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1.
Using a single drop experiment, the uptake of NO3 radicals on aqueous solutions of the dye Alizarin Red S and NaCl was measured at 293 K. Uptake coefficients in the range (1.7–3.1) ⋅ 10− 3 were measured on Alizarin Red S solutions. The uptake coefficients measured on NaCl solutions were in the range of (1.1–2.0) ⋅ 10−3 depending on the salt concentration. Both experiments lead to a consistent result for the mass accommodation coefficient of αNO3 = (4.2− 1.7+2.2)⋅ 10−3. The product H(Dl kCl−II)0.5 for the NO3 radical was determined to be (1.9 ± 0.2) M atm− 1 cm s−0.5 M−0.5 s−0.5 by fitting the uptake data for the NaCl solutions to the so-called resistance model. The yield of the chemical NO3 radical source was characterized using UV-VIS and FT-IR spectroscopy. The amount of gas-phase NO3 radicals measured at elevated humidities was less than expected. Instead, a rise of the gas-phase HNO3 concentration was found indicating a conversion of gas-phase NO3 radicals to gas-phase HNO3 on the moist reactor walls.  相似文献   

2.
Expedition data obtained in the coastal-shelf zone of the East Siberian Sea in September 2003, 2004, and 2008 are generalized. Studies of carbonate system in water and CO2 fluxes between ocean and atmosphere in this region confirmed that it was reasonable to divide the water area studied into two biogeochemical provinces and that the ecosystem of its coastal part is mainly of a heterotrophic nature. In different years, the extent of water supersaturation in carbon dioxide in the East Siberian Sea and the area of the CO2 release significantly changed. Geographic localization of the atmosphere action centers over the Arctic and their intensity were main determining factors; that told both on the formation of a basic character of the atmospheric and hydrological processes and on the dynamics of the CO2 exchange between water and air.  相似文献   

3.
Two parameterization schemes for vertical eddy diffusivity were utilized to investigate their impacts on both the daily and monthly mean concentrations of ozone and NOy, which are the major fractions of the sum of all reactive nitrogen species, i.e., NOy=NO＋NO2＋HNO3＋PAN. Simulations indicate that great changes in the vertical diffusivity usually occur within the planetary boundary layer （PBL）. Daily and monthly mean concentrations of NOy are much more sensitive to changes in the vertical diffusivity than those of ozone and ozone and NOy levels only at or in （relatively） clean sites and areas, where long-range transport plays a crucial role, display roughly equivalent sensitivity. The results strongly suggest that a widely-accepted parameterization scheme be selected and the refinement of the model＇s vertical resolution in the PBL be required, even for regional and long-term studies, and ozone only being examined in an effort to judge the model＇s performance be unreliable, and NOy be included for model evaluations.  相似文献   

4.
A dynamic global vegetation model (DGVM) is coupled to an atmospheric general circulation model (AGCM) to investigate the influence of vegetation dynamics on climate change under conditions of global warming. The model results are largely in agreement with observations and the results of previous studies in terms of the present climate, present potential vegetation, present net primary productivity (NPP), and pre-industrial carbon budgets. The equilibrium state of climate properties are compared among pre-industrial, doubled, and quadrupled atmospheric CO2 values using DGVM–AGCM and current AGCM with fixed vegetation to evaluate the influence of dynamic vegetation change. We also separated the contributions of temperature, precipitation and CO2 fertilization on vegetation change. The results reveal an amplification of global warming climate sensitivity by 10% due to the inclusion of dynamic vegetation. The total effects of elevated CO2 and climate change also lead to an increase in NPP and vegetation coverage globally. The reduction of albedo associated with this greening results in enhanced global warming. Our separation analysis indicates that temperature alters vegetation at high latitudes such as Siberia or Alaska, where there is a switch from tundra to forest. On the other hand, CO2 fertilization provides the largest contribution to greening in arid/semi-arid region. Precipitation change did not cause any drastic vegetation shift.  相似文献   

5.
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6.
Three-year summertime surface atmospheric N2O concentrations were observed for the first timeon the Fildes Peninsula, maritime Antarctica, and the relationships among the N2O concentration, totalatmospheric O3 amount, and sunspot number were analyzed. Solar activity had an important effecton surface N20 concentration and total O3 amount, and increases of sunspot number were followed bydecreases in the N2O concentration and total O3 amount. A corresponding relationship exists betweenthe N2O concentration and total atmospheric O3, and ozone destruction was preceded by N2O reduction.We propose that the extended solar activity in the Antarctic summer reduces the stratospheric N2O byconverting it into NOx, increases the diffusion of N2O from the troposphere to the stratosphere, decreasesthe surface atmospheric N2O, and depletes O3 via the chemical reaction between O3 and NOx. Ourobservation results are consistent with the theory of solar activity regarding the formation of the AntarcticO3 hole.  相似文献   

7.
Germany is one of the two OECD countries having achieved substantial greenhouse gas reductions in the last decade. While a part was large reductions in industry after the economic crash in East Germany, a relevant share is due to the huge public infrastructure investments in East Germany. The real success of German climate policy in the past decade is the strong reduction of methane and nitrous oxide which has been almost unnoticed.German climate policy is a good example of how lobbying of interest groups leads to a complex maze of hundreds of measures whose effects are difficult to evaluate. Paradoxically, policies have focused on expensive measures and Germany clearly is a pioneer in the most expensive forms of renewable energy. Concerning cost-effective measures and market instruments, Germany is a laggard. Only slowly, policymakers start to notice this distortion and first, shaky steps towards a more cost-efficient policy are made. Several challenges such as nuclear phase-out and trends in household energy consumption will put pressure on government to embrace the Kyoto Mechanisms and to refocus domestic instruments well before the first commitment period.  相似文献   

8.
In this study, CarbonTracker, an inverse modeling system based on the ensemble Kalman filter, was used to evaluate the effects of data assimilation parameters (assimilation window length and ensemble size) on the estimation of surface CO2 fluxes in Asia. Several experiments with different parameters were conducted, and the results were verified using CO2 concentration observations. The assimilation window lengths tested were 3, 5, 7, and 10 weeks, and the ensemble sizes were 100, 150, and 300. Therefore, a total of 12 experiments using combinations of these parameters were conducted. The experimental period was from January 2006 to December 2009. Differences between the optimized surface CO2 fluxes of the experiments were largest in the Eurasian Boreal (EB) area, followed by Eurasian Temperate (ET) and Tropical Asia (TA), and were larger in boreal summer than in boreal winter. The effect of ensemble size on the optimized biosphere flux is larger than the effect of the assimilation window length in Asia, but the importance of them varies in specific regions in Asia. The optimized biosphere flux was more sensitive to the assimilation window length in EB, whereas it was sensitive to the ensemble size as well as the assimilation window length in ET. The larger the ensemble size and the shorter the assimilation window length, the larger the uncertainty (i.e., spread of ensemble) of optimized surface CO2 fluxes. The 10-week assimilation window and 300 ensemble size were the optimal configuration for CarbonTracker in the Asian region based on several verifications using CO2 concentration measurements.  相似文献   

9.
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10.
Carbon dioxide (CO2) is an important greenhouse gas that influences regional climate through disturbing the earth’s energy balance. The CO2 concentrations are usually prescribed homogenously in most climate models and the spatiotemporal variations of CO2 are neglected. To address this issue, a regional climate model (RegCM4) is modified to investigate the non-homogeneous distribution of CO2 and its effects on regional longwave radiation flux and temperature in East Asia. One-year simulation is performed with prescribed surface CO2 fluxes that include fossil fuel emission, biomass burning, air–sea exchange, and terrestrial biosphere flux. Two numerical experiments (one using constant prescribed CO2 concentrations in the radiation scheme and the other using the simulated CO2 concentrations that are spatially non-homogeneous) are conducted to assess the impact of non-homogeneous CO2 on the regional longwave radiation flux and temperature. Comparison of CO2 concentrations from the model with the observations from the GLOBALVIEW-CO2 network suggests that the model can well capture the spatiotemporal patterns of CO2 concentrations. Generally, high CO2 mixing ratios appear in the heavily industrialized eastern China in cold seasons, which probably relates to intensive human activities. The accommodation of non-homogeneous CO2 concentrations in the radiative transfer scheme leads to an annual mean change of–0.12 W m–2 in total sky surface upward longwave flux in East Asia. The experiment with non-homogeneous CO2 tends to yield a warmer lower troposphere. Surface temperature exhibits a maximum difference in summertime, ranging from–4.18 K to 3.88 K, when compared to its homogeneous counterpart. Our results indicate that the spatial and temporal distributions of CO2 have a considerable impact on regional longwave radiation flux and temperature, and should be taken into account in future climate modeling.  相似文献   

11.
Experimental field and laboratory studies on washout of radionuclides from the snow cover during snow melting were carried out in the winter of 2005/06. In the field studies, a specially equipped runoff site was used. In the laboratory conditions, the experiments were conducted using prepared soil monoliths. In the winter of 2006, 25 g/m2 of water-free cesium chloride (CsCl) and 25 g/m3 of strontium chloride (SrCl2) were put onto the snow cover surface of the runoff site. The snow surface of the soil monolith was coated with a 137Cs-bearing solution, then with SrCl2. Under experimental conditions, practically no surface runoff from the runoff site was recorded. The experiments with the soil monoliths demonstrated that the coefficient of the liquid washout of 137Cs normalized to the runoff layer was within 0.9 × 10?6–1.2 × 10?4 mm?1, and that of 90Sr normalized to the runoff layer was within 2 × 10?–1.6 × 10?4 mm?1.  相似文献   

12.
Increases in extreme precipitation greater than in the mean under increased greenhouse gases have been reported in many climate models both on global and regional scales. It has been proposed in a previous study that whereas global-mean precipitation change is primarily constrained by the global energy budget, the heaviest events can be expected when effectively all the moisture in a volume of air is precipitated out, suggesting the intensity of these events increases with availability of moisture, and significantly faster than the global mean. Thus under conditions of constant relative humidity one might expect the Clausius–Clapeyron relation to give a constraint on changes in the uppermost quantiles of precipitation distributions. This study examines if the phenomenon manifests on regional and seasonal scales also. Zonal analysis of daily precipitation in the HadCM3 model under a transient CO2 forcing scenario shows increased extreme precipitation in the tropics accompanied by increased drying at lower percentiles. At mid- to high-latitudes there is increased precipitation over all percentiles. The greatest agreement with Clausius–Clapeyron predicted change occurs at mid-latitudes. This pattern is consistent with other climate model projections, and suggests that regions in which the nature of the ambient flows change little give the greatest agreement with Clausius–Clapeyron prediction. This is borne out by repeating the analyses at gridbox level and over season. Furthermore, it is found that Clausius–Clapeyron predicted change in extreme precipitation is a better predictor than directly using the change in mean precipitation, particularly between 60°N and 60°S. This could explain why extreme precipitation changes may be more detectable then mean changes.  相似文献   

13.
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14.
PM10 samples were collected over three years at Monzenmachi, the Japan Sea coast, the Noto Peninsula, Ishikawa, Japan from January 17, 2001 to December 18, 2003, using a high volume air sampler with quartz filters. The concentrations of the water-soluble inorganic ions in PM10 were determined with using ion chromatography. By analyzing the characteristics of these, the evidences were found that the Asian outflow had an obviously influence on the air quality at our study site. The results were as follows: the secondary pollutants SO42−, NO3− and NH4+ were the primary water-soluble inorganic ions at our study site. The monthly mean concentrations of SO42−, NH4+, NO3− and Ca2+ have prominent peak in spring due to the strong influence of the Asian continent outflow—these according to backward air trajectory analysis, the maximum of which were 6.09 for nss-SO42− in May, 2.87 for NO3− and 0.68 μg m−3 for nss-Ca2+ in April, respectively. Comparable to similar data reported from various points around East Asia, it had the characteristics of a polluted coastal area at our study site. The concentration of nss-Ca2+ in PM10 drastically increased when the Asian dust invaded, the mean value during the Asian dust days(AD) was 0.86 μg m−3, about 4 times higher than those of normal days (NAD). Meanwhile, the mean concentrations of nss-SO42−, NO3− and NH4+ in AD periods were higher than those in NAD periods which were 5.87, 1.76 and 1.82 μg m−3, respectively, it is due to the interaction between dust and secondary particles during the long-range transport of dust storms. Finally, according to the source apportionment with positive matrix factorization (PMF) method in this study, the major source profiles of PM10 at our study site were categorized as (1) marine salt, (2) secondary sulfate, (3) secondary nitrate and (4) crustal source.  相似文献   

15.
气候变暖对新疆乌昌地区棉花种植区划的影响   总被引：6，自引：0，他引：6  
在对新疆乌昌地区1961-2010年≥10℃积温、最热月（7月）平均气温和无霜期等热量要素时空变化进行分析的基础上,结合北疆棉区区划指标,完成了2004年前、后乌昌地区棉花种植气候区划。并对未来年平均气温升高1～4℃时,棉花种植气候区划的可能变化进行了预估。结果表明：乌昌地区热量资源在空间分布上表现为“平原多,山区少”的格局。1961-2010年≥l0℃积温、最热月平均气温和无霜期分别以每10年52.3℃• d、0.1℃和3.3 d的速率增多（升高、延长）,并分别于1995年、2004年和1987年发生了突变。受其影响,2004年后乌昌地区宜棉区较之前明显扩大,次宜棉区、风险棉区和不宜棉区有不同程度的缩小。未来气候变暖将对乌昌地区棉花种植气候区划产生较大影响,年平均气温每升高1℃,宜棉区面积将扩大6600 km2,次宜棉区和不宜棉区分别缩小2100 km2和4700 km2,风险棉区面积变化不大。  相似文献   

16.
This paper focuses on the data assimilation methods for sea surface winds, based on the level-2B HY-2A satellite microwave scatterometer wind products. We propose a new feature thinning method, which is herein used to screen scatterometer winds while maintaining the key structure of the wind field in the process of data thinning for highresolution satellite observations. We also accomplish feeding the ambiguous wind solutions directly into the data assimilation system, thus making better use of the retrieved information while simplifying the assimilation process of the scatterometer products. A numerical simulation experiment involving Typhoon Danas shows that our method gives better results than the traditional approach. This method may be a valuable alternative for operational satellite data assimilation.  相似文献   

17.
Cooperation in the economic sense considers efficiency issues. Cooperation in the political sense, like the Kyoto Protocol, considers other issues like equity and historical responsibility. The environmental and economic impacts of the Kyoto Protocol and other scenarios are thus examined. The US pullout may then be viewed, among others, as the result of not untying “economic” and “political” cooperation; and since the Protocol will be much less effective without the US, it is shown that an external economic stimulus should and may theoretically be found for retaining their participation.  相似文献   

18.
利用NCEP 每6h 1次的1°×1°格点资料和中尺度模式WRF（V3.2）,对2010年舟曲“0808”特大泥石流暴雨天气进行了数值模拟,运用模式输出资料对此次天气过程发生发展的机制进行了诊断分析。结果表明：舟曲强暴雨发生在高原短波槽、低涡切变线和副热带高压等共同作用的有利天气形势下,三重嵌套的WRF模式对此次暴雨具有良好的模拟能力。低层强辐合,中层无辐散和高层强辐散的配置,以及强烈的上升运动是此次暴雨发生的主要动力条件。从低层向上延伸的等θse线高能舌和水平风的垂直切变为暴雨的发生输送了大量的不稳定能量。中低层水汽的辐合上升为暴雨的发生创造了有利的水汽条件。  相似文献   

19.
Measurements of formaldehyde (HCHO) were made at the Cape Verde Atmospheric Observatory between November 2006 and June 2007 using the Long-Path Differential Optical Absorption Spectroscopy (LP-DOAS) technique. Observations show that typical HCHO mixing ratios ranged between 350 and 550 pptv (with typical 2-σ uncertainties of ~110 pptv), with several events of high HCHO, the maximum being 1,885?±?149 pptv. The observations indicate a lack of strong seasonal or diurnal variations, within the uncertainty of the measurements. A box model is employed to test whether the observations can be explained using known hydrocarbon photochemistry; the model replicates well the typical diurnal profile and monthly mean values. The model results indicate that on average 20% of HO2 production and 10% of OH destruction can be attributed to the mean HCHO levels, suggesting that even at these low average mixing ratios HCHO plays an important role in determining the HOx (HO2+OH) balance of the remote marine boundary layer.  相似文献   

20.
以冬小麦品种“齐麦2号”为试材,在水分关键期(拔节期~扬花期),设计5个水分处理(T1处于适宜水平,T2、T3、T4、T5分别按照水分关键期常年降水量减少20%、50%、75%、100%进行一次性补水)和1个雨养对照水分控制试验,模拟研究不同程度干旱胁迫对水分关键期冬小麦光合生理特性、抗氧化酶活性及产量结构的影响。结果表明：轻度干旱胁迫会造成冬小麦叶片最大光合速率、气孔导度、胞间CO2浓度降低,气孔限制值升高,气孔因素是导致冬小麦叶片光合速率降低的主要原因;而当干旱胁迫达到重度时,胞间CO2浓度升高,气孔限制值降低,非气孔因素是导致冬小麦叶片光合速率降低的主要原因。轻度干旱胁迫会使得冬小麦叶片SOD酶、POD酶、CAT酶活性显著升高,从而减轻MDA含量升高对冬小麦叶片膜系统的损伤,复水后抗氧化酶活性和MDA含量均可恢复至正常水平,而重度干旱胁迫下冬小麦叶片SOD酶、POD酶、CAT酶活性不同程度降低,复水后抗氧化酶活性及MDA含量均无法恢复至正常水平,抗氧化酶系统遭受不可逆损伤。此外,水分关键期干旱胁迫还导致冬小麦灌浆速率降低、不孕穗率升高,理论产量大幅降低。研究结论可为科学评估干旱胁迫对冬小麦生长发育及产量形成的影响提供理论依据。  相似文献   

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