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1.
Size distribution of oil droplets formed in deep water oil and gas blowouts have strong impact on the fate of the oil in the environment. However, very limited data on droplet distributions from subsurface releases exist. The objective of this study has been to establish a laboratory facility to study droplet size versus release conditions (rates and nozzle diameters), oil properties and injection of dispersants (injection techniques and dispersant types). This paper presents this facility (6 m high, 3 m wide, containing 40 m3 of sea water) and introductory data. Injection of dispersant lowers the interfacial tension between oil and water and cause a significant reduction in droplet size. Most of this data show a good fit to existing Weber scaling equations. Some interesting deviations due to dispersant treatment are further analyzed and used to develop modified algorithms for predicting droplet sizes in a second paper (Johansen et al., 2013).  相似文献   

2.
Testing dispersant effectiveness under conditions similar to that of the open environment is required for improvements in operational procedures and the formulation of regulatory guidelines. To this end, a novel wave tank facility was fabricated to study the dispersion of crude oil under regular non-breaking and irregular breaking wave conditions. This wave tank facility was designed for operation in a flow-through mode to simulate both wave- and current-driven hydrodynamic conditions. We report here an evaluation of the effectiveness of chemical dispersants (Corexit® EC9500A and SPC 1000™) on two crude oils (Medium South American [MESA] and Alaska North Slope [ANS]) under two different wave conditions (regular non-breaking and plunging breaking waves) in this wave tank. The dispersant effectiveness was assessed by measuring the water column oil concentration and dispersed oil droplet size distribution. In the absence of dispersants, nearly 8-19% of the test crude oils were dispersed and diluted under regular wave and breaking wave conditions. In the presence of dispersants, about 21-36% of the crude oils were dispersed and diluted under regular waves, and 42-62% under breaking waves. Consistently, physical dispersion under regular waves produced large oil droplets (volumetric mean diameter or VMD ? 300 μm), whereas chemical dispersion under breaking waves created small droplets (VMD ? 50 μm). The data can provide useful information for developing better operational guidelines for dispersant use and improved predictive models on dispersant effectiveness in the field.  相似文献   

3.
The effectiveness of chemical dispersants (Corexit 9500 and SPC 1000) on heavy fuel oil (IFO180 as test oil) has been evaluated under different wave conditions in a flow-through wave tank. The dispersant effectiveness was determined by measuring oil concentrations and droplet size distributions. An analysis of covariance (ANCOVA) model indicated that wave type and temperature significantly (p < 0.05) affected the dynamic dispersant effectiveness (DDE). At higher temperatures (16 °C), the test IFO180 was effectively dispersed under breaking waves with a DDE of 90% and 50% for Corexit 9500 and SPC 1000, respectively. The dispersion was ineffective under breaking waves at lower temperature (10 °C), and under regular wave conditions at all temperatures (10-17 °C), with DDE < 15%. Effective chemical dispersion was associated with formation of smaller droplets (with volumetric mean diameters or VMD ? 200 μm), whereas ineffective dispersion produced large oil droplets (with VMD ? 400 μm).  相似文献   

4.
An oil droplet size model was developed for a variety of turbulent conditions based on non-dimensional analysis of disruptive and restorative forces, which is applicable to oil droplet formation under both surface breaking-wave and subsurface-blowout conditions, with or without dispersant application. This new model was calibrated and successfully validated with droplet size data obtained from controlled laboratory studies of dispersant-treated and non-treated oil in subsea dispersant tank tests and field surveys, including the Deep Spill experimental release and the Deepwater Horizon blowout oil spill. This model is an advancement over prior models, as it explicitly addresses the effects of the dispersed phase viscosity, resulting from dispersant application and constrains the maximum stable droplet size based on Rayleigh-Taylor instability that is invoked for a release from a large aperture.  相似文献   

5.
This study determined the limiting oil viscosity for chemical dispersion of oil spills under simulated sea conditions in the large outdoor wave tank at the US National Oil Spill Response Test Facility in New Jersey. Dispersant effectiveness tests were completed using crude oils with viscosities ranging from 67 to 40,100 cP at test temperature. Tests produced an effectiveness-viscosity curve with three phases when oil was treated with Corexit 9500 at a dispersant-to-oil ratio of 1:20. The oil viscosity that limited chemical dispersion under simulated at-sea conditions was in the range of 18,690 cP to 33,400 cP. Visual observations and measurements of oil concentrations and droplet size distributions in the water under treated and control slicks correlated well with direct measurements of effectiveness. The dispersant effectiveness versus oil viscosity relationship under simulated at sea conditions at Ohmsett was most similar to those from similar tests made using the Institut Francais du Pétrole and Exxon Dispersant Effectiveness (EXDET) test methods.  相似文献   

6.
Hudson River sediment microcosms from Piles Creek (PC), Piermont Marsh (PM), and Iona Island (II) were amended with ∼100 mM nitrate or sulfate to stimulate anaerobic bioremediation. Nitrate and sulfate decreased over two years of field incubation and the fraction of these losses due to diffusion to the water column was predicted using Fick’s law. Apparent diffusion (Dapp) values of 1-4 × 10−10 m2 s−1 predicted the majority of loss/gain from/to the sediments by 700 d, but not at all times. Effective diffusion (Deff) values predicted by the porosity function (Deff = Dmol ε4/3) were larger than those observed in the field, and field data indicates a cube power relationship: Deff = Dmol ε3. Dapp greatly increased in surficial layers at PM and PC in year two, suggesting that bioadvection caused by bioturbating organisms had occurred. The effects of bioturbation on transport to/from the sediments are modeled, and results can be applied to various sediment treatment scenarios such as capping.  相似文献   

7.
Deep unconsolidated sediments in the Mississippi embayment will influence ground motions from earthquakes in the New Madrid seismic zone. Shear wave velocity profiles of these sediments are important input parameters for modeling wave propagation and site response in this region. Low-frequency, active-source surface wave velocity measurements were performed to develop small-strain shear wave velocity (VS) profiles at eleven deep soil sites in the Mississippi embayment, from north of New Madrid, Missouri to Memphis, Tennessee. A servo-hydraulic, low-frequency source was used to excite surface wave energy to wavelengths of 600 m, resulting in VS profiles to depths of over 200 m. The average VS profile calculated from the eleven sites is in good agreement with common reference VS profiles that have been used in seismic hazard studies of this region. The variability in VS profiles is shown to be associated with changes in formation depth and thickness from site-to-site. Using lithologic information at each site, average formation velocities were developed and compared to previous studies. We found average VS values of about 193 m/s for alluvial deposits, 400 m/s for the Upper Claiborne formations, and 685 m/s for the Memphis Sand formation.  相似文献   

8.
The influence of riverine inputs on biogeochemical cycling and organic matter recycling in sediments on the continental shelf off the Rhône River mouth (NW Mediterranean Sea) was investigated by measuring sediment oxygen uptake rates using a combination of in situ and laboratory techniques. Four stations were investigated during two cruises in June 2001 and June 2002, with depths ranging from 9 to 192 m and over a distance to the Rhône River mouth ranging from 4 to 36 km. Diffusive oxygen uptake (DOU) rates were determined using an in situ sediment microprofiler and total oxygen uptake (TOU) rates were measured using sediment core incubations. There was good agreement between these two techniques which indicates that the non-diffusive fraction of the oxygen flux was minimal at the investigated stations. DOU rates ranged from 3.7±0.4 mmol O2 m−2 d−1 at the continental shelf break to 19.3±0.5 mmol O2 m−2 d−1 in front of the Rhône River mouth. Sediment oxygen uptake rates mostly decreased with increasing depth and with distance from the Rhône mouth. The highest oxygen uptake rate was observed at 63 m on the Rhône prodelta, corresponding to intense remineralization of organic matter. This oxygen uptake rate was much larger than expected for the increasing bathymetry, which indicates that biogeochemical cycles and benthic deposition are largely influenced by the Rhône River inputs. This functioning was also supported by the detailed spatial distribution of total organic carbon (TOC), total nitrogen (TN) and C/N atomic ratio in surficial sediments. Sediments of the Rhône prodelta are enriched in organic carbon (2–2.2%) relative to the continental shelf sediments (<1%) and showed C/N ratios exceeding Redfield stoichiometry for fresh marine organic matter. A positive exponential correlation was found between DOU and TOC contents (r2=0.98, n=4). South-westward of the Rhône River mouth, sediments contained highly degraded organic matter of both terrestrial and marine origin, due to direct inputs from the Rhône River, sedimentation of marine organic matter and organic material redeposition after resuspension events.  相似文献   

9.
A theoretical model of grain size variation of domain transitions in titanomagnetite (x = 0.6) as a function of oxidation (z) is presented. The superparamagnetic (SP) to single-domain (SD) transition ds, the SD to two-domain (TD) transition d0, the TD to three-domain (3D) transition and the pseudo-single domain (PSD) to multi-domain (MD) transition are calculated as a function of z. It is shown that all the transition grain sizes increase with z, except for the PSD-MD transition for z > 0.6. The calculations predict that ds increases from 0.044 to 0.197 μm, d0 increases from 0.54 to 13 μm, the TD-3D transition increases from 1.6 to 49 μm as z varies from 0 to 0.8. The PSD-MD transition increases from 42 μm at z = 0 to 150 μm at z = 0.6, whereas between z = 0.6 to z = 0.8, the PSD-MD transition decreases to 49 μm. Qualitatively, the model explains some of the trends in magnetic properties of submarine basalts with low-temperature oxidation. Quantitatively, the model does give reasonable estimates of the PSD-MD boundary and d0, which are close to the experimental values for x = 0.6 and z = 0. Furthermore, the model predicts that psarks or two-domain grains could be the major contributors to the remanence of oxidized submarine pillow basalts.  相似文献   

10.
Field investigations following the 2008 Wenchuan earthquake (Ms=8.0) identified 118 liquefaction sites nearly all of which are underlain by gravelly sediment in the Chengdu Plain and adjacent Mianyang area. Field studies, including core drilling, dynamic penetration tests (DPT), and multiple channel analysis of surface wave velocity tests (MASW) for measurement of shear wave velocities, reveal the following: (1) Sand boils and ground fissures, indicative of liquefaction, occurred across hundreds of square kilometers affecting 120 villages, 8 schools and 5 factories. (2) The Chengdu plain is underlain by sandy gravels ranging in thickness up to 540 m; loose upper layers within the gravels beds liquefied. (3) Mean grain sizes for gravelly layers that liquefied range from 1 mm to more than 30 mm. (4) Shear wave velocities in gravels that liquefied range up to 250 m/s. (5) A 50% probability curve, developed from logistic procedures, correctly bounds all but four data points for the 47 compiled Vs data.  相似文献   

11.
Huang L  Ma T  Li D  Liang FL  Liu RL  Li GQ 《Marine pollution bulletin》2008,56(10):1714-1718
A novel bacterium T7-2 was isolated from the oil-polluted sea-bed mud of Bohai Sea, northern China, which can degrade diesel oil at 15 °C. This bacterium was identified as a strain of Rhodococcus erythropolis according to its 16S rDNA gene. In order to enhance degradation efficiency, a five-level, three-factor central composite design was employed to optimize the nutrition supplied to artificial seawater. The results indicate that a supplement of 2.53 g (NH4)2SO4 L−1, 2.75 g Na2HPO4 L−1 and 0.01 g yeast extract L−1 to artificial seawater increases the degradation rate from 12.61% to 75% within 7 d.  相似文献   

12.
Seven years after the April 2000 spill of 140,000 gallons of a mixture of No. 6 and No. 2 fuel oils in the Patuxent River, Maryland, heavily oiled brackish marshes showed continuing effects. Stem density and stem height were significantly lower in oiled versus unoiled sites for Spartina alterniflora but not Spartina cynosuroides habitats. In contrast, belowground biomass was significantly lower in S. cynosuroides habitats but not S. alterniflora habitats. Total PAH concentrations were up to 453 mg/kg in surficial soils (0-10 cm) and 2921 mg/kg with depth (10-20 cm). The oil had lost 22-76% of its initial PAH content after seven years, although the oil in marsh soils has undergone little to no additional weathering since Fall 2000. Based on amphipod acute toxicity tests and sediment quality guidelines, 25% of the soils in the marsh are expected to be toxic (ESB-TUFCV values > 3.0; PMax > 0.65).  相似文献   

13.
The aim of this study is to explore the contribution of living phytoplankton carbon to vertical fluxes in a coastal upwelling system as a key piece to understand the coupling between primary production in the photic layer and the transfer mechanisms of the organic material from the photic zone. Between April 2004 and January 2005, five campaigns were carried out in the Ría de Vigo (NW Iberian Peninsula) covering the most representative oceanographic conditions for this region. Measurements of particulate organic carbon (POC), chlorophyll-a (chl a), phaeopigments (phaeo), and identification of phytoplankton species were performed on the water column samples and on the organic material collected in sediment traps.The POC fluxes measured by the sediment traps presented no seasonal variation along the studied period ranging around a mean annual value of 1085±365 mg m−2 d−1, in the upper range of the previously reported values for other coastal systems. The fact that higher POC fluxes were registered during autumn and winter, when primary production rates were at their minimum levels points to a dominant contribution of organic carbon from resuspended sediments on the trap collected material. On the contrary, fluxes of living phytoplankton carbon (Cphyto) and chl a clearly presented a seasonal trend with maximum values during summer upwelling (546 mg m−2 d−1 and 22 mg chl a m−2 d−1, respectively) and minimum values during winter (22 mg m−2 d−1 and 0.1 mg chl a m−2 d−1, respectively). The contribution of Cphyto to the vertical flux of POC ranged between 2% and 49% in response to the pelagic phytoplankton community structure. Higher values of Cphyto fluxes were registered under upwelling conditions which favour the dominance of large chain-forming diatoms (Asterionellopsis glacialis and Detonula pumila) that were rapidly transferred to the sediments. By contrast, Cphyto fluxes decreased during the summer stratification associated with a pelagic phytoplankton community dominated by single-cell diatoms and flagellates. Minimal Cphyto fluxes were observed during the winter mixing conditions, when the presence of the benthic specie Paralia sulcata in the water column also points toward strong sediment resuspension.  相似文献   

14.
Tidal current and elevation data were collected from five oceanographic moorings during October 2004 in Torres Strait, northern Australia, to assess the effects of large bedforms (i.e., sand banks) on the drag coefficient (CD) used for estimating bed shear stress in complex shallow shelf environments. Ten minute averages of tidal current speed and elevation data were collected for 18 days at an on-bank site (<7 m water depth) and an off-bank site (<10 m). These data were compared to data collected simultaneously from two shelf locations (<11 m) occupied to measure regional tidal behaviour. Overall CD estimates at the on- and off-bank sites attained 7.0±0.1×10−3 and 6.6±0.1×10−3, respectively. On-bank CD estimates also differed between the predominant east–west tidal streams, with easterly directed flows experiencing CD=7.8±0.18×10−3 and westerly directed flows CD=6.4±0.12×10−3. Statistically significant differences between the off-bank and on-bank sites are attributed to the large form drag exerted by the sand banks on the regional tidal currents, and statistically significant differences between the westward and eastward flows is ascribed to bedform asymmetry. Form drag from the large bedforms in Torres Strait comprises up to 65% of the total drag coefficient. When constructing sediment transport models, different CD estimates must therefore be applied to shelf regions containing steep bedforms compared to regions that do not. Our results extend the limited inventory of seabed drag coefficients for shallow shelf environments, and can be used to improve existing regional seabed mobilisation models, which have direct application to environmental management in Torres Strait.  相似文献   

15.
Semi-diurnal and fortnightly surveys were carried out to quantify the effects of wind- and navigation-induced high-energy events on bed sediments above intertidal mudflats. The mudflats are located in the upper fluvial part (Oissel mudflat) and at the mouth (Vasière Nord mudflat) of the macrotidal Seine estuary. Instantaneous flow velocities and mudflat bed elevation were measured at a high frequency and high resolution with an acoustic doppler velocimeter (ADV) and an ALTUS altimeter, respectively. Suspended particulate matter concentrations were estimated by calibrating the ADV acoustic backscattered intensity with bed sediments collected at the study sites. Turbulent bed shear stress values were estimated by the turbulent kinetic energy method, using velocity variances filtered from the wave contribution. Wave shear stress and maximum wave–current shear stress values were calculated with the wave–current interaction (WCI) model, which is based on the bed roughness length, wave orbital velocities and the wave period (TS). In the fluvial part of the estuary, boat passages occurred unevenly during the surveys and were characterized by long waves (TS>50 s) induced by the drawdown effect and by short boat-waves (TS<10 s). Boat waves generated large bottom shear stress values of 0.5 N m−2 for 2–5 min periods and, in burst of several seconds, larger bottom shear stress values up to 1 N m−2. At the mouth of the estuary, west south-west wind events generated short waves (TS<10 s) of HS values ranging from 0.1 to 0.3 m. In shallow-water environment (water depth <1.5 m), these waves produced bottom shear stress values between 1 and 2 N m−2. Wave–current shear stress values are one order of magnitude larger than the current-induced shear stress and indicate that navigation and wind are the dominant hydrodynamic forcing parameters above the two mudflats. Bed elevation and SPM concentration time series showed that these high energy events induced erosion processes of up to several centimetres. Critical erosion shear stress (τce) values were determined from the SPM concentration and bed elevation measurements. Rough τce values were found above 0.2 N m−2 for the Oissel mudflat and about 1 N m−2 for the Vasière Nord mudflat.  相似文献   

16.
Most entrained estuarine sediment mass occurs as flocs. Parameterising flocculation has proven difficult as it is a dynamically active process dependent on a set of complex interactions between the sediment, fluid and the flow. However the natural variability in an estuary makes it difficult to study the factors that influence the behaviour of flocculation in a systematic manner. This paper presents preliminary results from a laboratory study that examined how floc properties of a natural estuarine mud from the Medway (UK), evolved in response to varying levels of suspended sediment concentration and induced turbulent shearing. The experiments utilised the LabSFLOC floc video camera system, in combination with an annular mini-flume to shear the suspended sediment slurries. The flows created in the mini-flume produced average shear stresses, at the floc sampling height, ranging from 0.01 N m−2 to a peak of 1.03 N m−2. Nominal suspended particulate matter concentrations of 100, 600 and 2000 mg l−1 were introduced into the flume. The experimental runs produced individual flocs ranging in size from microflocs of 22.2 μm to macroflocs 583.7 μm in diameter. Average settling velocities ranged from 0.01 to 26.1 mm s−1, whilst floc effective densities varied from 3.5 up to 2000 kg m−3. Low concentration and low shear stress were seen to produce an even distribution of floc mass between the macrofloc (>160 μm) and microfloc (<160 μm) fractions. As both concentration and stress rose, the proportion of macrofloc mass increased, until they represented over 80% of the suspended matter. A maximum average macrofloc settling velocity of 3.3 mm s−1 was attained at a shear stress of 0.45 N m−2. Peak turbulence conditions resulted in deflocculation, limiting the macrofloc fall velocity to only 1.1 mm s−1 and placing over 60% of the mass in the microfloc size range. A statistical analysis of the data suggests that the combined influence of both suspended concentration and turbulent shear controls the settling velocity of the fragile, low density macroflocs.  相似文献   

17.
The metabolic balance between production and respiration in plankton communities of the Gulf of Papua was investigated in May 2004. Water samples taken at 19 stations were allocated to groups on the basis of physico-chemical characteristics. Oxygen consumption and production in flasks incubated in the dark and in the light was determined by micro-Winkler titration. Dark bottle respiration in samples influenced by the estuarine plume averaged 3.09±1.92 (SD) mmol O2 m−3 d−1 and production within surface light bottles averaged 7.63±3.36 (SD)  mmol O2 m−3 d−1. Corresponding values in stations more typical of the central Gulf of Papua were 1.68±1.30 (SD) mmol O2 m−3 d−1 and 1.08±2.25 (SD) mmol O2 m−3 d−1. Despite a shallow (<10 m) euphotic zone within the plume stations, phytoplankton production in the surface layers was sufficiently high to subsidise total water column respiration. Integrating production and respiration over the water column resulted in a calculation of net community production (NCP) of 626±504 (SD) mg C m−2 d−1, and community respiration (CR) of 712±492 mg C m−2 d−1 at the plume stations, with an average P:R ratio of 1.97. In the offshore group NCP was 157±450 (SD) mg C m−2 d−1 and CR was 1620±1576 mg C m−2 d−1. The average P:R ratio was 1.27. Three of the 7 stations allocated to the offshore group were net heterotrophic. In contrast to earlier studies in the area indicating that the Gulf of Papua waters is heterotrophic [Robertson, A.I., Dixon, P., Alongi, D.M., 1998. The influence of fluvial discharge on pelagic production in the Gulf of Papua, Northern Coral Sea. Estuarine, Coastal and Shelf Science 46, 319–331], our data indicate that in May 2004 the Gulf was in positive metabolic balance, but by only ∼120 mg C m−2 d−1. We conclude that waters of the Gulf of Papua under riverine influence are net autotrophic, but that within the central Gulf there is a fine metabolic balance alternating between autotrophy and heterotrophy.  相似文献   

18.
There is increasing interest in tidal wetlands as mechanisms for sustainable and long-term coastal defence. The complexities of the interaction between the deposition of suspended particulate matter (SPM) and submerged vegetation, however, is to a large extent poorly understood. Consequently, accurate parameterisation of cohesive sediment settling fluxes in these environments is a crucial requirement for the development of high-resolution numerical models of wetland morphodynamics. A novel laboratory experiment is described in which the turbulent flow structure within a canopy of the halophytic macrophyte Spartina anglica is examined, and floc characteristics quantified using a unique floc camera configuration able to measure directly the full spectral floc size (D) and settling velocity (Ws). We provide the first quantitative observations of floc characteristics from shallow (h<0.5 m), vegetated flows and investigate the potential influence that variations in vegetative density may have on flocculation, and thus depositional fluxes, in comparison to unvegetated flows.  相似文献   

19.
Low tide rainfall may represent an important but little studied process affecting sediment fluxes on intertidal mudflats. In this study, we simulated rainfall events on an intertidal mudflat (median grain size=18.4 μm) of low slope (1 in 300) then quantified effects on sediment erodibility. Treatments consisted of a high (4.1 mm min−1 for 6 min) and low (0.36 mm min−1 for 60 min) rain intensity, chosen to match naturally occurring events and experiments were conducted seasonally (May and August) to encompass variations in ambient sediment stability. Changes in bed elevation due to rainfall were estimated using marked rods and sediment erodibility parameters (mass of sediment eroded at a flow velocity of 0.3 m s−1 (ME-30, g m−2) and critical erosion velocity (Ucrit, m s−1)) were determined in annular flumes (bed area=0.17 m2). Ambient/control sediment erodibility in May (ME-30=211 g m−2, Ucrit=0.18 m s−1) was higher than in August (ME-30=30 g m−2, Ucrit=0.26 m s−1) and was correlated with changes in biological activity. In May, surface sediment was influenced by high densities of the bioturbating snail Hydrobia ulvae (1736 ind. m−2) and low biomass of the sediment stabilising microphytobenthos (5.7 μg chlorophyll a cm−2). In contrast, in August H. ulvae densities were low (52 ind. m−2) and microphytobenthic biomass higher (9.2 μg chlorophyll a cm−2). The high rain treatment caused a decrease in bed elevation of between 1.5 mm (May) and 4.4 mm (August) and significantly reduced sediment organic content and microphytobenthic biomass. Rainfall increased sediment erodibility; compared to ambient sediments ME-30 increased by a factor of 1.4× in May and 8.8× in August and caused a 10–30% decline in Ucrit. The seasonal difference in treatment effect was due to the change in ambient sediment stability. The low rain treatment in August had no effect on bed elevation, microphytobenthic biomass or sediment erodibility. In May, the same treatment caused a reduction in bed elevation (0.5 mm) and microphytobenthic biomass but counter-intuitively, a decrease in sediment erodibility (ME-30 was reduced by 40%, Ucrit increased by 5%) compared to controls. We attribute this result to removal by rainfall of easily eroded surface flocs and biogenic roughness which resulted in an underlying sediment with a smoother surface and greater resistant to erosion. Results suggest that high intensity rain events may destabilise intertidal sediments making them more susceptible to erosion by returning tidal currents and that the sediment eroded during such events may represent a considerable fraction (up to 25%) of the seasonal variation in shore elevation. The impact of natural rain events are likely to vary considerably due to variations in droplet size, intensity and duration and the interaction with ambient sediment stability.  相似文献   

20.
The spatiotemporal distributions of dissolved and/or dispersed oil in seawater and pore water were monitored on site by fluorometric detection method after the Hebei Spirit oil spill. The oil concentrations in intertidal seawater, 15 days after the spill, were as high as 16,600 μg/L and appeared to decrease below the Korean marine water quality standard of 10 μg/L at most sites 10 months after the spill. Fluorometric detection of oil in pore water was introduced to eliminate the effects of grain size for the quantification of oil in sediments and to better explain spatial and temporal distribution of oil pollution at sandy beaches. The fluorescence detection method was compared with the conventional laboratory technique of total petroleum hydrocarbon analysis using gas chromatography. The method of fluorescence detection of oil was capable of generating results much faster and more cost-effectively than the traditional GC technique.  相似文献   

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