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1.
黄河三角洲贝壳堤的锶同位素特征 总被引：5，自引：0，他引：5
依据黄河三角洲王子岛海滩潮间带活贝壳、王子岛第 1道贝壳堤和邢家山子第 2道贝壳堤中贝壳样品的锶同位素记录 ,初步探讨渤海湾南部最近 60 0 0多年来海水锶同位素变化特征及其环境意义 ,发现 :①黄河三角洲贝壳堤的贝壳87Sr/ 86Sr变化较大 ,其范围在 0 70 92 1 5± 1 2～0 70 9489± 1 5之间 ,平均值 0 70 93 60 ;Δ87Sr范围在 0 0 2 1‰～ 0 40 8‰之间 ,平均 0 2 2 6‰ ,明显高于现在大洋海水的值。②渤海湾南部 1 5～ 2 0kaBP海水锶同位素87Sr/ 86Sr较目前的低 ,陆源物对渤海湾的输入较目前弱 ,而开阔海域海水对渤海湾的影响较目前强 ;4 5～ 6 0kaBP海水锶同位素87Sr/ 86Sr较 1 5～ 2 0kaBP的低 ,陆源物对渤海湾的输入比 1 5～ 2 0kaBP的还弱 ,而开阔海域海水对渤海湾的影响比 1 5～ 2 0kaBP的还强。③贝壳锶同位素记录了 4次陆源物对渤海湾的强输入事件和两次海退事件。 相似文献
2.
利用等离子体质谱仪(ICP-MS)和多接收同位素质谱仪(HR-MC-ICP-MS)等技术,对黄河入海口湿地区3个典型区(湿地保护区、采油区和河道)表层沉积物进行了系统的重金属微量元素和Pb同位素分析。结果表明,湿地保护区、采油区和黄河河道三个子区域表层沉积物重金属含量依次降低,受粒度控制明显,且符合第一类沉积物质量标准,处于较清洁水平。Pb同位素数据表明,黄河入海口湿地保护区表层沉积物样品207 Pb/206 Pb和208 Pb/206 Pb比值(0.839,2.090)与已发表文献的中国黄土207Pb/206Pb和208 Pb/206 Pb比值(0.841,2.083)接近,表明黄河湿地保护区内表层沉积物中的重金属Pb的主要来源为黄河自然源(黄土)。采油区及河道样品207 Pb/206 Pb,208 Pb/206 Pb比值(0.848,2.100;0.849,2.105)均高于湿地保护区样品,介于黄河悬浮体(0.865,2.131)及中国黄土之间,表明采油区和河道表层沉积中的Pb主要来源于自然源和人类生产活动。 相似文献
3.
本研究对渤海中部表层和柱状沉积物中Pb的含量和同位素进行了分析,研究了其时空分布规律,并探讨了其物质来源。结果表明,表层沉积物中Pb的含量为14.54×10-6~59.42×10-6,其含量在渤海湾近岸、黄河口附近、研究区的东北部较高,而在研究区的中部和渤海湾北部含量较低;Pb同位素207Pb/206Pb的值为0.8341~0.8489,208Pb/206Pb的值为2.0828~2.0980。岩心沉积物中Pb含量、同位素组成与表层沉积物相似,整体上较为稳定,但在1990s以来呈现增大的趋势。渤海中部沉积物中Pb以自然来源为主,黄河沉积物是其主要物质来源,但渤海湾北端则与滦河源物质或沿岸侵蚀相关;人类活动影响主要出现在1990s以后,与中国含Pb矿石的燃烧等工业活动相关,但影响微弱,仅在黄河口西北近岸海域、渤海湾等个别站位得到体现。 相似文献
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FuYongtao LiAnehun 《海洋通报(英文版)》2003,5(2):29-39
The major elements, trace elements, K-Ar age and Sr-Nd-Pb isotopic systems of the Cenozoic volcanic rocks in Daheishan Island and Cishan, Penglai, Shandong Province are measured. The volcanic rocks ( olivine-nephelinite and nepheline-basanite ) in DaheishanIsland erupted periodically in an interval of 0.32 Ma, from 8.72 Mm 8.39 Ma, 8.08 Ma to 7.73Ma. The volcanic rocks are all rich in light REEs. They are similar to the OIB-type alkali basalt in the trace elements normalized model by primordial mantle: rich in high field elements such as Nb and Ta, and imcompatible elements such as Cs, Rb, Ba, Th, U. The volcanic rocks show a depletion of K and Rb elements. It is suggested by the trace elements that the olivine-nephelinite in Daheishan Island is originated fi‘om deep resources under the continental mantle, ε Nd (0) values of the volcanic rocks in Daheishan Island and Cishan are 5.31 - 8.51 and 7.33 respectively, suggesting that the volcanic rocks are from the depleted mantle resources, which have higher Sm/Nd ratios than the CHUR. ^143Nd /^144Nd ratios of Daheishan Island olivine-nephelinite and Cishan alkali basalts are 0.512 910 - 0.513 074 and 0.513 014 resoeetivelv. The ^87Sr /^86Sr of Daheishan lsland volcanic rocks are lower than that of Cishan, 0.703 427 - 0.703 482 and 0.703 895 respectively. The Daheishan Island olivinenephelinite has the Pb isotopic values as follows: ^206Pb /^204pb= 18.028 9 ～17.972 8,^207Pb /^204Pb= 15,435 8 - 15.402 2 and ^208Pb /^204Pb=38.087 6 - 37.997 5, lower than those of Cishan basanite. The Cishan basanite has ^206Pb / ^204Pb = 18.240 1, ^208Pb /^204Pb = 15.564 5 and ^208Pb /^204Pb=38.535. The authors suggest that the olivine-nephelinite in Daheishan Island is similar to the E-type MORB or Hawaii OIB, and the alkali basalts in Cishan similar to the Kerguelen OIB. The dominant mantle components of DM PREMA and perhaps DM( Dupal type ) are the dominant mantle components for volcanic rocks in Daheishan Island and Cishan. The PREMA component plays an important role. 相似文献
5.
对1999年9～10月采自北太平洋亚热带环流区的19份表层海水样品的Ra同位素分析表明。研究海域表层水中的^226Ra、^228Ra放射性比度分别介于0．67～0．92、0．08～0．30Bq／m^3之间，平均值分别为0．74、0．11Bq/m^3．^226Ra/^228Ra)A．R．活度比的变化范围为0．11～0．44，平均值为0．19．上述数值明显低于近岸海域水体的相应值，表现为典型的开阔大洋水的特征．从空间分布的特征看，研究海域Ra同位素含量与^226Ra/^228Ra)A.R.值均呈均匀分布态势．将本研究结果与历史数据进行对比后发现，本研究获得的^226Ra、^228Ra放射性比度比20世纪60～80年代得到的数据来得低，可能与水体层化作用加强导致的Ra补充量的减少以及生物生产力升高导致的Ra迁出量的增加有关．北太平洋亚热带环流区表层水中Ra同位素的时间变化与文献报道的该海域叶绿素a、硅酸盐、磷酸盐含量与初级生产力的历史变化趋势相吻合． 相似文献
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通过对东海周边9条中小型河流沉积物进行锶钕铅(Sr-Nd-Pb)同位素测试,分析了其组成特征及其物源指示意义。结果表明,~(87)Sr/~(86)Sr、~(143)Nd/~(144)Nd、~(206)Pb/~(204)Pb平均值分别为0.719 056、0.512 056和18.614 94。Sr-Nd-Pb同位素组成主要受地质背景和风化作用的制约,空间变化规律明显,可作为区分不同来源河流沉积物的有效指标。统计结果确立出三个端元值,分别为台湾岛东部河流(~(87)Sr/~(86)Sr-0.713 355,ε_(Nd)--8.488)、台湾西部河流(~(87)Sr/~(86)Sr-0.718 804,ε_(Nd)--12.375 7)和大陆东南部河流(~(87)Sr/~(86)Sr-0.722 195,ε_(Nd)--11.944 4)。确立这些端元可为认识中国东部陆架区沉积物"源-汇"过程及陆海相互作用提供科学依据。 相似文献
8.
南海海盆15°N附近呈东西向展布的珍贝-黄岩海山被认为是32~17Ma前南海海盆的残留扩张中心.对采自黄岩海山的两个火山岩样品(9DG,9DG-2)进行了岩石学、地球化学和年代学研究.两个样品的SiO2含量分别为60.3%和63.6%,Al2O3含量分别为17.56%和17.55%,TiO2含量分别为0.48%和0.31%,碱度率分别为3.88和3.62.根据岩石学和岩石化学分类,样品属碱性系列的粗面岩.对稀土元素和微量元素分析表明岩石具有洋岛玄武岩(OIB)型配分型式,轻重稀土总量比(∑c(LREE)/∑c(HREE))和球粒陨石标准化镧镱比((La/Yb)N)分别高达17.22和27.23,并具有铕负异常和锶、磷、钛亏损的特点.样品9DG的锶-钕-铅同位素分析结果为锶-87的含量与锶-86的含量之比值为0.704183,钕-143的含量与钕-144的含量之比值为0.512827,铅-206的含量与铅-207的含量之比值为18.68668,铅-207的含量与铅-204的含量之值为15.67962,铅-208的含量与铅-204的含量之比值为39.00261,表明初始岩浆来自软流圈地幔,具有与珍贝海山玄武岩相似的同位素组成.经钾-氩法测年,粗面岩的年龄为(7.77±0.49)Ma,略晚于珍贝海山玄武岩的年龄[(9.1±1.29)~10.0±1.80Ma],属于南海扩张期后晚中新世火山活动的产物.对比珍贝海山玄武岩的地球化学和同位素特征,认为两者有相同的岩浆源区,但是它们经历了不同程度的结晶分异过程,在晚中新世期间珍贝-黄岩海山可能有地幔柱活动. 相似文献
9.
应用浮游有孔虫定量统计、底栖有孔虫氧同位素和磁性地层学等资料来确定南海ODP1148站深海沉积中的上新统／更新统(P／P)界线。氧同位素期(MIS)64和65之间的P／P界线在1148站位于井深112．75m处，计算年龄为1．805Ma，在地层对比上与Vrica层型剖面的P／P界线一致。浮游有孔虫Pulleniatina obliquiloculata在MIS62出现以右旋壳为主的转变，计算年龄为1．76Ma，此事件和Olduvai极性亚时顶界看来是最接近P／P界线的可靠时间面。除此以外，在1148站P／P界线及其附近没有发现重大的地层学和环境变化事件。相比之下，1148站底栖δ^18O值在3．05～2．53Ma期间快速变重，冬季表层海水温度下降了5℃，指示了北半球冰盖的形成。 相似文献
10.
对南海南部ODP1143站氧同位素11-5e期大约2ka分辨率的粉红色Globigerinoides ruber进行分析,发现其冰期／间冰期旋回与代表全球冰量的底栖有孔虫氧同位素(δ^18O)的变化相反,即在间冰期时含量低,而冰期时高,与其他海区的记录相反。海水表层温度和温跃层深度转换函数结果以及碎壳率的变化显示,在一定的温度背景下,温跃层深度的变化可能是控制粉红色G．ruber冰期旋回的主要因素,而这段时期南海南部溶解作用的影响则不明显。 相似文献
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Si-Fe-Mn-oxyhydroxides dredged at the PACMANUS(Papua New Guinea–Australia–Canada–Manus)hydrothermal field, Eastern Manus Basin, have 87Sr/86Sr=0.708 079–0.708 581; εNd=5.149 833–6.534 826;208Pb/204Pb=38.245–38.440; 207Pb/204Pb=15.503–15.560; 206Pb/204Pb=18.682–18.783. 87Sr/86 Sr isotope ratios are relatively homogeneous and close to the value of the surrounding seawater(0.709 16). The content of Sr in the samples contributed by seawater was estimated to be 76.7%–83.1% of total amount. The mixing temperature of hydrothermal fluids and seawater were ranging from 53.2°C to 72.2°C and the hydrothermal activities were unstable when the samples precipitated. The εNd values of all the samples are positive, which differ from the values of ferromanganese nodules(crusts) with hydrogenic origin. Nd was mainly derived from substrate rocks leached by hydrothermal circulation and preserved the hydrothermal signature. Pb isotopic compositions of most samples show minor variability except Sample #9–2 that has relatively high values of Pb isotopes. The Pb may be derived from the Eastern Manus Basin rocks leached by the hydrothermal fluid. The slightly lower 208Pb/204 Pb and207Pb/204 Pb values of the samples indicated that the hydrothermal circulation in PACMANUS was not entire and sufficient, or that hydrothermal circulation had transient changes in the past. Si-Fe-Mn-oxyhydroxides in the samples preserved the heterogeneities of local rocks. 相似文献
12.
大西洋洋中脊海底表层热液沉积物的铅同位素组成及其地质意义 总被引：5，自引：0，他引：5
新测得 TAG热液区中 6件海底表层热液沉积物样品的铅同位素组成 ,其变化范围不大 ,具有均一性的特征。在 Pb- Pb图解上 ,热液沉积物的铅同位素数据大多落在 MARB的铅同位素组成范围内 ,与大西洋沉积物和 Fe- Mn结核相比明显具较少的放射成因铅 ,反映其上部洋壳岩石为该区热液沉积物的形成提供了铅。对比研究表明 ,因不同地质 -构造环境中的海底热液区为热液沉积物形成提供物源的情况不同 ,是导致有沉积物覆盖洋中脊中热液沉积物的铅同位素组成与无沉积物覆盖洋中脊不同的主要原因。海底扩张中心的扩张速率与热液沉积物的铅同位素组成有一定的对应关系 ,但其并不是热液沉积物铅同位素组成的唯一控制因素 相似文献
13.
To investigate the factors controlling lead (Pb) concentration and identify the sources of Pb in Yellow Sea sediments along the Korean coast, the concentration of Pb and Pb isotopes in 87 surface and 6 core sediment samples were analyzed. The 1 M HCl leached Pb concentrations had a similar geographic distribution to those of fine-grained sediments, while the distribution of residual Pb concentrations resembled that of coarse-grained sediments. Leached Pb was presumed to be associated with manganese (Mn) oxide and iron (Fe) oxy/hydroxide, while residual Pb was associated with potassium (K)-feldspar, based on good linear relationships between the leached Pb and the Fe/Mn concentrations, and the residual Pb and K concentrations. Based on a ratio–ratio plot with three isotopes (207Pb/206Pb and 208Pb/206Pb) and the geographic location of each sediment, sediments were categorized into two groups of samples as group1 and group2. Group 1 sediments, which were distributed in Gyeonggi Bay and offshore (north of 36.5°N), were determined to be a mixture of anthropogenic and natural Pb originating from the Han River, based on a 208Pb/206Pb against a Cs/Pbleached mixing plot of core and surface sediments. Group 2 sediments, which were distributed in the south of 36.5°N, also showed a two endmembers mixing relationship between materials from the Geum River and offshore materials, which had very different Pb concentrations and isotope ratios. Based on the isotopes and their concentrations in core and surface sediments, this mixing relationship was interpreted as materials from two geographically different origins being mixed, rather than anthropogenic or natural mixing of materials with the same origin. Therefore, the relative percentage of materials supplied from the Geum River was calculated using a two endmembers mixing model and estimated to be as much as about 50% at 35°N. The spatial distribution of materials derived from the Geum River represented that of fine-grained sediments originating from the Geum River. It was concluded that Pb isotopes in sediments could be used as a tracer in studies of the origin of fine-grained sediments along the Korean Yellow Sea coast. 相似文献
14.
Feng H. Lu 《Geo-Marine Letters》2008,28(5-6):339-349
Low-Mg calcite shells have been widely used to reconstruct the chemistry of ancient seawater. There is always a question: are the shells chemically pristine? This paper presents the isotope and elemental geochemistry of low-Mg calcite bivalve shells in late Miocene platform carbonates, SE Spain. The platform carbonates were extensively dolomitized, and limestone is restricted to older stratal units, and to units mainly in topographically higher and more landward strata. Low-Mg calcite oyster shells were completely dissolved out in the basinward dolomite, but are well preserved in the limestone. These shells appear to retain the original growth microstructures, based on hand samples. Under the microscope, however, dissolution and recrystallization, as well as pristine growth lines are all present. Sr isotopes in these shells range from that of normal Miocene seawater to radiogenic values. δ18O and δ13C values, and Mg, Sr, and Na concentrations in these shells are rather variable. The high end members are consistent with the typical values of modern/late Miocene normal-seawater low-Mg calcite shells, whereas the low end members are close to those of diagenetic calcite cements, which have low δ18O, δ13C, Sr and Na values, and radiogenic Sr. The Nijar shells were altered physically and chemically to different degrees by diagenesis, although these shells are consistent with some “criteria” of unalteration. The isotopic and trace-element data collected in altered and pristine (or less altered) portions coexisting in the same shells are clearly differentiable. Quantitative simulation of covariations of geochemical pairs indicates that solid mixing of unaltered and altered portions by sampling is consistent with the variations in isotopic and elemental data recorded in the Nijar shells. The geological significance of this study is that ancient fabric-retentive calcite shells may have been altered geochemically although they may appear pristine. Calcite shells that underwent intensive diagenesis should be examined rigorously under the microscope, coupled with investigations of multiple geochemical proxies to assess chemical alteration. Only the data of unaltered shells can be used to reconstruct the chemistry of ancient seawater. 相似文献
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According to analyses on the texture and structure of sediment, species component and accumulative way of shells, geometry of sana body and its vertical sequence, this paper points out that the sand ridge located in the west of Shanghai is a kind of ancient chenier, and the entire broad plain of cheniers and the mud flats in between is called chenier plain. The origin of the chenier is related to the shifting of main branch channel in the Changjiang estuary and coastal changes during the historical periods. Based on 14C dating data, the ages of the cheniers from west to east are 6800-6000,5800-5500, 4200-4000 and 3200 years B. P. respectively. These cheniers of different ages illustrate the development processes of the Changjiang Delta during the Middle Holocene. 相似文献
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Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for 207Pb/206Pb and 208Pb/206Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for 207Pb/206Pb (208Pb/206Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for 207Pb/206Pb and 208Pb/206Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores. 相似文献
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The geographic variation in the isotopic composition of lead in surface waters of the central Pacific provides new evidence of the global anthropogenic perturbation of the element's cycle. Ratios of 206Pb/207Pb decrease from 1.196 in the northern hemisphere (19°N, 158°W) to 1.176 in the southern hemisphere (15°S, 150°W). This decrease parallels the geographic variation in surface concentrations of soluble lead which decrease from 13 ng kg?1 at the northern station to 4 ng kg?1 at the southern station. Both the 206Pb/207Pb and the 206Pb/208Pb ratios of those waters fit between the isotopic ratios of Australian (Broken Hill) and North American (Mississippi Valley) leads which are the predominant sources of leads in anthropogenic emissions to the Pacific Ocean basin. 相似文献