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轻柴油/海水微乳[状液]形成的相图研究 总被引：1，自引：0，他引：1
用相图方法研究轻柴油／海水微乳的形成。体系相图由水或人工海水（盐度分别为S＝0，10，115，29．471和41．071）／柴油／表面活性剂（AS、CTAB或BRIJ35）／助表面活性剂（正丁醇）在40℃时构成。本文分别研究了表面活性剂类型，油、醇、表面活性剂三者配比及海水盐度对微乳形成的影响。研究结果表明：三种表面活性剂中CATB，酸与表面活性剂的重量比值大于0．43，含油量≤25％，最适宜于形成微乳；形成微乳区面积分数随柴油含量增加而减少，也随海水盐度增加而减少，微乳区总面积分数随海水盐度变化率CTAB＞AS＞BRIJ35，三种表面活性剂体系的微乳区总面积分数依次为CTAB＞AS＞BRIJ35；在含紫油量＞50％时，三体系主要形成的W／O微乳区，在柴油含量≤25％时，对于CTAB体系可形成O／W至W／O连续变化微乳区，对于AS体系，可形成W／O和O／W两个独立的微乳区，而对于BRIJ35体系只形成W／O微乳区。 相似文献
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根据麦克斯韦电磁理论,在地磁场中运动的海水将产生感应电磁场。利用一个简单的数学物理模型对感应电磁场在海水内部的分布进行了计算,结果表明海浪产生的电磁场明显依赖于海浪波动的周期及浪高。在100 m的海水深度内,海浪产生的磁感应强度的大小为纳特数量级,而电场强度的大小为几个微伏每米。在同一海水深度处,磁感应强度随海水波动的周期呈现近线性变化,而电场强度的大小有一个极值,该极值随海水深度的增加向长周期方向移动。海浪产生的电磁场是影响海洋电磁探测数据精度的主要噪声之一。 相似文献
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油溢、工业排放以及污水处理场处理过的污水进入海洋已经成为最近海洋污染的主要污染源。浮游植物是鱼与高等有机生物的主要食物，它从海水中吸附大量的溶解有机物，因此，浮游植物对各种污染非常敏感，如烃、原油与工业废水等。Barbeau(1996)、Behrenfeld(1996)、La—Roche等(1996)已经对浮游植物中Fe的毒性进行了研究。 相似文献
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海上浮体动力定位外力计算 总被引：5，自引：1，他引：4
动力定位系统（dynamic positioning system）是一种闭环自动控制系统,采用推力器来抵抗风、浪、流等作用在浮体上的境力,使其保持在所要求的位置上。船舶的风和流作用力由经验公式求得,波浪力主要考虑二阶漂移力,由三维势流理论的直接积分法求得。通过模拟仿真,表明其结果能够用于船舶动力定位系统研究。 相似文献
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基于二维不可压缩两相流模型建立了数值风浪水槽,采用SST k-ω雷诺时均湍流模型,研究了风作用下孤立波在珊瑚礁上的传播变形规律。将计算结果与实验数据对比,证明了该两相流模型计算孤立波在珊瑚礁上传播的准确性,并进一步分析了不同风速对珊瑚礁上孤立波传播变形的影响。结果表明：风的作用会使波面发生随机脉动特征。当地波高随风速的增大而增大;当地波高关于风速的变化梯度随入射波高的增大而增大。风的作用会加快孤立波的传播并且使孤立波提前发生破碎;孤立波开始破碎的位置随风速的增大向远离礁坪的方向移动。反射系数随风速的增大而增大;反射系数关于风速的变化梯度随入射波高的增大而减小;透射系数随风速的增大呈增大趋势。平底区波峰剖面同一水深处的水平流速随风速的增大而增大;且一定的风速不改变水平流速沿水深的变化梯度。有风时波面上方的矢量密度和大小均明显高于无风时且与风速呈正相关,并且波峰上方气流不再循环。随着风速的增大,水气交界面附近的正涡量和负湍流剪应力减小,负涡量和正湍流剪应力增大。水体动能、势能和总能达到高值的时间随风速的增大而减少;水体动能、势能和总能随风速的增大而增大,并且风速对水体动能的相对影响大于势能。 相似文献
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海草所形成的植物消波体系能有效防止岸线的侵蚀。利用Sánchez-González等的实验数据分析了波浪非线性对海草消波特性的影响。研究结果表明，相对水深和波陡对海草床的波能衰减系数影响依赖于海草淹没度。相对波高一定时，拖曳力系数随相对水深的增大而增大。对给定的相对水深，拖曳力系数随波陡的增大而减小。波浪非线性对于规则波和非规则波海草消波特性的影响并不一致。用无量纲参数（邱卡数、雷诺数、厄塞尔数）表达拖曳力系数的效果取决于拖曳力系数与无量纲参数的关系中是否充分考虑波浪非线性对拖曳力系数的影响。 相似文献
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Suppression of Flow Separation Around A Circular Cylinder by Utilizing Lorentz Force 总被引：2，自引：0，他引：2
Both experimental and numerical investigations on the flow past a cylinder under the influence of Lorentz force （electromagnetic force） were conducted in an electrically low-conducting fluid. The Lorentz force is applied beth locally, wholly and periodically on the surface of the cylinder, and their control effects for flow ,separation were investigated Both experimental and numerical results show that Lorentz force can suppress the flow separation with Lorentz force applied on beth local and whole surface of the cylinder. However, when the periodic and opposite Lorentz force adopted, the cylinder wake cannot be stabilized. 相似文献
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Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity 总被引：1，自引：0，他引：1
Azetsu-Scott K Yeats P Wohlgeschaffen G Dalziel J Niven S Lee K 《Marine environmental research》2007,63(2):146-167
Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations. 相似文献
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为深入认识深海溢油输运过程和提高深海溢油事故的应急响应能力,文章以2010年墨西哥湾“深水地平线”事故为例,采用深海溢油输移扩散模型,以三维流场和海面风场为主要环境动力,数值模拟溢油深海泄漏后的浮射扩散、水体中输移扩散以及在风场和流场共同作用下在海面上输移扩散的全过程,同时模拟实施海底消油剂喷注处理措施后溢油输移轨迹和扩散范围的变化。研究结果表明：数值模拟结果与相关报道的悬浮油带实际观测结果以及美国国家海洋与大气管理局的海水异常遥感监测结果总体相符,可为更加全面和精细的深海溢油输移扩散数值模拟研究奠定良好的基础。 相似文献
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Geng Zhaoquan Ni Yongqiang Zhou Anguo Senior Engineer Zhejiang Provincial Institute of Estuarine Coastal Engineering Research Hangzhou Engineer Zhejiang Provincial Institute of Estuarine Coastal Engineering Research Hangzhou Engineer Zhejiang Institute of Environmental Protection Science Hangzhou 《中国海洋工程》1992,(1)
This paper adopted an upstream FEM of 2-D unsteady flow to calculate the tidal flow in Zhoushan sea area. Based on the verification of the tidal current and environmental situation, the effects of the oily waste discharged from the oil berths on water quality have been calculated with a similar method. The isodilutions of oil pollutant are drawn from different sewage discharges. The moving loci of the slick centrepoint of oil spill have been calculated. The spreading area of the oil spill has also been forecasted. The results indicate that the set of models can predict the transport of oil spill in the sea area with reasonable accuracy. 相似文献
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A thorough understanding of the biogeochemical cycling of trace metals in the ocean is crucial because of the important role these elements play in regulating metabolism in marine biotas and thus, the climate. However, a precise and accurate analysis of trace metals in seawater is difficult because they are present at extremely low concentrations in a high salt matrix. In this study, we report an analytical method for the preconcentration and separation of six trace metals, Fe, Ni, Cu, Zn, Cd and Pb, in seawater using a seaFAST automatic solid-phase extraction device, analysis by a triple quadrupole collision/reaction technique with inductively coupled plasma mass spectrometry (ICP-MS), and quantification by the isotope dilution technique. A small volume (10 mL) of seawater sample was mixed with a multi-element isotope spike and subjected to seaFAST procedures. The preconcentrate solution was then analyzed using the optimized collision/reaction cell mode of ICP-MS, with NH3 gas for Fe and Cd with a flow rate of 0.22 mL/min and He for Ni, Cu, Zn and Pb with a flow rate of 4.0 mL/min. The procedure blanks were 130 pmol/L, 3.0 pmol/L, 6.8 pmol/L, 37 pmol/L, 0.29 pmol/L and 0.42 pmol/L, for Fe, Ni, Cu, Zn, Cd and Pb, respectively. The method was validated using five reference materials (SLRs-6, SLEW-3, CASS-6, NASS-7 and GEOTRACE-GSC), and our results were consistent with the consensus values. The method was further validated by measuring full-water-column seawater samples from the subtropical Northwest Pacific Ocean, and our results demonstrated good oceanic consistency. 相似文献
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The influence of several operational parameters, including pH, flow rate, total volume of water passed, and choice of eluants, upon the efficiency of extraction of organic matter from seawater by two forms of commercially-available resin, XAD-2 and XAD-8, is considered. The overall efficiency of adsorption is at best 40%. The main factor determining the adsorption efficiency of XAD resin for natural organic matter is pH. The efficiency at normal seawater pH is only half that at pH 2.0. Although the efficiency decreases with increasing flow rate, the decrease is not great up to 3 bed vol./min. With increasing volume of water passed, the adsorption capacity of the resin initially drops, but reaches an approximately constant level after 1000 bed volumes. Alkaline solutions, either NH4OH or NaOH, followed by methanol, completely recover adsorbed organic material from the resin. There is no significant advantage of XAD-8 over XAD-2 for seawater extractions, and the materials adsorbed by the two forms of resin are not substantially different.A new separation method combining XAD-2 resin and activated carbon as adsorbents in series in a column has been developed. Efficiencies of up to 90% were obtained in the extraction of acidified seawater. When the volume of water passed was less than 500 bed volumes, the adsorption as measured by UV-oxidation was quantitative. Elution of 90–100% of the adsorbed organic carbon was possible when ammonium hydroxide (7 M), methanol and an ammonium hydroxide—methanol mixture were used sequentially. 相似文献
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针对深水油气田主动旋流分离器强制涡流前推段锥度对分离性能的影响进行研究,应用RSM(reynolds stress model)湍流模型对主动旋流器内部强旋流场进行数值模拟计算,在强制涡流前推段锥角变化时,合理预测并对比其内部轴向速度、切向速度、离心力以及分离效率的变化。研究表明在一定范围内,前推段锥度的增加可以提高混合液在前推段内的轴向速度和切向速度,进而可以获得更高的分离效率。当锥角达到15°时,可以获得最为理想的分离效果。此外,在不同深水环境下对该主动旋流分离器进行仿真计算表明,不同的环境压力对旋流器分离效率影响很小。 相似文献
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Takenobu Toyota Shinya Takatsuji Kazutaka Tateyama Kazuhiro Naoki Kay I. Ohshima 《Journal of Oceanography》2007,63(3):393-411
The general properties of sea ice and overlying snow in the southern Sea of Okhotsk were examined during early February of
2003 to 2005 with the P/V “Soya”. Thin section analysis of crystal structure revealed that frazil ice (48% of total core length)
was more prevalent than columnar ice (39%) and that stratigraphic layering was prominent with a mean layer thickness of 12
cm, indicating that dynamic processes are essential to ice growth. The mean thickness of ice blocks and visual observations
suggest that ridging dominates the deformation process above thicknesses of 30 to 40 cm. As for snow, it was found that faceted
crystals and depth hoar are dominant (78%), as which is also common in the Antarctic sea ice, and is indicative of the strong
vertical temperature gradients within the snow. Stable isotope measurements (δ18O) indicate that snow ice occupies 9% of total core length and that the mass fraction of meteoric ice accounts for 1 to 2%
of total ice volume, which is lower than the Antarctic sea ice. Associated with this, the effective fractionation coefficient
during the freezing of seawater was also derived. Snow ice was characterized by lower density, higher salinity, and nearly
twice the gas content of ice of seawater origin. In addition, it is shown that the surface brine volume fraction and freeboard
are well correlated with ice thickness, indicating some promise for remote sensing approaches to the estimation of ice thickness. 相似文献