where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4−, H2B = H2SO3 and HB = HSO3−. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3−), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   

2.
A dynamic equation for the potential energy anomaly for analysing mixing and stratification in estuaries and coastal seas   总被引：5，自引：0，他引：5  
Hans Burchard  Richard Hofmeister 《Estuarine, Coastal and Shelf Science》2008,77(4):679-687
In this paper, a time-dependent dynamic equation for the potential energy anomaly, , is rigorously derived from dynamic equations for potential temperature and salinity, the continuity equation and the equation of state for sea water. The terms locally changing are (A) the -advection, (B) the depth-mean straining, (C) the non-mean straining, (D) the vertical advection, (E) the vertical mixing, (F) surface and bottom density fluxes, (G) inner sources of density e.g. due to absorption of solar radiation and the non-linearity of the equation of state, and (H) horizontal divergence of horizontal turbulent density fluxes. In order to derive the equation in concise form, a vertical velocity (linearly varying with depth) with respect to depth-proportional vertical coordinates had to be defined. The evaluation of the terms in the -equation is then carried out for a one-dimensional tidal straining study and a two-dimensional estuarine circulation study. Comparisons to empirical estimates for these terms are made for the one-dimensional study. It is concluded that the -equation provides a general reference for empirical bulk parameterisations of stratification and mixing processes in estuaries and coastal seas and that it is a tool for complete analysis of the relevant terms from numerical models.  相似文献   

3.
Dissociation constants of protonated cysteine species in seawater media     
Virender K. Sharma  Aurelie Moulin  Frank J. Millero  Concetta De Stefano 《Marine Chemistry》2006,99(1-4):52
The dissociation constants (pK1, pK2 and pK3) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK3 in the Na–Mg–Cl solutions have been attributed to the formation of Mg2+ complexes with Cys2− anions
Mg2+ + Cys2− = MgCys
The stability constants have been fitted to
after corrections are made for the interaction of Mg2+ with H+.The pK1 seawater measurements indicate that H3Cys+ interacts with SO42−. The Pitzer parameters β0(H3CysSO4), β1(H3CysSO4) and C(H3CysSO4) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK2 and pK3 in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK1, pK2 and pK3 that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids.  相似文献   

4.
Undrained pullout capacity of modified suction caisson in clay by finite element limit analysis     
Dayong Li  Shili Ma 《Marine Georesources & Geotechnology》2013,31(3):291-300
  相似文献   

5.
Steepness and spectrum of nonlinear deformed shallow water wave     
Narcisse Zahibo  Irina Didenkulova  Andrey Kurkin  Efim Pelinovsky   《Ocean Engineering》2008,35(1):47-52
  相似文献   

6.
Earthquake response of submerged circular cylinder     
Anthony N. Williams 《Ocean Engineering》1986,13(6)
  相似文献   

7.
Interference of chlorophyll a in liquid scintillation counting of phytoplankton productivity samples by the C technique     
S. Nayar  B. P. L. Goh  L. M. Chou 《Estuarine, Coastal and Shelf Science》2003,56(5-6):957-960
  相似文献   

8.
Effects of stratification and mesoscale eddies on Kuroshio path variation south of Japan     
Kazunori Akitomo   《Deep Sea Research Part I: Oceanographic Research Papers》2008,55(8):997-1008
Bimodality of the Kuroshio current path south of Japan is investigated, focusing on the effects of stratification and mesoscale eddies. For this purpose, wind-driven numerical experiments are executed in barotropic and two-layered ocean models. Stratification has two effects on the path selection of the Kuroshio south of Japan. First, it makes an alongshore path stable at intermediate wind stress strength τ0 by arresting an eddy southeast of Kyushu. This enables an alongshore path to appear in the entire experimental range of τ0. Second, the upper limit of τ0 which allows a meandering path decreases from ( in the Sverdrup transport at the Tokara Strait) to () as Δρ/ρ0 increases from 2.0×10-3 to 4.0×10-3. While an anticyclonic eddy imposed upstream (southeast of Kyushu) can cause the transition from an alongshore to a meandering path, it occurs most easily when (). The transition from a meandering to an alongshore path requires an eddy imposed downstream (east of the meandering segment) which suppresses redevelopment of the meandering segment and breaks the balance between the advective and beta effects. Applicability of the results to previously observed path variations is discussed.  相似文献   

9.
Response of a two-layer ocean with a baroclinic current to a moving storm,part I     
Takashi Ichiye 《Journal of Oceanography》1977,33(3):151-160
A storm moves with a constant speed parallel to a stationary geostrophic current which flows only in the upper layer of a two-layer, infinite ocean. It is assumed that the lower layer is motionless. The quasi-geostrophic approximation is valid for a moving speed less than 4 ms–1 for a storm radius of 100 km. The primary change of the upper layer thickness is caused by the wind stress divergence and the time integral of the wind stress curl. A cyclonic storm generates upwelling in its wake. The effect of the stationary flow similar to a western boundary current is minor by an order of magnitude and noticeable only on the left edge of the flow. Scaling of equations of motion and continuity for a more general upper geostrophic flow leads to expansion with a parametera 2=gH m(fL)–2, whereg is reduced gravity,H m is the maximum thickness of the upper layer,f is Coriolis' parameter andL is the storm radius. The zeroth order perturbations of transport and thickness do not include the stationary flow which appears only in the first order perturbations ina 2. When there is a coast, the change of the interface near the coast is dependent on the time integral of the wind stress component parallel to the coast, thus leading to upwelling or downwelling according to the center being to the left or right of the coastline.  相似文献   

10.
Reply     
C. Kuo  Y. Welaya 《Ocean Engineering》1982,9(1):101-102
  相似文献   

11.
Seasonal changes of antioxidant and oxidative parameters in the coral Pocillopora capitata on the Pacific coast of Mexico     
Marco A. Liñán‐Cabello  Laura A. Flores‐Ramírez  Tania Zenteno‐Savin  Norma O. Olguín‐Monroy  Ramón Sosa‐Avalos  Manuel Patiño‐Barragan  Aramis Olivos‐Ortiz 《Marine Ecology》2010,31(3):407-417
The physiological responses of the coral Pocillopora capitata to environmental conditions common in winter and summer were studied in 2007 during February–March (winter) and June–July (summer) at La Boquita reef (Manzanillo, Colima, Mexico). Shallow and deep sampling stations were established at different distances from a small jetty built next to the Juluapan Lagoon. We analyzed superoxide radicals () and lipid peroxidants (TBARS); the activities of superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx), glutathione reductase (GR), and glutathione‐S‐transferase (GST); chlorophyll a (Chl a), zooxanthellae density (ZD); and mycosporine‐like amino acids (MAAs). Our results showed that the , TBARS, CAT, GST, MAAs, and Chl a, levels were significantly higher in summer (P < 0.05); no seasonal difference was found for GPx, GR or ZD. We found significant differences (P < 0.05) in winter only for Chl a and ZD at shallow sites and, in contrast, for at deeper sites. The results of this study indicate that increasing temperature and radiation associated with seasonal changes (from winter to summer), the efficiency of the enzymes GST, CR and GPX, and the production of MAAs together form a powerful mechanism for P. capitata to offset the detrimental effects of environmental change.  相似文献   

12.
Diversity patterns in macrobenthos across a continental slope in the NE Atlantic     
Els Flach  Wim de Bruin 《Journal of Sea Research》1999,42(4):2851
Different estimates were used to assess the diversity of the total macrofauna and its major taxonomic groups separately from a broad bathymetric range at a site in the NE Atlantic. In the Goban Spur region, a transect was sampled from the shelf to the abyssal plain over a depth range from 200 to 4500 m and in the Porcupine Sea Bight two stations were sampled (at 3670 m and 4115 m). Species diversity (the number of species per number of individuals) increased with increasing water depth, both when expressed as Hurlbert's E(Sn) and as Shannon's H′log e. The expected number of species in a 100-individual sample E(S100) of total macrofauna increased from 30 on the shelf to 68 on the abyssal plain. Evenness (the proportional abundance of species), estimated with Shannon's J′, also increased with water depth from 0.66 to 0.91, whereas dominance (Simpson's D) decreased from 0.09 to 0.01. Species richness (the number of species per unit of area), however, showed a parabolic pattern with a peak at the upper slope. The largest number of species was found at the slope station at 1425 m (232 species within 0.66 m2). It is argued that species richness is not a synonym of species diversity, but that species richness depends both on species density (which decreases with increasing water depth) and on species diversity. Across the whole bathymetric range (200 to 4500 m) a total of 696 species within 8327 specimens in a total sampled area of 4.12 m2 were counted, yielding mean values of 12 individuals per species and 169 species per m2. Different communities were found to exist on the shelf, slope and abyss. It is suggested that this could have been caused by different selection processes. Differences in life-history strategies and organic-matter supply could (at least partly) explain the different community structures and diversity patterns found along the depth gradient.  相似文献   

13.
Seasonal changes in beach morphology along the sheltered coastline of Perth,Western Australia     
《Marine Geology》2001,172(3-4):243-263
  相似文献   

14.
Comparison of two methods to derive the size-structure of natural populations of phytoplankton     
《Deep Sea Research Part I: Oceanographic Research Papers》2014
  相似文献   

15.
Biodiversity and community structure of deep-sea foraminifera around New Zealand     
《Deep Sea Research Part I: Oceanographic Research Papers》2007,54(9):1641-1654
  相似文献   

16.
Impact of Satellite-Derived Diffuse Attenuation Coefficient on Upper Ocean Simulation Using High-Resolution Numerical Ocean Model: Case Study for the Bay of Bengal     
Subrat Kumar Mallick  Neeraj Agarwal  Rashmi Sharma  K.V.S.R. Prasad  Robert A. Weller 《Marine Geodesy》2013,36(6):535-557
  相似文献   

17.
Some properties of surf-beats     
Yukio Fujinawa 《Journal of Oceanography》1979,35(1):9-25
Long ocean waves with periods of several minutes (surf-beats) were observed at a marine observation tower. We have analysed time series data of an envelope of incident swell, long period current velocity and surface elevation fluctuations. Current velocity was measued by an electromagnetic flow meter. Surf-beats amplitudeH (l) is shown to be proportional to 3/2 power of incident swell amplitudeH (s), and decreases with increase of depthh in proportional toh –1/2 such thatH (l) H (s) (H (s)/h)1/2. Frequency energy density functionP LL (f) of surface elevation had two dominant peaks whose frequencies were highly stable through the entire observational period. Cross-spectral analysis suggested that those peaks correspond to traveling edge waves caused by the excess momentum and mass flux in the surf zone. The forced long ocean waves predicted byLonguet-Higgins andStewart (1964) was ditected. Phase-shift and wave height of the wave with respect to those of incident swell envelope are shown to be in remarkable agreement with the predictions. However the forced long wave is only a minor component in the total energy of surf-beats. Current fields are shown to be largely composed of non-surface modes.  相似文献   

18.
Experimental study of a porous floating breakwater     
H.Y. Wang  Z.C. Sun 《Ocean Engineering》2010,37(5-6):520-527
  相似文献   

19.
A proof and applications of the expansion theorem for the Rossby normal modes in a closed rectangular basin     
Akira Masuda 《Journal of Oceanography》1987,43(4):237-243
An expansion theorem is derived for Rossby normal modes in a closed rectangular basin and the set of Rossby normal modes is proved to be complete. This theorem provides a general linear solution to the initial value problem as well as to the response problem. In particular, the Green's function is obtained for the instantaneous localized torque anywhere in the basin. Weakly nonlinear versions are solved also by the combination of the general linear solution with the asymptotic expansion in terms of small amplitude. Further, an application is suggested to the spectral method of numerical simulation based on Rossby normal modes relevant to the more nonlinear evolution equation on a-plane, instead ofsin functions or Chebyshev polynomials, which have been employed conventionally for this purpose.  相似文献   

20.
The Reddy maker     
《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(9):1531-1549
  相似文献   

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1.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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