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1.
针对海洋环境条件,重点研究了粉煤灰混凝土的抗冻性和氯离子渗透性能的相互关系.试验分别研究了水胶比、粉煤灰等量取代水泥掺量大小、引气剂掺量等因素对抗冻性和抗氯离子渗透性能的影响,并与普通混凝土进行了对比.结果表明,粉煤灰不增加混凝土的抗海水冻融耐久性;粉煤灰增加混凝土的抗氯离子渗透性能,但是掺量超过30%,抗氯离子渗透性能下降;粉煤灰对混凝土抗冻性和抗氯离子渗透性的耦合影响在30%左右存在一个最佳掺量.为评估混凝土的抗冻性和氯离子扩散性的耦合性能,提出了新的评价方法--冻渗比(R值方法),并进行了试验验证.SEM和MIP微观分析与R值方法评价的结果是吻合的.  相似文献   

2.
海洋潮汐浪溅区混凝土表面氯离子浓度计算模型   总被引:2,自引:0,他引:2  
蔡荣  杨绿峰  余波 《海洋工程》2014,32(5):25-33
海洋混凝土结构的表面氯离子浓度反映了海洋氯化物环境的腐蚀作用强度,是海洋混凝土结构耐久性分析和定量设计的重要参数。本文依据国内外不同地区的大量自然暴露试验数据,通过数理统计和回归分析,确定了各种海洋环境条件下表面氯离子浓度的统计特征值,分析了海洋潮汐浪溅区混凝土中氯离子的传输机理和积聚规律,揭示了水胶比对混凝土表面氯离子浓度的影响规律,进而综合考虑水胶比、胶凝材料种类和时变特性等因素的影响,建立了海洋潮汐浪溅区混凝土表面氯离子浓度的改进计算模型。结合国内外各种表面氯离子浓度经验模型的预测结果和海洋自然暴露试验的实测数据,对比验证了所建立表面氯离子浓度计算模型的有效性和适用性,为海洋氯化物环境下混凝土结构的耐久性设计和服役寿命分析提供了重要边界条件。  相似文献   

3.
对服役12年的华南某跨海大桥典型构件开展碳化性能、氯离子扩散性能等指标的耐久性检测,评估了海水环境下掺粉煤灰的高性能混凝土长期耐久性。研究表明:随高程的增加混凝土碳化深度逐渐增大,其中大气区浪溅区水位变动区,碳化作用对粉煤灰混凝土结构耐久性的影响较小;粉煤灰可显著提升实体结构混凝土抗氯离子侵蚀性能,粉煤灰高性能混凝土的氯离子扩散系数不大于0.40×10-12m2/s,比普通混凝土氯离子扩散系数降低了约6倍;利用规范计算了引桥承台混凝土中氯离子含量计算值,其计算值与实测值吻合较好,可用于实体工程混凝土结构的耐久性评估,评估结果显示采用粉煤灰高性能的桥梁典型构件满足100年设计使用寿命的要求。  相似文献   

4.
海洋潮汐环境下混凝土硫酸盐侵蚀机理研究   总被引:2,自引:0,他引:2  
研究海洋潮汐区侵蚀环境下混凝土中硫酸盐侵蚀机理,对不同配合比混凝土试件在海洋潮汐环境下进行现场暴露试验。同时利用分光光度计法测定不同侵蚀龄期及不同配合比混凝土中硫酸根离子质量分数。试验结果表明:早期海洋暴露环境下,混凝土中总硫酸根离子质量分数随着腐蚀龄期的增加而显著升高,但随着时间增加幅度逐渐降低;混凝土中总硫酸根离子质量分数因水胶比、水泥用量不同而不同;一定比例的矿物掺合料可以有效提高混凝土抗硫酸盐侵蚀性能。  相似文献   

5.
标准养护和夏季自然养护的内养护混凝土在盐渍土环境中腐蚀不同龄期,测试其抗压强度及氯离子渗透性能。结果表明:无论标准养护还是自然养护,高吸水树脂的掺加均降低了混凝土早期强度,但当高吸水树脂掺量为1kg/m3时可提高混凝土后期强度,且提升幅度对低水胶比混凝土更明显。在盐渍土腐蚀环境中,普通混凝土强度先上升后下降,而内养护混凝土强度先下降后上升。高吸水树脂能够延缓混凝土抗压强度下降的速率,提升混凝土抗氯离子渗透能力。  相似文献   

6.
有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。  相似文献   

7.
人工鱼礁在自然海水条件下的腐蚀寿命研究   总被引:1,自引:0,他引:1  
有氯盐侵蚀的钢筋腐蚀,是钢筋混凝土结构性能劣化的主要原因之一,混凝土构件使用寿命的关键是氯离子的传输速率和使钢筋产生锈蚀的时间。本文以人工鱼礁混凝土构件为研究对象,分析海水氯离子在C30、C35和钢渣复合材料人工鱼礁混凝土中的扩散系数,以混凝土中钢筋锈蚀的临界氯离子浓度为寿命预测的边界条件,利用氯离子扩散模型预测C30、C35和钢渣复合材料人工鱼礁在海水中的腐蚀寿命。研究结果表明,氯离子在混凝土人工鱼礁中的扩散规律基本满足Fick第二定律。通过模型计算得出C30、C35和钢渣复合材料混凝土人工鱼礁的腐蚀寿命分别为51.6,54.8和56.8年。  相似文献   

8.
海洋大气及污染海洋大气对典型钢腐蚀的影响   总被引:6,自引:0,他引:6  
对典型钢(碳钢Q235和耐候钢09CuPCrNi)在海洋大气(麦岛)和污染海洋大气(团岛)环境中进行了2年的暴露腐蚀实验,并测试了其环境的大气污染因子。结果显示典型钢在团岛的腐蚀明显地比麦岛重,团岛的氯离子浓度几乎是麦岛氯离子浓度的3倍。讨论了海洋大气和污染海洋大气对典型钢的腐蚀作用的差异。  相似文献   

9.
钢筋混凝土耐久性海洋暴露试验   总被引:4,自引:0,他引:4  
对不同技术条件的钢筋混凝土试件进行长期的海洋暴露腐蚀试验,以了解其服役特性,为钢筋混凝土结构的耐久性设计提供依据。近7年的暴露结果表明:在混凝土中掺加高炉矿渣等活性掺合料,能大大降低氯离子渗透速率,提高钢筋混凝土的耐久性。  相似文献   

10.
表面氯离子含量(C_s)是研究海洋环境条件下混凝土结构耐久性和服役寿命的氯离子扩散方程的边界条件,是海洋混凝土结构耐久性分析和定量设计的重要参数。依据国内外大量自然暴露试验与工程实测数据,通过采用Excel、Origin等数据分析软件进行数据统计和回归分析,确定了海洋混凝土结构表面自由氯离子含量(C_(sf))与表面总氯离子含量(C_(st))之间的相互关系,探讨了海洋混凝土结构的C_(sf)时变规律,建立了C_(sf)与暴露时间之间的关系表达式及其取值范围,并运用可靠度理论和修正氯离子扩散理论分析了C_(sf)时变性对海洋混凝土结构寿命的影响。结果表明:C_(sf)与C_(st)线性相关,且C_(sf)随着暴露时间的延长呈指数或者幂函数的增长关系;采用不同的C_(sf)时变性规律,对海洋混凝土结构寿命具有重大的影响。  相似文献   

11.
The interdependence between the seismo-acoustic properties of a marine sediment and its geotechnical/physical parameters has been known for many years, and it has been postulated that this should allow the extraction of geotechnical information from seismic data. Though in the literature many correlations have been published for the surficial layer, there is a lack of information for greater sediment depths. In this article, a desktop study on a synthetic seafloor model illustrates how the application of published near-surface prediction equations to subsurface sediments (up to several tens of meters burial depth) can lead to spurious predictions. To test this further, acoustic and geotechnical properties were measured on a number of sediment core samples, some of which were subjected to loading in acoustically-equipped consolidation cells (oedometers) to simulate greater burial depth conditions. For low effective pressures (representing small burial depths extending to around 10 meters subsurface), the general applicability of established relationships was confirmed: the prediction of porosity, bulk density, and mean grain size from acoustic velocity and impedance appears generally possible for the investigated sedimentary environments. As effective pressure increases through, the observed relationships deviate more and more from the established ones for the near-surface area. For the samples tested in this study, in some instances increasing pressure even resulted in decreasing velocities. There are several possible explanations for this abnormal behavior, including the presence of gas, overconsolidation, or bimodal grain size distribution. The results indicate that an appropriate depth correction must be introduced into the published prediction equations in order to obtain reliable estimates of physical sediment properties for greater subsurface depths.  相似文献   

12.
Specific properties of the interannual sea level variations and annual tides in the Northwestern Pacific were studied. Several tide stations were monitored. The monthly mean sea level for the year of 1995 was analyzed at each tide station. A seismic event in 1995, some tectonic activity around the subject area, and the Kuroshio (the oceanic western boundary current) may possibly contaminate results which would have occurred from the astronomical annual tide alone.  相似文献   

13.
The effect of different fixation and storage protocols on the flow cytometric (FCM) simultaneous analysis of bacterioplankton and phytoplankton in coastal seawater samples (Mediterranean coastal lagoons) was investigated. FCM measurements (cell number, fluorescence and scatter characteristics) were obtained through DAPI staining. Three fixatives [glutaraldehyde (GA), formaldehyde (FA) and paraformaldehyde (PFA)] and two storage (3 months duration) methods (5 °C and −196 °C) were tested. Two dominant populations were detected in studied samples: bacteria and eukaryotic picophytoplankton. Adding fixatives (2% final concentration) appears necessary to obtain FCM exhaustive counts of all the bacteria and phytoplanktonic cells. This was related to the permeation effect of fixatives which allowed a better DAPI staining of the cells. Maximum fluorescence, i.e. optimal staining of the cells was obtained with FA or PFA, and significant lower fluorescences with GA. Fixed samples stored at 5 °C induced rapid cell loss. Only storage in liquid nitrogen of samples fixed with FA or PFA, allows mid-term (≥4 months) preservation of bacteria or picophytoplankton cell numbers, and limited evolution of DAPI-induced fluorescence and scatter characteristics.  相似文献   

14.
Coastal inundation associated with extreme sea levels is the main factor which leads to the loss of life and property whenever a severe tropical cyclonic storm hits the Indian coasts. The Andhra and Orissa coasts are most vulnerable for coastal inundation due to extreme rise in sea levels associated with tropical cyclones. Loss of life may be minimized if extreme sea levels and associated coastal flooding is predicted well in advance. Keeping this in view, location specific coastal inundation models are developed and applied for the Andhra and Orissa coasts of India. Several numerical experiments are carried out using the data of past severe cyclones that struck these regions. The simulated inland inundation distances are found to be in general agreement with the reported flooding.  相似文献   

15.
16.
《海洋学报(英文版)》2014,(9):F0003-F0003
<正>Acta Oceanologica Sinica(AOS)is a comprehensive academic journal edited by the Editorial Committee of Acta Oceanologica Sinica and is designed to provide a forum for important research papers of the marine scientific community which reflect the information on a worldwide basis.The journal publishes scholarly papers on marine science and technology,including physics,chemistry,biology,  相似文献   

17.
Grain size and water content in box-core sediments from the Clarion-Clipperton fracture zone (C-C zone) in the northeast equatorial Pacific were analyzed in detail to understand the downcore variations across a hiatus between Quaternary and Tertiary layers. Grain-size distributions in the topmost core sediments show two modes: a coarse mode (peaked at 50 μm) and a fine mode (at 2-25 μm). The coarse mode disappears gradually with depth accompanied by the dissolution of siliceous fossil tests, whereas the fine mode coarsens due to the formation of authigenic minerals. Water content increases abruptly across a color boundary between an upper pale brown layer and a lower dark brown layer that is the hiatus between Quaternary and Tertiary layers. Abundant smectites and microvoid molds, which are created by the prolonged fossil dissolution in the underlying sediment, are attributed for the abrupt downcore variation of water content. Overall variations in grain size and water content in the topmost core sediments in the western C-C zone are possibly constrained by the dissolution of biogenic siliceous fossils. Variations in geotechnical properties related to these changes must be considered in the design of nodule collectors.  相似文献   

18.
This article concerns an interrelation between the sea levels and the western boundary flow near a tectonic boundary in a local zone in the Northwestern Pacific. In this zone, sea level variations at stations located on the coast facing the Pacific are studied to find the interrelation between variations of the Kurosio flow as an index of the distance of the flow axis off a specific coast. The result is discussed after data processing of the monthly means of the sea levels, and a notice is taken of variations caused by active crustal upheavals during a seismic event, a local earthquake.  相似文献   

19.
This study tests the hypothesis that the in situ void ratio of surficial marine sediments may be predicted from shear wave velocity-depth data with a reliability equal to that of other methods currently available. Shear wave velocity is fundamentally controlled by the number of grain-to-grain contacts per unit volume of material and by the effective stress across those contacts. In this study, three previously established empirical formulae are used to predict void ratio from velocity-depth data. Field data were acquired along a transect off the northern Californian coast across which water depth increased from 35 to 70 m and seafloor sediment type varied from sand to silty-sand, respectively. A towed seafloor sled device was used to collect shear wave refraction data, and a marked, systematic decrease in velocity was observed along the line, ranging from 35-70 m/s for the coarse, near-shore material to 25-40 m/s for the finer, offshore deposits. Void ratios predicted from these velocities were compared with data measured directly from box-core samples. Of the formulae used for prediction, two agree remarkably well with the control data. Both predicted and control values increase from 0.6-0.8 for the sandy material to 1.1-1.5 for the silty-sand. Thus, this study does not disprove the hypothesis set and demonstrates the potential of field shear wave velocity-depth data as a means of delineating spatial variation in void ratio for surficial marine sediments in a remote, nondestructive manner.  相似文献   

20.
Particulate samples were collected from the Changjiang river system during a flood period, in May 1997, and POC, stable isotope and lipids associated with particles were examined. Results showed the decrease (0.84% ~ 1.88%) of organic carbon content from the upper reaches to the estuary.δ13C values of particulate organic carbon was in the range of -24.9×10-3 to -26.6×10-3, which were close to the isotopic signature of continental C3 vegetation. Total particulate n-alkanes concentrations varied from 1.4 to 10.1μg/dm3,or from 23.7 to 107μg/g of total suspended matter. Fatty acids were present in all the samples, from 1.4 to 5.4μg/dm3, with saturated and unsaturated straight-chain and branched compounds in the carbon number range from C12 to C30. Both δ13C and the ratio of carbon content to nitrogen content indicate the predominance of terrestrial inputs (soil organic matter) among the particles. The biomarker approach has been used to identify the relative portion of terrigenous and autochthonous fraction in the particulate samples. The distribution of fatty acids suggests a striking phytoplanktonic and microbial signal in most particle samples. The terrestrial alkanes are used to estimate the contribution of terrestrial inputs along the mainstream.  相似文献   

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