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沿海地区氯盐侵蚀会对混凝土结构造成严重的耐久性问题,混凝土设计使用寿命难以保障。对于新建工程,若在自由水含量较高混凝土养护期进行电迁阻锈处理,则有利于电迁移性阻锈剂在钢筋周围聚集以达到更佳的阻锈效果。为此,针对两种电迁移性阻锈剂对处于氯盐侵蚀环境中的混凝土适用性展开研究,并测试了干湿循环前后混凝土内钢筋电化学参数、氯离子扩散特征及钢筋周围电迁移性阻锈剂含量研究两种电迁移性阻锈剂对混凝土耐久性保障的作用。结果表明,试验中养护期介入电迁阻锈后试件阻锈效果良好,经过干湿循环后钢筋腐蚀电位正向高于-162.6 m V,同时,钢筋附近出现明显的阻锈剂聚集现象,能保持钢筋的钝化状态。 相似文献
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氯盐干湿环境下受弯横向裂缝对钢筋混凝土耐久性影响 总被引：1，自引：0，他引：1
为了研究持续开裂状态下横向裂缝对钢筋混凝土结构耐久性的影响特性,开展了8根受弯开裂钢筋混凝土梁构件的盐溶液干湿循环试验;借助无损检测技术和破损实测方法,分别对氯离子侵入量、钢筋半电池电位、腐蚀电流密度以及平均锈蚀率等进行了对比分析。研究结果表明,裂缝的存在将提高混凝土的渗透性,裂缝处及周围混凝土内的氯离子含量明显增大;对于一定裂缝分布状况的钢筋混凝土试验梁,内部钢筋的腐蚀电位、腐蚀电流密度以及平均锈蚀率均高于裂缝自愈及无裂缝的试验梁,并受到保护层厚度与裂缝开展状态的影响,其影响规律可用单位长度内的平均裂缝宽度与保护层厚度的比值wm/c来进行综合评价。综合试验结果,初步建议海洋干湿侵蚀环境下钢筋混凝土构件的最大裂缝宽度wmax宜小于0.003 3 c,相关结论可为海洋混凝土结构的耐久性设计提供参考。 相似文献
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海洋环境中温湿度变化对混凝土氯离子传输研究 总被引：1，自引：0，他引：1
氯离子渗透到混凝土内部诱发钢筋锈蚀是海洋钢筋混凝土面临的耐久性关键问题。构建考虑骨料、浆体集料界面区的混凝土模型,建立了环境温度、湿度影响的氯离子传输模型,基于COMSOL数值模拟软件分析了材料、环境对混凝土氯离子传输的影响规律,并通过试验进行了验证。结果表明:模拟结果和试验数据具有较高的吻合度;随着温度的升高,氯离子扩散加快,而混凝土中氯离子的渗透深度随着内部湿度的增大而呈现减小趋势。混凝土中高致密骨料存在阻碍了氯离子传输,但界面区存在使得氯离子沿界面区传输并在骨料背后形成传输前锋。 相似文献
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根据人工模拟的流动海水环境(流速约为0.15m/s)下的混凝土侵蚀试验测得的混凝土中氯离子质量分数,分别测定了腐蚀350,380,400d后混凝土的氯离子扩散系数,并计算和预测了混凝土人工鱼礁的耐久性寿命。研究结果表明:氯离子在混凝土人工鱼礁中的扩散规律基本上遵循Fick第二定律;钢筋混凝土人工鱼礁的耐久性寿命与保护层厚度的平方成正比;海水盐度对混凝土人工鱼礁的耐久性寿命影响较大。 相似文献
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In jacket-type offshore structures, corrosion damage affects the structural performance under compressive loading, which is created by the working and design loads of the main system. In this study, the effects of corrosion damage on the compressive structural behavior and strength of steel tubular members were investigated. Artificial corrosion damage was applied to the tubular specimens via mechanical processing and hand drilling to replicate the inclined nature of jacket-type offshore structures. The damage was applied to either half or all of the circumference of the specimens. The compressive failure modes of the artificially corroded tubular members were affected by the corrosion conditions. The compressive strengths were also affected by the level of corrosion. From the results of this study, the residual compressive strengths of corroded tubular steel members can be estimated based on the condition of the damaged sectional areas. 相似文献
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氯化物是钢筋混凝土结构在使用寿命期内可能遇到的一种最危险的侵蚀介质,混凝土中钢筋表面的氯离子浓度超过一定的限值,钢筋就可能会发生锈蚀,锈蚀的钢筋会导致混凝土构件的承载力下降.通过分析国内外研究者所做的大量工作,讨论了氯离子侵入引起的锈蚀钢筋混凝土构件的抗力计算方法,为氯化物环境条件下混凝土结构的耐久性评估提供参考. 相似文献
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To study the inhibitory effects of chloride ions on concrete sulfate attack in the marine adsorption environment, a series of cubic concrete specimens was fabricated. These specimens were totally submerged or partially submerged in 10% Na2SO4 solutions with 0, 0.5, 2, and 5% NaCl concentration. Three specific aspects, namely, superficial phenomenon, compressive strength degradation, and X-ray fluorescence spectrometry analysis, were studied during 450 days of long-term exposure. Results showed that Na2SO4 solution had a strong corrosive effect on concrete in both the adsorption and submersion zones, especially in the adsorption zone. Chloride ions exerted inhibitory effects on concrete sulfate attack in both the submersion and adsorption zones, and higher concentration of chloride ions will produce stronger inhibitory effects. However, given the different inhibitory effects of chloride ions on concrete sulfate attack with different corrosion mechanisms, the inhibitory effect of the same chloride concentration on concrete sulfate attack was a little lower in the adsorption zone than in the submersion zone. 相似文献
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系统阐述宁波舟山港主通道跨海工程混凝土结构耐久性评估与维护技术。首先介绍宁波舟山港主通道工程概况及100年使用年限的总体要求;确定耐久性极限状态为海洋氯离子侵入引起的钢筋表面脱钝。针对此极限状态,建立了氯离子侵入过程的耐久性评估模型,确定了不同暴露条件下模型参数的统计规律;根据混凝土保护层厚度的现场实测数据和修正的暴露条件下氯离子扩散系数,对模型参数进行了更新;考虑施工阶段混凝土构件的耐久性附加措施,以某标段非通航孔桥为例,使用全概率方法计算了各类混凝土桥梁构件的失效概率和可靠指标;最终在混凝土构件耐久性评估的基础上,提出了某标段非通航孔桥各类混凝土构件的基本维护制度和维护周期。 相似文献
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氯离子侵蚀已成为影响海洋及近海环境中混凝土结构耐久性的主要因素。考虑材料组成的非匀质特性,将混凝土看作由粗骨料、硬化水泥砂浆及二者界面过渡区组成的三相复合材料的细观层次方法,是开展物质传输过程研究的新途径。建立非饱和混凝土中氯离子传输的一维非线性对流扩散方程,并利用伽略金加权余数法给出了该方程的有限元形式,采用适用于物质传输的细观格构网络模型开展了水分及氯离子在非饱和混凝土中传输过程及分布规律研究,分析了干湿循环周期和循环机制对水分及氯离子传输性能的影响规律。数值计算结果表明,干湿交替下,相同的干燥时间,非饱和混凝土内水分及氯离子的侵入深度主要取决于湿润时间,而干燥时间和循环周期数则影响混凝土表层氯离子含量,并在混凝土表层10 mm处有浓度集中现象。 相似文献
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开展了5根锈胀开裂钢筋混凝土梁疲劳试验并实时记录了梁表面的钢筋压磁信号,研究锈胀开裂混凝土梁的疲劳特性和压磁信号演化规律。结果表明梁疲劳寿命随钢筋锈蚀率增大而急剧减小,梁破坏时混凝土剥落,纵筋发生疲劳断裂;磁信号时变曲线随疲劳进程不断演化,在临近疲劳破坏时曲线形态发生明显畸变,能够反映梁疲劳损伤信息;磁感应强度变化幅值的发展符合三阶段特性,在疲劳初期和破坏前增长明显;磁感应强度变化幅值对钢筋锈蚀敏感,随锈蚀率增加而增大,因此建立了疲劳作用不同阶段磁信号幅值和梁内钢筋锈蚀率的相关关系。 相似文献
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表面氯离子含量(C_s)是研究海洋环境条件下混凝土结构耐久性和服役寿命的氯离子扩散方程的边界条件,是海洋混凝土结构耐久性分析和定量设计的重要参数。依据国内外大量自然暴露试验与工程实测数据,通过采用Excel、Origin等数据分析软件进行数据统计和回归分析,确定了海洋混凝土结构表面自由氯离子含量(C_(sf))与表面总氯离子含量(C_(st))之间的相互关系,探讨了海洋混凝土结构的C_(sf)时变规律,建立了C_(sf)与暴露时间之间的关系表达式及其取值范围,并运用可靠度理论和修正氯离子扩散理论分析了C_(sf)时变性对海洋混凝土结构寿命的影响。结果表明:C_(sf)与C_(st)线性相关,且C_(sf)随着暴露时间的延长呈指数或者幂函数的增长关系;采用不同的C_(sf)时变性规律,对海洋混凝土结构寿命具有重大的影响。 相似文献
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Probabilistic Durability Assessment of Concrete Structures in Marine Environments: Reliability and Sensitivity Analysis 总被引：1，自引：1，他引：0 
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下载免费PDF全文 A probabilistic framework for durability assessment of concrete structures in marine environments was proposed in terms of reliability and sensitivity analysis, which takes into account the uncertainties under the environmental, material, structural and executional conditions. A time-dependent probabilistic model of chloride ingress was established first to consider the variations in various governing parameters, such as the chloride concentration, chloride diffusion coefficient, and age factor. Then the Nataf transformation was adopted to transform the non-normal random variables from the original physical space into the independent standard Normal space. After that the durability limit state function and its gradient vector with respect to the original physical parameters were derived analytically, based on which the first-order reliability method was adopted to analyze the time-dependent reliability and parametric sensitivity of concrete structures in marine environments. The accuracy of the proposed method was verified by comparing with the second-order reliability method and the Monte Carlo simulation. Finally, the influences of environmental conditions, material properties, structural parameters and execution conditions on the time-dependent reliability of concrete structures in marine environments were also investigated. The proposed probabilistic framework can be implemented in the decision-making algorithm for the maintenance and repair of deteriorating concrete structures in marine environments. 相似文献
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It is inevitable that marine structures suffer from corrosion and extreme cyclic loading. In order to study the influence of corrosion damage and cumulative fatigue damage on mechanical properties of marine steel, high performance steel NV-D36 was analyzed under electrochemical corrosion and cyclic loading. It was found that corrosion damage can reduce the elastic modulus, yield strength, ultimate stress and ultimate strain of steel NV-D36. And it was also found that cumulative fatigue damage will increase the ultimate stress of steel NV-D36 and reduce the ultimate strain of steel NV-D36. The effect of double damage on mechanical properties of steel NV-D36 was coupled with these two kinds of damage. The Chaboche model parameters calibrated under incremental cyclic loading scheme can exactly describe the stiffness and peak stress of steel NV-D36. 相似文献
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Factors affecting corrosion and approaches for improving durability of ocean reinforced concrete structures 总被引：1，自引：0，他引：1
Investigation shows that concrete corrosion is a common problem for ocean reinforced concrete (R.C.) structures along China’s coast. A discussion of the corrosion characteristics, based on real project cases and field surveys, is presented in this paper. These factors that might affect corrosion, such as environmental effects, construction quality, cover thickness, property of the concrete material and structure type, are evaluated. Based on the analysis of these corrosion characteristics and affecting factors, the approaches available to improve the durability of ocean R.C. structures are proposed. 相似文献
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AbstractA type of sealed steel box was designed to simulate sulfate attack and hydraulic pressure on concrete. Cup-shaped concrete specimens with water/cement (w/c) ratios of 0.4, 0.5, and 0.6 were fabricated. During the 270 days corrosion time, corrosion behavior on concrete surfaces was observed every 30 days. The extent of damage on concrete was calculated on the basis of the results of periodic ultrasonic testing. After the completion of experiments, X-ray fluorescence analysis was conducted on the element contents at different depth locations of partial specimens. Experimental results showed that hydraulic pressure accelerated the sulfate attack on concrete, and high pressure yielded serious damage. In comparison with zero pressure, the accelerating coefficients of 0.1, 0.2, and 0.3?MPa hydraulic pressures were 1.48, 1.75, and 2.35, respectively. Hydraulic sulfate corrosion can bring additional sulfate ions into concrete and cause chemical and physical sulfate corrosions on concrete simultaneously, thereby resulting in serious damage on concrete. The reduction of w/c ratio and incorporation of fly ash are beneficial for concrete to resist hydraulic sulfate attack. 相似文献
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为研究河流入海口处盐度周期变化时铝牺牲阳极对钢结构的保护效果,测试对比了盐度固定与盐度循环条件下Q235钢有无阳极保护时的腐蚀失重和电位变化、铝牺牲阳极的电流效率。结果表明盐度循环会造成Q235钢的严重腐蚀,盐度差越大腐蚀越严重,甚至可能超过天然海水的腐蚀程度;在盐度循环条件下铝牺牲阳极对Q235钢具有良好的保护效果,但与稳定的盐度相比,阳极的消耗量增加、电流效率降低;在稳定的低盐度条件（0.5%）下,虽然铝牺牲阳极的电流效率较高,被保护的Q235钢电位足够负,但是保护效果不理想。本文通过Q235钢腐蚀失重数据检验铝牺牲阳极的保护效果,得到了不同盐度循环条件下铝牺牲阳极的初步性能数据,为河流入海口处钢结构设施的阴极保护提供了依据。 相似文献