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1.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

2.
A Comparative Analysis of Transpiration and Bare Soil Evaporation   总被引：4，自引：0，他引：4  
Transpiration Ev and bare soil evaporation Eb processes are comparatively analysed assuming homogeneous and inhomogeneous areal distributions of volumetric soil moisture content . For a homogeneous areal distribution of we use a deterministic model, while for inhomogeneous distributions a statistical-deterministic diagnostic surface energy balance model is applied. The areal variations of are simulated by Monte-Carlo runs assuming normal distributions of .The numerical experiments are performed for loam. In the experiments we used different parameterizations for vegetation and bare soil surface resistances and strong atmospheric forcing. According to the results theEv()-Eb() differences are great, especially in dry conditions. In spite of this, the available energy flux curves of vegetation Av() and bare soil Ab() surfaces differ much less than the Ev() and Eb() curves. The results suggest that Ev is much more non-linearly related to environmental conditions than Eb. Both Ev and Eb depend on the distribution of , the wetness regime and the parameterization used. With the parameterizations, Eb showed greater variations than Ev. These results are valid when there are no advective effects or mesoscale circulation patterns and the stratification is unstable.  相似文献   

3.
Equilibrium evaporation beneath a growing convective boundary layer   总被引：1，自引：1，他引：0  
Expressions for the equilibrium surface Bowen ratio ( s ) and equilibrium evaporation are derived for a growing convective boundary layer (CBL) in terms of the Bowen ratio at the top of the mixed layer i and the entrainment parameter A R . If AR is put equal to zero, the solution for s becomes-that previously obtained for the zero entrainment or closed box model. The Priestley-Taylor parameter is also calculated and plotted in terms ofA R and i . Realistic combinations of the atmospheric parameters give values of in the range 1.1 to 1.4.  相似文献   

4.
Cloud water and interstitial aerosol samples collected at Mt. Sonnblick (SBO) were analyzed for sulfate and aerosol carbon to calculate in-cloud scavenging efficiencies. Scavenging efficiencies for sulfate (SO) ranged from 0.52 to 0.99 with an average of 0.80. Aerosol carbon was scavenged less efficiently with an average value (AC) of 0.45 and minimum and maximum values of 0.14 and 0.81, respectively. Both SO and AC showed a marked, but slightly different, dependence on the liquid water content (LWC) of the cloud. At low LWC, SO increased with rising LWC until it reached a relatively constant value of 0.83 above an LWC of 0.3 g/m3. In the case of aerosol carbon, we obtained a more gradual increase of AC up to an LWC of 0.5 g/m3. At higher LWCs, _ remained relatively constant at 0.60. As the differences between SO and A varied across the LWC range observed at SBO, we assume that part of the aerosol carbon was incorporated into the cloud droplets independently from sulfate. This hypothesis is supported by size classified aerosol measurements. The differences in the size distributions of sulfate and total carbon point to a partially external mixture. Thus, the different chemical nature and the differences in the size and mixing state of the aerosol particles are the most likely candidates for the differences in the scavenging behavior.  相似文献   

5.
We analyze the checkerboard problem of many alternating surfaces with different properties, on scales up to (say) 3,000 m. Power-law representations of the vertical profiles of mean wind speed and eddy diffusivity lead to solutions in terms of Kelvin and trigonometric functions.These solutions are used to determine blending heights (*), where deviations from the mean of concentration, or of vertical flux density, fall to some small fraction, , of their value at the surface. Values of *are important for regional and larger-scale meteorological models. In smaller scale micrometeorological studies, they may serve also as the top levels of surface boundary layers.An important result for both theoretical and experimental contexts is that deviations of flux persist with elevation much more strongly than those of concentration, so that, in general, * should be based on flux rather than concentration. Representative values of *, for = 0.05, are of order 5 and 30 m for surface pattern wavelengths of 102 and 103 m, respectively. Values of * are robust to changes in adopted power-law indices, and are independent of wind speed. Surface roughness has a mild but calculable effect.  相似文献   

6.
Components of the radiation and energy balances were measured over a clear-cut area and a mature, mixed forest during the summer of 1981 at the Petawawa National Forestry Institute, Chalk River, Ontario. The work concentrated on the clear-cut site which supported a canopy layer composed primarily of bracken fern and logging remnants.Forty days of radiation data were collected at the clear-cut site. After the first four weeks of measurements (the green season), most of the ferns quickly died, and their foliage changed appearance from a green to brownish colour (the brown season). The daily mean reflection coefficient of solar radiation determined over the green season was 0.20 and decreased to 0.13 for the brown season. The corresponding value for the forest was 0.13, based on a limited amount of data. The clear-cut site received 11% and 21% less net radiation than the forest on a 24-hr and daylight-hours basis, respectively, as a consequence of the higher reflection coefficient and larger daytime longwave radiation emission.A reversing temperature difference measurement system (RTDMS), incorporating ten-junction thermopiles was employed at each site in order to determine Bowen ratios () via differential psychrometry. Both systems performed well, especially the RTDMS over the forest which was capable of resolving very small differences of temperature, typically less than 0.2 °C over a height of 3 m. The mean hourly Bowen ratio, calculated from values from 0800 to 1600 hr, varied from 0.2 to 1.0 for the forest and from 0.4 to 0.8 for the clear-cut site in the green season.A significant canopy heat storage component of the energy balance, Q S , was found at the clear-cut site. In the early morning, a portion of the available energy was used to heat the biomass materials and air within the canopy layer. The stored heat within the canopy was released later in the day, increasing the available energy total.The daily mean value of the Priestley-Taylor coefficient (Priestley and Taylor, 1972) for the green season at the clear-cut site was 1.14, and individual values tended to increase during wet surface conditions and decrease when the surface dried. The daylight mean value during dry canopy conditions at the forest was 1.05, and much higher values occurred when the canopy was wet. The enhancement of for the wet forest was a result of the evaporation of intercepted rain (which is not limited by stomatal resistance) and the concomitant transfer of sensible heat to the forest.  相似文献   

7.
The standard E – model generates aplanetary boundary layerthat appears to be much too deep. The cause of theproblem is traced to the equation for the dissipationrate () of turbulent kinetic energy (E), specifically theparameterization of dissipation production anddestruction. In the context of atmosphericboundary-layer modelling, we argue that a part of thedissipation production should be modelled as the inputto the spectral cascade from the energy-containingpart of the spectrum, with a characteristic length , while the equilibrium imbalancebetween local production and destruction ofdissipation is modelled as proportional toE2/E, as in the standard model. Wepropose an E – – turbulence closurescheme, in which both the mixing length, m, and are prescribed. The importance ofthe equation is diminished, though itstill determines the dissipation rate in the Eequation.  相似文献   

8.
An observation of waves and turbulence in the earth's boundary layer   总被引：1，自引：1，他引：1  
An account is given of an observation of a wave-like phenomenon obtained during a study of nocturnal inversions. Associated bursts of turbulent activity are also described.  相似文献   

9.
We formulate a method for determining the smallest time interval Tover which a turbulence time series can be averaged to decompose it intoinstantaneous mean and random components. From the random part the method defines the optimal interval (or averaging window) AW over which this part should be averaged to obtain the instantaneous spectrum. Both T and AW vary randomly with time and depend on physical properties of the turbulence. T also depends on the accuracy of the measurements and is thus independent of AW. Interesting features of the method are its real-time capability and the non-equality between AW and T.  相似文献   

10.
The effect of changes in zonal and meridional atmospheric moisture transports on Atlantic overturning is investigated. Zonal transports are considered in terms of net moisture export from the Atlantic sector. Meridional transports are related to the vigour of the global hydrological cycle. The equilibrium thermohaline circulation (THC) simulated with an efficient climate model is strongly dependent on two key parameters that control these transports: an anomaly in the specified Atlantic–Pacific moisture flux (Fa) and atmospheric moisture diffusivity (Kq). In a large ensemble of spinup experiments, the values of Fa and Kq are varied by small increments across wide ranges, to identify sharp transitions of equilibrium THC strength in a 2-parameter space (between Conveyor On and Off states). Final states from this ensemble of simulations are then used as the initial states for further such ensembles. Large differences in THC strength between ensembles, for identical combinations of Fa and Kq, reveal the co-existence of two stable THC states (Conveyor On and Off)—i.e. a bistable regime. In further sensitivity experiments, the model is forced with small, temporary freshwater perturbations to the mid-latitude North Atlantic, to establish the minimum perturbation necessary for irreversible THC collapse in this bistable regime. A threshold is identified in terms of the forcing duration required. The model THC, in a Conveyor On state, irreversibly collapses to a Conveyor Off state under additional freshwater forcing of just 0.1 Sv applied for around 100 years. The irreversible collapse is primarily due to a positive feedback associated with suppressed convection and reduced surface heat loss in the sinking region. Increased atmosphere-to-ocean freshwater flux, under a collapsed Conveyor, plays a secondary role.  相似文献   

11.
Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (Exc/Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at Exc/Em240/405 nm and Exc/Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.  相似文献   

12.
A previously published technique for using tethered spherical balloons as anemometers for measuring light low-level winds has been further developed. Earlier data on the relationship between the aerodynamic drag coefficient and the Reynolds number of spherical rubber balloons were combined with a large number of new data and re-analysed; and the errors in the relationship were estimated. The results allowed a more accurate calculation of wind speed from the deflection of a tethered balloon from the vertical. When combined with a new technique for calculating the effects of the tether, this enabled light to moderate low-level winds at fixed heights up to 600 m or more to be measured with simple, cheap, and readily mobile equipment; and a slight modification of the technique allowed measurement of winds in and above fog. Wind speeds measured by the ballon technique showed reasonably good agreement with measurements by an anemometer carried beneath the balloon.Glossary of Symbols a, b, c Coefficients in the relationship between lnC d and lnR - A Quantity under square root in solution for lnV whena0 - C d Wind drag coefficient for balloon - C dc Value ofC d given by calibration curve of Table I - D Dynamic wind pressure force on balloon - F Buoyant free lift of balloon with load - Re Reynold's number of balloon (sphere) - R = Re/105 - r Radius of sphere - T Tension in tether - V Wind speed - 83() =(lnC dc -lnC d ) when 83° , or 0 for other - Error in lnC d - Elevation of tether where attached to balloon - Elevation of balloon from ground tether point - Molecular viscosity of air - Ratio of circumference to diameter of circle - Density of air  相似文献   

13.
The commonly measured value of in the relaxed eddy accumulationmethod of about 0.56is shown to arise from the non-Gaussiannature of turbulence. Fourth-orderGram–Charlier functions forthe two-dimensional probability distributionsof variation in the horizontal component of wind velocityand concentrations of water vapour, carbondioxide and methane with respect to thevertical component of wind velocity are used to examinethe value of .An analytical solution for ispresented in terms of fourth-order moments.Under mean conditions, this solution givesa value for of0.557. Variation of is shown to be controlledprimarily by the ratio of the mean ofc'w3 (where c'is relevant to the entity of interest andw' is vertical component of windvelocity) to the correlationcoefficient between the entity concentrationand vertical component of wind velocity.  相似文献   

14.
Summary The electromagnetic radiation of cloud discharge known as atmospheric radio noise field strength (ARNFS) shows a gradual fall from a frequency of 9 kHz to 81 kHz as studied over a period of two years at Calcutta, very close to Bay of Bengal. The main characteristic features of ARNFS at Calcutta are that-(i) ARNFS shows that midday median value is smaller than midnight median value in all months, (ii) level of daily minimum is higher in February and monsoon compared to other seasons, (iii) sunrise effect and sunset effect are well correlated with local sunrise and sunset times, (iv) the magnitude of sunrise fade and sunrise fade rate are maximum in April and lowest during winter period, (v) the magnitude of sunset fade is higher in premonsoon and postmonsoon while it is lowest in monsoon, (vi) number of occurrence of both sunrise effect and sunset effect is remark-ably smaller in monsoon. The positions of the sun and of atmospheric sources are jointly the causes of seasonal and diurnal variations. The missing of sunrise effect and sunset effect are due to local cloud activity and variation of electron density during geomagnetic storms.With 7 Figures  相似文献   

15.
TheConvectiveDiffusionObserved byRemoteSensors (CONDORS) field experiment conducted at the Boulder Atmospheric Observatory used innovative techniques to obtain three-dimensional mappings of plume concentration fields, /Q, of oil fog detected by lidar and chaff detected by Doppler radar. It included extensive meteorological measurements and, in 1983, tracer gases measured at a single sampling arc. Final results from ten hours of elevated and surface release data are summarized here. Many intercomparisons were made. Oil fog /Q measured 40m above the arc are mostly in good agreement withSF 6 values, except in a few instances with large spacial inhomogeneities over short distances. After a correction scheme was applied to compensate for the effect of its settling speed, chaff dy/Q agreed well with those of oil except in two cases of oil fog hot spots. Mass or frequency distribution vs. azimuth or elevation angle comparisons were made for chaff, oil, and wind, with mostly good agreements. Spacial standard deviations, y and z, of chaff and oil agree overall and are consistent at short range with velocity standard deviations vand w 0.6w* (the convective scale velocity), as measured atz>100m. Surface release y is enhanced up to 60% at smallx, consistent with the Prairie Grass measurements and with larger v and reduced wind speed measured near the surface. Decreased y at small dimensionless average times is also noted. Finally, convectively scaled dy, C y, were plotted versus dimensionlessx andz for oil, chaff, and corrected chaff for each 30–60 min period. Aggregated CONDORSC y fields compare well with laboratory tank and LES numerical simulations; surface-released oil fog compares expecially well with the tank experiments. However, large deviations from the norm occurred in individual averaging periods; these deviations correlated strongly with anomalies in measured distributions.On assignment to the US Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory, RTP, NC.  相似文献   

16.
A vapour of radio-lead (212Pb) has been used to measure the Sherwood number, Sh, of model leaves at various angles of incidence,, to the airstream in a wind tunnel. The results for=0 are compared with Pohlhausen's formula and the results for 0, with Powell's experiments. The local values of Sh on the upwind and downwind sides of discs have been obtained. For leaves in the canopy, Sh was found to be about 25% greater than would be predicted by applying Pohlhausen's equation without correction for orientation.  相似文献   

17.
Shear convection     
The paper discusses convection in the presence of wind shear, a condition analysed previously by Zilitinkevich (1971). This region (between the forced and fully developed convective layers) was also considered by Betchov and Yaglom (1971). In the present paper the author endeavors to develop a consistent analysis from the basic hypothesis of a very weak interaction between the vertical convective motions and mechanical turbulence, employing a new similarity model of the turbulent regime. Additional experimental data are introduced. Unlike the notation used in the references quoted above, this regime is termed shear convection rather than free convection. The latter is traditionally regarded as synonymous with the terms pure or fully developed convection.  相似文献   

18.
This paper considers the near-field dispersion of an ensemble of tracer particles released instantaneously from an elevated source into an adiabatic surface layer. By modelling the Lagrangian vertical velocity as a Markov process which obeys the Langevin equation, we show analytically that the mean vertical drift velocity w(t) is w()=bu *(1–e –(1+)), where is time since release (nondimensionalized with the Lagrangian time scale at the source), b Batchelor's constant, and u *, the friction velocity. Hence, the mean height and mean depth of the ensemble are calculated. Although the derivation is formally valid only when 1, the predictions for w, mean height and mean depth are consistent in the downstream limit ( 1) with surface-layer Lagrangian similarity theory and with the diffusion equation. By comparing the analytical predictions with numerical, randomflight solutions of the Langevin equation, the analytical predictions are shown to be good approximations at all times, both near-field and far-field.  相似文献   

19.
The variations of and in the drainage flow in the Brush Creek valley of western Colorado are investigated using data from Doppler acoustic sodars and instrumented towers. The data were obtained on two experimental nights during the 1984 ASCOT field study. There is good agreement between the variations derived from low-level observations of the sodars and those derived from the towers located throughout the valley. The observed hourly average and in the nocturnal drainage flow are about 20 ° to 25 ° and 5 °, respectively; these values are much larger than those generally observed over flat terrain during nighttime stable conditions. After sunrise (about 0600 MST), as the valley warms and the flow direction changes to up-valley, these parameters increase sharply to their peak values at about 0800 MST and then decrease to their normal daytime values after about two hours.In the drainage flow, the hourly average varies inversely with wind speed according to the relation u 0.7ms-1. The vertical standard deviation is much less enhanced by complex terrain than the horizontal standard deviation. The observed values are predicted fairly well by the local similarity theory.Oak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 andOak Ridge Associated Universities (ORAU) Summer Research Participant at ATDD in 1987 and  相似文献   

20.
Parameterization of evaporation from a non-plant-covered surface is very important in the hierarchy strategy of modelling land surface processes. One of the representations frequently used in its computation is the resistance formulation. The performance of the evaporation schemes using the , , and their combination resistance approaches to parameterize evaporation from bare soil surfaces is discussed. For that purpose, the nine schemes, based on a different dependence of and on volumetric soil moisture content and its saturated value, are used.The tests of performances of the considered schemes are based on time integrations by the land surface module (BARESOIL) using observed data. The 23 data sets at a bare surface experimental site in Rimski anevi, Yugoslavia on chernozem soil, were used for the resistance algorithm evaluation. The quality of the schemes was compared with the observed values of the latent heat flux using several statistical parameters.  相似文献   

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