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1.
Dissolved Al carried in river water apparently undergoes a fractional removal at the early stages of mixing in the Conway estuary. On the other hand, dissolved Al behaves almost conservatively in high salinity (>13) estuarine waters. In order to understand the geochemistry of Al in these estuarine waters, simple empirical sorption models have been used. Partitioning of Al occurs between solid and solution phases with a distribution coefficient, Kd, which varies from 0.67 × 105 to 3.38 × 106 ml g−1 for suspended particle concentrations of 2–64 mg l−1. The Kd values in general decrease with increasing suspended particulate matter and this tendency termed the “particle concentration effect” is quite pronounced in these waters. The sorption model derived by previous workers for predicting concentrations of dissolved Al with changing suspended sediment loads has been applied to these data. Reasonable fits are obtained for Kd values of 105, 106 and 107 ml g−1 with various values of α. Further, a sorption model is proposed for particulate Al concentrations in these waters that fits the data extremely well defined by a zone with Kd value 107 ml g−1 and C0 values 16 × 10−6 mg ml−1 and 92 × 10−6 mg ml−1. These observations provide strong evidence of sorption processes as key mechanisms influencing the distribution of dissolved and particulate Al in the Conway estuary and present new insight into Al geochemistry in estuaries.  相似文献   

2.
A video plankton recorder (VPR) and a remotely operated vehicle (ROV) were utilized on three cruises in the oligotrophic North Pacific Subtropical Gyre (NPSG) between 1995 and 2002 to quantify the size and abundance of marine snow and Rhizosolenia diatom mats within the upper 305 m of the water column. Quantitative image analysis of video collected by the VPR and an ROV-mounted particle imaging system provides the first transect of marine snow size and abundance across the central North Pacific Gyre extending from 920 km NW of Oahu to 555 km off Southern California. Snow abundance in the upper 55 m was surprisingly high for this oligotrophic region, with peak values of 6.0–13.0×103 aggregates m−3 at the western- and easternmost stations. At stations located in the middle of the transect (farthest from HI and CA), upper water column snow abundance displayed values of 0.5–1.0×103 aggregates m−3. VPR and ROV imagery also provided in situ documentation of the presence of nitrogen-transporting, vertically migrating Rhizosolenia mats from the surface to >300 m with mat abundances ranging from 0 to 10 mats m−3. There was clear evidence that Rhizosolenia mats commonly reach sub-nutricline depths. The mats were noted to be a common feature in the North Pacific Gyre, with the lower salinity edge of the California Current appearing to be the easternmost extent of their oceanic distribution. Based on ROV observations at depth, flux by large (1.5 cm) mats is revised upward 4.5-fold, yielding an average value of 40 μmol N m−2 d−1, a value equaling previous estimates that included much smaller mats visible only to towed optical systems. Our results suggest that the occurrence across a broad region of the NPSG of particulate organic matter production events represented by high concentrations of Rhizosolenia mats, associated mesozooplankton, and abundant detrital marine aggregates may represent significant stochastic components in the overall carbon, nitrogen, and silica budgets of the oligotrophic subtropical gyre. Likewise, their presence has important implications for the proposed climate-driven, ecosystem reorganization or domain shift occurring in the NPSG.  相似文献   

3.
A liquid-liquid partition, ligand exchange procedure involving the formation of copper(II) complexes with acetylacetone is presented for the determination of stability constants and concentrations of copper chelators in seawater. Acetylacetone competes with natural ligands for copper, and the equilibrium concentration of the copper acetylacetonate complex is used in speciation calculations. The concentration of the complex is calculated by partitioning a fraction of it into an organic phase and determining the total Cu concentration in that phase by back extracting with acid, and analyzing by flameless atomic absorption spectroscopy. The concentration of Cu acetylacetonate in seawater in equilibrium with the organic phase is calculated from the partition coefficient. The simple, thermodynamically well characterized procedure offers several advantages over previous techniques. Studies using organic free seawater and model ligands show good agreement between experimental and calculated conditional stability constants. Studies from seawater in Biscayne Bay, Florida, indicate two ligand types are present; type 1, K1 = 1.2 × 1012, CL1 = 5.1 × 10−9 M; type 2, K2 = 2.8 × 1010, CL2 = 1.1 × 10−7 M. Speciation is dominated by ligand type 1. Depth profiles of [Cu(II)]free/[Cu(II)]total measured with the procedure at ambient copper concentrations show an increase from < 5 × 10−5 at 50–60 m to > 1 × 10−3 at the surface at two stations off the Florida coast.  相似文献   

4.
Measurements of plankton respiration and heterotrophic bacterial abundance and production were made at seven deep water stations within the upper 500 m of the Gulf of Mexico during the summer of 1995. Bacterial abundance [(1.1–4.6)×108 1−1] and rates of bacterial production (2–19 nM C h−1) and plankton respiration (50–245 nM O2 h−1) decreased with depth by four- to nine-fold, and were similar to those reported for oligotrophic waters. Bacterial turnover times increased with depth from approximately 1 to 5 days. Bacterial growth efficiencies decreased from 15% at the surface to 8% at 500 m. Depth-integrated plankton respiration exceeded known estimates of primary production for the region, suggesting that heterotrophic utilization of previously and concurrently produced organic matter (e.g. spring phytoplankton growth, and summer blooms of Trichodesmium sp.) was occurring during the summer. Estimates for the upper 500 m showed that roughly half of the bacterial biomass (56%), bacterial production (49%), and plankton respiration (60%) occurred below the euphotic zone. Routine oceanographic studies have focused exclusively on the metabolic activity occurring within the euphotic zone. Our measurements, however, indicate that mesopelagic plankton also contribute substantially to heterotrophic metabolism and nutrient cycling in the ocean.  相似文献   

5.
The acute lethality and sublethal heavy metal contamination potential to marine organisms of a waste brine solution from a potash mining operation were determined. The brine was acutely lethal to marine organisms of the Bay of Fundy, Canada, at concentrations between 47 and 55‰ salinity (96-h LC50 values: threespine stickleback, Gasterosteus aculeatus, 47·7‰; polychaete worm, Nephtys incisa, 52·5‰; blue mussel, Mytilus edulis, lethal to whole animal and reduced ciliary activity of gills above 55‰).The brine diluted to sublethal concentrations (≤40‰) contained manganese (≤ 49·5 ×), copper and zinc (≤ 5·2 ×), lead (≤ 2·6 ×) and cadmium (≤ 0·7 ×) in decreasing order of enrichment relative to control seawater. Copper was accumulated in mussels exposed to these solutions over 44 days to the greatest degree (4 ·4 ×), followed by manganese and lead. Tissue lead concentration reached a steady value within 44 days and cadmium was not accumulated.  相似文献   

6.
The “Wind Events and Shelf Transport” (WEST) program was an interdisciplinary study of coastal upwelling off northern California in 2000–03. WEST was comprised of modeling and field observations. The primary goal of WEST was to better describe and understand the competing influences of wind forcing on planktonic productivity in coastal waters. While increased upwelling-favorable winds lead to increased nutrient supply, they also result in reduced light exposure due to deeper surface mixed layers and increased advective loss of plankton from coastal waters. The key to understanding high levels of productivity, amidst these competing responses to wind forcing, is the temporal and spatial structure of upwelling. Temporal fluctuations and spatial patterns allow strong upwelling that favors nutrient delivery to be juxtaposed with less energetic conditions that favor stratification and plankton blooms. Observations of winds, ocean circulation, nutrients, phytoplankton and zooplankton off Bodega Bay and Point Reyes (38°N) were combined with model studies of winds, circulation and productivity. This overview of the WEST program provides an introduction to the WEST special issue of Deep-Sea Research, including the motivation for WEST, a summary of study components, an integrative synthesis of major research results to-date, and background on conditions during field studies in May–June 2001 (the upwelling period on which this special issue is focused).  相似文献   

7.
A key goal of the Western Arctic Shelf Basin Interactions program is to understand how physical and biological processes together impact shelf–basin exchange of biological, chemical, and physical properties. High-resolution vertical distributions of plankton and particles were obtained using an Auto Video Plankton Recorder from 29 locations on the Chukchi Shelf, in the deep Beaufort Sea, and across the Beaufort–Chukchi Shelf-break during a cruise on the USCGC Healy in July–August, 2002. Coincident velocity estimates were collected using hull-mounted acoustic Doppler current profilers. Images of plankton and particles were extracted automatically and identified manually to taxa and type. Copepods, diatom chains, decaying diatoms, marine snow, and radiolarians were the most abundant categories observed. Distinct regional differences in abundance were observed that were associated with different oceanographic regimes and with the prevailing circulation in the region. Vertical distributions were closely associated with the physical structure of the water column. A sharp horizontal discontinuity in abundance of all categories between shelf and basin was observed, located over the shelf break and potentially established and maintained by transport of plankton and particles along-shelf to the east rather than northwards towards the basin. Barrow Canyon and the shelf and shelf-break east of Barrow Canyon had very high concentrations of plankton and particles, especially marine snow, that may have resulted from elevated production on the eastern Chukchi Shelf that subsequently was advected out of Barrow Canyon and to the east. Comparisons of downward flux, estimated from particle sinking rates based on individual marine snow particle size, and horizontal velocities suggested that much of the marine snow carbon was sinking to the benthos of the Chukchi Sea prior to being advected off-shelf. Velocities and plankton concentrations together indicated that little off-shelf flux of plankton or particles to the basin was occurring except in an eddy located off of the Beaufort Shelf.  相似文献   

8.
Southwest Pacific subtropical mode water: A climatology   总被引：1，自引：0，他引：1  
The large-scale distribution and changes in Southwest Pacific subtropical mode water (STMW) are investigated and discussed. The paper presents for the first time geographic maps showing the spatial distribution of STMW thicknesses, with a vertical temperature gradient <2.0 °C/100 m occupying the 14–20 °C range below the mixed layer depth, across the entire Southwest Pacific region. STMW changes in areal thickness extent, vertical cross-sectional area along selected transects, and total volume, are examined on seasonal and interannual time scales between 1973 and 1988.We find that STMW extends across the entire width of the Tasman Sea in a very broad swath between the Tropical Convergence in the north (just to the south of New Caledonia), the southeast Australian coast in the west to as far south as 39°S (likely due to the southward extension of the EAC), and eastwards along the Southern STMW boundary in a meandering pathway that broadly follows the Tasman Front. The total STMW volume across the region (i.e., west of 180°) varies seasonally by a factor of more than three between the estimated maximum of 6.6 (±0.5) × 1014 m3 in October and minimum of 1.9 (±0.4) × 1014 m3 in May. Interannual variations O (±0.5 × 1014 m3) are also observed in the spatial extent of the thick mode water and its total volume. El Niño composite maps show an anomalous thickening of the STMW during the El Niño year with October positive thickness anomalies in excess of +20 m (total volume anomaly of +0.6 × 1014 m3) manifested throughout the subtropical gyre interior as far north as New Caledonia. Total volume anomalies tend to be positive from January of the El Niño year through to the July following (18 months). The maximum correlation coefficient r = −0.3 between 3-monthly STMW volume anomalies and the Southern Oscillation index is statistically significant at the 95% confidence level. We conclude that during the anomalous cooling of the upper Southwest Pacific Ocean in the El Niño year, winter-time convection and STMW formation is enhanced across the region resulting in an El Niño – Southern Oscillation climate signal that is identifiable below the mixed layer by the increased STMW volume which persists through to the following winter. Finally, some evidence for the possible decadal modulation of the STMW variability is also discussed.  相似文献   

9.
印度洋浮游生态系统的特点及其对全球变暖的响应   总被引：1，自引：0，他引：1  
与太平洋和大西洋相比,印度洋有独特的季风和洋流系统和由此驱动的浮游生物分布及生产规律.在全球变暖的背景下,印度洋的变暖趋势比太平洋和大西洋更为显著,是研究变暖对海洋浮游生态系统影响的热点海区之一.文章结合国内外文献,评述印度洋浮游生态系统的现状、特点及对全球变暖的响应,包括印度洋的浮游生物地理分布、南北印度洋浮游生态系...  相似文献   

10.
A batch sorption technique for the determination of particle–water interactions of hydrophobic organic micropollutants under simulated estuarine conditions is described. Results are presented for the behaviour of 2,2′,5,5′-tetrachlorobiphenyl (2,2′,5,5′-TCB) in river and sea waters, both in the presence and absence of estuarine suspended particles. Adsorption onto particles in sea water was enhanced compared with adsorption in river water owing to salting out of the compound, and possibly of the particulate organic matter, in the presence of high concentrations of dissolved ions. The particle–water distribution coefficient, KD, decreased from about 120×103 to 10×103 ml g−1, and from about 150×103 to 20×103 ml g−1, in river water and sea water, respectively, over a particle concentration range of 10–1000 mg l−1. Incomplete recovery of compound from the reactor walls is partly responsible for a particle concentration effect, while artefacts relating to inadequate sediment and water phase separation were ruled out following further experiments. The particle concentration effect, which is replicated in many field studies of hydrophobic organic micropollutants, including 2,2′,5,5′-TCB, is incorporated into a simple partitioning model and is discussed in the context of the likely estuarine behaviour of such compounds.  相似文献   

11.
The distribution and abundance of viable and non-viable (so-called resting eggs) embryos of the calanoid copepod Tortanus forcipatus were determined in the laboratory by the enumeration of nauplii that emerge from sediments collected in Victoria Harbor (Hong Kong). Sediment cores sliced down to a depth of 37 cm showed the highest number of viable resting eggs near the surface layer (0–5 cm). The number of viable eggs sharply decreased with sediment depth, particularly at the inner harbor stations, although diapause eggs remained viable as deep as 25 cm. 210Pb analyses of the sediments indicated that the mean egg age was 4.9 years. The egg mortality of T. forcipatus in the sediments was 0.135 year−1, or 78.22% annual egg survival, calculated by regressing ln (egg density) from sediment age. The range of horizontal distribution of viable resting eggs was 24.25 × 103–58.90 × 103 m−2, with a mean value of 36.8 × 103 m−2 over all stations. The accumulation of viable resting eggs that can persist for an extended period of time provided evidence for the existence of an egg bank of T. forcipatus in the sediments of Victoria Harbor.  相似文献   

12.
The spreading of water of Mediterranean origin west of the Iberian Peninsula was studied with hydrographic data from several recent cruises and current measurements from the BORD-EST programme. The vertical breakdown of the “Mediterranean salt” content reveals the dominant contribution of the so-called lower core of the outflow (60%), and the significant fraction (22%) brought downward to levels below 1500 m by diffusion. Intense salinity maxima in the upper core (18%) are only encountered south of 38°N in the vein flowing northward along the continental slope, and at a few stations in the deep ocean. Apart from the coastally trapped vein, other preferred paths of the water mass are revealed by the horizontal distributions of salinity maximum and Mediterranean Water percentage. One is southward, west of the Gorringe Bank, and two northwestward ones lie around 40°N and west of the Galicia Bank. Year-long velocity measurements in the Tagus Basin show westward mean values of 7 × 10−2 m s−1 at 1000 m associated with a very intense mesoscale variability. This variability is related to the pronounced dynamical signature of the outflow which favours instability in any branch having detached from the slope current. From a mixing point of view, the strong interleaving activity occurring near Cape St-Vincent is illustrated, but its contribution to the downstream salinity decrease in the coastally trapped vein is weak. Current and meddy detachment play the dominant role, with a scaling estimate of their associated lateral diffusivity of order 500 m2 s−1. The statistical distribution of the density ratio parameter, which governs double-diffusion at the base of the Mediterranean Water, was found to be very tight around Rπ = 1.3 in the temperature range of 5°C< φ < 8°C. North of 40°N, the presence of a fraction of Labrador Sea Water in the underlying water is shown to decrease that parameter and should favour the formation of salt fingers.  相似文献   

13.
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14.
The present study extends the investigations of the hydrodynamic forces on a cylinder, laid on, or partly buried in the bed. They were determined by measuring the pressure distribution on the cylinder surface in the case of steady current, waves and coexisting flow. The pressure distribution around the cylinder was measured by using pressure transducers, which were replaced in the cylinder. Force coefficients were obtained for the ranges of Re=0.8×104–1.5×104, for steady current, low KC numbers (KC<5) for wave alone case and, for current-to-wave velocity RATIO=0, 3, 6 and infinity (current) for coexisting flow. The forces were also determined for the various burial-depth-to-diameter ratios between 0 and 0.7 values of the cylinder.  相似文献   

15.
The distributions, contamination status and annual sedimentation flux of trace metals in surface sediments of the East China Sea (ECS) were studied. Higher concentrations of the studied metals were generally found in the inner shelf and the concentrations decreased seaward. The sequences of the enrichment factor (EF) of the studied metals are Cu > Mn > Ni > Zn > Pb > Fe. The values of EF suggest that the metals contamination in the middle and outer shelves of the ECS is still minor. The annual sedimentation fluxes of trace metals in the ECS were: Fe, 3.48 × 107 t/y; Mn, 9.07 × 105 t/y; Zn, 1.08 × 105 t/y; Ni, 4.48 × 104 t/y; Pb, 4.32 × 104 t/y and Cu, 3.1 × 104 t/y, respectively. Approximately 55–70% and 10–17% of the sedimentation fluxes of trace metals were deposited in the inner shelf and the Changjiang estuarine zone.  相似文献   

16.
The study of the distribution of biomass by size provides an ataxonomic approach for analyzing the structure of the pelagic ecosystem. However, empirical data regarding planktonic size-structure in offshore areas are scarce. Here, we report the results of a study of the planktonic biomass size-distribution at several stations located within two regions (Sargasso Sea and New England Seamounts Area) of the Northwest Atlantic. The biomass size-spectra covered a body-size range from bacteria to mesozooplankton and a depth range from the surface to 400 m. It is shown that the slope of the normalized biomass size-spectrum (NBS-spectrum) varies depending on whether volume or carbon units are used. The transformation from volume to carbon units makes the slope of the NBS-spectrum approximately 0.15 units more negative. The distribution of normalized-biomass by size was linear (plotted on a log–log scale) at all stations. The slopes of the NBS-spectra (volume scale) ranged from −0.96 to −1.01. There were no significant differences among the slopes of the NBS-spectra within either of the two areas studied. In addition, no significant differences were detected between the stations in the Sargasso Sea and those located in the New England Seamounts area. Apart from a tendency towards a decrease in the intercept of the normalized-biomass axis of the size-spectra in deeper waters, the NBS-spectra were also very similar through depth. The slopes of the NBS-spectra in biovolume units are not significantly different from −1.0 (p<0.01), and therefore are in agreement with Sheldon’s Linear Biomass Hypothesis. By contrast, the slopes of the NBS-spectra in carbon units are significantly different (p<0.01) from −1.0 (range=–1.09 to –1.17; all stations TOGETHER=–1.14) and their numerical values are in close agreement with Platt and Denman’s model and with the findings of [Rodríguez and Mullin, 1986a]) for the North Pacific Central Gyre. The results of this study support the hypothesis that the planktonic size-structure of offshore oligotrophic systems is a conservative property.  相似文献   

17.
In May and September 1999 11 stations were sampled in the southern and central North Sea, located in the German Bight, eastern Oyster Ground and Dogger Bank. The study focused on the influence of particle mixing on transport of chlorophyll a to deeper sediment layers and vertical bacterial distribution (max. DEPTH=10 cm). The sampling stations were chosen to reflect a gradient in environmental conditions in the North Sea. The sampling stations differed in respect to redox potential (eH up to −243 mV in the German Bight and up to 274 mV in the offshore regions), silt content (up to 54% in the German Bight and 0·34% at the northern Dogger Bank) and different proportion of fresh organic material on total organic matter content (C/N ratios ranging from 9·27 in the German Bight up to 1·72 in the offshore sediments). Although bacterial densities (8·55×109 g−1in the German Bight up to 0·35×109 g−1in offshore sediments) were significantly correlated to chlorophyll a content in the sediment (P<0·01), inconsistencies in the temporal pattern of both variables in the surficial sediment layer suggested, that the dynamics of bacterial densities is generally controlled by food supply but also by other variables. The chlorophyll a content in the surficial sediments of the German Bight (up to 1·84 μg g−1) was significantly higher than in the Oyster Ground (up to 0·58 μg g−1) and the Dogger Bank area (up to 0·68 μg g−1). With increasing chlorophyll a input to the benthic realm a subsequent enhanced burial of this compound into deeper sediment layers was expected either by biological (bioturbation) or by physical sediment mixing. However, the vertical profile of chlorophyll a decreased steeply in the sediments of the German Bight. Contrary, subsurface peaks were measured in the offshore areas. It was concluded from these results, that the vertical distribution of organic matter in sediments is less limited by the quantitative input from the water column but concomitant with particle mixing itself. The extent and possible mechanisms of particle mixing in the different study areas in relation to specific environmental factors is discussed.  相似文献   

18.
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19.
A three-dimensional σ-coordinate ocean model with realistic forcing is used to derive and compare flushing time, residence time and water age distributions in Bass Strait, a broad shallow shelf sea in south-eastern Australia which exhibits seasonal variation in water mass properties and circulation. Results illustrate flushing out of most old water occurs each winter–spring period and the circulation in summer increases age of remnant older water in the Strait. A correlation between water age and salinity is found in winter which is the result of advective “erosion” of the interior water mass. The presence of an area in the south-eastern part of the interior with low flushing is suggested to result from a number of physical factors including the presence of quasi-stationary eddies which entrain age, leading to relatively older water residing there.  相似文献   

20.
Analyses of the concentration product (Ca2+) × (CO32−) in the pore waters of marine sediments have been used to estimate the apparent solubility products of sedimentary calcite (K′SPc) and aragonite (K′SPa) in seawater. Regression of the data gives the relation In K′PSPc = 1.94 × 10−3 δP − 14.59 The 2°C, 1 atm value of K′SPc is, then, 4.61 × 10−7 mol2 l−2. The pressure coefficient yields a at 2°C of −43.8 cm3 atm−1. A single station where aragonite is present in the sediments gives a value of K′SPa = 9.2 × 10−7 (4°C, 81 atm). The calcite data are very similar to those determined experimentally by Ingle et al. (1973) for K′SPc at 2°C and 1 atm. The calculated is also indistinguishable from the experimental results of Ingle (1975) if is assumed to be independent of pressure.  相似文献   

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