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1.
《高原气象》2016,(1)
利用IPCC第5阶段试验计划(CMIP5)整理提供的全球臭氧(O_3)分析资料和全球O_3和紫外线辐射数据中心(WOJDC)提供的O_3台站观测资料评估了国家气候中心最新发展的全球大气化学环流模式BCC-AGCM-Chem0对对流层大气O_3变化趋势的模拟能力。结果表明,BCC-AGCM—Chem0模式对对流层O_3的变化趋势具有较好的模拟能力,具体表现在:(1)BCC-AGCM—Chem0模式可以较好地模拟出1871-1999年全球对流层不同高度O_3浓度逐渐升高的基本特征;(2)BCC—AGCM-Chem0模式对1871-1999全球对流层O_3柱浓度纬圈平均异常变化的模拟与CMIP5资料一致,北半球升高趋势明显大于南半球,且升高最大区域的中心位置和强度也与CMIP5资料一致;(3)BCC-AGCM—Chem0模式对1000~300 hPa整体O_3柱浓度变化趋势模拟较好,对O_3柱浓度快速上升的区域和上升速度的模拟都与CMIP5资料一致,但对低层O_3柱浓度升高模拟偏强,对高层O_3柱浓度变化模拟偏弱;(4)与台站观测资料对比,在对流层中低层模拟结果在亚洲Sapporo站和欧洲Hohenpeissenberg站与实际观测比较接近,并与CMIP5资料相似,均呈升高趋势。对流层中高层模式模拟的O_3浓度异常存在明显的周期变化,与台站观测结果一致。 相似文献
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《高原气象》2015,(6)
利用由国家气候中心最近研发的全球大气环流化学模式BCC-AGCM-ChemO对1871-1999年全球大气O_3浓度进行了模拟,并利用全球臭氧和紫外线辐射数据中心(WOUDC)提供的O_3台站观测资料以及第5次耦合模式国际比较计划(CMIP5)整理的一套全球O_3分析资料对BCC-AGCM-ChemO模拟的O_3的气候平均态及季节变化特征进行了评估。结果表明:(1)BCC-AGCM-ChemO模式模拟出了全球年平均的O_3空间分布特征,表现为北半球O_3浓度高于南半球,O_3的经向分布大致呈由低纬向高纬递增;模式可以再现台站观测的O_3浓度垂直分布结构;相对于CMIP5分析数据,BCC-AGCM-ChemO模拟的O_3气柱总量在40°S以南的南大洋区域,模拟值偏低3~6 DU,在40°S-50°N中低纬地区略偏高3~6DU,陆地地区差异明显大于海洋地区,这些模拟偏差与地面排放和模式中O_3水平和垂直平流输送的影响有关。(2)BCC-AGCM-ChemO模式对全球O_3浓度的季节变化特征也有较好的模拟能力,模拟的O_3柱浓度与CMIP5资料的结果在1、4、7和10月的全球格点空间相关系数分别达到0.89,0.97,0.86和0.91;模式再现了南、北半球O_3浓度春季偏大、秋季偏小的特点;(3)从模式模拟和台站观测的对比分析来看,500 hPa以上的对流层中高层与以下的对流层中低层的O_3季节变化峰值存在明显的不一致性,表明500 hPa以下的中低层区域O_3变化可能受地面排放和干、湿等过程的影响较大,而对流层中高层的O_3变化可能与化学过程和平流层向下的输送影响较大有关。 相似文献
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将区域海气耦合模式RegCM3-POM和区域气候模式RegCM3 40年(1963-2002年)的模拟结果与NCEP/NCAR再分析资料进行对比,检验区域海气耦合模式对中国华北地区夏季大气水汽含量和水汽输送特征的模拟能力,比较耦合模式与单独区域气候模式的差异.结果表明,区域海气耦合模式RegCM3-POM的模拟性能相对于单独区域气候模式RegCM3,大气水汽输送特征的模拟能力有了较大的改进.分析显示两种模式都能够较好地再现东哑地区气候平均夏季大气水汽储量浅红和水汽输送的空间分布特征,而耦合模式对大气水汽输送的模拟更为合理.在对流层中低层更接近观测;耦合模式对中国华北地区夏季平均大气水汽输送通量在垂直方向卜的分布型及水平4个边界水汽输送收支的模拟,相对于单独大气模式有了一定的改进;耦合模式对伴随华北地区夏季早涝的大气水汽异常输送也具有较好的模拟能力,其模拟的水汽输送异常的来源与观测基本一致,尤其是在20°N以北地区,耦合模式结果相对于单独区域气候模式有了很大的改进.但同时耦合模式在低纬度海洋上对气候平均夏季大气水汽含量模拟的偏差比区域气候模式显著;与观测相比,耦合模式对来自孟加拉湾地区的大气水汽输送模拟偏弱,而对西太平洋副热带高压西侧水汽输送模拟偏强,与华北夏季旱涝相联系的水汽输送异常的模拟在低纬度海洋上也存在明显偏差. 相似文献
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本文利用MODIS和MISR卫星反演的地面PM2.5浓度和来自大气化学和气候模式比较计划（ACCMIP）的4个耦合了大气化学模块的气候模式（GFDL-AM3、NCAR-CAM3.5、GISS-E2-R和MIROC-CHEM）模拟的PM2.5浓度数据,评估分析了4个全球模式对中国地区地面PM2.5浓度时空变化特征的模拟能力。结果表明：4个模式集合模拟的PM2.5浓度在中国东部模拟效果较好。对比单个模式,GFDL-AM3模式对中国PM2.5浓度的空间分布型模拟效果最好。模式结果之间的一致性差异显著的地区主要出现在新疆中部和内蒙古西部地区。从整个中国地区的区域平均的时间序列来看,4个模式集合平均结果与观测结果相差不大,基本能够反映出东北、华中、华东沿海、新疆西部地区的PM2.5浓度的变化趋势。 相似文献
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利用第五次耦合模式比较计划(Phase 5 of Coupled Model Intercomparison Project,CMIP5)提供的30个全球气候模式模拟的1961~2005年的夏季逐月环流场资料及同期NCEP再分析资料,引入泰勒图及各种评估指标,探讨全球气候模式对东亚夏季平均大气环流场的模拟能力,寻求具有较好东亚夏季环流场模拟能力的气候模式。结果表明:1)全球气候模式能够模拟出东亚夏季平均大气环流的基本特征,CMIP5模式的总体模拟能力较第三次耦合模式比较计划(CMIP3)有较大程度的提高,如CMIP5模式对东亚大部分地区夏季海平面气压(Sea Level Pressure,SLP)场的模拟偏差在6 h Pa以内。2)模式对不同层次环流场的模拟能力存在差异,500 h Pa高度场的模拟能力最强,其次为100 h Pa高度场、850 h Pa风场,SLP场最弱;对东亚夏季主要环流系统的模拟对比发现,模式对印度热低压及东伸槽强度指数的模拟能力最好。3)综合CMIP5模式对东亚夏季各层次平均环流场以及主要环流系统的模拟能力,发现模拟较好的5个模式为CESM1-CAM5、MPI-ESM-MR、MPI-ESM-LR、MPI-ESM-P和Can ESM2。4)相对于单一模式,多模式集合平均(MME)模拟能力较强,但较优选的前5个模式集合平均的模拟能力弱。 相似文献
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利用2014—2016年的中国气象局地面观测资料和中国环境保护部公布的6种大气污染物浓度数据,对降雨天气前后的大气污染物浓度变化进行分析。结果表明:在京津冀、长三角和珠三角区域,降雨天气后6种大气污染物浓度降低的时次约占43%—60%,其中PM_(10)浓度降低最为明显,PM_(2.5)、O_3、SO_2和NO_2次之,最不明显的是CO。一般而言,降水天气前大气污染物浓度越高,降雨后浓度降低的时次所占比例越大,浓度降低值也越大,但当降雨天气前大气污染物浓度较低时,降雨天气后浓度升高的个例也很多,约占21%—61%。京津冀地区由于平均大气污染物浓度较高,降水天气对大气污染浓度的降低效果比长三角和珠三角地区更明显。对于大多数降雨时次,小时降水量越大,大气污染物浓度降低的时次所占比例越大,但浓度降低值反而越小。例外的是,小时雨强大于10 mm的降雨后,京津冀地区的O_3和SO_2浓度以及长三角地区的PM_(10)、PM_(2.5)和SO_2浓度降低程度不如小时雨强小于10 mm时;而珠三角地区的NO_2和O_3在降雨后的浓度变化对小时雨强不敏感。在京津冀地区,降雨天气对较大浓度的O_3清除作用非常明显。在长三角和珠三角地区,降雨前CO浓度较低时,降雨后浓度升高时次比浓度减小的多;另外,降雨天气对SO_2的清除作用非常明显。 相似文献
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全球海气耦合模式系统(NIM/COAMS)Ⅱ.年际变化的模拟 总被引：1，自引：1，他引：1
利用文献[1]建立的全球海气耦合模式系统（NIM／COAMS），对模式的年际变化模拟能力进行了检验。50a积分显示，模式模拟出了大气和海洋界面的主要年际变率，能真实地模拟热带太平洋ENSO循环的主要特征，较好地再现了ENSO循环的过程，循环周期在3—5a之间，与实际观测值一致，同时模式也较好地反映了大气和海洋的耦合特征，对年际变化有较强的模拟能力，这与FRAC耦合方案设计有关，该方法能避免气候场的牵制作用，增强模式对年际变化的模拟能力。 相似文献
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复杂地形城市冬季大气污染的数值模拟研究 总被引：10，自引：21，他引：10
采用中尺度大气动力模式与大气扩散模式相结合的方法，针对复杂地形条件下兰州市冬季无明显冷空气入侵天气过程时段（1994年12月2－3日）的大气污染状况，进行污染物（二氧化硫和烟尘）浓度分布的数值模拟研究，分析了模拟的风场的气温层结随时间的变化以及污染物浓度的分布及其变化，进一步分析了模拟的风场和气温层结与污染物浓度分布的关系。结果表明，该模式系统对兰州市大气边界层结构及污染物浓度的分布有较好的模拟能力，并证明了该模式系统可适用于兰州市大气质量预测预报研究。 相似文献
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Models-3空气质量模式对兰州市污染物输送的模拟 总被引：23，自引：7，他引：16
较详细地介绍了美国环保总局的第三代空气质量模式系统Models-3的特点,并且针对兰州市冬季采暖期污染严重的特点,选取2002年12月份的个例,将兰州市最新的大气污染源资料加入模式中．对模式进行调试并检验了该模式对兰州污染的模拟性能。从模式对SO2,NO2和O3等几种大气污染物浓度的模拟结果与监测资料对比分析,表明该模式系统较好地模拟出了SO2,NO2的空间分布格局,模拟结果与监测结果比较吻合,而且模式模拟的污染物浓度场比较均匀;模式模拟的O3的日变化规律与资料分析结论基本一致,也符合O3的生成机理。因此该模式系统对于复杂地形条件下的城市污染物输送具有一定的模拟能力。 相似文献
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Currently, air pollution in Beijing has become a complex problem with two types of source pollutants： coal smoke and photochemical smog. Furthermore the maximum hourly mean concentration of O3 increases continuously, especially in the summer. In order to simulate the photochemical reaction, develop an air quality simulation model and further improve the air quality of Beijing, a precisely temperature-controlled, indoor, smog chamber facility was designed and constructed at Tsinghua University. Characterization experiments have been carried out to acquire the basic parameters of the smog chamber, such as the wall loss rates of NO2, NO, O3, C3H6 and particulate matter （PM）, the intensity of ultraviolet （UV） light in the chamber, the reactivity of the purified air and the reproducibility of the experimental results. The results indicate that the facility performs up to specifications, and can meet the demands required for simulating the photochemical reaction. The effect of high primary contaminated PM on the formation of ozone and secondary organic aerosol （SOA） is under investigation. 相似文献
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应用查表法模拟区域对流层O3、Nox分布和演化的研究 总被引：2，自引：0，他引：2
应用STEM-II气相光化学模式探讨了影响对流层O3、NOx气相光化学转化率的各物理、化学因子。表明在我国多数地区光化学污染物特征(NMHC/NOx较高)下,光辐射强度、温度、初始O3浓度和NOx浓度是影响O3、NOx气相光化学转化率的主要因子。将以上因子分档组合,计算并建立了各种情况下O3、NOx气相光化学转化率的查算表,并将之用于模拟区域O3、NOx的演化和分布。结果表明,与光化学模式直接耦合计算法相比,该方法既能显著缩短计算时间,又能基本反映大气化学反应的非线性过程,并与直接耦合法符合得较好。 相似文献
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南京地区大气颗粒物影响近地面臭氧的个例研究 总被引：4，自引：0，他引：4
通过对2008年4月2～7日南京地区地面气象观测数据以及两个站点空气质量(O3、NOx、PM10)监测资料的分析, 发现O3和PM10之间存在一定程度的反相关。利用一个光化学箱模式对该个例中大气颗粒物影响近地面臭氧的过程进行模拟, 结果发现大气颗粒物浓度的升高使得气溶胶光学厚度增加20％～40%, 导致NO2和O3近地面光解率下降20%～30%, OH和HO2自由基浓度分别减少20%～50%, 造成O3净生成率下降30%～40%。研究表明, 颗粒物对光化学过程的抑制造成了大气氧化能力的降低, 是近地面臭氧浓度减少的可能原因。 相似文献
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Min XUE Jianzhong MA Guiqian TANG Shengrui TONG Bo HU Xinran ZHANG Xinru LI Yuesi WANG 《大气科学进展》2021,38(7):1209-1222
Photochemical smog characterized by high concentrations of ozone (O3) is a serious air pollution issue in the North China Plain (NCP) region, especially in summer and autumn. For this study, measurements of O3, nitrogen oxides (NOx), volatile organic compounds (VOCs), carbon monoxide (CO), nitrous acid (HONO), and a number of key physical parameters were taken at a suburban site, Xianghe, in the NCP region during the summer of 2018 in order to better understand the photochemical processes leading to O3 formation and find an optimal way to control O3 pollution. Here, the radical chemistry and O3 photochemical budget based on measurement data from 1-23 July using a chemical box model is investigated. The daytime (0600-1800 LST) average production rate of the primary radicals referred to as ROx (OH + HO2+ RO2) is 3.9 ppbv h-1. HONO photolysis is the largest primary ROx source (41％). Reaction of NO2 + OH is the largest contributor to radical termination (41％), followed by reactions of RO2 + NO2 (26％). The average diurnal maximum O3 production and loss rates are 32.9 ppbv h-1 and 4.3 ppbv h-1, respectively. Sensitivity tests without the HONO constraint lead to decreases in daytime average primary ROx production by 55％ and O3 photochemical production by 42％, highlighting the importance of accurate HONO measurements when quantifying the ROx budget and O3 photochemical production. Considering heterogeneous reactions of trace gases and radicals on aerosols, aerosol uptake of HO2 contributes 11％ to ROx sink, and the daytime average O3 photochemical production decreases by 14％. The O3-NOx-VOCs sensitivity shows that the O3 production at Xianghe during the investigation period is mainly controlled by VOCs. 相似文献
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Numerical Simulation Study on the Impacts of Tropospheric O_3 and CO_2 Concentration Changes on Winter Wheat. Part Ⅱ: Simulation Results and Analyses 
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下载免费PDF全文 With the rapid development of industrialization and urbanization, the enrichment of tropospheric ozone and carbon dioxide concentration at striking rates has caused effects on biosphere, especially on crops. It is generally accepted that the increase of CO2 concentration will have obverse effects on plant productivity while ozone is reported as the air pollutant most damaging to agricultural crops and other plants. The Model of Carbon and Nitrogen Biogeochemistry in Agroecosystems (DNDC) was adapted to evaluate simultaneously impacts of climate change on winter wheat. Growth development and yield formation of winter wheat under different O3 and CO2 concentration conditions are simulated with the improved DNDC model whose structure has been described in another paper. Through adjusting the DNDC model applicability, winter wheat growth and development in Gucheng Station were simulated well in 1993 and 1999, which is in favor of modifying the model further. The model was validated against experiment observation, including development stage data, leaf area index, each organ biomass, and total aboveground biomass. Sensitivity tests demonstrated that the simulated results in development stage and biomass were sensitive to temperature change. The main conclusions of the paper are the following: 1) The growth and yield of winter wheat under CO2 concentration of 500 ppmv, 700 ppmv and the current ozone concentration are simulated respectively by the model. The results are well fitted with the observed data of OTCs experiments. The results show that increase of CO2 concentration may improve the growth of winter wheat and elevate the yield. 2) The growth and yield of winter wheat under O3 concentration of 50 ppbv, 100 ppbv, 200 ppbv and the based concentration CO2 are simulated respectively by the model. The simulated curves of stem, leaf, and spike organs growth as well as leaf area index are well accounted with the observed data. The results reveal that ozone has negative effects on the growth and yield of winter wheat. Ozone accelerates the process of leaf senescence and causes yield loss. Under very high ozone concentration, crops are damaged dramatically and even dead. 3) At last, by the model possible effects of air temperature change and combined effects of O3 and CO2 are estimated respectively. The results show that doubled CO2 concentration may alleviate negative effect of O3 on biomass and yield of winter wheat when ozone concentration is about 70-80 ppbv. The obverse effects of CO2 are less than the adverse effects of O3 when the concentration of ozone is up to 100 ppbv. Future work should determine whether it can be applied to other species by adjusting the values of related parameters, and whether the model can be adapted to predict ozone effects on crops in farmland environment. 相似文献
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Numerical Study on the Impacts of Heterogeneous Reactions on Ozone Formation in the Beijing Urban Area 总被引：2，自引：0，他引：2
The air quality model CMAQ-MADRID （Community Multiscale Air Quality-Model of Aerosol Dynamics, Reaction, Ionization and Dissolution） was employed to simulate summer O3 formation in Beijing China, in order to explore the impacts of four heterogeneous reactions on O3 formation in an urban area. The results showed that the impacts were obvious and exhibited the characteristics of a typical response of a VOC-limited regime in the urban area. For the four heterogeneous reactions considered, the NO2 and HO2 heterogeneous reactions have the most severe impacts on O3 formation. During the O3 formation period, the NO2 heterogeneous reaction increased new radical creation by 30%, raising the atmospheric activity as more NO→NO2 conversion occurred, thus causing the O3 to rise. The increase of O3 peak concentration reached a maximum value of 67 ppb in the urban area. In the morning hours, high NO titration reduced the effect of the photolysis of HONO, which was produced heterogeneously at night in the surface layer. The NO2 heterogeneous reaction in the daytime is likely one of the major reasons causing the O3 increase in the Beijing urban area. The HO2 heterogeneous reaction accelerated radical termination, resulting in a decrease of the radical concentration by 44% at the most. O3 peak concentration decreased by a maximum amount of 24 ppb in the urban area. The simulation results were improved when the heterogeneous reactions were included, with the O3 and HONO model results close to the observations. 相似文献
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Numerical Simulation Study on the Impacts of Tropospheric O3 and CO2 Concentration Changes on Winter Wheat. Part II: Simulation Results and Analyses 下载免费PDF全文
下载免费PDF全文 With the rapid development of industrialization and urbanization, the enrichment of tropospheric ozone and carbon dioxide concentration at striking rates has caused effects on biosphere, especially on crops. It is generally accepted that the increase of CO2 concentration will have obverse effects on plant productivity while ozone is reported as the air pollutant most damaging to agricultural crops and other plants. The Model of Carbon and Nitrogen Biogeochemistry in Agroecosystems (DNDC) was adapted to evaluate simultaneously impacts of climate change on winter wheat. Growth development and yield formation of winter wheat
under different O3 and CO2 concentration conditions are simulated with the improved DNDC model whose structure has been described in another paper. Through adjusting the DNDC model applicability, winter wheat growth and development in Gucheng Station were simulated well in 1993 and 1999, which is in favor of modifying the model further. The model was validated against experiment observation, including development stage data, leaf area index, each organ biomass, and total aboveground biomass. Sensitivity tests demonstrated that the simulated results in development stage and biomass were sensitive to temperature change. The main conclusions of the paper are the following: 1) The growth and yield of winter wheat under CO2 concentration of 500 ppmv, 700 ppmv and the current ozone concentration are simulated respectively by the model. The results are well fitted with the observed data of OTCs experiments. The results show that increase of CO2 concentration may improve the growth of winter wheat and elevate the yield. 2) The growth and yield of winter wheat under O3 concentration of 50 ppbv, 100 ppbv, 200 ppbv and the based concentration CO2 are simulated respectively by the model. The simulated curves of stem, leaf, and spike organs growth as well as leaf area index are well accounted with the observed data. The results reveal that ozone has negative e ects on the growth and yield of winter wheat. Ozone accelerates the process of leaf senescence and causes yield loss. Under very high ozone concentration, crops are damaged dramatically and even dead. 3) At last, by the model possible effects of air temperature change and combined effects of O3 and CO2 are estimated respectively. The results show that doubled CO2 concentration may alleviate negative effect of O3 on biomass and yield of winter wheat when ozone concentration is about 70-80 ppbv. The obverse effects of CO2 are less than the adverse effects of O3 when the concentration of ozone is up to 100 ppbv. Future work should determine whether it can be applied to other species by adjusting the values of related parameters, and whether the model can be adapted to predict ozone e ects on crops in farmland environment. 相似文献
20.
中国大气本底条件下不同地区地面臭氧特征 总被引：20，自引：1，他引：20
分析了晴天和阴天时瓦里关本底台、临安和龙凤山本底站地面 O3浓度的特点。晴天时 ,临安站地面 O3有明显日变化 ,以春季最大 (42 .9× 1 0 - 9) ,夏季最小 (2 0 .3× 1 0 - 9) ;龙凤山站日变化更规则 ,秋季最大 (约 2 7× 1 0 - 9) ;瓦里关本底台除了夏季有微弱日变化外 ,其它季节没有明显的日变化 ,日较差也很小 ,但夏季地面 O3浓度显著高於冬季 ;夏季晴天瓦里关地面O3浓度要比龙凤山、临安高 2 0× 1 0 - 9以上。阴天时 ,临安和龙凤山站除了日变化不很规则和日较差较小外 ,其它大致与晴天相同。阴天时瓦里关不仅没有日变化 ,而且日较差更小 ,但夏季地面 O3仍然高於冬季。太阳总辐射和 NOx 浓度是控制龙凤山和临安晴天和阴天地面O3浓度的决定性因子 ,它在不同季节和地区发挥着重要作用。夏季青藏高原周围地区气流向高原输送作用 ,是形成夏季瓦里关地面 O3高值以及微弱日变化的主要原因。在美国 MaunaLoa基准站也曾观测到类似的输送影响。O3在低对流层随垂直高度增加的分布特征 ,决定了东西部测点地面 O3的差异 相似文献