共查询到18条相似文献，搜索用时 140 毫秒
1.
东海近海水质总汞测定中的不确定度探讨 总被引：1，自引：0，他引：1
采用国际通用的方法分析探讨了东海近海水质总汞测定中不确定度的影响因素。其中，考虑到海洋环境监测的一些特殊性。在建立评定不确定度分量的数学模型时，引入了重复性实验校正因子f，并根据2002-2004年东海区海洋环境监测中的内拉质量数据（原始平行样测定）资料以A类方式评定量化重复性实验校正因子f的不确定度；同时，以A类或B类的方式对近海水质总汞测定中的其它各个不确定度分量进行了评定。结果表明，重复性实验校正因子f是近海水质总汞测定中不确定度的主要来源；东海近海水质总汞测定中的相对合成标准不确定度约为0．16。 相似文献
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胶州湾海水中氮的地球化学 总被引：1，自引：0，他引：1
《海洋湖沼通报》1982,(3)
海水中的氮化合物,已知包括无机的及有机的两大部分。前者主要是NO_3~-、NO_2~-及NH_4~ ,后者主要是从蛋白质到氨基酸、脲等的一系列有机含氮化合物,按其形态的不同,而又区分为粒状有机氮及溶解有机氮。 NO_3~-、NO_2~-、NH_4~ 及有机氮化合物,在海洋中的分布是具有明显规律性的。而它们的时间变化及循环,则更是复杂而有趣的、。无机氮作为浮游植物的养分而被吸收,并合成为有机氮。而浮游植物又作为浮游动物等的饵料,并两者在排泄或死亡分解时,则释出有机氮。后者经过细菌的分解作用,而 相似文献
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近岸海域实施污染物排放总量控制的理论与实践 总被引：5，自引：0，他引：5
多年来在近海和近岸海域进行的水质监测和其它随机性监测的结果表明,我国近岸海域海洋环境日益恶化,污染加剧,生态系统退化,并使外海受到威胁。污染物主要来源于陆源排污,主要污染物是无机氮、无机磷和石油类。 海洋环境的恶化引起了我国政府的高度重视。还在70年代初,我国就从控制污染源排放着 相似文献
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为了研究厦门市大气湿沉降中的无机氮情况,分析了2000～2014年厦门市内和郊区的雨水中NO_3~--N和NH_4~+-N的浓度及其沉降通量的变化情况,并对湿沉降中无机氮对厦门近海海水生态系统的影响进行讨论。结果表明,厦门市内和郊区雨水中NO_3~--N和NH_4~+-N的浓度均为春季较高,夏季较低;高浓度无机氮在一年中出现的时间段在两个区域有差别,这可能与这两个区域的季风转换和大气混合层高度变化有关。在2000～2014年,雨水中NO_3~--N的浓度在市内总体呈下降趋势,在郊区总体呈上升趋势;NH_4~+-N浓度的年变化规律不明显。湿沉降给厦门近岸海域带来的NO_3~--N和NH_4~+-N的量分别为1056 t/a和1278 t/a,低于该区域河流输入的无机氮的量的10%,说明湿沉降不是厦门近岸海域海水中无机氮的主要来源。通过比较厦门雨水和近岸海水中的营养盐情况,发现雨水的沉降可能会促进厦门近海部分区域海水中浮游植物的生长。 相似文献
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采用实验测定和误差分析的方法, 对燃烧氧化-非分散红外吸收总有机碳分析仪vario TOC cube测定海水DOC 含量的不确定度进行了分析, 对导致测定结果不确定度的各分量进行了量化估算。结果表明, 其测定结果的不确定度主要来源于四个方面, 即样品重复性测量、标准曲线拟合、标准溶液配制(包括称量、定容、移液产生的不确定度, 标准物质纯度和相对原子质量产生的不确定度)及测量仪器本身, 相对标准不确定度分量分别为0.016、0.018、0.0086、0.0079。标准曲线拟合与样品重复性测量是影响海水DOC 测定不确定度的主要因素, 但标准溶液配制和测量仪器所引起的不确定度亦不可忽略。对实际海水DOC 浓度为1.20 mg/L 的样品分析,合成以上四种不确定度分量得到DOC 测定结果的标准不确定度为0.21 mg/L。按照正态分布,取扩展因子k=2, 则扩展不确定度为0.07 mg/L, 此海水样品中DOC 含量的测定结果应为(1.20±0.07) mg/L(k= 2)。 相似文献
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电位测定法测海水氧化还原电位的不确定度评定 总被引：2，自引：0，他引：2
采用电位测定法对实际海水的氧化还原电位进行测定,分析了影响测量不确定度的主要来源,对曲线拟合、测定过程的标准溶液的使用、仪器使用和测量重复性等影响不确定度的分量进行分析,按JJF1059—1999《测量不确定度评定与表示》的规定进行合成,最终给出扩展不确定度。结果表明,实际海水电位值的合成标准不确定度为14.18 mV,扩展不确定度为28.4 mV(近似95%置信概率)。这样结果的表达更加客观和真实,更具有参考意义。 相似文献
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冷原子荧光法测定近海沉积物中汞含量的不确定度探讨 总被引：1，自引：0，他引：1
采用直观的因果图，分析冷原子荧光法测定近海沉积物中汞含量的不确定度影响因素。建立有效的数学模型，对测试过程中不确定度的各个分量进行了分步计算及整体合成，并对评定结果进行了讨论。结果表明，校准曲线、测量标准及仪器性能是冷原子荧光法测定近海沉积物中汞含量不确定度的主要影响因素. 相似文献
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LIU Sumei ZHAO Yingfei REN Jingling ZHANG Jing SUN San JIN Jie ZHANG Guiling 《海洋学报(英文版)》2010,29(1):42-51
Phosphorus (P) is an essential nutrient utilized by all organisms for energy transport and growth.
Both the conventional molybdenum-blue method and the magnesium-induced coprecipitation
(MAGIC) procedures were applied for the measurement of dissolved inorganic phosphorus (DIP)
and total dissolved phosphorus (TDP) in more than 840 water samples collected between 2003 and
2005, including seawater (the Huanghai Sea, the East China Sea, and the northern South China
Sea), water from rivers and estuaries (the Changjiang, the Huanghe, and the major rivers emptying
into the Jiaozhou Bay), groundwater (in the drainage basin surrounding the Jiaozhou Bay), rain-
water, and aquaculture water samples. The MAGIC method allows the investigation of phosphorus
distributions and cycling for systems in which DIP is below the detection limits of conventional
methods. Comparison between the two methods demonstrated that the concentrations obtained
with both methods were signiˉcantly correlated. The di?erences of DIP and TDP concentrations
measured with the two methods were higher when the concentrations of DIP and TDP were lower,
implying the lower reproducibility at low concentrations. The concentration di?erences increase
with the increase in the proportion of DOP in TDP, which indicates that the discrepancy of DIP
concentrations measured with the two methods increases when the DOP concentration is high. The
discrepancies indicated that the composition of P compounds di?ers depending on sample sources
and water type; it would be useful to infer the presence of di?erent phosphorus compound pools
from di?erences between the two methods. This study indicates the potential presence of a pool
of alkaline-labile compounds for samples from rainwater and rivers and estuaries surrounding the
Jiaozhou Bay; the potential presence of acid-labile compounds that were adsorbed by Mg(OH)2 for
samples from the Changjiang Estuary, Huanghai Sea, East China Sea, and groundwater; the po-
tential presence of a substantial pool of acid-labile compounds that were not adsorbed by Mg(OH)2
for samples from the Huanghe Estuary, aquaculture water, the East China Sea algal bloom water,
and the northern South China Sea. 相似文献
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本文综合2000～2003年期间9个航次的研究结果，讨论了总溶解态无机砷（TDIAs，[TDIAs]=[As^5＋]＋[As^3＋]）和亚砷酸盐（As^3＋）在黄、东海的分布和季节性变化。调查海区覆盖了黄、东海不同水文和化学性质的区域，研究重点放在自长江口向东南琉球群岛沿伸的PN断面以讨论陆源输送的物质对中国陆架边缘海的影响。利用氢化物发生原子荧光光谱法（HG-AFS）分析砷的不同形态（TDIAs，As^3＋）。TDIAs受河流陆源输送的影响在近岸区域含量较高，并随着离岸距离的增加含量逐步下降。在东海陆架坡折带的近底层水中也存在TDIAs的高值中心，此区域具有低温、高盐、低悬浮颗粒物含量的特征，显示出入侵陆架的黑潮水是陆架区TDIAs另一个主要的源。TDIAs的季节性变化趋势受到长江冲淡水水量及黑潮入侵陆架强度的季节及年际变化共同影响。研究区域中As^3＋的分布特征与TDIAs相反，其含量、分布及季节性变化受到浮游植物活动的影响，表现出与叶绿索含量存在正相关关系。夏季东海陆架PN断面中As／P的化学计量比值约为2×10^3。黄、东海溶解态砷的含量与世界其它海区相近，表明其未受到明显人为活动的影响。 相似文献
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东海溶解无机氮(dissolved inorganic nitrogen, DIN)有四个主要外部来源,包括黑潮、台湾海峡、河流径流和大气沉降。为探究它们的共同作用对东海浮游植物时空变化带来的多重影响,利用添加分源模块的物理-生态耦合模型分析了东海表层不同来源DIN支持的浮游植物(以叶绿素a浓度chlorophylla,chla表征)季节变化与空间分布以及它们之间的响应关系,从而评估多源营养盐对东海陆架表层浮游植物的影响。各来源DIN支持的chl a浓度中,黑潮来源和河流径流来源先后占据主导地位,且除了河流径流来源chl a,其余三种来源chl a季节变化均呈双峰结构。不同来源chl a空间分布特征存在季节变化差异,并且各来源chl a在东海陆架不同季节存在不同的主导区域,这与不同来源DIN供给的物理过程,如环流、混合、层化以及温度变化等密切相关。研究不同来源营养盐对东海浮游植物的影响对理解多重压力下东海生态系统变化有重要意义。 相似文献
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Fenghua Li Jianjun Liu Renhe Zhang 《Oceanic Engineering, IEEE Journal of》2004,29(4):1060-1066
A bottom-scattering model based on sediment small scatterers, single scattering approximation is presented, which is combined with a normal-mode-based reverberation model. The combined model (for total reverberation) is compared with measurements of shallow-water reverberation from the 2001 Asian Sea International Acoustic Experiment (ASIAEX) in the East China Sea. Reverberation intensities as a function of time and frequency are compared with theoretical predictions with reasonable agreement. The effects of the rough sea surface on the reverberation are also discussed. 相似文献
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1 Indroduction The coastal zone and continental shelf area is an important region in the global biogeochemical cycle of nutrients in the ocean. This portion of the global ocean interacts closely with the continents, atmosphere and the open ocean in a comp… 相似文献
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Atsuhiko Isobe 《Journal of Oceanography》1999,55(2):185-195
Using a temperature data set from 1961 to 1990, we estimated the monthly distribution of the vertically integrated heat content
in the East China Sea. We then drew the monthly map of the horizontal heat transport, which is obtained as the difference
between the vertically integrated heat content and the surface heat flux. We anticipate that its distribution pattern is determined
mainly due to the advection by the ocean current if it exists stably in the East China Sea. The monthly map of the horizontal
heat transport showed the existence of the Taiwan-Tsushima Warm Current System (TTWCS) at least from April to August. The
T-S (temperature-salinity) analysis along the path of TTWCS indicated that the TTWCS changes its T-S property as it flows
in the East China Sea forming the Tsushima Warm Current water. The end members of the Tsushima Warm Current water detected
in this study are water masses in the Taiwan Strait and the Kuroshio surface layer, the fresh water from the mainland of China,
and the southern tip of the Yellow Sea Cold Water extending in the northern part of the East China Sea.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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黄东海沉积物中的还原无机硫 总被引：2，自引：1，他引：1
Cold diffusion methods are used to separate and quantify the three reduced inorganic sulfur species into acid volatile sulfide(AVS), pyrite–S and element sulfur(ES) in the sediments of the Yellow and East China Seas. The results show that up to 25.02 μmol/g of AVS, 113.1 μmol/g of pyrite–S and 44.4 μmol/g of ES are observed in the sediments of the Yellow Sea and East China Sea. Pyrite–S is the predominant sulfide mineral in the sediments, while the concentration of AVS is quite low at most stations in the study area. The amounts and reactivity of organic matter are the primary limited factor for the sulfide formation, while an iron limitation and a sulfate limitation are not observed in the sediments of the Yellow Sea and East China Sea. The irregular profiles of the three reduced inorganic sulfur species also reflected the comprehensive influence of sediment composition and sedimentation rates. 相似文献
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Yanpei Zhuang Yangjie Li Xizhen Liu Shichao Tian Bin Wang Zhongqiang Ji Haiyan Jin Jianfang Chen 《海洋学报(英文版)》2023,42(1):103-108
Here, we report the results of high-resolution nitrate measurements using an optical nitrate profiler(in situ ultraviolet spectrophotometer, ISUS) along transect across a high-turbidity shelf(East China Sea) and a lowturbidity shelf(Chukchi Sea). The ISUS-measured nitrate concentrations closely reproduced the results measured by conventional bottle methods in low-turbidity waters. However, for high-turbidity waters of the East China Sea(salinity<30), a correction factor of 1.19 was required t... 相似文献