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1.
The upwelling area in the Changjiang Estuary was selected to collect the core, where the red tide occurred frequently and hypoxic existed. The total organic carbon (TOC), total nitrogen (TN), biogenic silica (BSi) and stable organic carbon isotopic ratios(δ13 Corg) were determined on the 210pb-dated sediment core. The concentrations of TOC, TN, BSi as well as their sedimentation fluxes have in- creased to some extent since the 1970s. TOC and TN fluxes increased about 45%, 36% respectively. The average δ13 Coorg value in the core was -23.67 ×10^-3 which remained nearly constant before the 20 century. The δ13 Corg values increased after the 1900s, two marked increases were observed from the 1950s and the 1970s. A simple δ13 Cors model was used to estimate the contribution of terrigenous and marine organic matter inputs for the sediment, which indicated the increase in accumulation since the 1970s has been almost exclusively marine. The increasing of marine organic matter accumulation (TOC, TN and BSi) was corresponding with the increasing of fertilizer consumption and the NO3-N budgets from the Changjiang River. The riverine runoff of fertilizers and nutrients stimulated the algae blooming. Enhanced primary production resulted in an enrichment of organic matter in the sediment. These data support the hypothesis that anthropogenic nutrient loading has been a significant factor on the eutrophication in the Changjiang Estuary.  相似文献   

2.
Naturally existing stable carbon and nitrogen isotopes are important in the study of sedimentary organic matter sources. To identify the sources of sedimentary organic matter in Sanggou Bay and its adjacent areas, which is characterized by high-density shellfish and seaweed aquaculture, the grain size, organic carbon(OC), total nitrogen(TN), carbon and nitrogen isotopic composition(δ13C and δ15N) of organic matter in the surface sediment were determined. The results showed that, in August, sedimentary OC and TN ranged from 0.17% to 0.76% and 0.04% to 0.14%, respectively. In November, OC and TN ranged from 0.23% to 0.87% and 0.05% to 0.14%, respectively. There was a significant positive correlation between OC and TN(R=0.98, P0.0001), indicating that OC and TN were homologous. In August, the δ13C and δ15N of organic matter varied from-23.06‰ to-21.59‰ and 5.10‰ to 6.31‰, respectively. In November, δ13C and δ15N ranged from-22.87‰ to-21.34‰ and 5.13‰ to 7.31‰, respectively. This study found that the major sources of sedimentary organic matter were marine shellfish biodeposition, seaweed farming, and soil organic matter. Using a three-end-member mixed model, we estimated that the dominant source of sedimentary organic matter was shellfish biodeposition, with an average contribution rate of 65.53% in August and 43.00% in November. Thus, shellfish farming had a significant influence on the coastal carbon cycle.  相似文献   

3.
The characteristics of grain-size,total organic carbon(TOC) and total nitrogen(TN) contents,TOC/TN ratios,stable carbon isotope(δ13C) and 210 Pb dating were measured in six sediment cores from the Xiaohai Lagoon.The results show distinct spatial and temporal variations in sedimentation patterns.The sediments are dominated by clayey silt,sandy silt and by silty sand in the southern,middle lagoon and the northern lagoon,respectively.TOC and TN contents decline from south to north.Sedimentation rates,determined by 210 Pb dating,tend to decrease from south to middle.However,the determination of sedimentation rate in the north is difficult.These spatial variations are related to the variations in sediment sources and hydrodynamic conditions in the Xiaohai Lagoon.The variations of organic matter signatures can be divided into two stages in the cores from the southern and middle lagoon.Before 1988,the organic matter signatures are relatively stable.The contribution of terrestrial organic carbon sources varies between 60% and 85%.After 1988,the organic matter signatures demonstrate significant variations.TOC and TN contents increase rapidly,TOC/TN ratios decrease,δ13C values shift to higher and the contribution of terrestrial organic carbon sources decreases to 40%-50%.The contributions of phytoplankton organic matter have increased in the sediment since 1988.Increasing aquaculture activities have had a significant impact on organic matter signatures since 1988.The sedimentation rates have increased rapidly in the southern and middle lagoon since 1988 due to the anthropogenic activities which include aquaculture,mining and deforestation.These activities have caused eutrophication and increased siltation in the southern and middle lagoon.  相似文献   

4.
Phosphorus is a key element and plays an important role in global biogeochemical cycles. The evolution of sedimentary environment is also influenced by phosphorus concentrations and fractions as well as phosphate sorption characteristics of the marine sediments. The geochemical characteristics of phosphorus and their environmental records were presented in Jiaozhou Bay sediments. Profiles of different forms of phosphorus were measured as well as the roles and vertical distributions of phosphorus forms in response to sedimentary environment changes were investigated. The results showed that inorganic phosphorus (IP) was the major fraction of total phosphorus (TP); phosphorus which is bound to calcium, iron and occluded phosphorus, as well as the exchangeable phosphorus were the main forms of IP, especially calcium-phosphorus, including detrital carbonate-bound phosphorus (Det-P) and authigenic apatite-bound phosphorus (ACa-P), are the uppermost constituent of IP in Jiaozhou Bay sediments. Moreover, the lead-210 chronology technology was employed to estimate how much phosphorus was buried ultimately in sediments. And the research showed that the impacts of human activities have increased remarkably in recent years especially between the 1980s and 2000. According to research, the development of Jiaozhou Bay environment in the past hundred years can be divided into three stages: (1) before the 1980s characterized by the relatively low sedimentation rate, weak land-derived phosphorus inputs and low anthropogenic impacts; (2) from the 1980s to around 2000, accelerating in the 1990s, during which high sedimentation rates, high phosphorus abundance and burial fluxes due to the severe human activities impacted on the whole environmental system; (3) after 2000, the period of the improvement of environment, the whole system has been improved including the decreasing sedimentation rates, concentration and the burial fluxes of phosphorus.  相似文献   

5.
In some studies, the researchers pretreated and measured organic carbon, nitrogen and their isotopes(δ~(13)C and δ~(15)N) of marine sediment together, to save costs and resources of analysis. However, the procedure of acidification to remove inorganic carbon for analysing δ~(13)C can affect the values of nitrogen and δ~(15)N, and the biases vary a lot depending on the CaCO_3 contents of sediments. In this study, the biases of total nitrogen(TN)and δ~(15)N values arising from acidified sediments were compared between the CaCO_3-poor(1%–16%) and CaCO_3-rich(20%–40%) samples. TN and δ~(15)N values were altered during acid treatment(without centrifugation) that possibly led to N-containing compounds volatilization. For CaCO_3-poor samples, acidification led to a range of 0%–40% TN losses and 0‰–2‰ shift in δ~(15)N values; and 10%–60% TN losses and 1‰–14‰ shift in δ~(15)N values for CaCO_3-rich samples. The biases from most samples exceeded the precision of the instrument(0.002% for TN and 0.08‰ for δ~(15)N), and high biases could mislead our judgment for the environmental implication of the data. Thus,avoiding co-analysis of organic carbon, nitrogen and their isotopes(δ~(13)C and δ~(15)N) in sediments, even for CaCO_3-poor marine sediments, is necessary.  相似文献   

6.
The present paper deals with the mineralogy and some chemical composition such as Organic Carbon、Carbonate and Sulphate of surficial sediments in Jiaozhou Bay using the data obtained from X-Ray diffraction,chemical analysis and microscopic observation. Quartz、plagioclase、patassium feldspars and clay minerals are the main terrigenous minerals, and calcite is the predominant authigenic mineral in the sediments. Relatively high content of organic carbon and So3 are drainged from industrial waste water from some river running into the Bay. Some X-Ray diffraction data and ratio of integrated intensity of mineral special peaks indicate the distribution tendency of these minerals.  相似文献   

7.
On the basis of data collected in the Jiaozhou Bay in June and July 2003, the DIC distribution in seawater is studied,and an average air-sea flux of CO2 is estimated. The results show that the content of DIC inside the bay is markedly higher than outside the bay in June, but the contem of DIC outside the bay is markedly higher than inside the bay in July. The trend of DIC distribution inside the bay is similar, viz. the content is the maximum in the northeast, then decreases gradually toward the west, and the content is the minimum in the west. The total trend of vertical distribution is to increase gradually from surface to bottom. This characteristic of DIC distribution is determined by Jiaozhou Bay hydrology and there is a close relation between DIC and particulate N.P. Average CO2 flux across the air-sea interface is 0.55 mol/(m^2.a) in June and 0.72 mol/(m^2.a) in July. Jiaozhou Bay is considered as a net annual source for atmospheric CO2 in June and July, and the total CO2 flux from seawater into atmosphere is about 740 t in June and 969 t in July.  相似文献   

8.
The composition, assemblage and distribution characteristics of heavy minerals from 63 to 125 μm grain sizes in surface sediment from the Xinghua Bay (17 stations) are studied. The matter source of silt and the relationship between heavy minerals and sedimentary environment are also discussed. The results show that there are 37 kinds of heavy minerals and the average content of them is 12.08%,which exceeds 6% compared with the Meizhou Bay (5.67%). The dominant minerals are magnetite, hornblende, epidote, ilmenite,hematite, limonite, zircon and so on. Mineral kinds reveal that the sources of silt in this bay are the fluvial input and eroded products of bedrock in circnmjacent land and islands of the Xinghua Bay. However, the matter source from outside this bay is less. Four mineral assemblage zones can be divided based on heavy mineral contents and distribution characteristics in the Xinghua Bay, which are not only influenced by matter source, but also controlled by hydrodynamic condition and sedimentary environment in the Xinghua Bay.  相似文献   

9.
A three-dimensional coupled physical and water quality model was developed and applied to the Jiaozhou Bay to study water quality involving nutrients, biochemical oxygen demand, dissolved oxygen, and phytoplankton that are closely related to eutrophication process. The physical model is a modified ECOM-si version with inclusion of flooding/draining processes over the intertidal zone. The water quality model is based on WASP5 which quantifies processes governing internal nutrients cycling, dissolved oxygen balance and phytoplankton growth. The model was used to simulate the spatial distribution and the temporal variation of water quality in the Jiaozhou Bay for the period of May 2005 to May 2006. In addition, the effect of reduction of riverine nutrients load was simulated and evaluated. The simulated results show that under the influence of nutrients discharged from river, the concentrations of nutrients and phytoplankton were higher in the northwest and northeast of the bay, and decreased from the inner bay to the outer. Affected by strong tidal mixing, the concentrations of all state variables were vertically homogeneous except in the deeper regions where a small gradient was found. Obvious seasonal variation of phytoplankton biomass was found, which exhibited two peaks in March and July, respectively. The variation of riverine waste loads had remarkable impact on nutrients concentration in coastal areas, but slightly altered the distribution in the center of the bay.  相似文献   

10.
Distributions and sources of total organic carbon (TOC)in seabed sediments and their implications for hydrodynamics are analyzed, in the turbidity maximum of the Changjiang Estuary. Ecology ecoenvironmental effects of estuary water on the continuously increasing terrigenous organic carbon from the Changjiang River are also explored through variations of organic carbon content and water quality indicators. Results show that, hydrodynamics exert important influences on distributions of organic carbon in the tur- bidity maximum of Changjiang Estuary. For their redistribution effect of terrigenous organic carbon within the moving layer in the whole region, variations from land to sea are not indicated by surficial and vertical average values of TOC and total nitrogen (TN) contents in core sediment, as well as organic stable carbon isotopes in surface sediments. However, on the long-time scale, the trend of terrigenous organic carbon decreasing from land to sea is still displayed by variations of stable carbon isotopic average values becoming heavier from land to sea. Previous studies have shown that high content of Chl a cannot appear in the Changjiang Estuary in despite of adequate nourishment supply, because photosynthesis of phytoplankton is constrained by high suspended sediment concentration(SSC). However, an area with a high content of Chl a occurs, which may be caused by resuspended benthic algae with bottom fine grain-size sediments. Tremendous pressures are imposed on the environment of Changjiang Estuary, because of uhrophication trends and special hydrodynamics. Phytoplankton bloom area tends to extend from the outer sea to the mouth of Changjiang River.  相似文献   

11.
This work concerns the trophic web positioning of the alien crab Rhithropanopeus harrisii and other common marine invertebrate species and fishes in the benthic ecosystem of the shallows of Taman Bay, Sea of Azov. The base of the trophic web in this system is composed of phytoplankton, macrophytes (algae and marine grasses), and reeds that use atmospheric carbon for photosynthesis. Analysis of the isotopic composition of nitrogen and carbon has shown that although marine grasses are dominating primary producers in the shallows of the bay, primary consumers (such as Cerastoderma glaucum, Porifera gen. sp., Gammarus aequicauda, Deshayesorchestia deshayesii and Idotea balthica) only partially use this organic source; instead, they use a combination of different sources of primary production. It has been shown that the food source of the alien crab is primarily of animal origin. In Taman Bay, R. harrisii is on the same trophic level as other carnivores/scavengers: benthic fishes Syngnathus nigrolineatus, Gobius spp. and native crab Pilumnus hirtellus and shrimp Palaemon adspersus.  相似文献   

12.
为节约成本和样品,一些学者同时分析海洋沉积物中的碳、氮及其同位素(TOC、TN、δ13C和δ15N)。分析沉积物中的δ13C,需要对样品进行酸化去除无机碳,但是这一酸化过程会使TN和δ15N的分析结果产生偏差,且偏差范围与沉积物中无机碳含量(CaCO3)有关。本研究选取了低CaCO3含量(1-16%)和高CaCO3含量(20-40%)的海洋沉积物样品,比较了酸化过程对TN和δ15N的影响。研究结果表明,酸化过程对海洋沉积物中TN和δ15N的分析结果产生了显著影响。对于低CaCO3含量的样品,酸化导致样品中TN流失了约0-40%,δ15N偏移了约0-2‰;而对于高CaCO3含量的样品,酸化导致样品中TN流失了约10-60%,δ15N偏移了约1-14‰。表明酸化对TN和δ15N的影响已经超过了仪器的误差范围0.002%(TN)和0.08‰(δ15N),将影响TN和δ15N的环境指示意义。因此,即使海洋沉积物样品中CaCO3含量很低,也必须用原样分析TN和δ15N以避免酸化过程的影响。  相似文献   

13.
The spatial distributions of δ13C, δ15N, and n-alkanes were investigated to determine the source and transportation of allochthonous organic matter from the mouth of the Seomjin River to the southern inner shelf break of Korea. Total organic carbon (%) ranged from 0.3% to 1.6% (average = 0.80%, n = 81), and the C/N ratio varied from 2.4 to 12.4 (average = 6.76, n = 81). The δ13C values ranged from ?25.86 to ?20.26‰ (average = ?21.47‰, n = 81), and δ15N values ranged from 4.37‰ to 8.57‰ (average = 6.72‰, n = 81). The contribution of the terrestrial fraction of organic matter to the total ranged from 4.4% to 97.7% (average = 24.4%, n = 81), suggesting higher amounts around the catchment area and lower amounts in the offshore area. The concentration of total n-alkanes (nC25 ? nC35) was higher at the boundary between the outer bay and inner shelf break (BOBIS). Average chain length and the carbon preference index both indicated that major leaf wax n-alkanes accounted for the observed distribution of terrestrial organic matter, and were dominant in the inner shelf break (around BOBIS) and outer shelf break. Based on the spatial distribution of the total n-alkanes and the sum of nC27, nC29, and nC31, the terrestrial organic matter distribution was considered to be controlled by local oceanographic conditions, especially at the center of the BOBIS. In addition to enabling the distribution and source of terrestrial organic matter to be identified, the n-alkanes indicated that minor anthropogenic allochthonous organic materials were superimposed on the total organic materials in the central part of Yeosu Bay and the catchment area. The n-alkane indices revealed weathered petroleum contamination, with contamination levels being relatively low at the present time.  相似文献   

14.
The species composition, phytoplankton abundance, and relative yield of the variable fluorescence (F v /F m ) were determined in the mesotrophic Nhatrang Bay in October–November of 2004. The species diversity (250 taxonomic units) and heterogeneity of the phytoplankton structure were high. With respect to the number of species and their abundance, diatoms prevailed. In selected parts of the bay, dinoflagellates dominated. The mean biomass in the water column under 1 m2 (B t ) varied from 2.3 to 64.4 mg C/m3 being 31.0 mg C/m3 on average. The values of B t were the lowest at the stations nearest to the river mouth. Seaward, B t increased. The values of B t increased with depth at some stations and decreased at others. In the surface sea layers, the biomass was lower than that in the underlying waters. The values of F v /F m ranged from 0.10 to 0.64 (at a mean value of 0.49). The lowest values of F v /F m were observed in the area close to the seaport. Over the greater part of the bay, the values of F v /F m were higher than 0.47. Such values are indicative of the relatively high potential photosynthetic activity of the phytoplankton. The abundance and species diversity were higher than those in the dry season (March–April).  相似文献   

15.
Oxygen and carbon isotope ratios(δ~(18)O and δ~(13)C) in otoliths were used to identify the stock structure of small yellow croaker,Larimichthys polyactis.Otoliths were collected from fish at five locations across the Yellow Sea and the Bohai Sea representing most of their distributional range and fisheries areas.The significant differences in the isotopic signatures showed that the five locations could be chemically distinguished and clearly separated,indicating stock subdivision.Correlation of δ~(18)O and δ~(13)C values suggested that population of L.polyactis could be divided into the Bohai Sea group,the southern Yellow Sea group and the central Yellow Sea group.Discriminant analysis of δ~(18)O and δ~(13)C values demonstrated a high significant difference with 85.7% classification accuracy.The spatial separation of L.polyactis indicated a complex stock structure across the Yellow Sea and the Bohai Sea.These results indicate that optimal fisheries management may require a comprehensive consideration on the current spatial arrangements.This study has provided further evidence that measurement of the stable isotopes ratios in otolith can be a valuable tool in the delineation of fishery management units.  相似文献   

16.
Vestimentiferan tubeworms acquire their symbionts through horizontal transmission from the surrounding environment. In the present study, we constructed a 16S rRNA gene clone library to investigate the phylogenetic relationship between diverse microbes in the sediment and symbiotic bacteria in the trophosome of the tubeworm, Lamellibrachia satsuma, from Kagoshima Bay, Japan. Two symbiotic bacterial phylotypes belonging to the classes γ- and ε-Proteobacteria were found from this tubeworm trophosome. They were very closely related to the symbionts of several other marine invertebrates. The most predominant bacteria in the sediment were ε-Proteobacteria. A broad diversity of bacteria belonged to non-proteobacterial phyla such as Planctomycetes, Acidobacteria, and Chloroflexi was observed. The presence of sulfur oxidizers (i.e., ε-Proteobacteria and γ-Proteobacteria) and sulfur reducers (i.e., δ-Proteobacteria) may play a significant role in the sulfur cycle in these habitats and provide multiple sources of nutrition to the cold-seep communities. Closely related clones of ε-Proteobacteria symbiont in the species level and of γ-Proteobacteria symbiont in the genus level were found in the surrounding sediment. The similarity of symbiont clones of L. satsuma with other symbionts and free-living bacteria suggests the possibility of opportunistic symbiosis in ε-Proteobacteria and the co-evolution of γ-Proteobacteria having occurred after symbiosis with the tubeworms.  相似文献   

17.
Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ 15N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ 15N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ 15N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ 15N(SUS) signature was reflected by δ 15N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ 15N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ 15N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ 15N(DST) vs. PP regression to δ 15N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

18.
The current study was carried out from May 2014 to April 2015 to estimate the stock status of P. viridis in Marudu Bay. The gonad development was monitored by histological examination, while the population parameters including asymptotic length (L), growth coefficient (K), mortality rate (Z, F and M), exploitation level (E) and recruitment of P. viridis were estimated using the lengthfrequency data. Results of the current study demonstrated that P. viridis in Marudu Bay spawned throughout the year with two major peaks, one in April to May and another one in October to December. The recruitment pattern was continuous with the peak in May to June 2014, which corresponded to the first spawning peak in April. However, no significant recruitment was observed from the second spawning peak due to the difference in spawning timing between male and female populations. The estimated asymptotic length (L), growth coefficient (K), total mortality (Z), natural mortality (M), fishing mortality (F) and growth performance (ф) of P. viridis in Marudu Bay were estimate to be 117 mm, 0.97 yr-1, 4.39 yr-1, 1.23 yr-1, 3.16 yr-1 and 4.123, respectively. The exponent b of the lengthweight relationship was 2.4 and exploitation level (E) was 0.72. The high mortality, low condition indices and negative allometric of P. viridis in Marudu Bay is caused by a lack of suitable food in the surrounding water.  相似文献   

19.
基于对胶州湾表层沉积物中总可水解氨基酸(THAA)的含量、组成、构型及分布特征的系统研究,通过氨基酸碳氮归一化产率(THAA-C%,THAA-N%)、降解因子DI、反应活性指数RI以及D型氨基酸占比(D-AA%,摩尔百分比)等指标结合碳氮比(TOC/TN)、碳稳定同位素(δ13C)探析了胶州湾沉积物中有机质的来源与降解状态,利用细菌源有机质及胞外肽酶活性(EEA)探讨了微生物在有机质迁移转化过程中的作用与贡献。结果表明,胶州湾表层沉积物中氨基酸平均含量为(7.60±3.64)μmol/g,在陆源与海源混合影响下,其水平分布呈现湾内高于湾外、湾内东部高于西部的特点,表明湾内东部陆源输入对沉积物THAA具有较高贡献。THAA-C%、THAA-N%、DI、RI以及D-AA%等指示因子均显示胶州湾表层沉积物中有机质的降解程度呈现湾外高于湾内、湾内东部高于西部的变化趋势,有机质来源、微生物活性与上覆水水深共同影响了有机质的降解程度。胶州湾表层沉积物中细菌源有机碳的贡献率为(29.35±18.73)%,其水平分布显示出湾内西部与湾外相近且高于湾内东部的特点。细菌胞外肽酶活性(EEA)平均为(0.81±1.31)nmol/(g·h)(以MCA计),整体分布趋势与细菌贡献率相反,呈现湾内东部高于湾内西部和湾外的特性。沉积物中有机质的不同海源、陆源占比决定了有机质的可降解性,而有机质的降解程度进一步影响了细菌源有机质的贡献与胞外肽酶活性。  相似文献   

20.
Benthic fauna in Tsivolki Bay (Novaya Zemlya Archipelago, Kara Sea) has been studied during the voyage of the R/V Professor Shtokman in 2013 and 2014. A peculiar feature of the bay is the presence of the Serp i Molot glacier in its inner part, which determines the extremely high content of suspended particles in the water column. The bay is divided into three parts: the inner part (close to the glacier), the middle basin, and the outer slope. These parts are separated from each other by several rises. Benthic communities changed gradually from the inner part of the bay towards the outer slope. Three communities were described from the data of nine grab stations (26 samples). The apex of the bay is occupied by the depleted community dominated by the isopod Saduria sabini and the bivalve Yoldiella lenticula, which can successfully survive the increased mineral sedimentation. In the middle basin, it is replaced by the transitional community with Ennucula tenuis and Portlandia arctica being the main dominants. Finally, the outer slope is inhabited by the community typical for the open parts of the Kara Sea. It is dominated by Astarte crenata, Ophiacantha bidentata, and Ophiopleura borealis. The main reason for macrobenthic distribution in the studied region is the content of mineral particles in the water column and bottom layers.  相似文献   

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