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1.
黄海、渤海沉积物中生物硅的测定及存在问题的讨论   总被引:16,自引:3,他引:16  
叶曦雯  刘素美  张经 《海洋学报》2002,24(1):129-134
硅是水生态系统中构成生物群落的重要元素[1].海洋中硅主要来源于河流输入(4.2±0.8)×1014g/a和热液喷发(1.9.77;10)×1014g/a[2].另外冰川风化、低温海底玄武岩风化、沉积物的成岩作用和大气沉降亦是其来源之一[3].沉积物中的生物硅又称生物蛋白石(简称蛋白石),指化学方法测定的无定形硅的含量,主要由硅藻、放射虫、硅鞭毛虫和海绵骨针组成.沉积物中蛋白石的积累反映了生产力在时间和空间尺度的变化[4,5].对于生物硅的测定,至今已提出了许多种方法.其中最灵敏、应用最广泛的是化学提取法[6,7].  相似文献   

2.
悬浮颗粒物中生物硅测定方法的改进与应用   总被引:1,自引:3,他引:1  
硅是河流和海洋中非常重要的营养盐,硅藻、放射虫、硅质海绵、硅鞭毛虫的生长和骨骼形成都离不开硅[1].硅在河流和沿岸海域生态系统中扮演着非常重要的角色,在浮游植物大量繁殖季节,由于硅藻的大量繁殖,使活性硅酸盐含量急剧下降,甚至使硅藻的生长繁殖受到限制.在其他环境条件适宜的情况下,充足的硅又将成为发生硅藻赤潮的物质基础[2].生物硅是用化学方法测定的无定形硅的含量[3],称为生物蛋白石或简称蛋白石,是地球化学、古海洋学研究中非常重要的参数[4].根据世界部分河流生物硅和溶解硅的平均值计算,河流输送入海的硅中有16%的是生物硅,因此河流输送的生物硅的量是全球海洋硅收支中不可忽略的部分[5].  相似文献   

3.
珠江中氮的迁移   总被引:1,自引:0,他引:1  
研究河流中氮的变化与迁移,主要意义是:(1)从环境化学的角度了解其分布规律和地球化学过程;(2)探讨河水中溶解状态的无机氮输入海洋后,作为重要营养盐的作用。另外,也为研究海洋中氮的变化及循环提供依据。 珠江是中国唯一的热带亚热带大河,其河水中氮的变化,过去没有进行测定,也未见文章报道。我们首次进行了氮的分析工作,研究了不同形态氮的相互作用与转化规律及其向海洋的输送量。同时还对珠江与世界河流中氮的平均含量进行了比较。  相似文献   

4.
向海湿地沉积剖面化学元素相对迁移特征分析   总被引:4,自引:0,他引:4  
旨于探索沉积剖面元素迁移强度的描述方法,讨论向海沼泽湿地沉积物化学元素的迁移积聚等基本地球化学特征,以深化对沼泽湿地沉积化学行为的某些认识。冬季在向海两处沼泽采集了代表一定范围汇水区与人类活动影响的沉积芯。利用Tessier等(1979)提出的连续提取法对沉积物中多种常量与微量元素地球化学相进行分离。可迁移系数、潜在迁移系数、非迁移系数的计算结果表明,在向海沼泽沉积剖面中,化学元素相对迁移强度为:Ca、Sr、Mn、Pb潜在活性最大,Ti、Al、K、Rb潜在活性最小,以此为依据,Ti、Al、K、Rb等元素适宜作为示踪元素。为消除沉积物构成组织的影响,以Al为参考元素对重金属元素形态两种分量进行归一化后,重金属环境非迁移分量与相对迁移分量均表现出在表层的富集,尤其表现在上游霍林河煤矿开发后20余年这一时期,人类活动的介入加速了重金属元素通过河流搬运向下游湿地的输入。  相似文献   

5.
浮泥层测量及其应用   总被引:1,自引:1,他引:0  
我国地势呈西北高东南低走势,发源于内陆高原的大河以及众多的中、小河流均沿着由西北向东南的倾斜面,向东、向南汇流入海。这些河流每年在向海洋输送大量淡水的同时,也向海洋输送了数量可观的有机营养、溶解的矿  相似文献   

6.
本文将碳同位素比值用于研究亚马孙河及其主要支流中颗粒有机碳(POC)的来源,同时也探讨了河流POC向海洋环境的输送,在亚马孙河上游POC的碳同位索值δ13C(-24.5——28.0‰)较之在其中下游的相应值(-27.9——30.1‰)要重一些一般来说,其支流POC的同位素组成要比在亚马孙河主航道中测得的值要轻一些由碳同位素数据证明,亚马孙河主航道中POC的主要来源是陆地物质,而不是河生生物,在亚马孙河口区和淡水舌中观测到POC的同位素组成有很大的变化范围(-17.5——28.4‰),这被认为是河流的POC与海洋的POC在该区域中混合作用的结果.由同位素数据可计算出河流有机碎屑沿平行于河流航道方向向海可搬运至距河口290km处,而沿亚马孙河淡水舌方向在河口西北方向1100km处仍可看到河流POC的稳定同位素信号.  相似文献   

7.
长江口稀土元素地球化学特征   总被引:8,自引:0,他引:8  
河口地区是陆海相互作用最具特色的典型区域,这里陆地与海洋之间的物质和能量交换迅速,物理、化学和生物学过程之间的相互作用极其复杂,对河流迁移的化学信号起着过滤器的作用[1].利用稀土元素(REEs)化学性质相似而又有系统差别的特点可以进行河口区河海相互作用过程的地球化学研究[2].准确测定河口区溶解态、胶体态、悬浮颗粒态、沉积物态以及生物体中REEs是研究河海相互作用的关键.随着现代仪器分析技术的发展,准确测定河海相互作用过程中不同相态尤其是水体溶解态超痕量稀土元素含量成为可能[3~7],从而使稀土元素地球化学,尤其是河口稀土元素地球化学的研究得以深入[8~16].  相似文献   

8.
潮滩是联系陆地生态系统和海洋生态系统的交互过渡带,与陆地湖泊、河流和深海系统相比有其特殊性和复杂性.在潮汐作用下由于潮滩受潮水周期性浸没和暴露的影响,使得潮滩界面成为一个典型的沉积物-水-气周期性交互作用界面.潮水的周期性涨退将诱使潮滩沉积物中发生一系列的物理、化学和生物变化[1].在暴露期间,因蒸发作用潮滩沉积物可能会发生失水现象,并引起沉积物孔隙水发生迁移和水溶性物质扩散梯度发生变化[2,3].在暴露失水过程中,空气也可能会占据沉积物间隙,并引起潮滩沉积物物理结构发生变化,加剧了沉积物-气界面之间需氧过程的发生[4,5].  相似文献   

9.
朱赖民  李犇 《海洋学报》2008,30(3):148-152
活性磷(正磷酸盐)是海洋浮游植物生长所必需的物质基础[1-8],磷的生物可利用性直接影响全球的初级生产力水平.磷在特定的海洋环境中还可能限制固氮作用,成为限制海洋初级生产力的重要因素[1,3,6].海水中磷酸盐含量的测定也是海洋污染调查的重要指标之一[4,9].农业和工业废水中磷的过度排放导致河口和近岸海水富营养化,引起浮游植物异常繁殖,造成“赤潮”现象[4].因此,海水中磷的准确测定对深入理解生物地球化学过程及海洋环境保护具有重要理论和实际意义[4-6,9].磷钼蓝分光光度法是海水中活性磷的经典测定方法,检测限为324 nmo1/dm3[5],但在一些寡营养盐海域,例如在南海、地中海  相似文献   

10.
海水化学模型或海水中元素溶存形式的研究在海洋化学上具有特殊的重要性,它不仅是研究海洋中元素分布、迁移和变化规律等等“元素海洋地球化学”的基础,而且也是研究海洋污染和防污、海水化学资源开发等的基础之一.迄今文献报道研究海水化学模型的方法均属化学平衡法[1-7].  相似文献   

11.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

12.
Specific properties of the interannual sea level variations and annual tides in the Northwestern Pacific were studied. Several tide stations were monitored. The monthly mean sea level for the year of 1995 was analyzed at each tide station. A seismic event in 1995, some tectonic activity around the subject area, and the Kuroshio (the oceanic western boundary current) may possibly contaminate results which would have occurred from the astronomical annual tide alone.  相似文献   

13.
The effect of different fixation and storage protocols on the flow cytometric (FCM) simultaneous analysis of bacterioplankton and phytoplankton in coastal seawater samples (Mediterranean coastal lagoons) was investigated. FCM measurements (cell number, fluorescence and scatter characteristics) were obtained through DAPI staining. Three fixatives [glutaraldehyde (GA), formaldehyde (FA) and paraformaldehyde (PFA)] and two storage (3 months duration) methods (5 °C and −196 °C) were tested. Two dominant populations were detected in studied samples: bacteria and eukaryotic picophytoplankton. Adding fixatives (2% final concentration) appears necessary to obtain FCM exhaustive counts of all the bacteria and phytoplanktonic cells. This was related to the permeation effect of fixatives which allowed a better DAPI staining of the cells. Maximum fluorescence, i.e. optimal staining of the cells was obtained with FA or PFA, and significant lower fluorescences with GA. Fixed samples stored at 5 °C induced rapid cell loss. Only storage in liquid nitrogen of samples fixed with FA or PFA, allows mid-term (≥4 months) preservation of bacteria or picophytoplankton cell numbers, and limited evolution of DAPI-induced fluorescence and scatter characteristics.  相似文献   

14.
Coastal inundation associated with extreme sea levels is the main factor which leads to the loss of life and property whenever a severe tropical cyclonic storm hits the Indian coasts. The Andhra and Orissa coasts are most vulnerable for coastal inundation due to extreme rise in sea levels associated with tropical cyclones. Loss of life may be minimized if extreme sea levels and associated coastal flooding is predicted well in advance. Keeping this in view, location specific coastal inundation models are developed and applied for the Andhra and Orissa coasts of India. Several numerical experiments are carried out using the data of past severe cyclones that struck these regions. The simulated inland inundation distances are found to be in general agreement with the reported flooding.  相似文献   

15.
16.
《海洋学报(英文版)》2014,(9):F0003-F0003
<正>Acta Oceanologica Sinica(AOS)is a comprehensive academic journal edited by the Editorial Committee of Acta Oceanologica Sinica and is designed to provide a forum for important research papers of the marine scientific community which reflect the information on a worldwide basis.The journal publishes scholarly papers on marine science and technology,including physics,chemistry,biology,  相似文献   

17.
Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2-25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   

18.
This article concerns an interrelation between the sea levels and the western boundary flow near a tectonic boundary in a local zone in the Northwestern Pacific. In this zone, sea level variations at stations located on the coast facing the Pacific are studied to find the interrelation between variations of the Kurosio flow as an index of the distance of the flow axis off a specific coast. The result is discussed after data processing of the monthly means of the sea levels, and a notice is taken of variations caused by active crustal upheavals during a seismic event, a local earthquake.  相似文献   

19.
This study tests the hypothesis that the in situ void ratio of surficial marine sediments may be predicted from shear wave velocity-depth data with a reliability equal to that of other methods currently available. Shear wave velocity is fundamentally controlled by the number of grain-to-grain contacts per unit volume of material and by the effective stress across those contacts. In this study, three previously established empirical formulae are used to predict void ratio from velocity-depth data. Field data were acquired along a transect off the northern Californian coast across which water depth increased from 35 to 70 m and seafloor sediment type varied from sand to silty-sand, respectively. A towed seafloor sled device was used to collect shear wave refraction data, and a marked, systematic decrease in velocity was observed along the line, ranging from 35-70 m/s for the coarse, near-shore material to 25-40 m/s for the finer, offshore deposits. Void ratios predicted from these velocities were compared with data measured directly from box-core samples. Of the formulae used for prediction, two agree remarkably well with the control data. Both predicted and control values increase from 0.6-0.8 for the sandy material to 1.1-1.5 for the silty-sand. Thus, this study does not disprove the hypothesis set and demonstrates the potential of field shear wave velocity-depth data as a means of delineating spatial variation in void ratio for surficial marine sediments in a remote, nondestructive manner.  相似文献   

20.
Particulate samples were collected from the Changjiang river system during a flood period, in May 1997, and POC, stable isotope and lipids associated with particles were examined. Results showed the decrease (0.84% ~ 1.88%) of organic carbon content from the upper reaches to the estuary.δ13C values of particulate organic carbon was in the range of -24.9×10-3 to -26.6×10-3, which were close to the isotopic signature of continental C3 vegetation. Total particulate n-alkanes concentrations varied from 1.4 to 10.1μg/dm3,or from 23.7 to 107μg/g of total suspended matter. Fatty acids were present in all the samples, from 1.4 to 5.4μg/dm3, with saturated and unsaturated straight-chain and branched compounds in the carbon number range from C12 to C30. Both δ13C and the ratio of carbon content to nitrogen content indicate the predominance of terrestrial inputs (soil organic matter) among the particles. The biomarker approach has been used to identify the relative portion of terrigenous and autochthonous fraction in the particulate samples. The distribution of fatty acids suggests a striking phytoplanktonic and microbial signal in most particle samples. The terrestrial alkanes are used to estimate the contribution of terrestrial inputs along the mainstream.  相似文献   

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