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1.
Moss transplants of the species Rhytidiadelphus squarrosus and Pleurozium schreberi were used as active biomonitoring organisms as a part of a monitoring study to assess the impact of metals associated with ambient particles on mosses at roadsides.The moss samples were exposed at a semi-urban and roadside site for 3 months for subsequent analysis of metal concentration (Cu, Pb and Zn). This field experiment was carried out to investigate the accumulation of the metals over a period of 0, 4, 8 and 12 weeks at the two sites. The metal concentration in the moss samples generally increased with the length of exposure and was higher at the roadside site. The two species, however, showed slightly different accumulation patterns. In addition to the metal analysis chlorophyll concentrations were analysed as a measure of stress response in the moss samples of the above mentioned field exposures. The chlorophyll concentrations of exposed mosses showed no or only weak correlations to the concentration of the three metals measured in the moss, which suggests that other conditions have a greater influence on the chlorophyll concentration.The effect of a single metal on the moss was studied in laboratory experiments exposing R. squarrosus to the metals copper, lead and zinc at concentrations based on the above field data. At the concentrations used there was a significant reduction in the chlorophyll a concentration after exposure to copper.  相似文献   

2.
Rainwater is a major source of dissolved iron to much of the world's oceans, including regions where iron may be a limiting nutrient for marine phytoplankton primary production. Rainwater iron is therefore potentially important in regulating global photosynthetic uptake of CO2, and hence climate. Two rainwater addition bioassay experiments (2% rain) conducted at the Bermuda Atlantic Time-series Station (BATS) during March 2000 using 50 or 100 nM FeCl2 or FeCl3 in synthetic rain (pH 4.5 H2SO4) showed an increase in chlorophyll a 50% greater than controls after three days. Addition of 20 μM hydrogen peroxide, a typical rainwater concentration at BATS, completely removed the chlorophyll a increase with both forms of iron additions, suggesting stimulation of phytoplankton growth by rainwater iron can be limited by rainwater H2O2. In laboratory experiments using Gulf Stream seawater, iron-enriched (100 nM Fe(III)) synthetic rain was mixed with seawater in a 5% rain 95% seawater ratio. Dissolved iron concentrations increased two times above concentrations predicted based on dilution alone. The increase in soluble iron probably resulted from release from seawater particles and was maintained for more than 24 hours. No increase was observed in controls that did not have iron added to the synthetic rain, or with synthetic rainwater containing both added iron and H2O2. The increase in iron concentration above that predicted by dilution indicates rain may have a larger effect on seawater iron concentrations than that calculated for rainwater iron addition alone.  相似文献   

3.
Studied are the interannual variations of physical (temperature, salinity, and relative density) and chemical (dissolved oxygen and biogenic elements) parameters of sea water and chlorophyll a concentration in the Japan Sea in autumn. It is demonstrated that the increase in the water flow from the East China Sea through the Korea (Tsushima) Strait leads to the temperature rise and decrease in salinity and dissolved oxygen content in the surface water layer of the Japan Sea. It is revealed that in the central part of the Japan Sea from 1978 to 2012 trends were observed towards the increase in the content of dissolved inorganic nitrogen N, decrease in the content of inorganic phosphorus, and decrease in the concentration of chlorophyll a at the level of 50 m and its increase in the layer of 0–30 m. The observed trends are explained by the intensification of the effect of coastal water of the East China Sea subjected to the significant anthropogenic load on the water of the central part of the Japan Sea.  相似文献   

4.
Using the data of long-term observations of the Secchi disk visibility depth and water salinity (1947-2000) and satellite monitoring of chlorophyll a concentration (1978-1986), their seasonal spatial distributions and intraannual variability in the coastal waters of the western Black Sea are considered. The estimates of seasonal variations are obtained for the coastal zone of the sea. A good agreement is demonstrated between intraannual variations in the salinity of transformed river water, chlorophyll a concentration, and transparency in the areas where these waters propagate. We studied the effects of the Danube River runoff and transformed river water on the phytoplankton development and chlorophyll a concentration which largely define water transparency.  相似文献   

5.
Methyl halides such as methyl chloride (CH3Cl) are known to be important carriers of halogen from the ocean to the atmosphere, and the halogens they release into the stratosphere by photolysis catalyze ozone depletion. Marine phytoplankton have been reported as a source of CH3Cl, but the effects of environmental temperature on the CH3Cl production by phytoplankton have not been investigated. In this study, we investigated the effects of temperature on the production of CH3Cl in the culture of a marine diatom, Phaeodactylum tricornutum CCMP 630, incubated at 10, 15, 20, 25, and 30 °C. CH3Cl concentrations in cultured samples were determined using purge and trap gas chromatograph–mass spectrometry. Phytoplankton growth was monitored by measuring the chlorophyll a concentrations. CH3Cl production was observed for several weeks at four different temperatures ranging from 10 to 25 °C. The CH3Cl production from P. tricornutum was increased with increasing temperature from 10 to 25 °C, and the maximum production rate for CH3Cl was 0.21~0.26 μmol (g chlorophyll a)?1 d?1 at 25 °C, which was several times higher than that at 10 °C (~0.03 μmol (g chlorophyll a)?1 d?1). The Arrhenius equation was successfully used to characterize the effects of temperature on the production rates of CH3Cl in the culture of P. tricornutum. Our results suggest that water temperature directly affects CH3Cl production derived from P. tricornutum and that water temperature would be a significant factor for estimating the emissions of CH3Cl from marine environments.  相似文献   

6.
A sensitivity analysis is performed in order to study recently observed changes in atmospheric methane and carbon monoxide trends. For the analysis we have adapted a one-dimensional transport/chemistry model in order to comply with changes in vertical transport, stratosphere-troposphere flux of ozone, the water vapour cycle and the short-wave radiative transfer. In addition we have formulated an improved relationship which expresses the steady state OH concentration in terms of longer lived compounds which has a fair agreement with the one-dimensional model results. An analysis of the observed changes and trends in methane and carbon monoxide shows that both emissions and changes in global OH concentrations can be main causes for the observed changes. Average methane emissions have slowed down, particularly in the NH, in the last five years, though perhaps not very significantly. Carbon monoxide emissions are decreasing faster in the last couple of years than in the period 1983–1990. The study suggests that climate fluctuations (tropospheric water vapour, temperature and convective activity) and the stratospheric ozone depletion (tropospheric UV radiation) have a significant influence on tropospheric composition and thus on trends in methane and carbon monoxide concentrations.The IMAU is partner in the Netherlands Centre for Climate Research (CCR).  相似文献   

7.
A climatic change was simulated transplanting samples of the lichens Evernia prunastri (L.) Ach. and Pseudevernia furfuracea (L.) Zopf v. furfuracea along a 1,400 m altitudinal gradient in the northern side of the island of Crete (Greece). The working hypothesis was that the photosynthetic performance (i.e. pigment content, chlorophyll degradation and photosynthetic efficiency) of transplanted lichens varies along the altitudinal gradient. The overall effect observed was a general depression of the photosynthetic performance along the gradient. Concentrations of chlorophyll a, chlorophyll b and carotenoids decreased with decreasing elevation and along with the hottest and driest months of the year, with chlorophyll b being the most sensitive parameter to dry conditions. Chlorophyll degradation decreased with increasing elevation. The exposure period was the main factor affecting photosynthetic efficiency, with lower values during summer months. We argued that the water content of lichen thalli is the most important factor determining differences in photosynthesis under the experimental conditions. This allowed to suggest that the lichen photosynthetic performance deserves further investigation as early biological indicator of atmospheric stress induced by dry conditions and, to a greater extent, for the assessment of the desertification risk in the arid Mediterranean environment.  相似文献   

8.
This study summarizes the effects of avenues of trees in urban street canyons on traffic pollutant dispersion. We describe various wind-tunnel experiments with different tree-avenue models in combination with variations in street-canyon aspect ratio W/H (with W the street-canyon width and H the building height) and approaching wind direction. Compared to tree-free street canyons, in general, higher pollutant concentrations are found. Avenues of trees do not suppress canyon vortices, although the air ventilation in canyons is hindered significantly. For a perpendicular wind direction, increases in wall-average and wall-maximum concentrations at the leeward canyon wall and decreases in wall-average concentrations at the windward wall are found. For oblique and perpendicular wind directions, increases at both canyon walls are obtained. The strongest effects of avenues of trees on traffic pollutant dispersion are observed for oblique wind directions for which also the largest concentrations at the canyon walls are found. Thus, the prevailing assumption that attributes the most harmful dispersion conditions to a perpendicular wind direction does not hold for street canyons with avenues of trees. Furthermore, following dimensional analysis, an estimate of the normalized wall-maximum traffic pollutant concentration in street canyons with avenues of trees is derived.  相似文献   

9.
The influence of chlorophyll spatial patterns and variability on the tropical Pacific climate is investigated by using a fully coupled general circulation model (HadOPA) coupled to a state-of-the-art biogeochemical model (PISCES). The simulated chlorophyll concentrations can feedback onto the ocean by modifying the vertical distribution of radiant heating. This fully interactive biological-ocean-atmosphere experiment is compared to a reference experiment that uses a constant chlorophyll concentration (0.06 mg m−3). It is shown that introducing an interactive biology acts to warm the surface eastern equatorial Pacific by about 0.5°C. Two competing processes are involved in generating this warming: (a) a direct 1-D biological warming process in the top layers (0–30 m) resulting from strong chlorophyll concentrations in the upwelling region and enhanced by positive dynamical feedbacks (weaker trade winds, surface currents and upwelling) and (b) a 2-D meridional cooling process which brings cold off-equatorial anomalies from the subsurface into the equatorial mixed layer through the meridional cells. Sensitivity experiments show that the climatological horizontal structure of the chlorophyll field in the upper layers is crucial to maintain the eastern Pacific warming. Concerning the variability, introducing an interactive biology slightly reduces the strength of the seasonal cycle, with stronger SST warming and chlorophyll concentrations during the upwelling season. In addition, ENSO amplitude is slightly increased. Similar experiments performed with another coupled general circulation model (IPSL-CM4) exhibit the same behaviour as in HadOPA, hence showing the robustness of the results.  相似文献   

10.
Elevated concentrations of S(IV) and formaldehyde were observed in fog- and cloudwater at sites in California. The highest concentrations (up to 3 mM S(IV) and 0.7 mM CH2O) were measured at Bakersfield, during a prolonged period of repeated fog. In Bakersfield [S(IV)] generally exceeded [CH2O], while in the Los Angeles area the reverse was observed. The lowest concentrations of both species were observed at marine and high altitude sites away from local emissions. Equilibrium computations indicate that high concentrations of S(IV) cannot be achieved without the formation of S(IV)-RCHO adducts.  相似文献   

11.
A version of the two-flow radiative transfer model is presented as a simple method to study the relationship between substances in water and the backscattered radiation field. It is shown that under the assumption of a diffuse radiative input into a water body, the irradiance attenuation coefficient k can be regarded as an inherent property. A cuvette system is presented which allows one to measure and calculate the attenuation coefficient k, the absorption coefficient a and the backscattering coefficient Bb of various substances. The model can be used to check the applicability of a remote sensing technique for a specific research area and for specific parameters, and to estimate the expected accuracy, and the signal depth. The inversion of the model can be applied as a technique to estimate concentrations in water from the backscattered radiation. The critical assumption of a diffuse radiative input and transfer, which has to be made when using the model for natural conditions, is discussed.The research work was supported by the Deutsche Forschungsgemeinschaft.  相似文献   

12.
Measurements of natural ice nuclei with a continuous flow diffusion chamber   总被引：1，自引：0，他引：1  
Measurements of natural ice nuclei were made in winter continental airmasses with a continuous flow thermal gradient diffusion chamber (described in a separate paper). Over the range of temperatures −7°C to −20°C, the concentration of ice nuclei was closely related to ice supersaturation (SSi) for humidities both below and above water saturation. Measurements below water saturation were interpreted as deposition nuclei with average concentrations (per liter) approximately 0.32 SSi(%)0.81. Measurements were made up to 5% above water saturation and activated both deposition and condensation-freezing nuclei. The average concentration of condensation-freezing nuclei was 0.25 e−0.15 T(°C). Sample residence time in the chamber was probably too small to detect contact nuclei, unless the nucleating aerosols are extremely small. There was large variability in nucleus concentrations, as much as two orders of magnitude at −15°C. Comparisons are made between these ice nuclei measurements and aircraft observations of ice crystal concentrations in winter orographic clouds.  相似文献   

13.
Abstract

Aquatic plants and lake bottoms in optically shallow waters (OSWs) wield great influence on reflectance spectra, resulting in the inapplicability of most existing bio-optical models for water colour remote sensing in lakes. Based on radiative transfer theory and measured spectra from a campaign for Lake Taihu in October 2008, absorption and backscattering coefficients were used to simulate the remote-sensing reflectance, which are considered to be reliable if matched to their measured counterparts. Several cases of measured spectra at different depths, Secchi disk depth transparency, and aquatic plant height and coverage were analyzed thoroughly for spectral properties. The contribution of aquatic plants was evaluated and compared with the measured and simulated remote-sensing reflectance values. This is helpful for removing the influence of aquatic plants and lake bottoms from the spectra and for constructing an improved chlorophyll a retrieval model for OSWs, such as that for Lake Taihu, China.  相似文献   

14.
During a cruise of RV Polarstern over the Atlantic in September/October 1988, C2–C4 hydrocarbons were measured in surface sea water. The ship passed through three different ocean regions divided by divergences at 8° N and 3° S. Hydrocarbon concentrations differed considerably in these regions. The highest values were obtained for ethene with mean concentrations of 246 pMol/l between 35° N and 8° N, 165 pMol/l between 8° N and 3° S, and 63 pMol/l between 3° S and 30° S. Low values were found for i- and n-butane and acetylene between 32 pMol/l and 1 pMol/l. The alkene concentrations were in general higher than the concentrations of their saturated homologs. Concentrations decreased with increasing carbon numbers. The various alkenes were well correlated with one another as were the various alkanes. Oceanic emission rates of the light hydrocarbons were calculated from their sea water concentrations using an ocean atmosphere exchange model. The averaged fluxes ranged from about 108 molec cm-2 s-1 for the alkenes and ethane to less than 107 molec cm-2 s-1 for the C4 alkanes. Acetylene emissions were below 3×106 molec cm-2 s-1. Based upon these rates budget estimates of NMHC in the ocean surface layer were made with a simple model considering production and destruction processes in the water. The emissions to the atmosphere appear to be the dominant loss process between 35° N and 8° N, whereas destruction in the water seems to be dominant in the latitude ranges 8° N-3° S and 3° S-30° S.  相似文献   

15.
基于水面实测光谱的太湖蓝藻卫星遥感研究   总被引：4，自引：1，他引：3       下载免费PDF全文
水体叶绿素a含量和蓝藻密度是评价水质污染的主要参数,对监测水体蓝藻水华有重要意义。该文利用2008年11月10日和11日太湖水面实测光谱及FY-3A/MERSI,AQUA/MODIS卫星的波段响应函数,计算了卫星波段的水体表面等效反射率。水体实测光谱显示蓝藻污染提高了近红外波段的遥感反射率,在蓝光波段和绿光波段有明显的吸收谷和反射峰。根据这一原理,该文建立了近红外和红光波段的比值指数RI模型,成功反演了太湖水体叶绿素a含量(均方根误差分别为0.0174 mg·L~(-1)和0.0188 mg·L~(-1))和蓝藻密度(均方根误差分别为247.21×10~6L~(-1)和275.64×10~6L~(-1))。这一结果为分析太湖水面光学特性、水质污染状况提供了重要依据。  相似文献   

16.
The first systematic study in Romania of atmospheric pollution from heavy metals and other toxic elements based on moss analysis was undertaken as a Romanian–Russian–Norwegian collaboration, primarily in order to assess the general state of heavy metal pollution in Romania. An additional goal was to contribute to the European heavy metals in mosses survey, conducted under the auspices UNECE ICP Vegetation which reports to the Working Group of Effects of the Long-range Transboundary Air Pollution Convention. Samples of the moss species Hypnum cupressiforme, Hylocomium splendens and Brachytechium salebrosum and B. rutabulum were collected during the period 1995–2001. A total of 40 elements were determined using NAA and AAS. The total concentrations of arsenic, cadmium, copper, nickel, vanadium and zinc are presented in the form of contour maps. Generally, the observed concentrations in Romania are markedly higher than those observed in most other countries of Europe using the moss technique.  相似文献   

17.
将非感应起电机制和放电参数化方案耦合到WRF模式的Morrison双参数微物理方案中,并在模式中引入了闪电潜势指数LPI,在此基础上模拟了2009年6月16日华北一次飑线过程,讨论模式对闪电活动再现能力。模拟结果显示,模式能够较好地再现雷达回波和降水分布特征,说明模式对此次飑线过程的宏观和微观特征具有一定的模拟能力。利用计算闪电潜势指数LPI的间接模拟,能够指示出大致的闪电分布特征,但闪电潜势指数LPI分布范围明显大于实际闪电落区;而通过耦合电过程的WRF模式直接输出闪电密度的直接模拟,模拟结果与实际闪电密度分布的对应关系较好,但由于模式中输出的闪电密度为总闪电密度,与观测地闪密度资料相比,模拟的闪电密度偏大。  相似文献   

18.
Gas exchange experiments were conducted in the tropical Atlantic Ocean during a ship expedition with FS Meteor using a small rubber raft. The temporal change of the mixing ratios of CO, H2, CH4 and N2O in the headspace of a floating glass box and the concentrations of these gases in the water phase were measured to determine their transfer velocities across the ocean-atmosphere interface. The ocean acted as a sink for these gases when the water was undersaturated with respect to the mixing ratio in the headspace. The transfer velocities were different for the individual gases and showed still large differences even when normalized for diffusivity. Applying the laminar film model, film thicknesses of 20 to 70 m were calculated for the observed flux rates of the different gas species. When the water was supersaturated with respect to atmospheric CO, H2, CH4 and N2O, the transfer velocities of the emission process were smaller than those determined for the deposition process. In case of H2 and CH4, emission was even not calculable although, based on the observed gradient, the laminar film model predicted significant fluxes at the air-sea interface. The results are interpreted by destruction processes active within the surface microlayer.  相似文献   

19.
Atmospheric PAH concentrations were determined in Gulbahce district of Bursa, Turkey between August 2004 and April 2005. Measured PAH concentrations were classified as heating and non-heating season samples. The concentrations of total PAHs in heating season were almost ten times higher than those in non-heating season. Diagnostic ratios and factor analysis results show that in the heating season traffic along with residential heating emissions heavily influence PAH concentrations. The plot of logKp versus logPL0 for all the data set of heating and non-heating season samples gave significantly different slopes. The slope for the heating season samples (− 0.92) was steeper than the one for the non-heating season samples (− 0.78). The partitioning results for individual samples further indicated that slope values varied depending on air parcel trajectories. Air parcels traveled over water (either over the Black Sea or Aegean Sea) prior to arriving at the sampling site had less steep slopes. Partitioning of PAHs was also investigated by comparing experimentally determined Kp values with the results obtained both from octanol-based model (Kp(Oct.)) and soot and octanol-based model (Kp (Soot + Oct.)). Both models were useful in predicting the experimental Kp values. However, they did not explain the observed variability in the experimental Kp values.  相似文献   

20.
The reduction in variance of concentration fluctuations due to line averaging is estimated assuming that the process is influenced by the integral distance scale, y I , of ambient turbulence and the scaling width, W, of the time-averaged plume. An analytical formula is derived for the line-averaged variance for situations where the autocorrelogram is exponential and the point variance decreases exponentially with distance from plume centerline. Predictions of concentration fluctuation variance are compared with water tank and field data, with the result that the decrease of variance with averaging distance is well-simulated if the model parameters y I and W are carefully chosen.  相似文献   

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