaiian volcanoes (Kilauea, Mauna Loa, Hualalai, and Mauna Kea) show a smooth decrease in 3He/4He with increasing volcano age and volume. We interpret this to be a synoptic picture of the time evolution of a hot-spot diapir: the earliest stage is characterized by primitive (> 30 RA) helium with some (variable) component of lithospheric contamination added during “breakthrough”, while the later stages are characterized by a relaxation toward lithospheric 3He/4He ratios (～ 8 RA) due to isolation of the diapir from the mantle below (as the plate moves on), and subsequent mining of the inherited helium and contamination from the surrounding lithosphere. The abrupt contrast in 3He/4He ratios between Kilauea and Loihi, despite their close proximity, is indicative of the small lateral extent of the plume.  相似文献   

19.
We report isotope analyses of helium, neon, argon, and xenon using different extraction techniques such as stepwise dynamic and static crushing, and high-resolution stepwise heating of three mantle xenoliths from Réunion Island. He and Ne isotopic compositions were similar to previously reported Réunion data, yielding a more radiogenic composition when compared to the Hawaiian or Icelandic mantle plume sources. We furthermore observed correlated 129Xe/130Xe and 136Xe/130Xe ratios following the mantle trend with maximum values of 6.93 ± 0.14 and 2.36 ± 0.06, respectively. High-resolution argon analyses resulted in maximum 40Ar/36Ar ratios of 9000–11,000, in agreement with maximum values obtained in previous studies. We observed a well-defined hyperbolic mixing curve between an atmospheric and a mantle component in a diagram of 40Ar/36Ar vs. 20Ne/22Ne. Using a mantle 20Ne/22Ne of 12.5 (Ne–B) a consistent 40Ar/36Ar value of 11,053 ± 220 in sample ILR 84-4 was obtained, whereas extrapolations to a higher mantle 20Ne/22Ne ratio of 13.8 (solar wind) would lead to a much higher 40Ar/36Ar ratio of 75,000, far above observed maximum values. This favours a mantle 20Ne/22Ne of about 12.5 considered to be equivalent to Ne–B. Extrapolated and estimated 40Ar/36Ar ratios of the Réunion, Iceland, Loihi, and MORB mantle sources, respectively, tend to be linearly correlated with air corrected 21Ne/22Ne and show the same systematic sequence of increasing relative contributions in radiogenic isotopes (Iceland–Loihi–Réunion–MORB) as observed for 4He/3He. In general, He–Ne–Ar isotope systematics of the oceanic mantle can be explained by following processes: (i) different degree of mixing between pure radiogenic and pure primordial isotopes generating the MORB and primitive plume (Loihi-type) endmembers; (ii) relatively recent fractionation of He relative to Ne and Ar, in one or both endmembers; (iii) after the primary fractionation event, different degrees of mixing between melts or fluids of MORB and primitive plume affinity generate the variety of observed OIB data, also on a local scale; (iv) very late-stage secondary fractionation during magma ascent and magma degassing leads to further strong variation in He/Ne and He/Ar ratios.  相似文献   

20.
This study presents new major and trace element, mineral, and Sr, Nd, and noble gas isotope geochemical analyses of basalts, gabbro, and clinopyroxenite from the Mariana Arc (Central Islands and Southern Seamount provinces) including the forearc, and the Mariana Trough (Central Graben and Spreading Ridge). Mantle source compositions beneath the Mariana Arc and the Mariana Trough indicate a mantle source that is depleted in high field strength elements relative to MORB (mid‐oceanic ridge basalt). Samples from the Mariana Arc, characterized by high ratios of Ba/Th, U/Th, 84Kr/4He and 132Xe/4He, are explained by addition of fluid from the subducted slab to the mantle wedge. Correlations of noble gas data, as well as large ion lithophile elements, indicate that heavy noble gases (Ar, Kr, and Xe) provide evidence for fluid fluxing into the mantle wedge. On the other hand, major elements and Sr, Nd, He, and Ne isotopic data of basalts from the Mariana Trough are geochemically indistinguishable from MORB. Correlations of 3He/4He and 40Ar/36Ar in the Mariana Trough samples are explained by mixing between MORB and atmosphere. One sample from the Central Graben indicates extreme enrichment in 20Ne/22Ne and 21Ne/22Ne, suggesting incorporation of solar‐type Ne in the magma source. Excess 129Xe is also observed in this sample suggesting primordial noble gases in the mantle source. The Mariana Trough basalts indicate that both fluid and sediment components contributed to the basalts, with slab‐derived fluids dominating beneath the Spreading Ridge, and that sediment melts, characterized by high La/Sm and relatively low U/Th and Zr/Nb, dominate in the source region of basalts from the Central Graben.  相似文献   

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