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1.
Abstract Carbon isotope fluctuations of sedimentary organic matter along the two geological traverses in the Yezo Group, Hokkaido, northern Japan, elucidate a detailed chemostratigraphy for the Cenomanian Stage on the northwestern Pacific margin. Visual characterization of the kerogen from mudstone samples shows that the major constituents of sedimentary organic matter originated as terrestrial higher plants. The atomic hydrogen/carbon ratios of the kerogen suggest that the original δ13C values of terrestrial organic matter (TOM) have not been affected significantly by thermal diagenesis. The patterns in two δ13CTOM curves are similar and independent of changes in lithology and total organic carbon contents, which suggests that TOM was mixed sufficiently before the deposition in the Yezo forearc basin for the δ13C composition having been homogenized. In addition, this implies that the Hokkaido δ13CTOM profiles represent the averaged temporal δ13C variations of terrestrial higher‐plant vegetation in the hinterlands of northeast Asia during Cenomanian time. Three shorter‐term (ca. 0.1 my duration) positive‐and‐negative δ13CTOM fluctuations of ∼1‰ are present in the Lower to Middle Cenomanian interval in the Yezo Group. On the basis of the age‐diagnostic taxa (ammonoids, inoceramids and planktic foraminifers), these discrete δ13CTOM events are interpreted to be correlated with those in the δ13C curves of pelagic carbonates from European basins. The correlation of δ13C events between the European and Yezo Group sections suggests that the shorter‐term δ13C fluctuations in Cenomanian ocean‐atmosphere carbon reservoirs are useful for global chemostratigraphic correlation of marine strata. In particular, the correlation of δ13C fluctuations of the so‐called ‘Mid‐Cenomanian event’ (MCE) implies: (i) the δ13C variations of global carbon reservoir during the MCE are precisely recorded in the δ13CTOM records; and (ii) the MCE δ13CTOM event is an efficient chronostratigraphic index for the Lower/Middle Cenomanian boundary of the Mid‐Cretaceous sequences.  相似文献   

2.
After the severest mass extinction event in the Phanerozoic, biotic recovery from the extinction at the Permian–Triassic boundary required approximately 5 my, which covers the entire Early Triassic. It is important to obtain information on the superocean Panthalassa, which occupied most of the world ocean, to explore paleoenvironmental changes during the Early Triassic at the global scale. In order to establish the continuous lithostratigraphy of pelagic sediments in Panthalassa during the Early Triassic, high‐resolution reconstruction of the Lower Triassic pelagic sequence in Japan was conducted for the first time based on detailed field mapping and lithostratigraphic correlation in the Inuyama area, central Japan. The reconstructed Early Triassic sequence is approximately 9.5 m thick, consists of five rock types, and is divided into eight lithological units. For the reconstructed continuous sequence, measurement of carbon isotopic composition of sedimentary organic matter (δ13Corg) was carried out. Stratigraphic variation of the δ13Corg value shows large‐amplitude fluctuations between ?34.4 and ?21.0‰ throughout the sequence. In order to establish a higher resolution age model for the reconstructed Lower Triassic pelagic sequence, we correlated δ13Corg records in the Inuyama area with high‐resolution isotopic profiles of carbonate carbon (δ13Ccarb) from shallow‐marine carbonate sequences in southern China based on the similarity in general variation patterns with age constraints by radiolarian and conodont biostratigraphy. The result provides a high‐resolution time scale for the pelagic sequence of Panthalassa during the Smithian and Spathian. The age model suggests a drastic increase in sedimentation rate during the late Smithian, which should have been caused by the increase in terrigenous input to this site.  相似文献   

3.
Immediately before the extinction of the end‐Guadalupian (Middle Permian; ca 260 Ma), a significant change to the global carbon cycle occurred in the superocean Panthalassa, as indicated by a prominent positive δ13C excursion called the Kamura event. However, the causes of this event and its connection to the major extinction of marine invertebrates remain unclear. To understand the mutual relationships between these changes, we analyzed the sulfur isotope ratio of the carbonate‐associated sulfate (CAS) and HCl‐insoluble residue, as well as the carbon isotope ratio of bulk organic matter, for the Middle‐Upper Permian carbonates of an accreted mid‐oceanic paleo‐atoll complex from Japan, where the Kamura event was first documented. We detected the following unique aspects of the stable carbon and sulfur isotope records. First, the extremely high δ13C values of carbonate (δ13Ccarb) over +5 ‰ during the Capitanian (late Guadalupian) were associated with large isotopic differences between carbonate and organic matter (Δ13C = δ13Ccarb ? δ13Corg). We infer that the Capitanian Kamura event reflected an unusually large amount of dissolved organic matter in the expanded oxygen minimum zone at mid‐depth. Second, the δ34S values of CAS (δ34SCAS) were inversely correlated with the δ13Ccarb values during the Capitanian to early Wuchiapingian (early Late Permian) interval. The Capitanian trend may have appeared under increased oceanic sulfate conditions, which were accelerated by intense volcanic outgassing. Bacterial sulfate reduction with increased sulfate concentrations in seawater may have stimulated the production of pyrite that may have incorporated iron in pre‐existing iron hydroxide/oxide. This stimulated phosphorus release, which enhanced organic matter production and resulted in high δ13Ccarb. Low δ34SCAS values under high sulfate concentrations were maintained and the continuous supply of sulfate cannot by explained only by the volcanic eruption of the Emeishan Trap, which has been proposed as a cause of the extinction. The Wuchiapingian δ34SCAS–δ13Ccarb correlation, likely related to low sulfate concentration, may have been caused by the removal of oceanic sulfate through the massive evaporite deposition.  相似文献   

4.
Early Permian (272 ± 2 Ma) diabase dikes from the Linxi area in central Inner Mongolia of NE China have high MgO (10.4 – 12.3 wt%), Cr (301 – 448 ppm) and Ni (167 – 233 ppm) concentrations, and show enrichments in large ion lithophile element (LILE) and light rare earth elements (REE) but depletions in high field strength element (HFSE, e.g., Nb and Ta), with depleted mantle‐type Sr [87Sr/86Sr (i) = 0.70315 – 0.70362], Nd [εNd (t) = +6.8 – +7.4], Pb [206Pb/204Pb (i) = 18.10 – 18.16] and zircon Hf [εHf (t) = +14.7 – +19.1] isotopic compositions, but slightly higher zircon δ18O (5.2 – 6.0 ‰ with an average of 5.7 ‰) than normal mantle. The combined geochemical data indicate their derivation from a depleted mantle metasomatized by recycled crustal component. Elemental and isotopic modeling results suggest that the primary magma was produced through 5 % to 10 % melting of a depleted mantle, which contained approximately 1 % sediment fluid released from the subducted paleo‐Asian Ocean. Considering the widespread distribution of contemporaneous mafic rocks across the central Inner Mongolia, which show REE patterns from E‐MORBs to normal MORBs, we propose a petrogenetic link between the Early Permian mafic magmatism and a back‐arc extension in response to northward subduction of the paleo‐Asian Ocean. The Permian mafic magmatism and the new age constraints from the metamorphic and sedimentary records in this area tend to indicate the ultimate closure of the paleo‐Asian Ocean by the end of Paleozoic.  相似文献   

5.
Study of Late Cretaceous lacustrine sedimentary strata in the eastern Songliao Basin, China revealed that the paleoclimate was relatively arid and hot during sedimentation of the upper Santonian of the Yaojia Formation, but became relatively humid and warm during deposition of the lower Campanian Nenjiang Formation. The upper Yaojia Formation was deposited in a freshwater lake environment, while the lower Nenjiang Formation was deposited in a slightly brackish to brackish environment. The average total organic carbon content in the upper Yaojia Formation is 0.15%, while the hydrogen index is 36 mgHC/gTOC, implying poor source rock for oil generation and the organic matter comprised of a mixture of woody and herbaceous organic matter. In contrast, the hydrogen index of oil shale and black shale of the lower Nenjiang Formation is 619 mgHC/gTOC, and total organic carbon content on average is 3.37%, indicating a mixed algae and herbaceous source of kerogen and an increase in aquatic bioproductivity. The black shale and oil shale have low Pristane/Phytane and C29 5α,14α,17α(H) ? stigmastane 20R/(20R + 20S) ratios, with maximum concentration of n‐alkanes at n‐C23, implying an anoxic depositional environment with algae, bacteria and higher plants providing most of the organic matter. Relatively abundant gammacerane and a higher Sr/Ba ratio in the oil shales suggest the presence of brackish water and development of salinity stratification in the lake. During sedimentation of the upper Yaojia through the lower Nenjiang Formations, the level of Songliao lake increased and a deep‐lake environment was formed with bottom waters being oxygen depleted. Concomitantly, as the lake deepened bottom conditions were changing from oxic to anoxic, and the input of organic matter changed from predominantly higher plants to a mixture of bacteria, algae and higher plants providing favorable conditions for oil source rock accumulation.  相似文献   

6.
Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen, residual kerogen and oil as well as dispersed liquid hydrocarbon (DLH) in source rocks were performed by closed system, and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity (R 0%) at laboratory conditions were analyzed. Several diagrams of gas origin were calibrated by using the experimental data. A diagram based on the ratio of normal and isomerous butane and pentane (i/nC4 ? i/nC5) was proposed and used to identify the origins of the typical marine natural gases in the Sichuan Basin and the Tarim Basin, China. And the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities (δ13C-R 0%) with different origins. The results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each other. For example, the dryness index of the oil-cracking gas is the lowest; the dryness indices of gases from DLH and kerogen in closed system are almost the same; and the dryness index of gases from residual kerogen is extremely high, indicating that the kerogen gases are very dry; the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking gases. The molecular carbon isotopes of oil-cracking gases are the lightest, those of kerogen in closed system and GLH-cracking gases are the second lightest, and those of cracking gases from residual kerogen are the heaviest. The calibration results indicate that the diagrams of In(C1/C2)-In(C2/C3) and δ4 3C2-δ4 3C3-In(C2/C3) can discriminate primary and secondary cracking gases, but cannot be used to identify gas origin sources, while the diagram of i/nC4 ? i/nC5 can differentiate the gases from different precursors. The application results of these diagrams show that gas mixtures extensively exist in China, which involved the gases from multiple precursors and those from different maturity stages. For example, marine gases in the Sichuan Basin involve the mixture of oil-cracking gases and high-over-maturated kerogen gases, while those in the Tarim Basin involve not only the mixture of gases from multiple precursors, but also those from different maturity gases and post-reservoir alternations such as oxidized degradation and gas intrusion processes.  相似文献   

7.
Koichi  Aoyagi Mamoru  Omokawa 《Island Arc》1993,2(4):273-279
Abstract Various siliceous rocks are found in the Ohdoji, Akaishi and Maido Formations from the western Aomori basin, and the Yotsuzawa and Wadagawa Formations from the eastern Aomori basin of northern Honshu, Japan. These rocks are classified into diatomite, siliceous shale and chert.
Diatomite is composed of abundant amorphous silica and has porosity between 50 and 65%. Siliceous shale is composed of a large amount of quartz, and has porosity ranging from 25 to 35%. Chert is chiefly composed of cristobalite or quartz, and has porosity between 20 to 30%.
Average contents of total organic carbon, S1 and S2 generally increase from argillaceous rocks → diatomites → siliceous shales → cherts. Maturation of organic matter in these rocks is generally lower than that in average source rocks. Diatoms, which appeared in the late Cretaceous and became increasingly important in the Miocene, are the principal primary producers of organic matter in the marine environment during the Cenozoic. Excellent organic components and higher biological productivity show that diatoms might be the most important source of petroleum during the Neogene in Japan.
Proteins, carbohydrates and lipids in diatoms have been transformed into fulvic acids, humic acids and humin by polycondensation and polymerization. Later, these humin materials could be changed into insoluble kerogen under the effect of mild temperature and pressure. A part of the lipids would transform to geochemical fossils (biomarkers). Amorphous silica in cells of diatoms would change to low-cristobalite and low-quartz by the increase of geothermal temperature.  相似文献   

8.
The light hydrocarbon composition of 209 natural gas samples and individual light hydrocarbon carbon isotopes of 53 natural gas samples from typical humic-sourced gas and sapropelic-sourced gas in the four basins of China have been determined and analyzed. Some identification parameters for humic-sourced gas and sapropelic-sourced gas are proposed or corrected. The differences of compound-specific δ 13C value of individual light hydrocarbon between humic-sourced gas and sapropelic-sourced gas have been founded. The humic-sourced gas has the distribution of δ 13Cbenzene> ?24‰, δ 13Ctoluene >?23‰, δ 13Ccyclohexane > ?24‰ and δ 13Cmethyl cyclohexane> ?24‰, while the sapropelic-sourced gas has the distribution of δ 13Cbenzene <?24‰, δ 13Ctoluene< ?24‰, δ 13Ccyclohexane< ?24‰ and δ 13Cmethyl cyclohexane< ?24‰. Among the components of C7 light hydrocarbon compound, such as normal heptane (nC7), methyl cyclohexane (MCH) and dimethyl cyclopentane (ΣDMCP), etc, relative contents of nC7 and MCH are influenced mainly by the source organic matter type of natural gas. Therefore, it is suggested that the gas with relative content of nC7 of more than 30% and relative content of MCH of less than 70% is sapropelic-sourced gas, while gas with relative content of nC7 of less than 35% and relative content of MCH of more than 50% is humic-sourced gas. Among components of C5–7 aliphatics, the gas with relative content of C5–7 normal alkane of more than 30% is sapropelic-sourced gas, while the gas with relative content of C5–7 normal alkane of less than 30% is humic-sourced gas. These paremeters have been suggested to identify humic-sourced gas and sapropelic-sourced gas.  相似文献   

9.
The kinetic parameters of generation have been obtained for different hydrocarbon classes, including methane, C2-C5 gas hydrocarbons, C6-C13 light hydrocarbons and C13+ heavy hydrocarbons, and vitrinite reflectance (R°) by the kinetic simulating experiment of kerogen cracking. Then, combined with the detailed geology of Sichuan Basin, the effective gas-generating intensity of the Lower Cambrian source rock is approximately estimated by applying these parameters.  相似文献   

10.
This study aimed to understand changes in the biogeochemical processing of organic matter (OM) in response to multiple stressors (e.g., littoral area expansion, wastewater input, and hydrological regulation) in East Dongting Lake (Central China) over the past 60 years, using analyses of total organic carbon (TOC), total nitrogen (TN), C/N ratios, δ13C, δ15N, and diatoms from 2 sediment cores collected from the littoral and central parts of the lake. OM mainly originated from phytoplankton and C3 plant‐derived soil OM based on the ranges of C/N ratios (from 7 to 11) and δ13C (between ?27‰ and ?23‰). Littoral area expansion due to siltation caused an increasing influx of terrestrial soil OM in the 1980s and the 1990s, subsequently lowering δ13C values and rising C/N ratios in both sediment cores. Meanwhile, higher δ15N was linked to a high influx of isotopically heavy nitrate from urban and agricultural wastewaters. After 2000, slight decreases in TOC and TN in the littoral area were attributable to reducing inputs of external OM, likely linked to declining sediment influx from the upper reaches resulting from the Three Gorges Dam impoundment. Contrasting increases in TOC, TN, and C/N ratios in the central part indicated a high influx of terrestrial soil OM due to the declining distance from the shoreline with littoral area expansion. Declining δ15N values after 2000 indicated an increase in N2‐fixing cyanobacteria with eutrophication. Changes in diatom assemblages in both the littoral and central zones reflected nutrient enrichment and hydrological alterations. These results indicate that littoral expansion, declining riverine influx, and anthropogenic nutrient inputs are potential driving forces for the biogeochemical processing of OM in floodplain lakes. This study provides sedimentary biogeochemical clues for tracking past limnological conditions of floodplain lakes that are subjected to increasing disturbances from hydrological regulation and eutrophication.  相似文献   

11.
Dissolved inorganic carbon isotope (δ13CDIC) is an important tool to reveal the carbon cycle in lake systems. However, there are only few studies focusing on the spatial variation of δ13CDIC of closed lakes. Here we analyze the characteristics of δ13CDIC of 24 sampled lakes (mainly closed lakes) across the Qiangtang Plateau (QTP) and identify the driving factors for its spatial variation. The δ13CDIC value of these observed lakes varies in the range of ? 15·0 to 3·2‰, with an average value of ? 1·2‰. The δ13CDIC value of closed lakes is close to the atmospheric isotopic equilibrium value, much higher than that in rivers and freshwater lakes reported before. The high δ13CDIC value of closed lakes is mainly attributed to the significant contribution of carbonate weathering in the catchment and the evasion of dissolved CO2 induced by the strong evaporation of lake water. The δ13CDIC value of closed lakes has a logarithmic correlation with water chemistry (TDS, DIC and pCO2), also suggesting that the evapo‐concentration of lake water can influence the δ13CDIC value. The δ13CDIC value shows two opposite logarithmic correlations with lake size depending on the δ13CDIC range. This study suggests that the δ13C in carbonates in lacustrine sediments can be taken as an indicator of lake volume variation in closed lakes on QTP. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

12.
Hu  AnPing  Li  Jian  Zhang  WenZheng  Li  ZhiSheng  Hou  Lu  Liu  QuanYou 《中国科学:地球科学(英文版)》2008,51(1):183-194

The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000×108m3 of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated δ 13C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the δ 13C1 values are mostly similar with those in the Upper Paleozoic, but the δ 13C2 and δ 13C3 values are slightly lighter, suggesting that the gases would be mixing of coal-type gases as a main member and oil-type gases. There are multiple reversals in carbon isotopes for gaseous alkanes, especially abnormal reversal for methane and ethane (i.e. δ 13C1>δ 13C2), inferring that gases would be mixed between high-mature coal-formed gases and oil-type gases. In the Mesozoic, the δ 13C values for gaseous alkanes are enriched in 12C, indicating that the gases are mainly derived from sapropelic sources; the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different maturity. In contrast to the Upper Paleozoic gases, the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane, which may be caused by gases generated from different kerogen types. Finally, according to δ 13C1-R 0 relationship and extremely low total organic carbon contents, the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source, bycontrast, the Upper Paleozoic source as a main gas source is contributed to the Lower Paleozoic gases.

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13.
The Ordos Basin, the second largest sedimentary basin in China, contains the broad distribution of natural gas types. So far, several giant gas fields have been discovered in the Upper and Lower Paleozoic in this basin, each having over 1000×108m3 of proven gas reserves, and several gas pools have also been discovered in the Mesozoic. This paper collected the data of natural gases and elucidated the geochemical characteristics of gases from different reservoirs, and then discussed their origin. For hydrocarbons preserved in the Upper Paleozoic, the elevated δ 13C values of methane, ethane and propane indicate that the gases would be mainly coal-formed gases; the singular reversal in the stable carbon isotopes of gaseous alkanes suggests the mixed gases from humic sources with different maturity. In the Lower Paleozoic, the δ 13C1 values are mostly similar with those in the Upper Paleozoic, but the δ 13C2 and δ 13C3 values are slightly lighter, suggesting that the gases would be mixing of coal-type gases as a main member and oil-type gases. There are multiple reversals in carbon isotopes for gaseous alkanes, especially abnormal reversal for methane and ethane (i.e. δ 13C1>δ 13C2), inferring that gases would be mixed between high-mature coal-formed gases and oil-type gases. In the Mesozoic, the δ 13C values for gaseous alkanes are enriched in 12C, indicating that the gases are mainly derived from sapropelic sources; the carbon isotopic reversal for propane and butane in the Mesozoic is caused by microbial oxidation and mixing of gases from sapropelic sources with different maturity. In contrast to the Upper Paleozoic gases, the Mesozoic gases are characterized by heavier carbon isotopes of iso-butane than normal butane, which may be caused by gases generated from different kerogen types. Finally, according to δ 13C1-R 0 relationship and extremely low total organic carbon contents, the Low Paleozoic gases would not be generated from the Ordovician source as a main gas source, bycontrast, the Upper Paleozoic source as a main gas source is contributed to the Lower Paleozoic gases.  相似文献   

14.
We evaluated sources and pathways of groundwater recharge for a heterogeneous alluvial aquifer beneath an agricultural field, based on multi‐level monitoring of hydrochemistry and environmental isotopes of a riverside groundwater system at Buyeo, Korea. Two distinct groundwater zones were identified with depth: (1) a shallow oxic groundwater zone, characterized by elevated concentrations of NO3? and (2) a deeper (>10–14 m from the ground surface) sub‐oxic groundwater zone with high concentrations of dissolved Fe, silica, and HCO3?, but little nitrate. The change of redox zones occurred at a depth where the aquifer sediments change from an upper sandy stratum to a silty stratum with mud caps. The δ18O and δ2H values of groundwater were also different between the two zones. Hydrochemical and δ18O? δ2H data of oxic groundwater are similar to those of soil water. This illustrates that recharge of oxic groundwater mainly occurs through direct infiltration of rain and irrigation water in the sandy soil area where vegetable cropping with abundant fertilizer use is predominant. Oxic groundwater is therefore severely contaminated by agrochemical pollutants such as nitrate. In contrast, deeper sub‐oxic groundwater contains only small amounts of dissolved oxygen (DO) and NO3?. The 3H contents and elevated silica concentrations in sub‐oxic groundwater indicate a somewhat longer mean residence time of groundwater within this part of the aquifer. Sub‐oxic groundwater was also characterized by higher δ18O and δ2H values and lower d‐excess values, indicating significant evaporation during recharge. We suggest that recharge of sub‐oxic groundwater occurs in the areas of paddy rice fields where standing irrigation and rain water are affected by strong evaporation, and that reducing conditions develop during subsequent sub‐surface infiltration. This study illustrates the existence of two groundwater bodies with different recharge processes within an alluvial aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

15.
The Flin Flon Belt of Canada contains Paleoproterozoic volcanic–sedimentary sequences that are related to the Trans‐Hudson Orogeny. The sequences include island arc volcanic and volcaniclastic rocks (Amisk Group) that are unconformably overlain by subaerial sedimentary rocks (Missi Group), and younger deep facies sediments. In the Flin Flon area, several north–south trending faults divide the sequences into blocks and obscure the depositional environment of the deep facies sediments. Locally, within the Flin Flon area, the Embury Lake Formation is in fault contact with island arc volcanic–sedimentary sequences of the Amisk and Missi Groups. To identify the depositional environment of the Embury Lake Formation, we used lithologic and geochemical approaches. Here, we report carbon isotopic values in organic matter (δ13Corg) and sulfur isotopes (δ34S), as well as total organic carbon and total sulfur measurements for the black shale in the formation. Samples were taken from a drill core that contains alternating bands of sandstone and black shale. Pyrite in the black shale is divided into four textural types: euhedral, vein‐type, elliptical, and microcrystalline. Microcrystalline pyrite is typically generated by microbially mediated sulfate reduction. An extremely low S/C ratio (avg. = 0.04) is consistent with lacustrine deposition. The ranges of δ13Corg (?36 ‰ to ?27 ‰) and δ34S (+3.0 ‰ to +7.7 ‰) values can be explained by bacterial photosynthesis that involved Calvin cycle and acetyl CoA pathways, and sulfate reduction in a low‐sulfate environment. Considering the depositional age reported in a previous study of < 1.84 Ga, the Embury Lake Formation was likely emplaced in a lacustrine setting during the Trans‐Hudson Orogeny.  相似文献   

16.

Natural gases discovered up to now in Lishui Sag, the East China Sea Basin, differ greatly in gaseous compositions, of which hydrocarbon gases amount to 2%–94% while non-hydrocarbon gases are dominated by CO2. Their hydrocarbon gases, without exception, contain less than 90% of methane and over 10% of C2 + heavier hydrocarbons, indicating a wet gas. Carbon isotopic analyses on these hydrocarbon gases showed that δ 13C1, δ 13C2 and δ 13C3 are basically lighter than −44‰, −29‰ and −26‰, respectively. The difference in carbon isotopic values between methane and ethane is great, suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation. δ 13 \( C_{CO_2 } \) values of nonhydrocarbon gases are all heavier than −10‰, indicating a typical abiogenic gas. The simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit, consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the latter. Moreover, δ 13C1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰ heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit while δ 13C2 and δ 13C3 values of the former are over 9‰ heavier than those of the latter. Currently the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag, where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter, therefore, natural gases in the LS36-1 oil-gas pool are mainly derived from the Yueguifeng Formation lacustrine source rock rather than the Lingfeng Formation marine or Mingyuefeng Formation coal-measures source rocks.

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17.
Individual vertical profiles and north-south sections for the distribution of theδ13C of total dissolved inorganic carbon are presented for the Atlantic stations of the GEOSECS program. In most cases theδ13C data parallel the distribution of dissolved O2. Differences are attributed to in-situ oxidation of organic matter and dissolution of particles of CaCO3. Antarctic Bottom and Intermediate Waters have aδ13C value of near 0.5‰ relative to the PDB isotopic standard. The lowest values in the Atlantic ocean were found in the Antarctic Circumpolar waters which haveδ13C values as low as 0.2‰. The core of the North Atlantic Deep Water has aδ13C value of 1.0‰.  相似文献   

18.
Oils, condensates and natural gases in the Kekeya Field, southeast depression of the Tarim Basin were studied for their geochemical characteristics. According to the distribution analysis of the C2/C3 values with C1/C2 values, C2/C3 values with C1/C3 values, as well as C2/C3 values with dryness index, there are two different types of natural gases in the studied field, which are spatially regularly distributed. One is the oil cracking gas, located on shallow reservoirs over X 5 2 reservoir, namely Upper oil legs; the other is kerogen cracking gas, located on X 7 2 reservoirs, X8 reservoirs and E2 k reservoirs, namely Lower oil legs. In addition, the distribution patterns of molar concentration of oils and condensates with different carbon numbers of the n-alkanes in the Kekeya Field indicate that the crude oils have experienced several kinds of secondary alterations, which were closely related to the charging of gaseous hydrocarbons after petroleum accumulation. These results indicate that, based on the research of δ 13C values of individual hydrocarbons, heptane values and isoheptane values of light hydrocarbons and aromatic maturity parameters for oils, condensates and natural gases, oils and gases were charged at different geological time in the Kekeya Field.  相似文献   

19.
Natural gases discovered up to now in Lishui Sag, the East China Sea Basin, differ greatly in gaseous compositions, of which hydrocarbon gases amount to 2%–94% while non-hydrocarbon gases are dominated by CO2. Their hydrocarbon gases, without exception, contain less than 90% of methane and over 10% of C2 + heavier hydrocarbons, indicating a wet gas. Carbon isotopic analyses on these hydrocarbon gases showed that δ 13C1, δ 13C2 and δ 13C3 are basically lighter than ?44‰, ?29‰ and ?26‰, respectively. The difference in carbon isotopic values between methane and ethane is great, suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation. δ 13 \(C_{CO_2 } \) values of nonhydrocarbon gases are all heavier than ?10‰, indicating a typical abiogenic gas. The simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit, consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the latter. Moreover, δ 13C1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰ heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit while δ 13C2 and δ 13C3 values of the former are over 9‰ heavier than those of the latter. Currently the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag, where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter, therefore, natural gases in the LS36-1 oil-gas pool are mainly derived from the Yueguifeng Formation lacustrine source rock rather than the Lingfeng Formation marine or Mingyuefeng Formation coal-measures source rocks.  相似文献   

20.
The Devonian–Carboniferous Tsetserleg terrane of Mongolia forms part of the complex Central Asian Orogenic Belt (CAOB). The Tsetserleg terrane consists mainly of clastic sediments, and is situated in the southern Hangay–Hentey Basin. Internally the terrane is divided into the Erdenetsogt (Middle Devonian), Tsetserleg (Middle‐Upper Devonian) and Jargalant (Lower Carboniferous) Formations. Provenance and tectonic setting of the Hangay–Hentey Basin remains controversial, with proposals ranging from passive margin through to island‐arc. A suite of 94 Tsetserleg sandstones and mudrocks was collected with the aim of constraining provenance, source weathering, and depositional setting, using established petrographic and whole‐rock geochemical parameters. Petrographically the sandstones are immature, with average compositions of Q22F14L64, Q14F17L69, and Q18F12L70 in the Erdenetsogt, Tsetserleg, and Jargalant Formations, respectively. Lv/L ratios range from 0.81 to 1.00 (average 0.95), and P/F from 0.68 to 0.93 (average 0.83). Framework compositions indicate deposition in an undissected or transitional arc. Geochemically, the sandstones are classified as greywackes. Geochemical contrasts between sandstone and mudrock averages in each formation are small, with lithotype means for SiO2 ranging only from 65.54 to 68.62 wt.%. These features and weak trends on variation diagrams reflect the immaturity of the sediments. Comparison of elemental abundances with average upper continental crust, major element discriminant scores, and immobile element ratios indicate a uniform average source composition between dacite and rhyolite. The maximum value for the Chemical Index of Alteration in the Erdenetsogt Formation is about 78 after correction for K‐metasomatism, indicating moderate source weathering. Lower maximum values (61 and 63, respectively) in the Tsetserleg and Jargalant Formations indicate they were derived from a virtually unweathered and tectonically active source. Tectonic setting discrimination parameters indicate a continental island‐arc environment, similar to several other CAOB suites of similar age. This arc source may have been built on a continental fragment situated within the Mongol–Okhotsk Ocean during Middle Devonian‐Lower Carboniferous time.  相似文献   

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