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1.
Laure Moulin Ana Isabel Catarino Thomas Claessens Philippe Dubois 《Marine pollution bulletin》2011,62(1):48-54
The effect of pH ranging from 8.0 to 6.8 (total scale - pHT) on fertilization, cleavage and larval development until pluteus stage was assessed in an intertidal temperate sea urchin. Gametes were obtained from adults collected in two contrasting tide pools, one showing a significant nocturnal pH decrease (lowest pHT = 7.4) and another where pH was more stable (lowest pHT = 7.8). The highest pHT at which significant effects on fertilization and cleavage were recorded was 7.6. On the contrary, larval development was only affected below pHT 7.4, a value equal or lower than that reported for several subtidal species. This suggests that sea urchins inhabiting stressful intertidal environments produce offspring that may better resist future ocean acidification. Moreover, at pHT 7.4, the fertilization rate of gametes whose progenitors came from the tide pool with higher pH decrease was significantly higher, indicating a possible acclimatization or adaptation of gametes to pH stress. 相似文献
2.
Virender K. Sharma Aurelie Moulin Frank J. Millero Concetta De Stefano 《Marine Chemistry》2006,99(1-4):52
The dissociation constants (pK1, pK2 and pK3) for cysteine have been measured in seawater as a function of temperature (5 to 45 °C) and salinity (S = 5 to 35). The seawater values were lower than the values in NaCl at the same ionic strength. In an attempt to understand these differences, we have made measurements of the constants in Na–Mg–Cl solutions at 25 °C. The measured values have been compared to those calculated from the Pitzer ionic interaction model. The lower values of pK3 in the Na–Mg–Cl solutions have been attributed to the formation of Mg2+ complexes with Cys2− anionsThe stability constants have been fitted toafter corrections are made for the interaction of Mg2+ with H+.The pK1 seawater measurements indicate that H3Cys+ interacts with SO42−. The Pitzer parameters β0(H3CysSO4), β1(H3CysSO4) and C(H3CysSO4) have been determined for this interaction. The formation of CaCys as well as MgCys are needed to account for the values of pK2 and pK3 in seawater.The consideration of the formation of MgCys and CaCys in seawater yields model calculated values of pK1, pK2 and pK3 that agree with the measured values to within the experimental error of the measurements. This study shows that it is important to consider all of the ionic interactions in natural waters when examining the dissociation of organic acids. 相似文献
Mg2+ + Cys2− = MgCys
3.
The influence of humic acids (HA) on the retention of Th(IV) onto the surface of Fe oxides has been investigated. Thorium (IV) is here considered as an analogue of tetravalent radionuclides (Zr, Hf, U, Np, Pu). Hematite (α–Fe2O3) and gœthite (α–FeOOH) have been chosen as model phases because of their widespread presence in the earth's crust. Retention experiments were performed by batch procedure at constant ionic strength and varying pH in the range 2–10; the HA concentration varied in the range 1–100 mg l−1. Compared with the former data obtained on the retention of Th(IV) with the same hematite sample free of HA, the study of a ternary system (i.e. hematite–HA–Th), clearly shows the influence of HA on the retention mechanisms of Th(IV) even in neutral to slightly alkaline medium. In particular, it is illustrated that the retention of Th(IV) onto Fe oxides closely depends upon the ratio between humic and surface (Fe oxide) sites. This ratio has to be greater than a critical value in order to impede the sorption of Th(IV). 相似文献
4.
M. N. Bouin D. Legain O. Traullé S. Belamari G. Caniaux A. Fiandrino F. Lagarde J. Barrié E. Moulin G. Bouhours 《Boundary-Layer Meteorology》2012,143(3):451-480
An extra large aperture scintillometer (XLAS) was used over several months across the Thau Lagoon (South of France) to retrieve
one-wavelength scintillation and, thence, sensible heat flux. We present the experiment with the XLAS, an eddy-covariance
station and meteorological stations measuring on or near the Thau Lagoon. Changes implemented to adapt the scintillometry
processing schemes to the above water conditions are presented together with a full error budget, including sensitivity tests
to the relevant parameters of the scintillometer processing scheme. The XLAS error budget amounts to 16% (systematic part)
±50% (random part). Sensible heat fluxes obtained using the XLAS under unstable atmospheric conditions are then compared to
eddy-covariance estimates used as a reference. The scintillometry technique proved to perform satisfactorily in such a watery
environment. Some discrepancies observed between the XLAS and eddy-covariance measurements were investigated according to
the lagoon fraction of the source area, to discriminate whether they were related to deviations from the Monin–Obukhov similarity
theory or to different atmospheric conditions at the respective instrument locations. Local atmospheric conditions agreed
well with the Monin–Obukhov similarity theory, especially measurements with source areas largely composed of the lagoon surface.
Retaining only the measurements with almost only the lagoon surface in the source area improved the agreement between the
XLAS and eddy-covariance measurements. The remaining discrepancies are interpreted as being due to significant location differences
between the two instruments, resulting in different atmospheric conditions, and to size differences in the source areas. 相似文献
5.
Abstract Alternative approaches to estimating monthly and annual potential evapotranspiration (PE) are explored in cases where daily climate data are not routinely recorded. A database consisting of data from 222 weather stations, representing a wide variety of climatic conditions, is used to draw general conclusions. In addition, two PE formulae with different data requirements are used: the standard FAO-56 Penman-Monteith equation, and a simple temperature-based equation. First, we tested the degree of bias introduced by using climate data averaged over long time periods instead of daily data. Second, we explored the sensitivity of PE estimation with respect to variations in sampling frequency of climate variables. The results show that using mean weather data has only a limited effect on monthly and annual PE estimates. Conversely, imperfect sampling of weather data may bias monthly and to a lesser extent annual PE estimates if the sampling period exceeds 5 and 10 days, respectively. Finally, we tested the impact of erroneous weather data on the simulations of annual actual evapotranspiration obtained with the Budyko model. The impact on the Budyko model outputs depends more on the dryness index of a given location than on annual PE; for regions under water stress, the errors in estimation of actual evapotranspiration are very limited, compared to humid regions where available energy is the dominating factor and the propagation of PE errors is important. Citation Oudin, L., Moulin, L., Bendjoudi, H. & Ribstein, P. (2010) Estimating potential evapotranspiration without continuous daily data: possible errors and impact on water balance simulations. Hydrol. Sci. J. 55(2), 209–222. 相似文献
6.
High‐resolution evolution of terrigenous sediment yields in the Provence Basin during the last 6 Ma: relation with climate and tectonics 
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下载免费PDF全文 Estelle Leroux Marina Rabineau Daniel Aslanian Christian Gorini Stéphane Molliex Francois Bache Cécile Robin Laurence Droz Maryline Moulin Jeffrey Poort Jean‐Loup Rubino Jean‐Pierre Suc 《Basin Research》2017,29(3):305-339
Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin. 相似文献
7.
Fractured archaeological glass blocks altered 1800 years in seawater are investigated because of their morphological analogy with vitrified nuclear waste. They provide an opportunity for understanding glass alteration in variable confined media (cracks), by studying an actual ancient system in a known stable natural environment. Characterization of the crack network from two-dimensional trace maps (length, alteration thickness, orientation) allows us to determine the three-dimensional geometric parameters (crack density, fracture ratio) and the percentage of alteration, using stereological relations. This methodology could be applied to nuclear glass. From a representative archaeological glass block, we showed that the surface developed by the cracks is 86 ± 27 times greater than the geometric surface but the volumetric alteration is 12.2 ± 4.1%, which is only 12 times greater than the volumetric alteration of the block periphery (about 1 vol%). This unexpected low value is explained by the large variation of the alteration thicknesses in the different types of cracks in relation with their location in the block. The alteration thickness is usually smaller in the internal zone than in the border zone. The alteration layers resulted from three main mechanisms (interdiffusion, glass dissolution, and secondary phase precipitation) leading to two different alteration products (a sodium-depleted layer and mainly a Mg-smectite). Geometric parameters such as the glass surface area/solution volume ratio and transport parameters (renewal of the alteration solution) strongly affected the glass dissolution kinetics. The confined conditions and the diffusive transport of reactive species favor low alteration kinetics. The precipitation of secondary phases also results in sealing of the cracks. Consequently, although it is not known if subcritical crack growth occurred, internal cracks account for only a minor contribution to the overall alteration. These results improve our understanding of alteration in cracks for assessing the predominant physical and chemical parameters that must be considered in long-term nuclear glass modeling. 相似文献
8.
Pascal Achim Marguerite Monfort Gilbert Le Petit Philippe Gross Guilhem Douysset Thomas Taffary Xavier Blanchard Christophe Moulin 《Pure and Applied Geophysics》2014,171(3-5):645-667
The present part of the publication (Part II) deals with long range dispersion of radionuclides emitted into the atmosphere during the Fukushima Dai-ichi accident that occurred after the March 11, 2011 tsunami. The first part (Part I) is dedicated to the accident features relying on radionuclide detections performed by monitoring stations of the Comprehensive Nuclear Test Ban Treaty Organization network. In this study, the emissions of the three fission products Cs-137, I-131 and Xe-133 are investigated. Regarding Xe-133, the total release is estimated to be of the order of 6 × 1018 Bq emitted during the explosions of units 1, 2 and 3. The total source term estimated gives a fraction of core inventory of about 8 × 1018 Bq at the time of reactors shutdown. This result suggests that at least 80 % of the core inventory has been released into the atmosphere and indicates a broad meltdown of reactor cores. Total atmospheric releases of Cs-137 and I-131 aerosols are estimated to be 1016 and 1017 Bq, respectively. By neglecting gas/particulate conversion phenomena, the total release of I-131 (gas + aerosol) could be estimated to be 4 × 1017 Bq. Atmospheric transport simulations suggest that the main air emissions have occurred during the events of March 14, 2011 (UTC) and that no major release occurred after March 23. The radioactivity emitted into the atmosphere could represent 10 % of the Chernobyl accident releases for I-131 and Cs-137. 相似文献
9.
Despite the abundance of large wood (LW) river studies there is still a lack of understanding of LW transport dynamics on large low gradient rivers. This study used 290 radio frequency identification tagged (RFID) LW and 54 metal (aluminum) tagged LW, to quantify the percent of in‐channel LW that moves per year and what variables play a role in LW transport dynamics. Aluminum tags were installed and monitored on LW in‐transit during the rising limb of a flood, the mean distance traveled by those pieces during the week was 13.3 river kilometers (km) with a maximum distance of 72 km. RFID tagged LW moved a mean of 11.9 km/yr with a maximum observed at 101.1 km/yr. Approximately 41% of LW low on the bank moves per year. The high rate of transport and distance traveled is likely due to the lack of interaction between LW floating in the channel and the channel boundaries, caused primarily by the width of the channel relative to length of the LW. Approximately 80% of the RFID tags moved past a fixed reader during the highest 20% of river stage per year. LW transport and logjam dynamics are complicated at high flows as pieces form temporary jams that continually expand and contract. Unlike most other studies, key members that create a logjam were defined more by stability than jam size or channel/hydrologic conditions. Finally, using an existing geomorphic database for the river, and data from this study, we were able to develop a comprehensive LW budget showing that 5% of the in‐channel LW population turns over each year (input from mass wasting and fluvial erosion equals burial, decomposition, and export out of system) and another 16% of the population moving within the system. Published 2013. This article is a U.S. Government work and is in the public domain in the USA. 相似文献
10.
Hossein Ghaffarian Hervé Piégay Diego Lopez Nicolas Rivière Bruce MacVicar Aurelie Antonio Emmanuel Mignot 《地球表面变化过程与地形》2020,45(10):2219-2234
Wood in rivers plays a major role both ecologically and morphologically. In recent decades, due to human activities in the river channels and along the riparian zone, wood obstruction and jamming has exacerbated flooding hazards and infrastructure damage. Therefore, it is necessary to quantify the wood flux and discharge in rivers to improve wood hazard management. Among the various methods for monitoring the wood flux in a river, the streamside videography technique is effective given its high temporal and spatial resolution. Previous work monitored the wood discharge (m3/s) using this technique in the Ain River (France) during three floods (MacVicar and Piégay, 2012), and the same method is implemented on the Isère River (France) to obtain the statistics of wood discharge for two floods. Comparison between the two sites supports the generalization of both the monitoring technique and the link between wood discharge and flood characteristics. We first show that the maximum wood discharge is observed at bankfull discharge, and we confirm the three stage model proposed by MacVicar and Piégay (2012). Additionally, transverse distributions of the number of wood pieces and corresponding wood length appear to be similar for different flood magnitudes on each site. As a technical contribution, the use of the same technique on two sites allows for recommendations on key decisions related to the location and implementation of the equipment. Both statistical and technical contributions can be used by decision makers to implement this monitoring technique, acquire the wood transport parameters, and evaluate the potential wood hazards at local scale or along a river. © 2020 John Wiley & Sons, Ltd. 相似文献