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1.
The results of acoustic investigations of over 250 gas “flares” (GFs) located in the depth range of 160–1400 m in the vicinity of the northeastern slope of Sakhalin Island are presented. Pronounced features in the GFs distribution by the seabed’s depth have been identified, which allowed dividing them into four groups corresponding to four depth intervals. The number of GFs per seabed unit area decreases, and the power of the individual GFs increases with depth. The average methane flux per seabed unit of area has been estimated for each depth interval. It has been demonstrated that the total quantity of methane emitted from the seabed in the form of bubbles in the studied area is ∼0.1 million tons per year.  相似文献   

2.
Phenylalkanes with carbon numbers between 16 and 19, characterized by the main carbon-18, have been identified in the modern sediments collected from gas hydrate area from the Gulf of Mexico. The structure of phenylalkanes with four isomers for every carbon number was determined by means of their mass spectra and previous studies. The distribution of the series characterized by a low molecular mass was similar to the distribution of n-alkane, alkylcyclohexanes and alkylbenzenes in each sample. There were differences in the distribution of the phenylalkane series between the S - 1, S - 4, S - 7, S - 9 samples and the S - 8, S - 10 and S - 11 samples. The phenylalkanes might be derived from Archaea associated with anaerobic oxidation of methane (AOM) processes in S - 1, S -4, S -7 and S -9 samples according to their distribution resembled with the distribution of the extract from a type of Archaea. The distribution of alkylcyclohexanes and alkylbenzenes in S - 1, S - 4, S - 7 and S - 9 sample was found to be similar to each other. The odd-over-even predominance of alkylcyclohexanes was seen as the input of some bac- terial.  相似文献   

3.
During the India National Gas Hydrate Program (NGHP) Expedition 01 in 2006 significant sand and gas hydrate were recovered at Site NGHP-01-15 within the Krishna–Godavari Basin, East Coast off India. At the drill site NGHP-01-15, a 5–8 m thick interval was found that is characterized by higher sand content than anywhere else at the site and within the KG Basin. Gas hydrate concentrations were determined to be 20–40% of the pore volume using wire-line electrical resistivity data as well as core-derived pore-fluid freshening trends. The gas hydrate-bearing interval was linked to a prominent seismic reflection observed in the 3D seismic data. This reflection event, mapped for about 1 km2 south of the drill site, is bound by a fault at its northern limit that may act as migration conduit for free gas to enter the gas hydrate stability zone (GHSZ) and subsequently charge the sand-rich layer. On 3D and additional regional 2D seismic data a prominent channel system was imaged mainly by using the seismic instantaneous amplitude attribute. The channel can be clearly identified by changes in the seismic character of the channel fill (sand-rich) and pronounced levees (less sand content than in the fill, but higher than in surrounding mud-dominated sediments). The entire channel sequence (channel fill and levees) has been subsequently covered and back-filled with a more mud-prone sediment sequence. Where the levees intersect the base of the GHSZ, their reflection strengths are significantly increased to 5- to 6-times the surrounding reflection amplitudes. Using the 3D seismic data these high-amplitude reflection edges where linked to the gas hydrate-bearing layer at Site NGHP-01-15. Further south along the channel the same reflection elements representing the levees do not show similarly large reflection amplitudes. However, the channel system is still characterized by several high-amplitude reflection events (a few hundred meters wide and up to ~ 1 km in extent) interpreted as gas hydrate-bearing sand intervals along the length of the channel.  相似文献   

4.
The deepwater of the northwestern South China Sea is located in the central to southern parts of the Qiongdongnan Basin(QDN Basin),which is a key site for hydrocarbon exploration in recent years.In this study,the authors did a comprehensive analysis of gravity-magnetic data,extensive 3D seismic survey,cores and cuttings,paleontology and geochemical indexes,proposed the mechanism of natural gas origin,identified different oil and gas systems,and established the model of hydrocarbon accumulations in the deep-water region.Our basin tectonic simulation indicates that the evolution of QDN Basin was controlled by multiple-phased tectonic movements,such as Indochina-Eurasian Plate collision,Tibetan Uplift,Red River faulting and the expansion of the South China Sea which is characterized by Paleogene rifting,Neogene depression,and Eocene intensive faulting and lacustrine deposits.The drilling results show that this region is dominated by marineterrestrial transitional and neritic-bathyal facies from the early Oligocene.The Yacheng Formation of the early Oligocene is rich in organic matter and a main gas-source rock.According to the geological-geochemical data from the latest drilling wells,Lingshui,Baodao,Changchang Sags have good hydrocarbon-generating potentials,where two plays from the Paleogene and Neogene reservoirs were developed.Those reservoirs occur in central canyon structural-lithologic trap zone,Changchang marginal trap zone and southern fault terrace of Baodao Sag.Among them,the central canyon trap zone has a great potential for exploration because the various reservoirforming elements are well developed,i.e.,good coal-measure source rocks,sufficient reservoirs from the Neogene turbidity sandstone and submarine fan,faults connecting source rock and reservoirs,effective vertical migration,late stage aggregation and favorable structural–lithological composite trapping.These study results provide an important scientific basis for hydrocarbon exploration in this region,evidenced by the recent discovery of the significant commercial LS-A gas field in the central canyon of the Lingshui Sag.  相似文献   

5.
The Dniepr-Donets Basin (DDB) hosts a multi-source petroleum system with more than 200 oil and gas fields, mainly in Carboniferous clastic rocks. Main aim of the present study was to correlate accumulated hydrocarbons with the most important source rocks and to verify their potential to generate oil and gas. Therefore, molecular and isotopic composition as well as biomarker data obtained from 12 oil and condensate samples and 48 source rock extracts was used together with USGS data for a geological interpretation of hydrocarbon charging history.Within the central DDB, results point to a significant contribution from (Upper) Visean black shales, highly oil-prone as well as mixed oil- and gas-prone Serpukhovian rocks and minor contribution from an additional Tournaisian source. Devonian rocks, an important hydrocarbon source within the Pripyat Trough, have not been identified as a major source within the central DDB. Additional input from Bashkirian to Moscovian (?) (Shebelinka Field) as well as Tournaisian to Lower Visean rocks (e.g. Dovgal Field) with higher contents of terrestrial organic matter is indicated in the SE and NW part, respectively.Whereas oil–source correlation contradicts major hydrocarbon migration in many cases for Tournaisian to Middle Carboniferous reservoir horizons, accumulations within Upper Carboniferous to Permian reservoirs require vertical migration up to 4000 m along faults related to Devonian salt domes.1-D thermal models indicate hydrocarbon generation during Permo-Carboniferous time. However, generation in coal-bearing Middle Carboniferous horizons in the SE part of the basin may have occurred during the Mesozoic.  相似文献   

6.
Based on high-resolution Chirp seismic, multibeam bathymetry and side scan sonar data collected in the ?zmir Gulf, Aegean Sea in 2008 and 2010, gas-related structures have been identified, which can be classified into three categories: (1) shallow gas accumulations and gas chimneys, (2) mud diapirs, and (3) active and inactive pockmarks. On the Chirp profiles, shallow gas accumulations were observed along the northern coastline of the outer ?zmir Gulf at 3-20 m below the seabed. They appear as acoustic turbidity zones and are interpreted as biogenic gas accumulations produced in organic-rich highstand fan sediments from the Gediz River. The diapiric structures are interpreted as shale or mud diapirs formed under lateral compression due to regional counter-clockwise rotation of Anatolian microplate. Furthermore, the sedimentary structure at the flanks suggests a continuous upward movement of the diapirs. Several pockmarks exist close to fault traces to the east of Hekim Island; most of them were associated with acoustic plumes indicating active degassing during the survey period in 2008. Another Chirp survey was carried out just over these plumes in 2010 to demonstrate if the gas seeps were still active. The surveys indicate that the gas seep is an ongoing process in the gulf. Based on the Chirp data, we proposed that the pockmark formation in the area can be explained by protracted seep model, whereby sediment erosion and re-distribution along pockmark walls result from ongoing (or long lasting) seepage of fluids over long periods of time. The existence of inactive pockmarks in the vicinity, however, implies that gas seepage may eventually cease or that it is periodic. Most of the active pockmarks are located over the fault planes, likely indicating that the gas seepage is controlled by active faulting.  相似文献   

7.
Mangrove forests are under the stress of sea level rise(SLR) which would affect mangrove soil biogeochemistry.Mangrove soils are important sources of soil-atmosphere greenhouse gas(GHG) emissions,including carbon dioxide(CO2),methane(CH4) and nitrous oxide(N2O).Understanding how SLR influences GHG emissions is critical for evaluating mangrove blue carbon capability.In this study,potential effects of SLR on the GHG emissions were quantified through static closed c...  相似文献   

8.
A growing number of studies on shallow marine gas/fluid systems from across the globe indicate their abundance throughout geological epochs. However, these episodic events have not been fully integrated into the fundamental concepts of continental margin development, which are thought to be dictated by three elements: tectonics, sedimentation and eustasy. The current study focuses on the passive sector of the Levant Basin on the eastern Mediterranean continental margin where these elements are well constrained, in order to isolate the contribution of gas/fluid systems. Single-channel, multichannel and 3D seismic reflection data are interpreted in terms of variance, chaos, envelope and sweetness attributes. Correlation with the Romi-1 borehole and sequence boundaries constrains interpretation of seismic stratigraphy. Results show a variety of fluid- or gas-related features such as seafloor and subsurface pockmarks, volumes of acoustic blanking, bright spots, conic pinnacle mounds, gas chimneys and high sweetness zones that represent possible secondary reservoirs. It is suggested that gas/fluid migrate upwards along lithological conduits such as falling-stage systems tracts and sequence boundaries during both highstands and lowstands. In all, 13 mid-late Pleistocene sequence boundaries are accompanied by independent evidence of 13 eustatic sea-level drops. Whether this connection is coincidental or not requires further research. These findings fill gaps between previously reported sporadic appearances throughout the Levant Basin and margin and throughout geological time from the Messinian until the present day, and create a unified framework for understanding the system as a whole. Repetitive appearance of these features suggests that their role in the morphodynamics of continental margins is more important than previously thought and thus may constitute one of the key elements of continental margin development.  相似文献   

9.
Offshore exploration and production in the U.S. Gulf of Mexico is supported by a large number of service vessels characterized by complex logistical patterns and demand points distributed across an expansive geographic area. No quantitative data on the spatial and temporal distributions of service vessel activity in the region is available due to the size, complexity and dynamics of the network. The purpose of this paper is to apply Automatic Identification System position data to quantify service vessel activity in the U.S. Gulf of Mexico from 2009 to 2010. A total of 1.1 million vessel arrivals and departures were recorded in 2009–2010, and in 2010, the number of vessel events increased by 40% due in part to the Macondo oil spill and cleanup response. Port-to-port movements comprise the majority of events and about 30% of activity relates to movements offshore. Port Fourchon, Venice, New Orleans, Sabine-Neches, and Lake Charles were the most active ports during the period. A detailed breakdown of vessel counts and the limitations of the analysis are outlined.  相似文献   

10.
The identification of reservoir oil–gas–water layers is a fundamental task in petroleum exploration and exploitation, but is difficult, especially in cases of complex hydrocarbon migration and accumulation. In such cases, hydrocarbon remigration and dysmigration take place very commonly, leading to the presence of residual or paleo-oil accumulations and layers, which cannot be easily identified or misinterpreted as oil layers by conventional logging and geophysical data. In this paper, based on a case study in the Luxi area of the central Junggar Basin, NW China, we seek to characterize such layers in terms of organic geochemistry. We suggest specific indicator parameters of organic geochemistry such as the chloroform bitumen content of reservoir extracts, which is usually >1.0% in oil layers. We explore the application of grains containing oil inclusions (GOI) (the ratio of mineral grains containing oil inclusions to the total number of mineral grains) for the identification of oil–gas–water layers in the Junggar Basin for the first time; this method has been used elsewhere. The maximum GOI values for the oil layers, oil–water layers, water layers and dry layers are >11%, 7%–11%, 6%–7% and <6%, respectively. In addition, gas layers and heavy-oil layers that are difficult to identify by conventional organic geochemical parameters were identified using biomarkers. The typical characteristics of the soluble reservoir bitumen in the gas layers include a much greater abundance of tricyclic terpanes (two times in general) relative to pentacyclic terpanes and a tricyclic terpane distribution of C20 > C21 > C23. In contrast, the typical characteristic of the heavy-oil layers is the presence of 25-norhopanes in reservoir bitumen extracts. These specific indicators can be applied in the Junggar Basin and in similar settings elsewhere.  相似文献   

11.
We have performed a simulation of the convectively induced ascent of the gas–dust cloud formed during the atmospheric passage and explosion of the Chelyabinsk meteoroid. The acceleration, velocity, and rise of the gas–dust cloud have been described as functions of time and altitude. The time of dust settling in the atmosphere has been estimated. The results of calculations are in a close agreement with the observational data.  相似文献   

12.
Abstract

Methane concentrations and sediment shear strengths were measured in three foundation borings taken from areas of variable acoustical penetration in the Mississippi river delta front. Acoustically impenetrable or “turbid”; zones were associated with sedimentary methane concentrations above about 30 ml/liter, measured at atmospheric pressure. Sediments in the high‐gas, acoustically turbid zones demonstrated a smaller percentage increase in shear strength with depth than in zones of low gas concentration. The results indicate that a 3.5‐kHz system used for sub‐bottom profiles is unable to determine the thickness of gas‐charged sediments.  相似文献   

13.
The present study is the first to directly address the issue of gas hydrates offshore West Greenland, where numerous occurrences of shallow hydrocarbons have been documented in the vicinity of Disko Bugt (Bay). Furthermore, decomposing gas hydrate has been implied to explain seabed features in this climate-sensitive area. The study is based on archive data and new (2011, 2012) shallow seismic and sediment core data. Archive seismic records crossing an elongated depression (20×35 km large, 575 m deep) on the inner shelf west of Disko Bugt (Bay) show a bottom simulating reflector (BSR) within faulted Mesozoic strata, consistent with the occurrence of gas hydrates. Moreover, the more recently acquired shallow seismic data reveal gas/fluid-related features in the overlying sediments, and geochemical data point to methane migration from a deeper-lying petroleum system. By contrast, hydrocarbon signatures within faulted Mesozoic strata below the strait known as the Vaigat can be inferred on archive seismics, but no BSR was visible. New seismic data provide evidence of various gas/fluid-releasing features in the overlying sediments. Flares were detected by the echo-sounder in July 2012, and cores contained ikaite and showed gas-releasing cracks and bubbles, all pointing to ongoing methane seepage in the strait. Observed seabed mounds also sustain gas seepages. For areas where crystalline bedrock is covered only by Pleistocene–Holocene deposits, methane was found only in the Egedesminde Dyb (Trough). There was a strong increase in methane concentration with depth, but no free gas. This is likely due to the formation of gas hydrate and the limited thickness of the sediment infill. Seabed depressions off Ilulissat Isfjord (Icefjord) previously inferred to express ongoing gas release from decomposing gas hydrate show no evidence of gas seepage, and are more likely a result of neo-tectonism.  相似文献   

14.
1Introduction Besidestheprecipitationandriverdischarges,the watersinthePacificOceanandtheAtlanticOceanare thesourcesoftheArcticOceanwater.TheAtlantic waterenterstheArcticOceanviatheFramStraitand theBarentsSea.Foritsdenserfeatureduetohigh salinity,mostofitsinkstothenorthofSvaldbardand circulatesinallthedeepbasinsintheArcticOcean, formingthedeepandbottomwatersoftheArcticO- cean(Aagaardetal.,1985;Rudelsetal.,1999).The BeringStraitistheonlychannelforthePacificwater toflowintotheArcticOce…  相似文献   

15.
Abstract

Where undissolved gas occurs within fine‐grained marine sediments it usually takes the form of discrete bubbles that are much larger than the normal void spaces. The possibility of buoyancy‐induced movement of these relatively large bubbles must be included when considering the transport of gas through marine sediments. A theoretical analysis shows that, under static loading conditions, bubbles larger than a critical size should have sufficient buoyancy to move upward through a fine‐grained sediment stratum, whereas bubbles smaller than the critical size should remain fixed in position. The critical radius is directly proportional to sediment shear strength, and bubbles of a realistic size should move upward only in extremely weak sediments. Further theoretical analysis shows that the critical bubble size is reduced under cyclic loading conditions, but movement of typical‐sized bubbles should still be restricted to sediments of low shear strength. A simple laboratory experiment provides support for the conclusions of the theoretical analysis. The results indicate that buoyancy‐induced movement of relatively large gas bubbles in fine‐grained sediments is most likely to occur under storm loading conditions and is unlikely to occur at depths greater than a few meters below the seabed.  相似文献   

16.
1 IntroductionTheBeringStrait, with them aximum depth lessthan 60 m , isthe uniquepassagebetween the ArcticOcean and the North Pacific Ocean, and links twoshelfseas:theBeringSeainthesouthandtheChukchiSea in the north. The background flow field oftheBering…  相似文献   

17.
Geochemical characteristics of organic matter in the profiles of Dukla, Silesian, Sub-Silesian and Skole units of the Polish Outer Carpathians and of the Palaeozoic–Mesozoic basement in the Dębica-Rzeszów-Leżajsk-Sanok area were established based on Rock-Eval, vitrinite reflectance, isotopic and biomarker analyses of 485 rock samples. The Oligocene Menilite beds have the best hydrocarbon potential of all investigated formations within the Dukla, Silesian, and Skole units. The Ordovician, Silurian, Lower Devonian and locally Middle Jurassic strata of the Palaeozoic–Mesozoic basement are potential source rocks for oil and gas accumulated in Palaeozoic and Mesozoic reservoirs. Thirty one natural gas samples from sandstone reservoirs of the Lower Cretaceous-Lower Miocene strata within the Outer Carpathian sequence and eight from sandstone and carbonate reservoirs of the Palaeozoic–Mesozoic basement were analysed for molecular and isotopic compositions to determine their origin. Natural gases accumulated both in the Outer Carpathian and the Palaeozoic–Mesozoic basement reservoirs are genetically related to thermogenic and microbial processes. Thermogenic gaseous hydrocarbons that accumulated in the Dukla and Silesian units were generated from the Menilite beds. Thermogenic gaseous hydrocarbons that accumulated in the Sub-Silesian Unit most probably migrated from the Silesian Unit. Initial, and probably also secondary microbial methane component has been generated during microbial carbon dioxide reduction within the Oligocene Menilite beds in the Dukla Unit and Oligocene-Lower Miocene Krosno beds in the Silesian Unit. Natural gases that accumulated in traps within the Middle Devonian, Mississippian, Upper Jurassic, and Upper Cretaceous reservoirs of the Palaeozoic–Mesozoic basement were mainly generated during thermogenic processes and only sporadically from initial microbial processes. The thermogenic gases were generated from kerogen of the Ordovician-Silurian and Middle Jurassic strata. The microbial methane component occurs in a few fields of the Dukla and Silesian units and in the two accumulations in the Middle Devonian reservoirs of the Palaeozoic–Mesozoic basement.  相似文献   

18.
Based on the analysis of the high-resolution 3D seismic data from the SW Barents Sea we study the hydrocarbon plumbing system above the Snøhvit and Albatross gas field to investigate the geo-morphological manifestation and the dynamics of leakage from the reservoir. Fluid and gas escape to the seafloor is manifested in this area as mega-pockmarks 1–2 km-wide, large pockmarks (<100 m wide) and giant pockmarks 100–300 m-wide. The size of the mega pockmarks to the south of the study area may indicate more vigorous venting, whilst the northern fluid flow regime is probably characterised by a widespread fluid and gas release. Buried mega depressions and large-to-giant pockmarks are also identified on the base Quaternary and linked to deep and shallow faults as well as to seismic pipes. A high density of buried and seafloor giant pockmarks occur above a network of faults overlying an interpreted Bottom Simulating Reflector (BSR), whose depth coincides with the estimated base of the hydrate stability zone for a thermogenically derived gas hydrate with around 90 mol% methane. Deep regional faults provide a direct route for the ascending thermogenic fluids from the reservoir, which then leaked through the shallow faults linked to seismic pipes. It is proposed that the last episodic hydrocarbon leakage from the reservoir was responsible for providing a methane source for the formation of gas hydrates. We inferred that at least two temporally and dynamically different fluid and gas venting events took place in the study area: (1) prior to late Weichselian and recorded on the Upper Regional Unconformity (URU) and (2) following the Last Glacial Maximum between ∼17 and 16 cal ka BP and recorded on the present-day seafloor.  相似文献   

19.
《Ocean Modelling》2011,40(3-4):284-290
The temperature dependency of ocean–atmosphere gas transfer velocities is commonly estimated in terms of Schmidt numbers, i.e. the ratio of kinematic viscosity to diffusivity. In numerical models least square regressions are used to fit the limited number of experimentally derived Schmidt numbers to a function of temperature. For CO2 a well established fit can be found in the literature. This fit constitutes an integral part in standardized carbon cycle simulation projects (e.g. C4MIP, OC4MIP, Friedlingstein et al., 2006). However, the fit is valid only in the range where diffusivity measurements exist, i.e., from 0 to about 30 °C. In many climate warming simulations like e.g. the MPI contribution to the fourth Intergovernmental Panel on Climate Change Assessment Report (IPCC AR 4), sea surface temperatures largely exceed the validated range and approach or even reach the range, where the standard fits leave the physically meaningful range. Thus, this paper underlines the demand for new measurements of seawater diffusivities for CO2 and other trace gases especially for the temperature range >30 °C.In this paper we provide improved fits for the temperature dependence of the Schmidt number. For carbon dioxide our fit is compared to the established fit under identical climate change simulations carried out with the 3D-carbon cycle model HAMOCC. We find that in many tropical and subtropical high temperature regions the established fit leads to unrealistically short adaption times of the surface water pCO2 to altered atmospheric pCO2. In regions where the local oceanic pCO2 is not primarily controlled by the atmospheric boundary pCO2 but by other processes such as biological activity, the atmosphere ocean pCO2 gradient is clearly underestimated when using the established fit. The effect on global oceanic carbon uptake in a greenhouse world is rather small and the potential climate feedback introduced by this bias seems to be negligible. However, the bias will clearly gain in significance the more regions warm up to over 30 °C. On a regional scale, especially in coastal regions at low latitudes, the effect is not negligible and a different steady state is approached.  相似文献   

20.
Total organic carbon and organic carbon stable isotope, biogenic silica, chlorin were measured from a high resolution sediment core to indicate the variation in paleoproductivity and the environmental implications over the past decades (1942 to 1997) in the Changjiang Estuary. Based on these biomarkers, the shift in the phytoplankton community structure in the past decades was discussed in response to the long-term variations in nutrient concentrations and nutrient ratios. The results showed that the δ 13 C values varied from –26.15‰ to –19.5‰, suggesting the combined organic carbon sources of riverine and marine organisms. Based on the biogenic proxies, paleoproductivity changes were categorized into three stages: low production before 1950; an increase in production with the dominance of diatoms during 1950 to 1980, consistent with increasing of nutrient concentrations; a decrease in production after 1980 when the diatom production decreased while the production of non-silicious phytoplankton increased due to high nutrient inputs, and high N/P and P/Si ratios in the Changjiang Estuary. The sedimentation records also indicated that the riverine organic carbon increased since 1980.  相似文献   

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