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1.
The usefulness of the apparent redox potential discontinuity (aRPD) in assessments of marine benthic habitat quality was explored at two intertidal mudflats along the north Pacific coast of Canada. Two transects were established at each intertidal site, with three sediment biogeochemistry cores collected from each transect four times over the summer of 2016. Measurements of the sediment pore water dissolved oxygen (DO) content and redox (Eh) conditions were taken at the surface of the core (measured vertically), as well as at increasing depths (1 cm between readings) into the sediment (measured horizontally through predrilled holes in the biogeochemistry corer). While oxic, anoxic, oxidized, and reduced sediment pore water was observed above and below the aRPD, in general, sediment above the aRPD had higher DO content, and higher Eh values than sediment below the aRPD. Therefore, the aRPD depth can be used as a relative indicator of sediment pore water DO and Eh conditions: sediment with a deeper aRPD depth has more available DO, and the pore water has higher Eh values (more oxidized or less reduced) than sediment with a shallower aRPD depth. As such, the aRPD depth is a useful parameter to include in models that assess the quality of marine benthic habitats.  相似文献   

2.
As global temperatures increase and dissolved oxygen(DO) content decreases in marine systems, indices assessing sediment DO content in benthic habitats are becoming increasingly useful. One such measure is the depth to the apparent redox potential discontinuity(aRPD), a transition of sediment color that serves as a relative measure of sediment DO content. We examined spatiotemporal variation of aRPD depth, and the nature of the relationships between aRPD depth and biotic(infauna and epibenthic predators) and abiotic variables(sediment properties), as well as the availability of resources(chlorophyll a concentration, and organic matter content) in the intertidal mudflats of the Bay of Fundy, Canada. aRPD depth varied significantly through space and time, and a combination of biotic(sessile and errant infauna, as well as epibenthic predators), and abiotic(exposure time of a plot, sediment particle size,penetrability, and water content) variables, as well as the availability of resources(sediment organic matter content, and chlorophyll a concentration) were correlated with aRPD depth. As such, knowledge of both biotic and abiotic variables are required for a holistic understanding of sediment DO conditions.Abiotic variables likely dictate a suite of potential aRPD depth conditions, while biota and resource availability, via bioturbation and respiration, strongly influence the observed aRPD depth. As DO conditions in marine systems will continue to change due to global climate change, elucidating these relationships are a key first step in predicting the influence decreasing DO content may have upon marine benthos.  相似文献   

3.
不同溶解氧水平下湖泊底泥-水界面磷交换影响因素分析   总被引：15，自引：2，他引：13  
龚春生  范成新 《湖泊科学》2010,22(3):430-436
在实验室控制条件下,研究了玄武湖底泥在饱和溶解氧、75%、50%、25%、0%溶解氧水平下底泥-水界面磷交换,探讨了溶解氧对底泥-水界面磷交换的影响途径.结果表明:(1)上覆水溶解氧与玄武湖底泥溶解性磷酸盐、溶解性总磷释放速率呈开口向上的抛物线关系;(2)上覆水溶解氧水平可以决定磷在底泥-水界面交换中的转换方向,而且还影响间隙水中溶解氧扩散深度,25%、50%、75%和饱和溶解氧水平下溶解氧最大扩散深度分别为0.974cm、1.377cm、1.687cm和1.948cm,溶解氧在间隙水中最大扩散深度影响底泥-水界面的磷交换;(3)溶解氧可通过影响底泥-水界面处电位、藻类聚磷作用以及pH来影响底泥-水界面的磷交换.  相似文献   

4.
天山天池水体季节性分层特征   总被引：4，自引：1，他引：3  
王斌  马健  王银亚  尹湘江 《湖泊科学》2015,27(6):1197-1204
于2014年6-10月,对高山深水湖泊天山天池水温、电导率、溶解氧、p H值、叶绿素a浓度和蓝绿藻细胞密度进行垂直剖面的连续监测,通过对其季节动态和垂直分层结构的分析,探讨天池水体季节性分层特征.天池出现明显水温分层的时间短(6-9月),夏季温跃层变化范围为2~18 m,而秋季温跃层不断下移,10月在18 m水深以下;受水温分层影响,天池水体溶解氧浓度、电导率、p H值、叶绿素a浓度和蓝绿藻细胞密度在垂直剖面表现出明显的季节性分层,尤其是夏季水温分层影响溶解氧浓度、叶绿素a浓度和蓝绿藻细胞密度在水体中的分布,对天池水质变化产生重要影响.天池浅水层(水深小于10 m)溶解氧浓度较高(大于8 mg/L),而深水层(水深超过18 m)溶解氧浓度9月接近4 mg/L,季节性缺氧导致底泥营养盐向上扩散,对水体水质产生不利影响.所以,应在夏、秋季节加强水质监测,以防止天池水华发生;天池叶绿素a浓度与蓝绿藻细胞密度的垂直剖面变化趋势相似,均随水深增加呈先增加后减小的趋势,但叶绿素a浓度在2~12 m水深处较高,蓝绿藻细胞密度在5~15 m水深处较高,表明5~15 m深度适合藻类生长,同时,电导率、p H值的垂直变化也说明藻类的生长情况,这为监测天池水体富营养化取样和分析提供依据.  相似文献   

5.
Dissolved oxygen (DO) plays a critical role in the development of the juvenile stages of benthic spawning fish and salmonids in particular. Factors influencing the DO regime within spawning gravels include the accumulation of fine sediment, penetration of groundwater or surface water into the gravels, thermal regime, and the consumption of oxygen by sediment and its associated organic fractions. In this field study, we quantify the DO regime within an artificial salmon redd at high temporal resolution. The environment within the redd is shown to be complex, with large variations in DO. Application of a numerical model (SIDO‐UK) enables for the first time, the quantification of the relative contributions to DO consumption from thermal regime, sediment accumulation and sediment oxygen demand. Sediment accumulation is shown to have a minor impact on DO in the redd whereas upwelling groundwater is identified as the most likely cause of the major changes in DO. Bed mobility has a minor impact on DO regime of the redd. The effects of fine sediment and oxygen supply on salmon embryo survival are estimated. Implications for river catchment management and prospects for future research are discussed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
Two types of river sediments with contrasting characteristics (anoxic or oxic) were resuspended and the release of heavy metals and changes in water chemistry were investigated. During resuspension of the anoxic sediment, the dissolved oxygen (DO) concentration and redox potential of the water layer decreased abruptly within the first 1 min, followed by increases toward the end of the resuspension period. Heavy metals were released rapidly in the first 6 h, probably due to the oxidation of acid volatile sulfide (AVS) of the anoxic sediment, and then the aqueous phase concentrations of the heavy metals decreased due to resorption onto the sediment until the 12‐h point. During resuspension of the oxic sediment, the DO concentration and redox potential remained relatively constant in the oxic ranges. The heavy metals were released from the oxic sediment gradually during a 24‐h resuspension period. The temporal maximum concentrations of Ni, Cu, Zn, and Cd in the aqueous phases in both experiments frequently exceeded the USEPA water quality criteria or the water quality guidelines of Australia and New Zealand. This suggests that a resuspension event could bring about temporal water quality deterioration in the two sediment environments.  相似文献   

7.
潘红玺 《湖泊科学》1990,2(2):53-60
本文是对横断山地区17个湖泊水体中溶解氧含迸的测定。其平均含货在5.86~8.35mg/L之间，最大含里可达14.54mg/L。湖泊中溶解氧含量在地域分布上随箝海拔高度升高而下降。由于受湖泊中水体运动影响，湖泊表层水中溶解氧分布较一致，但在深水湖泊中表层和底层含量即有明显差异，且随着水深加大溶解氧下降，如马湖，在水深l00m以下为无氧区，致使生物大量死亡。在深水层的温跃层附近（10—50m）溶解氧出现跃变现象。此外，湖泊中水生生物分布，以及有机质污染，对水体中溶解氧含量和分布亦有直接影响。  相似文献   

8.
为探究深水湖库溶解氧的时空分布规律及其主控因素,本文以南方亚热带大型深水湖库——江西省仙女湖为研究对象,基于2008—2021年仙女湖4个国控站点溶解氧的历史数据分析其年际变化的规律及原因;另于2016年水污染事件发生前(2014年5月—2015年4月)及水污染事件结束后(2018年1月—2018年12月)对仙女湖进行加密逐月监测,采用结构方程模型(SEM)分析仙女湖溶解氧的主要驱动因素。研究结果表明,2008—2021年仙女湖水体溶解氧浓度先下降后上升,变化范围为5.1～18.7 mg/L,季节均值为春季>冬季>秋季>夏季。水污染事件发生前高溶解氧区域多出现在舞龙湖湖心区及湖出口位置,水温、叶绿素a浓度和浊度是溶解氧浓度变化的主要驱动因素;水污染事件结束后高溶解氧区域多出现在钤阳湖及舞龙湖枝杈状湖湾位置,叶绿素a浓度及营养盐浓度成为溶解氧浓度变化的主要驱动因素;而pH与溶解氧主要是协同变化的关系。根据对仙女湖最深点(江口)的垂向监测结果,溶解氧的垂向差异为夏季>秋季>春季>冬季,夏、秋季在5 m以下出现低溶解氧(DO<5 mg/L)区域,且夏...  相似文献   

9.
The duration of the soil‐depth recovery needed for reoccurrence of shallow colluvial landslides at a given site in humid regions is much longer than the return period of rainfall needed to generate sufficient pore water pressure to initiate a landslide. Knowledge of the rate of change in soil depth in landslide scars is therefore necessary to evaluate return intervals of landslides. Spatial variation in sediment transport at the Kumanodaira landslide scar in central Japan was investigated by field observations. Spatial distribution of the rate of change in soil depth was estimated using sediment transport data and geographic information system (GIS) analysis. Observations revealed that the timing of sediment transport differed for shallow and deep soil layers. Near‐surface sediment transport (mostly dry ravel and some shallow soil creep at depths ≤0·05 m) measured in sediment traps was active in winter and early spring and was affected by freezing–thawing; soil creep of subsoil (i.e. >0·05 m), monitored by strain probes, was active in summer and autumn when precipitation was abundant. Near‐surface sediment flux was estimated by a power law function of slope gradient. Deeper soil creep was more affected by relative location to the landslide scar, which influences soil depth, than by slope gradient. Our study indicated that the rate of soil‐depth recovery is high just below the head scarp of the landslide. Abrupt changes in the longitudinal slope topography immediately above, within and just below the head scarp became smoother with time due to degradation proximate to the landslide head scarp and flanks, as well as aggradation just below the head scarp. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
The biogeochemistry of methane in the sediments of Lake Caviahue was examined by geochemical analysis, microbial activity assays and isotopic analysis. The pH in the water column was 2.6 and increased up to a pH of 6 in the deeper sediment pore waters. The carbon isotope composition of CH4 was between − 65 and − 70‰ which is indicative for the biological origin of the methane. The enrichment factor ε increased from − 46‰ in the upper sediment column to more than − 80 in the deeper sediment section suggesting a transition from acetoclastic methanogenesis to CO2 reduction with depth. In the most acidic surface layer of the sediment (pH < 4) methanogenesis is inhibited as suggested by a linear CH4 concentration profile, activity assays and MPN analysis. The CH4 activity assays and the CH4 profile indicate that methanogenesis in the sediment of Lake Caviahue was active below 40 cm depth. At that depth the pH was above 4 and sulfate reduction was sulfate limited. Methane was diffusing with a flux of 0.9 mmol m− 2 d− 1 to the sediment surface where it was probably oxidized. Methanogenesis contributed little to the sediments carbon budget and had no significant impact on lake water quality. The high biomass content of the sediment, which was probably caused by the last eruption of Copahue Volcano, supported high rates of sulfate reduction which probably raised the pH and created favorable conditions for methanogens in deeper sediment layers.  相似文献   

11.
苏正  陈多福 《地球物理学报》2007,50(5):1518-1526
除合适的温度和压力条件外，甲烷水合物的形成还需要有充足的甲烷供给，沉积物孔隙水中的甲烷浓度必须大于甲烷水合物的溶解度.本文建立了水合物－水－游离气三相体系、水合物－水二相体系、气－水二相体系的甲烷溶解度计算优选方法，计算确定了水合物系统的甲烷溶解度-深度相图，依此划分出游离气、溶解气、水-水合物、水-水合物-游离气四个甲烷不同相态分布区.对水合物脊ODP1249和1250钻位、布莱克海台ODP997钻位稳定带甲烷水合物含量和稳定带之下游离气含量进行了计算.ODP1249浅部13.5～72.4 mbsf(mbsf表示海底以下深度)的甲烷水合物是沉积物孔隙体积的10%～61%，ODP1250钻位35～1065 mbsf的甲烷水合物约为孔隙体积的0.7%～1.9%，水合物层之下游离气层厚约22 m，游离气含量约占孔隙的4%.布莱克海台ODP997钻位的浅部146.9 mbsf处无水合物发育，202.4～433.3 mbsf之间水合物占孔隙体积的约5%～7%，水合物层之下游离气层厚约80 m，游离甲烷含量为孔隙的0.2%～28%.  相似文献   

12.
The artificial reservoir Lagoa da Pampulha in central Brazil has been increasingly affected by sediment deposition and pollution from urban and industrial sources. This study investigates water chemistry and heavy metal concentrations and their fractionation in the lake sediment using ICP-OES, ICP-MS, and XRD analyses. Fractionation analysis was done by sequential extraction under inert gas as well as after oxidation. The lake exhibits a permanent stratification with an oxygen-free hypolimnion below 2 m depth. Nutrient concentrations are enriched for phosphorous components (SRP, PO4). In the sediment it was not possible to detect oxygen. Carbon, sulfur, and most of the analyzed heavy metals are enriched in the top sediment layer with a pronounced downward decrease, indicating the presence of an anthropogenic influence. Statistical analysis, including correlations and a Principal Component Analysis (PCA) of depth-related total concentration data, helps to distinguish presumably anthropogenic heavy metals from geogenic components. Some samples with high element concentrations in the sediment also show elevated concentrations in their pore water. Analyses of element distribution between sediment and pore water suggest a strong bonding of heavy metals to the anoxic sediment. The trend towards elevated solubility in the pore water of oxidized samples is clear for most of the analyzed elements. Fractionation analysis reveals characteristic associations of selected elements to specific mineral bonding forms. In addition, it indicates that the behavior of heavy metals in the sediment is strongly influenced by organic substances. These substances provide buffering against oxidation, acidification, and metal release. The high nutrient loading causes reducing conditions in the lake sediment. These conditions trigger the accumulation of sediments rich in S2−, which stabilizes the fixation of heavy elements. In the future, care must be taken to reduce the supply of contaminants and to prevent the release of heavy metals from sediments dredged for remediation purposes.  相似文献   

13.
Interstitial waters were extracted from cores at three locations in the eastern equatorial Pacific and analyzed for nutrients, dissolved carbonate species, Mn and Fe. From the depth variation in pore water chemistry, we infer that organic matter oxidation reactions occur with depth in the following sequence: O2 reduction, NO3? and MnO2 reduction, and then ferric iron reduction. From NO3? results we infer that O2 is largely or totally consumed within the top few centimeters of sediment. NO3? is completely reduced at a sediment depth of 20 cm at a site near the crest of the East Pacific Rise, but is preserved at levels of 20–30 μmol/kg at 40 cm depth at a Guatemala Basin site.We have calculated the alkalinity for pore water samples assuming ions diffuse according to relative ionic diffusion coefficients, that the stoichiometry of organic matter oxidation reactions is that of “Redfield” organic matter, and that the pore waters are saturated throughout with respect to CaCO3. The measured alkalinity increase is only about half of the predicted value. The difference is probably a result of either enhanced mixing of the pore water in the top few centimeters of sediments by biological or physical processes, or the occurrence of an inorganic reaction which consumes alkalinity.At depths of oxygen and nitrate reduction in the sediments, the ion concentration product of CaCO3 is the same, within the analytical error, as the solubility product of Ingle et al. [34] at 1 atm and 4°C. This result indicates CaCO3 resaturation on pressure change during coring. Where pore water Mn concentrations become measurable, the ion concentration product increases, indicating either supersaturation with respect to calcite or that another phase is controlling the carbonate solubility.  相似文献   

14.
Mineralization of 14C‐radiolabled vinyl chloride ([1,2‐14C] VC) and cis‐dichloroethene ([1,2‐14C] cis‐DCE) under hypoxic (initial dissolved oxygen (DO) concentrations about 0.1 mg/L) and nominally anoxic (DO minimum detection limit = 0.01 mg/L) was examined in chloroethene‐exposed sediments from two groundwater and two surface water sites. The results show significant VC and dichloroethene (DCE) mineralization under hypoxic conditions. All the sample treatments exhibited pseudo‐first‐order kinetics for DCE and VC mineralization over an extended range of substrate concentrations. First‐order rates for VC mineralization were approximately 1 to 2 orders of magnitude higher in hypoxic groundwater sediment treatments and at least three times higher in hypoxic surface water sediment treatments than in the respective anoxic treatments. For VC, oxygen‐linked processes accounted for 65 to 85% of mineralization at DO concentrations below 0.1 mg/L, and 14CO2 was the only degradation product observed in VC treatments under hypoxic conditions. Because the lower detection limit for DO concentrations measured in the field is typically 0.1 to 0.5 mg/L, these results indicate that oxygen‐linked VC and DCE biodegradation can be significant under field conditions that appear anoxic. Furthermore, because rates of VC mineralization exceeded rates of DCE mineralization under hypoxic conditions, DCE accumulation without concomitant accumulation of VC may not be evidence of a DCE degradative “stall” in chloroethene plumes. Significantly, mineralization of VC above the level that could reasonably be attributed to residual DO contamination was also observed in several nominally anoxic (DO minimum detection limit = 0.01 mg/L) microcosm treatments.  相似文献   

15.
选取贵州红枫湖为研究对象,在实验室条件下模拟了自然、好氧和厌氧条件下沉积物内源磷的释放过程,联合应用微电极技术和沉积物磷形态分析对沉积物—水界面开展了微尺度观测与研究.结果表明,厌氧条件下红枫湖沉积物总磷含量显著降低,且主要是NaOH提取态磷(NaOH-P)和残渣态磷(rest-P)含量降低所致,厌氧条件下沉积物孔隙水中磷酸盐浓度明显升高,而好氧条件下沉积物孔隙水磷酸盐浓度显著降低,反映厌氧条件显著促进了红枫湖沉积物磷释放.厌氧条件下沉积物内部溶解氧浓度下降、硫还原活动增强可能是导致NaOH-P释放的主要原因.O_2浓度的降低加速了沉积物还原作用并产生大量H2S,进而与二价铁离子形成硫化亚铁沉淀,最终导致NaOH-P(Fe-P)释放到孔隙水中.好氧条件向厌氧条件的转换可通过改变沉积物内部pH值分布和微生物活动促使rest-P释放:厌氧条件下,厌氧微生物不仅可以消耗硫酸根产生H_2S,导致pH值降低,还可消耗有机质,将有机磷转变为无机磷.上述研究结果表明,沉积物—水界面氧化还原环境可影响沉积物氧渗透深度、pH值分布、微生物活动、硫循环以及有机质降解过程,进而控制沉积物磷的形态转化与释放.联合应用微电极技术和沉积物磷形态分析对湖泊沉积物—水界面开展微尺度观测研究是揭示沉积物内源磷释放机制与控制因素的有效途径.  相似文献   

16.
Total mercury (Hg) and methylmercury (MeHg) were analyzed in near surface sediments (0-2 cm) and biota (zooplankton, macro-invertebrates, finfish) collected from Narragansett Bay (Rhode Island/Massachusetts, USA) and adjacent embayments and tidal rivers. Spatial patterns in sediment contamination were governed by the high affinity of Hg for total organic carbon (TOC). Sediment MeHg and percent MeHg were also inversely related to summer bottom water dissolved oxygen (DO) concentrations, presumably due to the increased activity of methylating bacteria. For biota, Hg accumulation was influenced by inter-specific habitat preferences and trophic structure, and sediments with high TOC and percent silt-clay composition limited mercury bioavailability. Moreover, hypoxic bottom water limited Hg bioaccumulation, which is possibly mediated by a reduction in biotic foraging, and thus, dietary uptake of mercury. Finally, most biota demonstrated a significant positive relationship between tissue and TOC-normalized sediment Hg, but relationships were much weaker or absent for sediment MeHg. These results have important implications for the utility of estuarine biota as subjects for mercury monitoring programs.  相似文献   

17.
This paper presents a novel triple‐layer model, called VART DO‐3L, for simulation of spatial variations in dissolved oxygen (DO) in fine‐grained streams, characterized by a fluid mud (fluff or flocculent) layer (an advection‐dominated storage zone) as the interface between overlying stream water and relatively consolidated streambed sediment (a diffusion‐dominated storage zone). A global sensitivity analysis is conducted to investigate the sensitivity of VART DO‐3L model input parameters. Results of the sensitivity analysis indicate that the most sensitive parameter is the relative size of the advection‐dominated storage zones (As/A), followed by a lumped reaction term (R) for the flocculent layer, biological reaction rate (μo) in diffusive layer and biochemical oxygen demand concentration (L) in water column. In order to address uncertainty in model input parameters, Monte Carlo simulations are performed to sample parameter values and to produce various parameter combinations or cases. The VART DO‐3L model is applied to the Lower Amite River in Louisiana, USA, to simulate vertical and longitudinal variations in DO under the cases. In terms of longitudinal variation, the DO level decreases from 7.9 mg l at the Denham Springs station to about 2.89 mg l?1 at the Port Vincent station. In terms of vertical variation, the DO level drops rapidly from the overlying water column to the advection‐dominated storage zone and further to the diffusive layer. The DO level (CF) in the advective layer (flocculent layer) can reach as high as 40% of DO concentration (C) in the water column. The VART DO‐3L model may be applied to similar rivers for simulation of spatial variations in DO level. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

18.
The aim of this contribution is to combine statistical methodologies to geographically classify homogeneous groups of water quality monitoring sites based on similarities in the temporal dynamics of the dissolved oxygen (DO) concentration, in order to obtain accurate forecasts of this quality variable. Our methodology intends to classify the water quality monitoring sites into spatial homogeneous groups, based on the DO concentration, which has been selected and considered relevant to characterize the water quality. We apply clustering techniques based on Kullback Information, measures that are obtained in the state space modelling process. For each homogeneous group of water quality monitoring sites we model the DO concentration using linear and state space models, which incorporate tendency and seasonality components in different ways. Both approaches are compared by the mean squared error (MSE) of forecasts.  相似文献   

19.
Pore water testing and analysis: the good,the bad,and the ugly   总被引：8，自引：0，他引：8  
The increasingly common practice of collecting and assessing sediment pore water as a primary measure of sediment quality is reviewed. Good features of this practice include: pore water is a key exposure route for some organisms associated with sediments; pore water testing eliminates particle size effects; pore water analyses and tests can provide useful information regarding contamination and pollution. Bad features include: pore water is not the only exposure route; pore water tests lack chemical or biological realism: their "sensitivity" relative to other tests may be meaningless due to manipulation and laboratory artifacts; many sediment and surface dwelling organisms are not directly influenced by pore water. Bad features can become ugly if: other exposure pathways are not considered (for toxicity or bioaccumulation); manipulation techniques are not appropriate; pore water tests are inappropriately linked to population-level effects. Pore water testing and analyses can be effective tools provided their limitations are well understood by researchers and managers.  相似文献   

20.
This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins.  相似文献   

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