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1.
Soil-sized particulates have been collected on board ship by a mesh technique from the lower troposphere of the North, Equatorial and South Atlantic Ocean, northern and southern Indian Ocean, South and East China Sea and various coastal localities.Spectrographic analysis reveals that, on average, the particulates have concentrations of Mn, Ni, Co, Ga, Cr, V, Ba, and Sr which are of the same order of magnitude as those in average crustal material. In contrast, the average concentrations of Pb, Sn, and Zn are one order of magnitude higher than those in average crustal material.Within this “world-wide” average there are significant geographical variations in the distributions of Pb, Sn, and Zn which may be related to anthropogenic sources.On the basis of trace-element distributions lower tropospheric soil-sized marine particulates have been divided into four genetic components; local, zonal, inter-zonal, and global. The proportions of these components vary geographically, and each component may have both a natural and an anthropogenic fraction. 相似文献
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Tautog, Tautoga onitis, is an abundant species of fish in estuaries of the northeastern United States. Planktonic tautog larvae are abundant in summer in these estuaries, but there is little information on rates of growth of tautog larvae feeding on natural assemblages of food in the plankton. We examined abundance and growth of larval tautog and environmental factors during weekly sampling at three sites along a nearshore‐to‐offshore transect in Buzzards Bay, Massachusetts, USA during summer 1994. This is the first study of a robust sample size (336 larvae) to estimate growth rates of field‐caught planktonic tautog larvae feeding on natural diets, using the otolith daily‐growth‐increment method. The study was over the entire summer period when tautog larvae were in the plankton. The sampling sites contrasted in several environmental variables including temperature, dissolved oxygen (DO), and chlorophyll a concentration. There was a temporal progression in the abundance of tautog larvae over the summer, in relation to location and temperature. Tautog larvae were first present nearshore, with a pronounced peak in abundance occurring at the nearshore sites during the last 2 weeks in June. Larvae were absent at this time further offshore. From late June through August, larval abundance progressively decreased nearshore, but increased offshore although never approaching the abundance levels observed at the nearshore sites. The distribution and abundance of tautog larvae appeared to be related to a nearshore‐to‐offshore seasonal warming trend and a nearshore decrease in DO. Otoliths from 336 larvae ranging from 2.3 to 7.7 mm standard length had otolith increment counts ranging from 0 to 19 increments. Growth of larval tautog was estimated at 0.23 mm·day?1, and length of larvae prior to first increment formation was estimated at 2.8 mm indicating that first increment formation occurs 3–4 days after hatching at 2.2 mm. Despite spatial and temporal differences in environmental factors, there were no significant differences in growth rates at any of three given sites over time, or between sites. Because larval presence only occurred at a narrow range of temperature (17–23.5 °C) and DO (6.5–9.3 mg·l?1), in situ differences in growth did not appear to be because of differences in larval distribution and abundance patterns relative to these parameters. 相似文献
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Klaus Kremling 《Marine Chemistry》1983,13(2):87-108
In June 1981, dissolved Zn, Cd, Cu, Ni, Co, Fe, and Mn were determined from two detailed profiles in anoxic Baltic waters (with extra data for Fe and Mn from August 1979). Dramatic changes across the O2H2S interface occur in the abundances of Cu, Co, Fe, and Mn (by factors of ?100). The concentrations of Zn, Cd, and Ni at the redox front decrease by factors between 3 to 5.Equilibrium calculations are presented for varying concentrations of hydrogen sulfide and compared with the field data. The study strongly supports the assumption that the solubility of Zn, Cd, Cu, and Ni is greatly enhanced and controlled by the formation of bisulfide and(or) polysulfide complexes. Differences between predicted and measured concentrations of these elements are mainly evident at lower ΣH2S concentrations.Cobalt proved to be very mobile in anoxic regions, and the results indicate that the concentrations are limited by CoS precipitation. The iron (Fe2+) and manganese (Mn2+) distribution in sulfide-containing waters is controlled by total flux from sediment-water interfaces rather than by equilibrium concentrations of their solid phases (FeS and MnCO3). The concentrations of these metals are therefore expected to increase with prolonged stagnation periods in the basin. 相似文献
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P.N. Froelich L.W. Kaul J.T. Byrd M.O. Andreae K.K. Roe 《Estuarine, Coastal and Shelf Science》1985,20(3):239-264
Concentrations of dissolved nutrients (NO3, PO4, Si), germanium species, arsenic species, tin, barium, dimethylsulfide and related parameters were measured along the salinity gradient in Charlotte Harbor. Phosphate enrichment from the phosphate industry on the Peace River promotes a productive diatom bloom near the river mouth where NO3 and Si are completely consumed. Inorganic germanium is completely depleted in this bloom by uptake into biogenic opal. The ratio taken up by diatoms is about 0·7 × 10?6, the same as that provided by the river flux, confirming that siliceous organisms incorporate germanium as an accidental trace replacement for silica. Monomethylgermanium and dimethylgermanium concentrations are undetectable in the Peace River, and increase linearly with increasing salinity to the seawater end of the bay, suggesting that these organogermanium species behave conservatively in estuaries, and are neither produced nor consumed during estuarine biogenic opal formation or dissolution. Inorganic arsenic displays slight removal in the bloom. Monomethylarsenic is produced both in the bloom and in mid-estuary, while dimethylarsenic is conservative in the bloom but produced in mid-estuary. The total production of methylarsenicals within the bay approximately balances the removal of inorganic arsenic, suggesting that most biological arsenic uptake in the estuary is biomethylated and released to the water column. Dimethylsulfide increases with increasing salinity in the estuary and shows evidence of removal, probably both by degassing and by microbial consumption. An input of DMS is observed in the central estuary. The behavior of total dissolvable tin shows no biological activity in the bloom or in mid-estuary, but does display a low-salinity input signal that parallels dissolved organic material, perhaps suggesting an association between tin and DOM. Barium displays dramatic input behavior at mid-salinities, probably due to slow release from clays deposited in the harbor after catastrophic phosphate slime spills into the Peace River. 相似文献
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Linjie Zheng Tomoharu Minami Shotaro Takano Hideki Minami Yoshiki Sohrin 《Journal of Oceanography》2017,73(5):669-685
A central theme of the ongoing GEOTRACES program is to improve the understanding of processes occurring at ocean interfaces with continents, sediments, and ocean crust. In this context, we studied the distributions of Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Pb around the Juan de Fuca Ridge (JdFR) in total dissolvable (td), dissolved (d), and labile particulate (lp) fractions, which represent a fraction in unfiltered samples, filtered samples through an AcroPak capsule filter, and the difference between td and d, respectively. Al and Fe were dominated by lp-species, while Ni, Zn, and Cd were dominated by d-species with undetectable amounts of lp-species. Major findings in this study are as follows: (1) The continental margin (CM) provided large sources of Al, Mn, Fe, and Co from the surface to ~2000 m in depth. The supply from CM caused high surface concentrations of dMn and dCo, a subsurface (100–300 m depth) maximum of dCo, and intermediate (500–2000 m depth) maxima of lpAl and lpFe. The supply of dFe from CM was ~10 times that from the high-temperature hydrothermal activity at station BD21, which is located at ~3 km from the Middle Valley venting site and ~ 200 km from Vancouver Island. (2) DPb was maximum at the top layer of North Pacific Intermediate Water, probably owing to isopycnal transport of anthropogenic Pb via advection of subducted surface waters. Although dCo and dPb had different sources in the upper water, they showed a strong linearity below 300 m (r 2 = 0.95, n = 38), indicating concurrent scavenging. (3) A high-temperature hydrothermal plume occurred at a depth of 2300 m at BD21, accounting for maxima of dAl, dMn, dFe, lpCu, and lpPb and a minimum of dCu. (4) Strong bottom maxima of lpAl, lpMn, lpFe, lpCo, and lpPb occurred above the abyssal plain at the western foot of the JdFR, indicating resuspension of sediments. However, bottom maxima of d-species were apparent only for dAl and dCu. 相似文献
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Lars-Göran Danielsson 《Marine Chemistry》1980,8(3):199-215
Results of trace-metal analyses of water samples obtained during a cruise with the Soviet R.V. “Akademik Kurchatov” in the Indian Ocean are presented. The determinations were performed on board with atomic absorption spectrophotometry after a two-stage dithiocarbamate—Freon extraction procedure. Trace-metal concentrations found are in the same range as those found recently for similar open-ocean areas by other workers. The values for lead and zinc are probably high due to contamination. Vertical profiles indicate biogenic processes as controlling factors for the increase of cadmium, copper and nickel concentrations with depth. Iron shows an irregular depth distribution as a result of large random variations in concentration. 相似文献
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E. Wolanski P. Colin J. Naithani E. Deleersnijder Y. Golbuu 《Estuarine, Coastal and Shelf Science》2004,60(4):705-716
Three years of temperature data along two transects extending to 90 m depth, at Palau, Micronesia, show twice-a-day thermocline vertical displacements of commonly 50–100 m, and on one occasion 270 m. The internal wave occurred at a number of frequencies. There were a number of spectral peaks at diurnal and semi-diurnal frequencies, as well as intermediate and sub-inertial frequencies, less so at the inertial frequency. At Palau the waves generally did not travel around the island because there was no coherence between internal waves on either side of the island. The internal waves at a site 30 km offshore were out-of-phase with those on the island slopes, suggesting that the waves were generated on the island slope and then radiated away. Palau Island was thus a source of internal wave energy for the surrounding ocean. A numerical model suggests that the tidal and low-frequency currents flowing around the island form internal waves with maximum wave amplitude on the island slope and that these waves radiate away from the island. The model also suggests that the headland at the southern tip of Palau prevents the internal waves to rotate around the island. The large temperature fluctuations (commonly daily fluctuations ≈10 °C, peaking at 20 °C) appear responsible for generating a thermal stress responsible for a biologically depauperate biological community on the island slopes at depths between 60 and 120 m depth. 相似文献
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Jerry Siok 《Marine Georesources & Geotechnology》2013,31(2-3)
Exploration for oil at Northstar has been long and costly. Northstar leases were first acquired in 1979 at a joint state and federal sale by Shell Oil, Amerada Hess, and Texas Eastern. The Northstar Unit is 6 mi offshore and about 4 mi northeast of the Point McIntyre Field. Oil was first discovered in Shell's Seal Island 1 in 1983. Five additional appraisal wells were drilled (1983-1986) from two man-made gravel islands in 40 ft of water. Early engineering estimates put the cost of development at $ 1.6 billion. In February 1995, BP Exploration (Alaska) acquired a 98 % interest in the Northstar Unit from Amerada Hess and Shell Oil. When developed by BP, Northstar will be the first oil produced from federal leases in Alaska. To date, the oil industry has invested in excess of $ 140 million in exploration and appraisal operations. An additional $ 90 million was spent on lease bonus bids. The giant Prudhoe Bay and Kuparuk Fields lie along the Barrow Arch. This arch is bounded to the north by a rift margin that deepens into the present-day offshore region. Northstar is located among a series of down-stepping faults off this northern rift margin of the Prudhoe Kuparuk high. The structure is a gently south-dipping northwest-trending faulted anticline. The crest of the structure is located near 10,850 ft subsea. The primary reservoir is the Ivishak Formation (325 ft thick) of the Sadlerochit Group. This is the same primary reservoir at Prudhoe Bay, approximately 12 mi to the south. At Northstar the Ivishak is a high-energy, coarse-grained conglomeratic facies of the Ivishak Formation. The primary lithology is a pebbly chert to quartz conglomerate with occasional sandstone. This very high net to gross reservoir appears to contain no regionally continuous permeability barriers. Cementation has reduced primary porosity to less than 15 %. Accurate porosity estimates are difficult to make due to the coarse-grained nature of the lithology and the presence of kaolinite and microporous chert. Permeability is highly variable, but averages 10 to 100 mDarcies. Oil is a very light and volatile 42 API crude with approximately 2,100 ft3 of gas per stock tank barrel of oil. This oil is very different from the heavier oils (26) found to the south in Prudhoe Bay. Estimated recoverable oil reserves range from 100 to 160 million barrels. A free-standing drilling rig is required at Northstar because the reserves are beyond extended-reach drilling techniques from shore-based facilities. The current development plan is to expand the existing Seal Island to about 5 acres. This is significantly less than Endicott's 40-acre island. The proposed drilling and produc tion island will be accessed by summer barges and winter ice roads. Oil, gas, and water will be processed at a stand-alone facility and then sent to shore via a subsurface pipeline. Northstar will have the first Arctic subsea pipeline in Alaska to transport oil to shore facilities (TAPS). Preliminary tests in Spring 1996 were very successful in demonstrating the technology to successfully bury a subsea pipeline safely in the Arctic. 相似文献
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以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。 相似文献
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Maryd De Wemton John S. Clayton Rohan D. S. Wells Chris C. Tanner Suzanne T. Miller 《新西兰海洋与淡水研究杂志》2013,47(2):145-151
The submerged vegetation of Lakes Sumner, Marion, Katrine, Taylor, and Sheppard was surveyed in May 1987. These high‐altitude lakes lie at c. 600 m a.s.l., within the largely unmodified upper Hurunui catchment. Submerged vegetation was diverse and included numerous short shallow‐water species, dense swards of Isoetes alpinus, low covers of taller native vascular plants, and charophyte meadows beyond the depth limit of vascular plants to a maximum of 15 m. A sparse deepwater bryophyte community was observed from 11 to 32 m depth in Lake Sumner. Displacement of native vegetation by dense growths of the adventive oxygen weed Elodea canadensis over mid‐depths of 3–6 m was noted in all lakes, except Lake Marion. 相似文献
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Izvestiya, Atmospheric and Oceanic Physics - Data on the relative contribution of the Ox, HOx, NOx, ClOx, BrOx, and IOx catalytic cycles to atmospheric ozone destruction are given for June and... 相似文献
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This is the first study of the flocculation of dissolved Fe, Al, Mn, Si, Cu, Pb and Zn during mixing in Zhujiang Estuary, based on the experiment on a series of solutions of salinities ranging from 0 to 24 by mixing the Zhujiang water near Zhongshan University and the seawater in Wan-shan Archipelago area. The mechanism of flocculation of the 7 elements is explored, and the effects of time, acidity and temperature on flocculation are discussed. The results show that the flocculation rates of Fe and Pb in the Zhujiang water are almost a hundred per cent, while that forCu reaches 76%; for Mn, 51%; for Al, 48%; for Zn, 28%; and for Si, 1.2%, indicating that Si is conservative. 相似文献