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In this work, the treatment of photographic processing wastewaters (PPW) by electro‐Fenton process has been investigated. The Influence of operating conditions on kinetics and efficiency of electro‐Fenton process has been evaluated using carbon felt cathode and platinium (Pt) or boron‐doped diamond (BDD) anode. The results of electro‐Fenton treatment of PPW have shown that nearly complete removal of total phenols was obtained for all combinations with pseudo‐first rate constants of 0.07, 0.012, and 0.018/min for carbon felt/Pt, carbon felt/BDD and Pt/BDD cathode/anode combinations, respectively. The combination of carbon felt cathode with BDD anode achieved the highest total organic carbon (TOC) removal of 90%, while it did not exeed 40% for carbon felt/Pt combination. Increasing current intensity and Fe2+ dose enhances the efficiency of electro‐Fenton process. However, increasing pH decreases TOC removal during the treatment of PPW by electro‐Fenton process. The highest efficiency of electro‐Fenton process using BDD anode can be explained by the contribution of direct and indirect oxidation routes in the degradation mechanism of organics including (i) oxidation via hydroxyl radicals generated from the catalytic decomposition of H2O2 and from water discharge on BDD anode, (ii) direct oxidation of certain organic compounds on BDD anode, and (iii) mediated oxidation with inorganic oxidants electrogenerated from anodic oxidation of supporting salts. 相似文献
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The effect of extraordinary degradation of phenol organics on the SnO2‐Sb2O3/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO2/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO2‐Sb2O3/Ti was superior to that of the PbO2/Ti electrode. At the same time, the SnO2‐Sb2O3/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb2O3 layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO2 part. 相似文献
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Kazuhiko Yamada 《地震工程与结构动力学》2000,29(4):545-554
A simple non‐linear control law is proposed for reducing structural responses against seismic excitations. This law defines control force dynamics by one differential equation involving a non‐linear term that restrains the control force amplitude. If non‐linearity is neglected, the control force becomes the force in a Maxwell element, so it is called the non‐linear‐Maxwell‐element‐type (NMW) control force. The NMW control force vs. deformation relation plots hysteretic curves. The basic performance of an SDOF model with the NMW control force is examined for various conditions by numerical analyses. Furthermore, the control law is extended to fit an MDOF structural model, and an application example is shown. The computational results show that the NMW control force efficiently reduces structural responses. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
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Major earthquakes (i.e., mainshocks) typically trigger a sequence of lower magnitude events clustered both in time and space. Recent advances of seismic hazard analysis stochastically model aftershock occurrence (given the main event) as a nonhomogeneous Poisson process with rate that decays in time as a negative power law. Risk management in the post‐event emergency phase has to deal with this short‐term seismicity. In fact, because the structural systems of interest might have suffered some damage in the mainshock, possibly worsened by damaging aftershocks, the failure risk may be large until the intensity of the sequence reduces or the structure is repaired. At the state‐of‐the‐art, the quantitative assessment of aftershock risk is aimed at building tagging, that is, to regulate occupancy. The study, on the basis of age‐dependent stochastic processes, derived closed‐form approximations for the aftershock reliability of simple nonevolutionary elastic‐perfectly‐plastic damage‐cumulating systems, conditional on different information about the structure. Results show that, in the case hypotheses apply, the developed models may represent a basis for handy tools enabling risk‐informed tagging by stakeholders and decision makers. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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The phase‐shift‐plus‐interpolation and extended‐split‐step‐Fourier methods are wavefield‐continuation algorithms for seismic migration imaging. These two methods can be applied to regions with complex geological structures. Based on their unified separable formulas, we show that these two methods have the same kinematic characteristics by using the theory of pseudodifferential operators. Numerical tests on a Marmousi model demonstrate this conclusion. Another important aspect of these two methods is the selection of reference velocities and we explore the influence of the selection of reference velocities by comparing the geometric progression method and the statistical method. We show that the geometric progression method is simple but does not take into account the velocity distribution while the statistical approach is relatively complex but reflects the velocity distribution. 相似文献
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Ji Feng Guimin An Biaohua Chen Yingxia Li Kunlun Ding Yun Xie Zhimin Liu 《洁净——土壤、空气、水》2009,37(7):527-533
Ti‐SBA‐15 materials with Ti incorporated into the framework of SBA‐15 and controllable Ti contents were successfully prepared via a post‐treatment route in supercritical CO2‐ethanol solution, followed by calcination. The resultant Ti‐SBA‐15 materials were characterized by means of different techniques including X‐ray diffraction, X‐ray photoelectron spectroscopy, transmission electron microscopy, IR analysis, and N2 sorption analysis. It was demonstrated that the resultant materials retained a structure similar to that of the parent SBA‐15, and Ti was incorporated into the framework of SBA‐15. At high Ti content, i.e, Si/Ti = 5:1, a TiO2 phase formed and was coated onto the inner surface of SBA‐15 in addition to the incorporation of the Ti in the framework. The BET surface areas of the Ti‐SBA‐15 samples decreased with increasing Ti content. The presence of small amounts of H2O in the reaction medium may have resulted in some TiO2 nanoparticles being uniformly distributed in the pores of the SBA‐15 accompanying the incorporation of Ti in the SBA‐15 framework. 相似文献
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It is important to include the viscous effect in seismic numerical modelling and seismic migration due to the ubiquitous viscosity in an actual subsurface medium. Prestack reverse‐time migration (RTM) is currently one of the most accurate methods for seismic imaging. One of the key steps of RTM is wavefield forward and backward extrapolation and how to solve the wave equation fast and accurately is the essence of this process. In this paper, we apply the time‐space domain dispersion‐relation‐based finite‐difference (FD) method for visco‐acoustic wave numerical modelling. Dispersion analysis and numerical modelling results demonstrate that the time‐space domain FD method has great accuracy and can effectively suppress numerical dispersion. Also, we use the time‐space domain FD method to solve the visco‐acoustic wave equation in wavefield extrapolation of RTM and apply the source‐normalized cross‐correlation imaging condition in migration. Improved imaging has been obtained in both synthetic and real data tests. The migration result of the visco‐acoustic wave RTM is clearer and more accurate than that of acoustic wave RTM. In addition, in the process of wavefield forward and backward extrapolation, we adopt adaptive variable‐length spatial operators to compute spatial derivatives to significantly decrease computing costs without reducing the accuracy of the numerical solution. 相似文献
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Using a large set of rainfall–runoff data from 234 watersheds in the USA, a catchment area‐based evaluation of the modified version of the Mishra and Singh (2002a) model was performed. The model is based on the Soil Conservation Service Curve Number (SCS‐CN) methodology and incorporates the antecedent moisture in computation of direct surface runoff. Comparison with the existing SCS‐CN method showed that the modified version performed better than did the existing one on the data of all seven area‐based groups of watersheds ranging from 0·01 to 310·3 km2. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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Hussein O. Okail P. Benson Shing William M. McGinley Richard E. Klingner Seongwoo Jo David I. McLean 《地震工程与结构动力学》2011,40(5):509-530
This paper presents the findings of shaking‐table experiments conducted to examine the seismic performance of a full‐scale, one‐story, wood‐framed structure with masonry veneer. The structure was designed and constructed in accordance with current U.S. code provisions. The veneer was attached to the wood backing with two kinds of metal anchors, corrugated ties fastened with 8d nails and rigid ties fastened with #8 screws. The tests have shown that the use of nails to fasten veneer anchors to the wood studs is highly unreliable due to the high variation of the nail extraction capacity, which can be influenced by the moisture content of the wood. Other than this, both the wood frame and the masonry veneer performed well under severe ground motions far exceeding a design level earthquake for Seismic Design Category D. Good performance was observed for the rigid veneer ties, which were attached to the wood studs with screws. The results have shown that the veneer walls parallel to the direction of shaking helped to restrain the motion of the wood structure and therefore should not be simply treated as added mass. The detailing of wood roof diaphragms requires special attention in consideration of the out‐of‐plane inertia force of the veneer that can be transmitted through the top plate of the wood‐stud wall to the rim joist. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Reliable estimation of the volume and timing of snowmelt runoff is vital for water supply and flood forecasting in snow‐dominated regions. Snowmelt is often simulated using temperature‐index (TI) models due to their applicability in data‐sparse environments. Previous research has shown that a modified‐TI model, which uses a radiation‐derived proxy temperature instead of air temperature as its surrogate for available energy, can produce more accurate snow‐covered area (SCA) maps than a traditional TI model. However, it is unclear whether the improved SCA maps are associated with improved snow water equivalent (SWE) estimation across the watershed or improved snowmelt‐derived streamflow simulation. This paper evaluates whether a modified‐TI model produces better streamflow estimates than a TI model when they are used within a fully distributed hydrologic model. It further evaluates the performance of the two models when they are calibrated using either point SWE measurements or SCA maps. The Senator Beck Basin in Colorado is used as the study site because its surface is largely bedrock, which reduces the role of infiltration and emphasizes the role of the SWE pattern on streamflow generation. Streamflow is simulated using both models for 6 years. The modified‐TI model produces more accurate streamflow estimates (including flow volume and peak flow rate) than the TI model, likely because the modified‐TI model better reproduces the SWE pattern across the watershed. Both models also produce better performance when calibrated with SCA maps instead of point SWE data, likely because the SCA maps better constrain the space‐time pattern of SWE. 相似文献
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Paul Sava 《Geophysical Prospecting》2015,63(5):1086-1096
Waveform inversion is a velocity‐model‐building technique based on full waveforms as the input and seismic wavefields as the information carrier. Conventional waveform inversion is implemented in the data domain. However, similar techniques referred to as image‐domain wavefield tomography can be formulated in the image domain and use a seismic image as the input and seismic wavefields as the information carrier. The objective function for the image‐domain approach is designed to optimize the coherency of reflections in extended common‐image gathers. The function applies a penalty operator to the gathers, thus highlighting image inaccuracies arising from the velocity model error. Minimizing the objective function optimizes the model and improves the image quality. The gradient of the objective function is computed using the adjoint state method in a way similar to that in the analogous data‐domain implementation. We propose an image‐domain velocity‐model building method using extended common‐image‐point space‐ and time‐lag gathers constructed sparsely at reflections in the image. The gathers are effective in reconstructing the velocity model in complex geologic environments and can be used as an economical replacement for conventional common‐image gathers in wave‐equation tomography. A test on the Marmousi model illustrates successful updating of the velocity model using common‐image‐point gathers and resulting improved image quality. 相似文献
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This paper describes least‐squares reverse‐time migration. The method provides the exact adjoint operator pair for solving the linear inverse problem, thereby enhancing the convergence of gradient‐based iterative linear inversion methods. In this formulation, modified source wavelets are used to correct the source signature imprint in the predicted data. Moreover, a roughness constraint is applied to stabilise the inversion and reduce high‐wavenumber artefacts. It is also shown that least‐squares migration implicitly applies a deconvolution imaging condition. Three numerical experiments illustrate that this method is able to produce seismic reflectivity images with higher resolution, more accurate amplitudes, and fewer artefacts than conventional reverse‐time migration. The methodology is currently feasible in 2‐D and can naturally be extended to 3‐D when computational resources become more powerful. 相似文献
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Tests and model calibration of high‐strength steel tubular beam‐to‐column and column‐base composite joints for moment‐resisting structures 
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下载免费PDF全文 Performance‐based engineering (PBE) methodologies allow for the design of more reliable earthquake‐resistant structures. Nonetheless, to implement PBE techniques, accurate finite element models of critical components are needed. With these objectives in mind, initially, we describe an experimental study on the seismic behaviour of both beam‐to‐column (BTC) and column‐base (CB) joints made of high‐strength steel S590 circular columns filled with concrete. These joints belonged to moment‐resisting frames (MRFs) that constituted the lateral‐force‐resisting system of an office building. BTC joints were conceived as rigid and of partial strength, whereas CB joints were designed as rigid and of full strength. Tests on a BTC joint composed of an S275 steel composite beam and high‐strength steel concrete‐filled tubes were carried out. Moreover, two seismic CB joints were tested with stiffeners welded to the base plate and anchor bolts embedded in the concrete foundation as well as where part of a column was embedded in the foundation with no stiffeners. A test programme was carried out with the aim of characterising these joints under monotonic, cyclic and random loads. Experimental results are presented by means of both force–interstory drift ratio and moment–rotation relationships. The outcomes demonstrated the adequacy of these joints to be used for MRFs of medium ductility class located in zones of moderate seismic hazard. Then, a numerical calibration of the whole joint subassemblies was successfully accomplished. Finally, non‐linear time‐history analyses performed on 2D MRFs provided useful information on the seismic behaviour of relevant MRFs. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献