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1.
Iodide and iodate concentrations are reported and discussed for the WOCE A23 transect from the Weddell Sea north to about 25°S. Iodide concentrations are very low in the surface waters of the Weddell Sea (20 nM) and increase steadily northwards to about 100 nM in the surface waters of the south Atlantic gyre. In deep waters iodide concentrations are low but detectable at 0.5–2 nM. There is no detectable total iodine depletion in the surface waters south of the polar front although there is a small depletion evident north of the front. The results are discussed in terms of the hydrography, nutrient concentrations and phytoplankton activity along the transect. In particular, a systematic change in the relationship between iodide and nitrate along the transect is discussed.  相似文献   

2.
This paper addresses the question of the eventual control of barium concentration in seawater by an equilibrium with barite. For this, we have used a new thermodynamic model to compute the barite saturation index of ocean waters, mainly from GEOSECS data. Our results show that equilibrium between barite and seawater is reached in a number of places: cold surface waters of the Southern Ocean, waters at intermediate depths (2000–3500 m) in the Pacific, deep waters (2000–3500 m) of the Gulf of Bengal. The only samples for which a slight barite supersaturation is found are the surface waters at GEOSECS station G89 in the Weddell Gyre. Besides these locations, the rest of the world's oceans is undersaturated, as was established by Church and Wolgemuth [Church, T.M., Wolgemuth, K., 1972. Marine barite saturation, Earth Planet. Sci. Lett. 15 35–44.]. There is a return to undersaturation of the water column at depths of about 3500 m in the Pacific and of about 2500 m in the Southern Ocean. The reverse is found for GEOSECS station 446 in the Gulf of Bengal for which the highest Ba concentrations can be found at depth: surface waters are undersaturated and equilibrium is reached below 2000 m. Finally, we briefly discuss the role of biogenic and inorganic processes on barite formation in the ocean as well as the influence of strontium substitution in marine barites.  相似文献   

3.
Observations of the equilibrium partial pressure of carbon dioxide in the surface waters of the North Pacific Ocean and Bering Sea indicate conditions of local upwelling or vertical mixing near the Aleutian Island passes, seasonal depletion of CO2 in the sea surface by photosynthesis, and conditions of CO2 supersaturation in the surface waters off the mouths of large rivers. Horizontal mixing has a large effect on the PCO2 distribution. The area distribution of carbon dioxide in the surface waters of the Pacific Ocean from 19°N to 55°N latitude and in the Bering Sea is presented.  相似文献   

4.
2008年11月末在青岛近海和胶州湾11个站点采集表层和底层海水中的悬浮颗粒物(SPM)样品,经消解后用等离子体发射光谱法测定了Al、Ca、Fe、Mg、Mn、Ti和Ba、Co、Cr、Cu、Ni、Pb、Sr、V、Zn共15个金属元素以及P的含量,结合SPM和元素含量聚类分析的结果探讨了秋末冬初青岛近海SPM的来源以及金属元素组成的影响因素.SPM含量范围在1.7~16.1mg/L之间,平均为7.9 mg/L;SPM来源以陆源风化产物为主,生物生产有较小的贡献.SPM中Ti、Fe、Mn、Mg、Al、V、Co、Sr和Ni的含量相对恒定,且主要受陆源输入的控制;Ca和P除受陆源影响外,生物生产亦有附加贡献.离陆地相对较远的区域表层海水SPM中Pb、Zn和Ba、Cr、Cu的含量较高,特别是Pb和Zn的富集因子较大,可能受到了潜在的污染影响.Ti的恒定性以及与SPM的良好相关性代表着在青岛近海可用Ti作为颗粒物陆源指示元素,且优于Al.  相似文献   

5.
Chronological variation in otolith chemistry can be used to reconstruct migration histories of fish. The use of otolith chemistry to study migration, however, requires knowledge of relationships between the chemical properties of the water and elemental incorporation into otoliths, and how water chemistry varies in space and time. We explored the potential for otolith chemistry of snapper, Pagrus auratus, to provide information on movement history between a large semi-enclosed bay, Port Phillip, and coastal waters in south-eastern Australia. Comparisons of water chemistry across two years demonstrated that ambient barium (Ba) levels in Port Phillip Bay were approximately double those in coastal waters (11 μg L−1 versus 6 μg L−1). Ba levels in otolith margins of wild juvenile snapper were highly positively correlated with ambient levels across 17 sampling locations, and levels in otolith margins of adult snapper collected from Port Phillip Bay were approximately double those of snapper collected in coastal waters. Mean partition coefficients for Ba (DBa) were similar for juvenile (0.43) and adult (0.46) otoliths, suggesting that otolith Ba incorporation relative to ambient levels was similar across life-stages. Low Ba variation across otoliths from adult snapper maintained in tanks for three years indicated that annual temperature and/or growth cycles did not strongly influence otolith Ba variation. We concluded that chronological Ba variation in snapper otoliths would be a reliable proxy for life-history exposure to variable ambient Ba. We used water chemistry data and Ba levels across otoliths of ocean resident snapper to estimate otolith Ba levels indicative of residence in Port Phillip Bay (>10 μg g−1) or coastal waters (<6 μg g−1). Peaks in Ba exceeding 10 μg g−1 were common across otoliths of snapper collected in Port Phillip Bay and a nearby coastal region. The location of strong Ba peaks within otoliths was consistent with residence in Port Phillip Bay during the spring/summer when snapper move into the Bay from coastal waters to spawn. Our results for snapper support the use of otolith Ba as a proxy for ambient levels throughout the life-history, however, confident interpretation of migration history from otolith Ba chronologies will most likely require matching time series of ambient Ba in the water bodies of interest.  相似文献   

6.
Nutrients, chlorophyll-a, particulate organic carbon (POC), and environmental conditions were extensively investigated in the northern East China Sea (ECS) near Cheju Island during three seasonal cruises from 2003 to 2005. In spring and autumn, relatively high concentrations of nitrate (2.6~12.4 μmol kg-1) and phosphate (0.17~0.61 μmol kg-1) were observed in the surface waters in the western part of the study area because of the large supply of nutrients from deep waters by vertical mixing. The surface concentrations of nitrate and phosphate in summer were much lower than those in spring and autumn, which is ascribed to a reduced nutrient supply from the deep waters in summer because of surface layer stratification. While previous studies indicate that upwellings of the Kuroshio Current and the Changjiang (Yangtze River) are main sources of nutrients in the ECS, these two inputs seem not to have contributed significantly to the build-up of nutrients in the northern ECS during the time of this study. The lower nitrate:phosphate (N:P) ratio in the surface waters and the positive correlation between the surface N:P ratio and nitrate concentration indicate that nitrate acts as a main nutrient limiting phytoplankton growth in the northern ECS, contrary to previous reports of phosphate-limited phytoplankton growth in the ECS. This difference arises because most surface water nutrients are supplied by vertical mixing from deep waters with low N:P ratios and are not directly influenced by the Changjiang, which has a high N:P ratio. Surface chlorophyll-a levels showed large seasonal variation, with high concentrations (0.38~4.14 mg m-3) in spring and autumn and low concentrations (0.22~1.05 mg m-3) in summer. The surface distribution of chlorophyll-a coincided fairly well with that of nitrate in the northern ECS, implying that nitrate is an important nutrient controlling phytoplankton biomass. The POC:chlorophyll-a ratio was 4~6 times higher in summer than in spring and autumn, presumably because of the high summer phytoplankton death rate caused by nutrient depletion in the surface waters.  相似文献   

7.
Chromium(VI) concentrations ranging between 3.0 and 6.1 nmol l−1 and 3.1 and 7.3 nmol l−1 were found in the Arctic and Atlantic Oceans, respectively. The vertical profiles show modest depletion of chromium(VI) in surface waters, but poor overall correlations between Cr(VI) and nutrient profiles. Given that Cr(VI) is the dominant oxidation state of chromium in open-ocean waters, these data are combined with literature data to reassess the distribution of Cr in oceanic waters. It is concluded that while Cr shows some characteristics of both “recycled” and “accumulated” vertical profiles, it does not fall clearly within either group.  相似文献   

8.
西沙群岛群体放射虫的初步调查   总被引:1,自引:0,他引:1  
过去已有不少学者对群体放射虫进行过专门研究报道。这类动物的每个群体虽然系由成百上千个单体放射虫联合组成,但在许多方面却起着独立有机体的作用。它们对外界刺激的反应是以整体的方式进行的,而且一些行为习性相当于简单的多细胞动物。群体放射虫的形状多种多样,其大小变化也很大,群体的长度可由数毫米达数十厘米,甚至超过一米;新近 Swanberg (1979)曾找到长达三米的群体,并且常与大型的浮游动物一起存在。据以往报道,群体放射虫多半居于海洋表层,是海洋浮游生物生态系成员之一,它们以原生动物或小型的甲壳类、海鞘、软体动物的幼虫等为食,同时又是被食者。但作为海洋食物链的构成者,这类原生动物尚未引起人们足够的重视,对它的研究也很少。 我国西沙群岛的群体放射虫过去尚无报道。1974和1975年中国科学院海洋研究所和南海海洋研究所曾进行西沙群岛浮游生物调査采集,本文据该两次调查所获资料进行整理鉴定,对以往中国沿海未记录过的种类加以描述,并对其分布作一初步探讨。 调査范围见图1。标本制片按以往方法。  相似文献   

9.
Geochemical and rock-magnetic investigations were carried out on a sediment core collected from the SE Arabian Sea at 1420 m depth in oxygenated waters below the present-day oxygen minimum zone. The top 250 cm of the core sediments represent the last 35 kaBP. The · 18O values of Globigerinoides ruber are heaviest during the Last Glacial Maximum (LGM) and appear unaffected by low-saline waters transported from the Bay of Bengal by the strong northeast monsoon and West Indian coastal current. The signatures of Bølling-Allerød and Younger Dryas events are distinct in the records of magnetic susceptibility, organic carbon (OC) and · 18O. Glacial sediments show higher OC, CaCO3, Ba, Mo, U and Cd, while the early-to-late Holocene sediments show increasing concentrations of OC, CaCO3, Ba, Cu, Ni and Zn and decreasing concentrations of Mo, U and Cd. Productivity induced low-oxygenated bottom waters and reducing sedimentary conditions during glaciation, and productivity and oxygenated bottom waters in the Holocene are responsible for their variation. The core exhibits different stages of diagenesis at different sediment intervals. The occurrence of fine-grained, low-coercivity, ferrimagnetic mineral during glacial periods is indicative of its formation in organic-rich, anoxic sediments, which may be analogous to the diagenetic magnetic enhancement known in sapropels of the Mediterranean Sea and Japan Sea. The glacial sediments exhibiting reductive diagenesis with anoxic sedimentary environment in this core correspond to reductive diagenesis and intermittent bioturbation (oxygenation) reported in another core in the vicinity. This suggests that the poorly oxygenated bottom water conditions during glacial times should not be generalized, but are influenced locally by productivity, sedimentation rates and sediment reworking.  相似文献   

10.
The dissolved O2, Fe, dissolved organic carbon (DOC), particulate organic carbon (POC), silica and U isotope measurements in river-estuarine waters of the Godavari and the concentrations of 23 elements in the suspended matter of the waters are reported.The DOC and Fe concentrations are lower compared with those in other estuaries of the world and are below the average value reported for world rivers. Silicon behaves non-conservatively; its depletion which is most likely due to biological activity during the non-monsoon periods of sampling ranges from 25 to 37%. The U isotopes behave conservatively although there is some scatter in the low-chlorinity (≤ 2 gCl 1−1) region. Based on the data collected during non-monsoon seasons, the annual U input from Godavari to the Bay of Bengal is estimated to be ≈ 52 tons, although this has to be considered an approximate value owing to the absence of data during the monsoon period.The suspended matter concentrations, ranging from 4.2 to 7.9 mg l−1, are one to two orders of magnitude lower than those of the main rivers on the west coast of India. Of the elemental concentrations and metal/Su ratios reported, Ag, Ai, Ba, Br, Ca and Zn show a large degree of scatter which has yet to be explained. Others, notably, rare earth elements (REE) show a near-constancy to slightly decreasing trend with increasing chlorinity above the ≈ 2 gCll−1 region.  相似文献   

11.
The study establishes an annual estimate for annual primary production of 81 g C m−2 for the open Greenland Sea based on data from five cruises and literature data. This estimate agrees well with a model estimate based on nutrient utilisation but is a factor of 2–5 less than published primary production estimates made by remote sensing of this area. The seasonal distribution of particulate primary production in open Greenland Sea waters followed the seasonal distribution of surface irradiance with a peak in June, indicating that light is the primary factor governing primary production in the area. At stations along the ice edge, blooms were recorded in both June and August, suggesting a pattern of repeated blooms during the summer season at the ice edge. Subsurface phytoplankton peaks were a persistent feature in the open Greenland Sea from May to August. These peaks were consisted of actively photosynthesising phytoplankton and up to 90% of total water column particulate primary production was estimated to occur in association with these peaks. Diatoms dominated the phytoplankton community during the spring bloom and in the Polar Water during August. Size distribution analyses of the phytoplankton communities indicated that the relative abundance of large cells compared to small cells was greatest in May as compared to June and August. No significant differences were noted between June and August in the slope of the phytoplankton size distribution spectra. Inorganic nitrogen and phosphorus nutrients were measurable in surface waters on all cruises. Only in August were there some indications (altered Redfield ratios and higher nutrient concentrations in subsurface chlorophyll peaks than at the surface) of nutrient depletion of surface waters. Implications for food web structure and carbon flux of these patterns in phytoplankton activity and distribution are discussed.  相似文献   

12.
黑潮与邻近东海生源要素的交换及其生态环境效应   总被引:2,自引:0,他引:2  
宋金明  袁华茂 《海洋与湖沼》2017,48(6):1169-1177
黑潮与东海生源要素的交换对东海的生态环境有重大影响,交换主要是经台湾东北部海域输送至东海陆架和通过日本九州西南海域由东海陆架向外海的黑潮输出两个通道。中国科学院海洋先导专项对黑潮与邻近东海生源要素的交换特征进行了系统的调查和研究,获得了一些新的认识:(1)在台湾东北部区域,碳主要以表层水-次表层水为载体输入,秋季的输入量高于夏季;黑潮溶解态营养盐的输入占据绝对主导地位,且以黑潮次表层热带水-中层水的输入为主,输入通量春季高于夏、秋季,可为东海春季水华提供一定的物质基础,但输入到东海的黑潮水其氮磷比与Redfield比值(16:1)接近,这些"正常水"——黑潮的输入显然对调和东海异常高的氮磷比有重要的作用,从而对东海的生态环境起到"稳定和缓冲"作用。所以,黑潮水对东海的输入不仅维持补充了东海生态系统运转所需的生源要素,更为重要的是缓冲了受人为影响强烈的东海海水的高氮磷比,使东海本已失常的营养盐结构向合适的氮磷比方向转变。因此,黑潮与东海生源要素的输入在一定程度上起着稳定和缓和东海生态环境的作用。(2)通过构建的海水Ba-盐度新指标体系,定量细致刻画了黑潮对东海生源物质在台湾东北部区域的输入范围和程度,黑潮次表层水从台湾东北陆架坡折处沿底部向北偏西方向入侵东海,其近岸分支可以入侵到浙江近岸,其黑潮次表层水占比仍可达到65%左右。垂直方向上,陆架外侧站位受黑潮次表层水的影响范围更大,黑潮水占50%比例位置可延伸至外侧TW0-1站位(122.59°E,25.49°N)表层,而内侧靠近大陆的站位则只限于陆架中部位置底层。  相似文献   

13.
梁霄  李巍  林建国 《海洋科学》2011,35(5):61-65
基于北极海域脆弱的生态环境特点,为了将溢油污染危害降至最低,以FLUENT为研究平台,建立多项因素共同作用下的船舶溢油模型,分析溢油在有冰海域中的运动特点.结果表明;当冰盖存在时溢油会黏附于冰的下表面,扩散范围小于相同温度下自由海面上的油膜扩散范围;部分溢油会被卷吸到冰盖表面并继续迁移,加速了冰盖的融化;溢油点距离冰盖...  相似文献   

14.
《Marine Chemistry》2001,73(1):37-51
Vertical profiles of 14C-uptake were acquired monthly from the mouths and landward stations of periodically anoxic Saanich Inlet and oxygenated Jervis Inlet, British Columbia, Canada from August 1985 to October 1989. Saanich Inlet (490 g C m−2 year−1) was 1.7 times more productive than Jervis Inlet (290 g C m−2 year−1) and primary production toward the mouths of both inlets was 1.4 times higher than at the landward stations. The elevated rates of primary production in Saanich Inlet may have been due to exchange with the nutrient-rich surface waters of the passages leading to the Pacific Ocean and the up-inlet gradients in both fjords also may have reflected relative nutrient supply. Sediment-trap results show enhanced fluxes of biogenic silica to the deep waters of Saanich Inlet; associated organic matter is likely to have caused a large oxygen demand. Combined with the high primary production and export flux, low rates of vertical mixing and particle-entrapment within the fjord, factors associated with weak estuarine circulation as well as weak winds and tides in Saanich Inlet, may also stimulate anoxia.Although in Jervis Inlet there is more stagnant water behind the sill and deep-water renewals appear to be less frequent than in Saanich Inlet, the deep sill allows degradation of a significant fraction of the sinking organic matter before the stagnant waters are reached, reducing the chances of oxygen depletion in the bottom waters.  相似文献   

15.
The variability of the phosphates, silicates, alkalinity, oxygen, CO2 pressure, salinity, and temperature in the surface mixed layer (SML), as well as the variations of its thickness along the drift passage of the North Pole 35 station, are considered. The station drifted over the Nansen Basin mainly eastwards from ??105 to ??30° E. The surveys were performed from October of 2007 till June of 2008 at three-day intervals. The SML parameters are mainly determined by the advection and mixing with the underlying waters. The analysis of the hydrochemical variability shows that the surface waters at the eastern and western areas of the drift are of different origins. The waters of the eastern area were subjected to the impact of riverine runoff. These waters were spread westwards. The fraction of riverine waters in the eastern area amounts to 3%. In the western area of the drift, presumably transformed Atlantic waters were observed, which spread eastwards from the Fram Strait. The drift path of the station crosses the boundary of the water masses near 85° N and 45° E.  相似文献   

16.
《Marine Chemistry》2002,78(1):1-8
The activities of naturally occurring radium isotopes (226Ra and 228Ra) in estuarine water were measured downstream of the dam constructed in the Nakdong River, Korea. The sampling of surface waters for radium, silicate, and suspended solid (SS) analyses was conducted at 18 stations during three periods (July 1997, April 1998, and June 1999). In general, radium activities exceeded the value expected from the mixing of two freshwater and seawater endmembers. We characterized the responses of Ra and Si according to three different conditions: (1) when the freshwater discharge and the water level of the dam relative to the sea level at low tide were lower (April 1998), the excess Ra and Si contents were lower in the estuary; (2) when the fresh water discharge was larger following heavy precipitation (July 1997), both excess Ra and Si contents were higher in the estuary with conservative mixing of Si; and (3) when the water level of the dam relative to the sea level at low tide was highest under low freshwater discharge (June 1999), high excess Ra but low Si levels were observed. The occurrence of high Ra activity in June 1999 was likely due to the large submarine brackish groundwater discharge downstream of the estuary. Since brackish groundwater in general contains high concentrations of nutrients, Ba, Ra, etc, our result suggests an important role for the submarine groundwater discharge on the biogeochemistry of estuarine/coastal waters, especially when the water level of the dam (hydraulic head) is high.  相似文献   

17.
On voyages in the Iceland Basin in 2007 and 2009, we observed low (ca. 0.1 nM) total dissolved iron concentrations [dFe] in surface waters (<150 m), which increased with depth to ca. 0.2–0.9 nM. The surface water [dFe] was low due to low atmospheric Fe inputs combined with biological uptake, with Fe regeneration from microbial degradation of settling biogenic particles supplying dFe at depth. The organic ligand concentrations [LT] in the surface waters ranged between 0.4 and 0.5 nM, with conditional stability constants (log KFeL) between 22.6 and 22.7. Furthermore, [LT] was in excess of [dFe] throughout the water column, and dFe was therefore largely complexed by organic ligands (>99%). The ratio of [LT]/[dFe] was used to analyse trends in Fe speciation. Enhanced and variable [LT]/[dFe] ratios ranging between 1.6 and 5.8 were observed in surface waters; the ratio decreased with depth to a more constant [LT]/[dFe] ratio in deep waters. In the Iceland Basin and Rockall Trough, enhanced [LT]/[dFe] ratios in surface waters resulted from decreases in [dFe], likely reflecting the conditions of Fe limitation of the phytoplankton community in the surface waters of the Iceland Basin and the high productivity in the Rockall Trough.Below the surface mixed layer, the observed increase in [dFe] resulted in a decrease of the [LT]/[dFe] ratios (1.2–2.6) with depth. This indicated that the Fe binding ligand sites became occupied and even almost saturated at enhanced [dFe] in the deeper waters. Furthermore, our results showed a quasi-steady state in deep waters between dissolved organic Fe ligands and dFe, reflecting a balance between Fe removal by scavenging and Fe supply by remineralisation of biogenic particles with stabilisation through ligands.  相似文献   

18.
This paper analyzed the distribution of thermohaline and circulation characteristics of Zhejiang and Fujian waters, based on the cross-sectional thermohaline data and on current data (up to 30 d duration) at fixed-point moorings, collected in the summer of 2006. We also performed low-pass filtering and spectrum analysis on the mooring submersible buoy data. Based on that analysis, we discussed the characteristics of low frequency currents and time-variations in these waters. The main conclusions are as follows. (1) There is a low salinity pinnate area near the Hangzhou Bay in summer, and outside the low salinity area, an obvious salinity front is present from surface to bottom near 123°E. There is also a temperature front below the surface at a corresponding position. (2) Bottom water of the Taiwan Warm Current comes from the subsurface of Kuroshio. (3) The direction of low frequency current at fixed anchor stations is N-NE or S, which mainly depends on the interaction of control currents in this waters. (4) Significant spectral peaks at all mooring stations are typically semidiurnal and diurnal tides. Semidiurnal tidal waves are the main ones in these waters, and have more energy closer to the shore. (5) Significant energy spectral peaks of middle period (3 to 8 d) of currents are responses to weather frequency. (6) Significant energy spectral peaks of long periods at the surface or bottom are probably responses to seasonal wind or bottom friction, while, the long period peaks of other depths can reflect cyclical changes of interactions between currents. We conclude that the pulsation period of the Taiwan Warm Current in these waters is 10-17 d.  相似文献   

19.
The δ18O, δ13C and trace element composition of pearls collected from Ago Bay, Japan, were investigated in order to evaluate biomineralization in the cultured pearl oyster (Pinctada fucata martensii). The oxygen isotopic data suggest that the pearls were produced around 23–24°C, mainly in June to early July, which is consistent with their occurrence in the field. Therefore the pearls were produced under or close to isotopic equilibrium conditions, although they showed high calcification rates (higher than 0.2–1.0 g cm− 2yr−1) under which, for example, coral skeletons (calcification rate ∼0.28 g cm− 2yr−1) often show non-equilibrium isotope partitioning. The δ13C values were ∼− 2.9‰ lower than those calculated for offshore waters under equilibrium conditions. This may be due to low-δ13C bottom waters resulting from the degradation of organic matter (OM) or to a contribution of low-δ 13C food. In the latter case, a simple mass balance calculation gives a respiration component of 14%. Twelve trace elements of bulk pearl samples were classified into four groups on the basis of their enrichment/depletion patterns relative to seawater and inter-element relationships: group 1, Co, Cr, Pb; group 2, Ba, Cs, U; group 3, Cu, Sn, V, and group 4, Mn, Rb, Mo. Comparison with coral skeletons suggests that Ba and Mn (groups 2 and 4) were definitely much enriched in proteinaceous OM relative to aragonite crystals in pearls and that V (group 3) in pearls showed only slight enrichment in the organicrich layer. By contrast, the other elements showed small differences between both layers (enrichment factor of <3), suggesting that these elements occur largely in aragonite crystals.  相似文献   

20.
This case study demonstrates how natural heterogeneities of formation and injection waters can be applied to a number of production related applications, extending into the mature life of a reservoir. Break-through of injection water, identification and characterisation of production intervals and evaluation of responses to operational events are some of the possible applications during production.The Oseberg Øst oil field in the North Sea represents a complex situation with commingled production from all Brent Group formations. The Sr isotope composition is an excellent parameter for defining the natural baseline of formation water, with a good spatial resolution and vertical stratification. Aquifer water from the Utsira Formation is injected for pressure support, and reinjection of produced water has also been applied since the onset of water production. Utsira Formation water has high Mg, low Ba and low Sr content compared to the reservoir formation waters. Isotopic compositions (δD and 87Sr/86Sr) are also distinct. A non-reactive behaviour of Ba and Sr is verified from binary cross-plots and geochemical modelling. Break-through of injection water could be identified in five production wells based on Ba/Mg ratios. In one of the reservoir compartments (Beta Saddle), water injection points were changed after approximately three years. The Ba/Mg ratio could also identify the second injection water break-through in one of the wells due to an intermediate period of higher formation water content. Since the Sr content in the Utsira water is low, the 87Sr/86Sr ratio is a good natural tracer for formation water movements even at high ratios of injected water. In particular, the vertical stratification of 87Sr/86Sr is useful for quantifying production from different intervals in commingled wells. A methodology for using operational events, such as production allocations or shut-ins, for characterisation of production zones is discussed.  相似文献   

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