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1.
长江口及毗邻海区沉积物中磷的分布特征   总被引:6,自引:2,他引:4       下载免费PDF全文
于2006年6月和2007年4月在长江口及毗邻海区采集了表层沉积物样品,利用水淘选法对沉积物进行了粒径分级,并采用改进后的SEDEX方法对沉积物样品及分粒级沉积物样品进行了磷形态分析。结果表明,2006年6月和2007年4月长江口及毗邻海区沉积物总磷变化分别为12.56~19.64μmol/g和8.99~19.91μmol/g,其中碎屑磷是磷的主要存在形态。可交换态磷、铁结合态磷、有机磷、自生磷灰石磷及难分解有机磷在长江口外的平面分布比较一致,均在紧邻长江口门外、杭州湾外的条状带出现了含量的高值,而在口门内及口门外河口靠海一侧碎屑磷含量较高。不同形态磷在不同粒径沉积物中的含量不尽相同:有机磷、自生磷灰石磷以及难分解有机磷是小于8μm粒级沉积物中磷的主要组成部分,而且其在总磷中所占比例随沉积物粒径的增加而下降;碎屑磷则主要集中在粗沉积物中,为32~63μm及大于63μm粒级沉积物中磷的主要贡献者。沉积物的粒度分异以及各形态磷在不同粒径沉积物中含量的差异,共同影响着河口沉积物中磷的分布。  相似文献   

2.
刘慧  姚鹏  孟佳  王金鹏  赵彬 《海洋学报》2017,39(8):115-128
磷是一种重要的生源要素,在河口、边缘海的初级生产中发挥重要作用,了解沉积物中磷的形态分布和迁移转化有助于深入了解该区域生态系统动力学。于2013年3月在长江口及邻近海域采集了表层沉积物样品,利用水淘选方法对沉积物进行了分级,并采用化学连续提取法分析了未分级和分级沉积物样品中的6种磷形态含量:可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷、碎屑磷和难分解有机磷,讨论了该区域沉积物中磷的形态分布、选择性输运过程和迁移转化。沉积物中总磷含量在14.0~18.4 μmol/g,其中碎屑磷是其主要成分,占54.5%,其次是有机磷和难分解有机磷,分别占到15.1%和13.1%。不同粒级沉积物中磷形态含量不同,可交换态磷、活性有机磷、铁结合态磷、自生磷灰石磷和难分解有机磷随粒级增加含量逐渐降低,而碎屑磷主要集中在粗粒级(大于32 μm)沉积物中。基于各粒级磷形态的质量分布,发现小于32 μm粒级的沉积物中各磷形态含量从长江口向浙闽沿岸逐渐增加,向外海方向逐渐减小,而大于32 μm沉积物的变化趋势与此相反,体现了不同形态磷的选择性输运。随粒径增大,总有机碳对有机磷比值(TOC/Or-P)先降低后升高,在大粒级沉积物中,TOC/Or-P比值较高主要是因为陆源有机碳贡献较高,而在小粒级沉积物中,主要是由于有机磷的迁移和转化更为活跃,体现了细颗粒物中有机磷相对有机碳的优先分解。本研究表明,从分级的角度可以对河口、边缘海的磷循环有一个更全面的认识。  相似文献   

3.
南沙群岛海域表层沉积物中磷的形态分布特征   总被引:1,自引:0,他引:1  
根据2002年56月南沙群岛海域调查时采集的表层沉积物样品,分析了磷的含量并把磷分为总磷(PT)、无机磷(PIN)、有机磷(POR)、非磷灰石结合态磷(PNAI)、磷灰石结合态磷(PAI)5种赋存形态。利用EPM-810Q电子探针测试沉积物的化学成分,讨论了沉积物中磷的形态和分布以及沉积物的地球化学特征与环境的意义。结果表明,调查海区表层沉积物中磷灰石结合态磷与无机磷的含量变化主要受控于生物活动,它们具有同源关系,同属可被生物利用而再次进人生物地球化学循环的磷。沉积物中的总磷和有机磷与FeO显著相关。沉积物中磷灰石结合态磷与CaO显著相关,它的来源和输入方式受控于水体中碎屑颗粒沉积作用的影响。  相似文献   

4.
河口潮滩沉积物磷的季节性累积和生物有效性   总被引:2,自引:0,他引:2       下载免费PDF全文
对长江口潮滩表层沉积生磷的赋存形态和含量的研究表明,碎屑态磷为沉积物中磷的主要形态,约占总磷的62.52%;铁结合态磷和有机磷次之,分别占总磷的18.06%和14.69%;自生磷灰石加钙结合态磷和吸附态磷最少。综合研究区内的各种理化条件,指出弱吸附态磷、铁结合态磷和有机磷是长江口潮滩潜在生物可利用磷,约占总磷的33.16%,是导致水体富营养化的潜在因素。上覆水的盐度效应是影响沉积物铁结合态磷含量的关键性因子;而自生磷灰石加钙结合态磷的含量变化则与上覆水的温度、溶氧量及沉积物有机质的分解有关;有机磷在时间和空间尺度上都存在较大变化,主要与潮滩生物动态过程,即磷的再矿化有关。  相似文献   

5.
对国家海洋局第二海洋研究所1998年5月调查过程中采集的长江口外东海特定海区表层沉积物综合运用了EDEX、ASPILA和李悦方法进行了系统的总磷及其磷赋存形态分析。把磷分为5种赋存形态:吸附态、铁结合态、钙结合态、碎屑态和有机态。同时,结合其他沉积物性质和化学组分以及海水环境特征,讨论了磷的地球化学特征及其环境意义。研究表明,表层沉积物中总磷(TP)、有机磷(0P)和铁结合态磷(Fe—P)的含量主要受控于物质来源;吸附态磷(Ad-P)与Fe—P和0P同属于沉积物中生物可利用磷范畴,其在沉积物中的循环主要与铁氧化物有关,钙结合态磷(Ca—P)主要来源于海洋浮游生物。  相似文献   

6.
长江口滨岸潮滩沉积物中磷的存在形态和分布特征   总被引:28,自引:0,他引:28  
通过对长江口滨岸潮滩表层及孔样沉积物中磷形态分析,揭示了潮滩沉积物中磷的存在形态及其分布特征。分析结果表明,潮滩沉积物中磷主要有可溶性磷(DP)、铁结合磷(Fe-P)、铝结合磷(Al-P)、钙结合磷(Ca-P)和有机磷(OP)5种,其中以钙结合磷(Ca-P)和有机磷(OP)为主。研究发现各形态磷的含量分布与水体沉积环境与沉积物粒度关系密切,并受沿岩污水排放及近岸养殖排污等人为活动的影响。  相似文献   

7.
综合运用 SEDEX化学法、ASPILA化学法和 XRF仪器分析法 ,对在东海赤潮多发区花鸟山外海域采集的柱状沉积物进行了总磷及其不同形态磷含量的系统分析。研究表明 ,总磷及其不同形态磷在沉积柱垂向上的分布有一定的变化规律。在采样深度范围内 ,总磷 (TP)、有机磷 (OP)和铁结合态磷 (Fe - P)的含量自下而上增高 ,而吸附态磷 (Ad - P)、自生钙结合态磷 (Ca- P)与碎屑态磷 (De- P)的含量向上递减。样品柱具有较均匀的粒度及矿物、化学组成 ,基本可以排除沉积物质来源和沉积环境变化对沉积物中磷含量的影响 ,而且也不能仅仅用早期成岩作用来解释磷的上述行为。不同形态磷在柱状沉积物中的分布规律 ,在一定程度上反映了近年来陆源区环境污染加剧的趋势。  相似文献   

8.
长江口夏季水体磷的形态分布特征及影响因素   总被引:2,自引:0,他引:2  
根据2006年7月至9月"海监49号"科学考察船夏季航次的调查数据,分析了长江口及邻近海域水体中磷形态的平面分布特征及其影响因素,结果表明,调查海域水体各种形态磷平均浓度均为底层高于表层,并呈现出由河口向邻近海域降低的趋势.杭州湾及最大混浊带部分区域水体中以颗粒态磷为主,且颗粒态无机磷为磷的主要存在形态;长江口门及江苏东部近海区域水体中以溶解态磷为主,溶解态无机磷为磷的主要存在形态;舟山群岛东部外海区表层水体以溶解态磷为主,溶解态有机磷为磷的主要存在形态,而底层水体中溶解态磷浓度略高于颗粒态磷,以溶解态无机磷为磷的主要存在形态.水体中颗粒态无机磷与颗粒态有机磷、颗粒总磷与总磷、总磷与悬浮颗粒物均呈非常显著的正相关,说明悬浮颗粒物是颗粒态磷的主要影响因素.调查海域外海区域绝大部分站位水体中溶解态无机磷表层浓度接近或小于浮游植物生长限制的动力学最低阈值,是磷限制或潜在的磷限制区域.  相似文献   

9.
长江口表层沉积物重矿物在不同粒级中的分布与研究意义   总被引:3,自引:0,他引:3  
王孟瑶  金秉福  岳伟 《海洋学报》2019,41(11):89-100
在粒度分析基础上,以0.5Φ为间距对长江口表层沉积物的不同粒级分样进行碎屑重矿物分析,并对各粒级重矿物特征与广粒级(1.5Φ~6Φ)进行相似度分析。结果表明,长江口沉积物粒度跨度大,从粗砂到泥(黏土)均有分布,粉砂含量高。样内不同粒级分样重矿物含量、种类和组合均有一定变化,样间表现出较一致的规律性。长江口出现碎屑重矿物30种左右,粗粒级分样中矿物种数为10余种,细粒级分样中重矿物种类增至20多种;3.5Φ~4.5Φ是重矿物种类多、矿物成分复杂的粒级区段。粗粒级(粒径大于3Φ)云母族富集,其重矿物组合为云母+角闪石,随粒级变细(粒径小于4Φ)云母急剧减少;闪石族分布粒级广泛,在3Φ~5Φ粒级含量相对较高;帘石族、稳定矿物尤其是金属矿物在粒径小于3.5Φ粒级逐渐增多。长江口重矿物整体组合为普通角闪石+绿帘石+褐铁矿,榍石为特征矿物。相似度分析表明,长江口沉积物样品中主要粒级与广粒级重矿物特征相近,能代表沉积物整体重矿物特征。长江口碎屑重矿物特征深受粒度分布的影响,其矿物种类、矿物组合和矿物指数及其所蕴含的水动力和物源意义都要结合粒度特征来综合分析。  相似文献   

10.
以长江口及邻近海域为研究区域,采用改进后的SEDEX法对沉积物中各形态磷的含量进行了分析,并通过模拟实验探讨了沉积物再悬浮对上覆水体磷酸盐浓度的影响。结果表明:碎屑磷(De-P)是沉积物磷的主要赋存形态,占总磷(TP)的50%以上;其次是可提取态有机磷(Or-P)和非活性有机磷(Re-P);生物可利用磷(BAP)占总磷的比例约为21%,可提取态有机磷(Or-P)是生物可利用磷(BAP)的主要存在形态。沉积物再悬浮时,水体磷酸盐的浓度显著升高,说明沉积物再悬浮会引起沉积物中磷的释放;水体磷酸盐浓度升高主要源于沉积物中磷的释放,而间隙水的贡献较低。沉积物发生再悬浮时,厌氧条件相对于好氧条件,更有利于沉积物磷的释放。  相似文献   

11.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

12.
Specific properties of the interannual sea level variations and annual tides in the Northwestern Pacific were studied. Several tide stations were monitored. The monthly mean sea level for the year of 1995 was analyzed at each tide station. A seismic event in 1995, some tectonic activity around the subject area, and the Kuroshio (the oceanic western boundary current) may possibly contaminate results which would have occurred from the astronomical annual tide alone.  相似文献   

13.
The effect of different fixation and storage protocols on the flow cytometric (FCM) simultaneous analysis of bacterioplankton and phytoplankton in coastal seawater samples (Mediterranean coastal lagoons) was investigated. FCM measurements (cell number, fluorescence and scatter characteristics) were obtained through DAPI staining. Three fixatives [glutaraldehyde (GA), formaldehyde (FA) and paraformaldehyde (PFA)] and two storage (3 months duration) methods (5 °C and −196 °C) were tested. Two dominant populations were detected in studied samples: bacteria and eukaryotic picophytoplankton. Adding fixatives (2% final concentration) appears necessary to obtain FCM exhaustive counts of all the bacteria and phytoplanktonic cells. This was related to the permeation effect of fixatives which allowed a better DAPI staining of the cells. Maximum fluorescence, i.e. optimal staining of the cells was obtained with FA or PFA, and significant lower fluorescences with GA. Fixed samples stored at 5 °C induced rapid cell loss. Only storage in liquid nitrogen of samples fixed with FA or PFA, allows mid-term (≥4 months) preservation of bacteria or picophytoplankton cell numbers, and limited evolution of DAPI-induced fluorescence and scatter characteristics.  相似文献   

14.
15.
《海洋学报(英文版)》2014,(9):F0003-F0003
<正>Acta Oceanologica Sinica(AOS)is a comprehensive academic journal edited by the Editorial Committee of Acta Oceanologica Sinica and is designed to provide a forum for important research papers of the marine scientific community which reflect the information on a worldwide basis.The journal publishes scholarly papers on marine science and technology,including physics,chemistry,biology,  相似文献   

16.
The relationship between the flux of exotic benthic foraminiferal tests (i.e. tests which are supplied from open-sea sources alone) in a tidal inlet and that of bulk sediment was analysed, which can be expressed as two first-order linear equations. According to this relationship, in order to determine net sediment transport directions in the entrance, the test concentration in surficial sediments of the tidal basin can be compared against a ‘ critical level ’. The critical level is determined for the conditions that no net transport of bulk sediment is present within the entrance. If the observed concentration (averaged over the tidal basin) is higher than the simulated critical level, then the net sediment transport is directed to landward. This method is applied to the analysis of net sand transport at Christchurch Harbour, a tidal inlet system located in southern England. In this investigation, concentrations of exotic foraminiferal tests in the surficial sediments of the tidal basin and ebb tidal delta area were obtained from the analysis of sea-bed sediment samples. A series of probable critical levels were calculated based upon the data sets with regard to: (1) sediment discharge from the rivers; (2) magnitude of sediment discharge within the entrance during the ebb; (3) the test concentration outside the harbour; (4) the thickness of the moving layer; and (5) two parameters associated with dispersive processes. The results show that the concentration in the tidal basin sediment is higher than a number of simulated critical concentrations for representative cases. Consequently, the high level of the concentration of exotic benthic foraminiferal tests within the harbour should be explained as a result of landward net transport of sands within the entrance.  相似文献   

17.
Coastal inundation associated with extreme sea levels is the main factor which leads to the loss of life and property whenever a severe tropical cyclonic storm hits the Indian coasts. The Andhra and Orissa coasts are most vulnerable for coastal inundation due to extreme rise in sea levels associated with tropical cyclones. Loss of life may be minimized if extreme sea levels and associated coastal flooding is predicted well in advance. Keeping this in view, location specific coastal inundation models are developed and applied for the Andhra and Orissa coasts of India. Several numerical experiments are carried out using the data of past severe cyclones that struck these regions. The simulated inland inundation distances are found to be in general agreement with the reported flooding.  相似文献   

18.
19.
Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2-25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   

20.
This article concerns an interrelation between the sea levels and the western boundary flow near a tectonic boundary in a local zone in the Northwestern Pacific. In this zone, sea level variations at stations located on the coast facing the Pacific are studied to find the interrelation between variations of the Kurosio flow as an index of the distance of the flow axis off a specific coast. The result is discussed after data processing of the monthly means of the sea levels, and a notice is taken of variations caused by active crustal upheavals during a seismic event, a local earthquake.  相似文献   

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