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1.
For the growth and departure of bubbles from an orifice, a free energy lattice Boltzmann model is adopted to deal with this complex multiphase flow phenomenon. A virtual layer is set at the boundary of the flow domain to deal with the no-slip boundary condition. Effects of the viscosity, surface tension, gas inertial force and buoyancy on the characteristics of bubbles when they grow and departure from an orifice in quiescent liquid are studied. The releasing period and departure diameter of the bubble are influenced by the residual gas at the orifice, and the interaction between bubbles is taken into consideration. The relations between the releasing period or departure diameter and the gravity acceleration show fair agreements with previous numerical and theoretical results. And the influence of the gas outflow velocity on bubble formation is discussed as well. For the bubbles growing in cross-flow field, effects of the cross-flow speed and the gas outflow velocity on the bubble formation are discussed, which is related to the application in ship resistance reduction. And optimal choice of the ship speed and gas outflow velocity is studied. Cases in this paper also prove that this high density ratio LBM model has its flexibility and effectiveness on multiphase flow simulations.  相似文献   

2.
Natural hydrocarbon seeps in a marine environment are one of the important contributors to greenhouse gases in the atmosphere,including methane,which is significant to the global carbon cycling and climate change.Four hydrocarbon seep areas,the Lingtou Promontory,the Yinggehai Rivulet mouth,the Yazhou Bay and the Nanshan Promontory,occurring in the Yinggehai Basin delineate a near-shore gas bubble zone.The gas composition and geochemistry of venting bubbles and the spatial distribution of hydrocarbon seeps are surveyed on the near-shore Lingtou Promontory.The gas composition of the venting bubbles is mainly composed of CO_2,CH_4,N_2 and O_2,with minor amounts of non-methane hydrocarbons.The difference in the bubbles' composition is a possible consequence of gas exchange during bubble ascent.The seepage gases from the seafloor are characterized by a high CO_2 content(67.35%) and relatively positive δ~(13)C_(V_PDB) values(-0.49×10~(-3)-0.86×10~(-3)),indicating that the CO_2 is of inorganic origin.The relatively low CH_4 content(23%) and their negative δ~(13)C_(V-PDB) values(-34.43×10~(-3)--37.53×10~(-3)) and high ratios of C_1 content to C_(1-5) one(0.98-0.99)as well point to thermogenic gases.The hydrocarbon seeps on the 3.5 Hz sub-bottom profile display a linear arrangement and are sub-parallel to the No.1 fault,suggesting that the hydrocarbon seeps may be associated with fracture activity or weak zones and that the seepage gases migrate laterally from the central depression of the Yinggehai Basin.  相似文献   

3.
Cold seeps are pervasive along the continental margin worldwide,and are recognized as hotspots for elemental cycling pathway on Earth.In this study,analyses of pore water geochemical compositions of one-400 cm piston core(S3) and the application of a mass balance model are conducted to assess methane-associated biogeochemical reactions and uncover the relationship of methane in shallow sediment with gas hydrate reservoir at the Makran accretionary wedge off Pakistan.The results revealed that approximately 77% of sulfate is consumed by the predominant biogeochemical process of anaerobic oxidation of methane.However,the estimated sulfate-methane interface depth is-400 cm below sea floor with the methane diffusive flux of 0.039 mol/(m~2·a),suggesting the activity of methane seepage.Based on the δ~(13)C_(DIC) mass balance model combined with the contribution proportion of different dissolved inorganic carbon sources,this study calculated the δ~(13)C of the exogenous methane to be-57.9‰,indicating that the exogenous methane may be a mixture source,including thermogenic and biogenic methane.The study of pore water geochemistry at Makran accretionary wedge off Pakistan may have considerable implications for understanding the specific details on the dynamics of methane in cold seeps and provide important evidence for the potential occurrence of subsurface gas hydrate in this area.  相似文献   

4.
The methane concentration of water samples at five stations collected by the CTD rosette water sampler in the areas of southwest Dongsha Islands and the Xisha Trough was analyzed by the gas-stripping method on aboard ship. It shows abnormal high methane concentrations in near bottom water samples at three stations. In the southwest Dongsha Islands area, the methane conc.entration of 4. 25 and 10. 64 nmol/dm3 occurs in near bottom water samples at Stas E105A and El06, respectively. In the Xisha Trough area, the high methane concentrations of 5. 17, 8.48 and 8.70 nmol/dm3 in water depths of 1 750, 1 900 and 2 050 m, respectively, have been observed at Sta. F413. It is believed that the abnormal high methane concentrations are generated from the leakage of methane from sediments. Combining with previous geophysical and geochemical data from these two areas, this was probably related to the submarine gas hydrates decomposition and cold seep system. In May 2007, gas hydrate samples were successfully obtained by the drilling in the Shenhu Sea area located in the southwest Dongsha Islands area. It is called for further drilling surveys to confirm the existence of gas hydrate and cold seep system in the Xisha Trough as early as possible.  相似文献   

5.
The Taixinan Basin is one of the most potential gas hydrate bearing areas in the South China Sea and abundant gas hydrates have been discovered during expedition in 2013. In this study, geochemical and microbial methods are combinedly used to characterize the sediments from a shallow piston Core DH_CL_11(gas hydrate free) and a gas hydrate-bearing drilling Core GMGS2-16 in this basin. Geochemical analyses indicate that anaerobic oxidation of methane(AOM) which is speculated to be linked to the ongoing gas hydrate dissociation is taking place in Core DH_CL_11 at deep. For Core GMGS2-16, AOM related to past episodes of methane seepage are suggested to dominate during its diagenetic process; while the relatively enriched δ18O bulk-sediment values indicate that methane involved in AOM might be released from the "episodic dissociation" of gas hydrate.Microbial analyses indicate that the predominant phyla in the bacterial communities are Firmicutes and Proteobacteria(Gammaproteobacteria and Epsilonproteobacteria), while the dominant taxa in the archaeal communities are Marine_Benthic_Group_B(MBGB), Halobacteria, Thermoplasmata, Methanobacteria,Methanomicrobia, Group C3 and MCG. Under parallel experimental operations, comparable dominant members(Firmicutes and MBGB) are found in the piston Core DH_CL_11 and the near surface layer of the long drilling Core GMGS2-16. Moreover, these members have been found predominant in other known gas hydrate bearing cores, and the dominant of MBGB has even been found significantly related to gas hydrate occurrence. Therefore,a high possibility for the existing of gas hydrate underlying Core DH_CL_11 is inferred, which is consistent with the geochemical analyses. In all, combined geochemical and microbiological analyses are more informative in characterizing sediments from gas hydrate-associated areas in the South China Sea.  相似文献   

6.
A new approach to high-order Boussinesq-type equations with ambient currents is presented. The current velocity is assumed to be uniform over depth and of the same magnitude as the shallow water wave celerity. The wave velocity field is expressed in terms of the horizontal and vertical wave velocity components at an arbitrary water depth level. Linear operators are introduced to improve the accuracy of the kinematic condition at the sea bottom. The dynamic and kinematic conditions at the free surface are expressed in terms of wave velocity variables defined directly on the free surface. The new equations provide high accuracy of linear properties as well as nonlinear properties from shallow to deep water, and extend the applicable range of relative water depth in the case of opposing currents.  相似文献   

7.
南海北部大陆边缘天然气水合物稳定带厚度的地热学研究   总被引:1,自引:1,他引:0  
The exploration of unconventional and/or new energy resources has become the focus of energy research worldwide,given the shortage of fossil fuels.As a potential energy resource,gas hydrate exists only in the environment of high pressure and low temperature,mainly distributing in the sediments of the seafloor in the continental margins and the permafrost zones in land.The accurate determination of the thickness of gas hydrate stability zone is essential yet challenging in the assessment of the exploitation potential.The majority of previous studies obtain this thickness by detecting the bottom simulating reflectors(BSRs) layer on the seismic profiles.The phase equilibrium between gas hydrate stable state with its temperature and pressure provides an opportunity to derive the thickness with the geothermal method.Based on the latest geothermal dataset,we calculated the thickness of the gas hydrate stability zone(GHSZ) in the north continental margin of the South China Sea.Our results indicate that the thicknesses of gas hydrate stability zone vary greatly in different areas of the northern margin of the South China Sea.The thickness mainly concentrates on 200–300 m and distributes in the southwestern and eastern areas with belt-like shape.We further confirmed a certain relationship between the GHSZ thickness and factors such as heat flow and water depth.The thickness of gas hydrate stability zone is found to be large where the heat flow is relatively low.The GHSZ thickness increases with the increase of the water depth,but it tends to stay steady when the water depth deeper than 3 000 m.The findings would improve the assessment of gas hydrate resource potential in the South China Sea.  相似文献   

8.
A new off-axis integrated cavity output spectroscopy(ICOS) is coupled to Weiss equilibrator for continuous highresolution dissolved methane measurement in the surface ocean. The time constant for the equilibrator in freshwater at room temperature is determined via dis-equilibration and re-equilibration experiments. The constant for methane is about 40 min. The system is calibrated using a standard gas of 3.980×10–6, and the precision of the ICOS for methane is 0.07%. This system is equipped onboard to measure the spatial distribution in methane concentrations of South Yellow Sea(SYS) along the cruise track from Shanghai to Qingdao. Result shows that the methane concentration varies from 2.79 to 36.36 nmol/L, reveals a significant pattern of methane source in SYS, and a distinct decreasing trend from south to north. The peak value occurs at the coast area outside mouth of the Changjiang River, likely to be affected by the Changjiang diluted water mass dissolving a large amount of rich in methane. Moreover, all the surface waters are oversaturated, air-to-sea fluxes range from 98.59 to 5 485.35 μmol/(m2·d)(average value(1 169.74±1 398.46) μmol/(m2·d)), indicating a source region for methane to the atmosphere. Key words: methane, equilibrator, off-axis integrated cavity output spectroscopy(ICOS), South Yellow Sea  相似文献   

9.
The natural gas generation process is simulated by heating source rocks of the Yacheng Formation, including the onshore-offshore mudstone and coal with kerogens of Type II_2-III in the Qiongdongnan Basin. The aim is to quantify the natural gas generation from the Yacheng Formation and to evaluate the geological prediction and kinetic parameters using an optimization procedure based on the basin modeling of the shallow-water area. For this, the hydrocarbons produced have been grouped into four classes(C_1, C_2, C_3 and C_(4-6)). The results show that the onset temperature of methane generation is predicted to occur at 110℃ during the thermal history of sediments since 5.3 Ma by using data extrapolation. The hydrocarbon potential for ethane, propane and heavy gaseous hydrocarbons(C_(4-6)) is found to be almost exhausted at geological temperature of 200℃ when the transformation ratio(TR) is over 0.8, but for which methane is determined to be about 0.5 in the shallow-water area. In contrast, the end temperature of the methane generation in the deep-water area was over 300℃ with a TR over 0.8. It plays an important role in the natural gas exploration of the deep-water basin and other basins in the broad ocean areas of China. Therefore, the natural gas exploration for the deep-water area in the Qiongdongnan Basin shall first aim at the structural traps in the Ledong, Lingshui and Beijiao sags, and in the forward direction of the structure around the sags, and then gradually develop toward the non-structural trap in the deep-water area basin of the broad ocean areas of China.  相似文献   

10.
An attenuation depth is defined for remote sensing purposes as a depth above which 90% of the arising light leaving the water surface is originated.The deeper the attenuation depth,the more information of water is detectable by remote sensing,then the more precise information of water is extracted.Meanwhile,the attenuation depth is helpful to know water layer (by its thickness) from which remote sensing will be able to extract information.A number of investigators are using the moderate resolution imaging spectroradiometer (or MODIS) for remote sensing of ocean color.It is necessary to have a rough idea of the effective attenuation depth of imagery in each of the spectral bands employed by the MODIS.The attenuation depth is directly determined from MODIS data.Though analyzing the spectral distribution of the attenuation depth on 7 August 2003 and the seasonal variation of the attenuation depth (551 nm) in the Bohai Sea indicated that:the spectral distribution of the attenuation depth for the spectral range between 400 to 700 nm is single-peak curve,and it''s similar and difference in different regions is consistent with other scholars'' results of zoning,moreover,it supports the Bohai Sea is Case 2 water; the maximum attenuation depth shifts toward longer wavelengths,liking the red shift,with increase of turbidity of water,just like the maximum attenuation depth in the outside of the northwest coast of the Bohai Sea and the Bohai Strait is at 531nm,in the central of the Bohai Sea is at 551nm,in the region controlled by the Huanghe (Yellow) River,the region impacted by the old Huanghe River,the western side of the Liaodong Bay and the eastern side of the Liaodong Bay is at 555 nm; the seasonal change of the attenuation depth is the largest in the summer,followed by the fall,and the ranking of winter and spring in different regions is distinct.The attenuation depth in different regions is dissimilar:the order of the attenuation depth in different regions from small to big is the region controlled by the Huanghe River or the eastern side of the Liaodong Bay,the western side of the Liaodong Bay,the region impacted by the old Huanghe River,the central of the Bohai Sea or the outside of the northwest coast of the Bohai Sea,the Bohai Strait (except at 412 nm and 645 nm),in which between the region controlled by the Huanghe River and the eastern side of the Liaodong Bay (and between the central of the Bohai Sea and the outside of the northwest coast of the Bohai Sea) it varies in different seasons and different bands.  相似文献   

11.
First direct evidence for ongoing gas seepage activity on the abandoned well site 22/4b (Northern North Sea, 57°55′ N, 01°38′ E) and discovery of neighboring seepage activity is provided from observations since 2005. A manned submersible dive in 2006 discovered several extraordinary intense seepage sites within a 60 m wide and 20 m deep crater cut into the flat 96 m deep seafloor. Capture and (isotope) chemical analyses of the gas bubbles near the seafloor revealed in situ concentrations of methane between 88 and 90%Vol. with δ13C–CH4 values around −74‰ VPDB, indicating a biogenic origin. Bulk methane concentrations throughout the water column were assessed by 120 Niskin water samples showing up to 400.000 nM CH4 in the crater at depth. In contrast, concentrations above the thermocline were orders of magnitude lower, with a median value of 20 nM. A dye tracer injection into the gas seeps revealed upwelling bubble and water motion with gas plume rise velocities up to ∼1 ms−1 (determined near the seabed). However, the dissolved dye did not pass the thermocline, but returned down to the seabed. Measurements of direct bubble-mediated atmospheric flux revealed low values of 0.7 ± 0.3 kty−1, much less than current state-of-the-art bubble dissolution models would predict for such a strong and upwelling in situ gas bubble flux at shallow water depths (i.e. ∼100 m).Acoustic multibeam water column imaging data indicate a pronounced 200 m lateral intrusion at the thermocline together with high methane concentration at this layer. A partly downward-orientated bubble plume motion is also visible in the acoustic data with potential short-circuiting in accordance to the dye experiment. This observation could partly explain the observed trapping of most of the released gas below the well-established thermocline in the North Sea. Moreover, 3D analyses of the multibeam water column data reveal that the upwelling plume transforms into a spiral expanding vortex while rising through the water column. Such a spiral vortex motion has never been reported before for marine gas seepage and might represent an important process with strong implication on plume dynamics, dissolution behavior, gas escape to the atmosphere, and is considered very important for respective modeling approaches.  相似文献   

12.
The present paper focuses on heat and mass exchange processes in methane hydrate fragments during in situ displacement from the gas hydrate stability zone (GHSZ) to the water surface of Lake Baikal. After being extracted from the methane hydrate deposit at the lakebed, hydrate fragments were placed into a container with transparent walls and a bottom grid. There were no changes in the hydrate fragments during ascent within the GHSZ. The water temperature in the container remained the same as that of the ambient water (~3.5 °С). However, as soon as the container crossed the upper border of the GHSZ, first signs of hydrate decomposition and transformation into free methane gas were observed. The gas filled the container and displaced water from it. At 300 m depth, the upper and lower thermometers in the container simultaneously recorded noticeable decreases of temperature. The temperature in the upper part of the container decreased to –0.25 °С at about 200 m depth, after which the temperature remained constant until the water surface was reached. The temperature at the bottom of the container reached –0.25 °С at about 100 m depth, after which it did not vary during further ascent. These observed effects could be explained by the formation of a gas phase in the container and an ice layer on the hydrate surface caused by heat consumption during hydrate decomposition (self-preservation effect). However, steady-state simulations suggest that the forming ice layer is too thin to sustain the hydrate internal pressure required to protect the hydrate from decomposition. Thus, the mechanism of self-preservation remains unclear.  相似文献   

13.
为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律,定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上,分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后,综合各因素的历史演化过程,初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大;水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件;超过600 m水深的海域水合物稳定带厚度大部分超过 100 m,其中西北部稳定带的最大厚度超过300 m,是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果,推测其形成与天然气水合物的分解释放有关。  相似文献   

14.
Natural gas hydrates is considered as a strategic unconventional clean hydrocarbon resource in the energy sector. Understanding the behavior of the rising methane gas bubbles during production leaks from the deep marine gas hydrate reservoirs well head is essential for environmental impact studies and to design environmental monitoring systems. Numerical model for quantitatively characterizing the vertical dissolution pattern of the wellhead released methane gas bubbles is analyzed for three potential gas hydrate locations in India. Simulation results indicate that the methane bubbles with diameter of 10?mm can transport methane gas till 650, 800, and 750?m from the seabed in the Krishna–Godavari(KG), Mahanadi and Andaman basins respectively. Results brought out that potential well head damage during methane hydrate production at 1050?m water depth could release up to 28?m3 of methane gas, in which 50% of the molar mass shall get dissolved within 40?m of water column from the seafloor.  相似文献   

15.
To confirm the seabed fluid flow at the Haima cold seeps, an integrated study of multi-beam and seismic data reveals the morphology and fate of four bubble plumes and investigates the detailed subsurface structure of the active seepage area. The shapes of bubble plumes are not constant and influenced by the northeastward bottom currents, but the water depth where these bubble plumes disappear (630–650 m below the sea level) (mbsl) is very close to the upper limit of the gas hydrate stability zone in the water column (620 m below the sea level), as calculated from the CTD data within the study area, supporting the “hydrate skin” hypothesis. Gas chimneys directly below the bottom simulating reflectors, found at most sites, are speculated as essential pathways for both thermogenic gas and biogenic gas migrating from deep formations to the gas hydrate stability zone. The fracture network on the top of the basement uplift may be heavily gas-charged, which accounts for the chimney with several kilometers in diameter (beneath Plumes B and C). The much smaller gas chimney (beneath Plume D) may stem from gas saturated localized strong permeability zone. High-resolution seismic profiles reveal pipe-like structures, characterized by stacked localized amplitude anomalies, just beneath all the plumes, which act as the fluid conduits conveying gas from the gas hydrate-bearing sediments to the seafloor, feeding the gas plumes. The differences between these pipe-like structures indicate the dynamic process of gas seepage, which may be controlled by the build-up and dissipation of pore pressure. The 3D seismic data show high saturated gas hydrates with high RMS amplitude tend to cluster on the periphery of the gas chimney. Understanding the fluid migration and hydrate accumulation pattern of the Haima cold seeps can aid in the further exploration and study on the dynamic gas hydrate system in the South China Sea.  相似文献   

16.
The distribution and origin of shallow gas seeps in the vicinity of the Posolsky Bank in Lake Baikal were studied based on the integration of detailed seismic, multibeam, and hydro-acoustic water-column investigations. In all, 65 acoustic flares have been detected on the Posolsky Fault scarp near the crest of the bank and in a similar, nearby setting at water depths of ?43 to ?332?m. The seismic data reveal BSRs (bottom-simulating reflectors) occurring up to water depths of ?300?m. Calculations involving hydrate stability, heat flow, and topographic modulation based on BSR occurrence and multibeam bathymetry enabled prediction of a methane–ethane gas mixture and heat-flow values that would account for gas hydrate stability in the lake sediments under prevailing ambient conditions. These predictions are supported by ground truth data. The findings suggest that seeps concentrated along the crest of the Posolsky Bank are fed mainly by gas coming from below the base of the gas hydrate stability zone, which would migrate updip via permeable stratigraphic pathways beneath the bank. Gas would ultimately be released into the water column where these pathways are cut off by faults.
Figure
Conceptual seep model for the Posolsky Bank, Lake Baikal  相似文献   

17.
Gas and fluid venting at the Makran accretionary wedge off Pakistan   总被引:2,自引:1,他引:1  
The Makran accretionary complex shows a distinct bottom-simulating reflector, indicating a thick gas-hydrate-bearing horizon between the deformational front and about 1350 m water depth which seals off the upward flow of gas-charged fluids. A field of presently inactive mud diapirs with elevations up to 65 m was discovered in the abyssal plain seawards of the deformation front, suggesting that in the past conditions were favorable for periodic but localized vigorous mud diapirism. Regional destabilization of the gas hydrate leading to focused flow was observed where deep-penetrating, active faults reach the base of the gas-hydrate layer, as in a deeply incised submarine canyon (2100–2500 m water depth). At this location we discovered seeps of methane and H2S-rich fluids associated with chemoautotrophic vent faunas (e.g., Calyptogena sp.). Driven by the accretionary wedge dynamics, the landward part of the gas-hydrate layer below the Makran margin is being progressively uplifted. Due to reduced hydrostatic pressure and rising ocean bottom-water temperatures, gas hydrates are progressively destabilized and dissociated into hydrate water, methane and H2S. Sediment temperatures lie outside the methane stability field wherever water depth is less than 800 m. Above this depth, upward migration of fluids to the seafloor is unimpeded, thus explaining the abundance of randomly distributed gas seeps observed at water depths of 350 to 800 m. Received: 14 June 1999 / Revision accepted: 6 February 2000  相似文献   

18.
Fossil methane from the large and dynamic marine gas hydrate reservoir has the potential to influence oceanic and atmospheric carbon pools. However, natural radiocarbon (14C) measurements of gas hydrate methane have been extremely limited, and their use as a source and process indicator has not yet been systematically established. In this study, gas hydrate-bound and dissolved methane recovered from six geologically and geographically distinct high-gas-flux cold seeps was found to be 98 to 100% fossil based on its 14C content. Given this prevalence of fossil methane and the small contribution of gas hydrate (≤ 1%) to the present-day atmospheric methane flux, non-fossil contributions of gas hydrate methane to the atmosphere are not likely to be quantitatively significant. This conclusion is consistent with contemporary atmospheric methane budget calculations.In combination with δ13C- and δD-methane measurements, we also determine the extent to which the low, but detectable, amounts of 14C (~ 1–2% modern carbon, pMC) in methane from two cold seeps might reflect in situ production from near-seafloor sediment organic carbon (SOC). A 14C mass balance approach using fossil methane and 14C-enriched SOC suggests that as much as 8 to 29% of hydrate-associated methane carbon may originate from SOC contained within the upper 6 m of sediment. These findings validate the assumption of a predominantly fossil carbon source for marine gas hydrate, but also indicate that structural gas hydrate from at least certain cold seeps contains a component of methane produced during decomposition of non-fossil organic matter in near-surface sediment.  相似文献   

19.
Methane bubble fluxes in gas flares from bottom sediments in Lake Baikal were estimated for the first time using hydroacoustic methods. Earlier work has demonstrated the occurrence of gas seeps both inside and outside of areas where bottom simulating reflectors were identified in seismic profiles. Fluxes ranged from 14 to 216 tons per year, with the flux for the entire area of the central and southern basins ranging from 1,400 to 2,800 tons per year. Comparison with other water bodies showed that fluxes from the most intensive Baikal flares were similar to those in the Norwegian and Okhotsk seas. Gas hydrates decompose at the lower boundary of the gas hydrate stability zone due to sedimentation. Calculation of the amount of methane produced due to sedimentation gave a total of between 2,600 and 14,000 tons per year for the central and southern basins of the lake. Based on rough estimation, the total flux from shallow- and deep-water gas seeps is similar to the amount of methane produced due to sedimentation. This suggests that gas hydrates possibly occupy much more than 10?% of the pore volume near the base of the gas hydrate stability zone, or that there are other reasons for gas hydrate dissociation and bubble flux from these bottom sediments.  相似文献   

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