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1.
The comparison of spatial and temporal distribution of Hg, Cd, Pb, Cu, Ni, Zn, Mn and Fe concentrations in sediments from the Gulf of Riga and open Baltic Sea along the coastal zone is presented for the first time. There were considerable differences in Pb, Zn, Mn and Fe levels in sediment at various stations of the Gulf of Riga. A significant difference of Cd, Pb, Cu, Ni, Zn levels was found in sediments of various stations in the open Baltic coast. The amount of Cd, Pb, Cu, Ni, Zn and Fe levels also differed significantly in the sediments of the Gulf of Riga in different years. A considerable yearly difference in amount of Hg, Cd, Pb, Cu, Ni and Mn levels was found in sediments in the open Baltic coast. The essential highest values of Pb and Zn in coastal sediments of the open Baltic Sea are stated in comparison with the Gulf of Riga. The concentrations of other metals have only a tendency to be higher in coastal sediments of the open Baltic Sea in comparison with the Gulf of Riga. Natural and anthropogenic factors were proved to play an important role in determining resultant metals concentrations in the regions. 相似文献
2.
Metal concentrations of Cu, Fe, Mn, Ni, Pb and Zn in an infaunal facultative deposit-feeding bivalve, the Baltic clam Macoma balthica, in the Gulf of Gdansk (southern Baltic Sea) were assessed and compared to selected concentrations of metals in the environment. Between October 1996 and September 1997, dissolved and easy extractable (by 1M HCl) metal fractions of total suspended particulate matter (TPM) in the overlying water and of surficial sediments (<63 microm) were measured monthly at five sublittoral sites in the Gulf of Gdansk, and accumulated tissue metal concentrations in M. balthica were determined simultaneously. The study highlights the importance of sediment geochemistry as a factor modifying ambient trace metal bioavailabilities. Surficial sediments appeared to contribute most to the accumulation of Cu and Pb in M. balthica, reflecting the high metal availability in the Gulf. Assimilation of Cu from sediments is controlled by Mn components possibly through an inhibitory effect of Mn oxyhydroxides, while Pb accumulation from sediments depends on the organic content of the sediment. A dual metal uptake pathway, with a suspended particulate-bound fraction and surficial sediments, was apparent for Mn and Zn. Partitioning of Mn in sediments was related to the concentration of labile Fe, with increased levels of Fe tending to inhibit the accumulation of Mn by the clam. Tissue accumulated Zn might have been altered by the clam's internal regulation, making Zn tissue concentrations, to some degree, independent of its environmental level. The principal source of Ni accumulated by the clams exists in the soluble phase. 相似文献
3.
Kongtae Ra Joung-Keun Kim Sang Hee Hong Un Hyuk Yim Won Joon Shim Seung-Yong Lee Young-Ok Kim Jaesoo Lim Eun-Soo Kim Kyung-Tae Kim 《Ocean Science Journal》2014,49(3):279-289
Heavy metal concentrations in the surface sediments of specially managed Ulsan Bay were investigated to determine metal distribution, pollution status and its ecological risk using pollution indices (enrichment factor and geo-accumulation index), potential ecological risk index and sediment quality guidelines (SQGs). The order of mean concentration (mg/kg) of metals was Zn (361.9) > Cu (95.6) > Pb (90.7) > Cr (64.7) > Ni (32.2) > Co (16.6) > As (15.8) > Cd (0.40) > Hg (0.16) in sediments of Ulsan Bay. Spatial distribution of metals in sediments showed a significantly higher concentration near industrial complexes, indicating that metal pollution is caused by anthropogenic sources. The results of enrichment factor (EF) and geo-accumulation index (Igeo) showed that sediments were significantly accumulated with Cu, Zn, As, Cd, Pb and Hg, indicating moderate to very severe enrichment (pollution) by these metals. Based on the potential ecological risk index, Hg and Cd posed a very high and a considerable potential ecological risk. Cu and As posed a moderate potential ecological risk, while, other metals (Cr, Co, Ni, Zn and Pb) rarely posed any potential ecological risk to the coastal environments. The sediments in Ulsan Bay showed a very high level of ecological risk, dominated by Hg and Cd. Metal concentrations in sediments were 80% for Cu, 96.7% for Zn, 50% for As, 70% for Pb and 50% for Hg above the threshold effects level (TEL), respectively. 相似文献
4.
Fourteen trace elements (Ag, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, V, and Zn) were analyzed in livers and muscles from 22 fish species from the New Caledonia lagoon, which is subjected to important chemical inputs due to intense land-based mining activities (New Caledonia is the third largest world producer of Ni). The results of this baseline research indicated that livers generally concentrated trace elements to a greater extent than muscles. Nevertheless, the overall trace element concentrations in both tissues were barely above the levels reported in fish and thus contamination at the local scale was poorly discriminated. Although these levels were low, preliminary risk assessment from a global health standpoint suggests that As would be an element potentially leading to exposure of concern for fish consumers. Based on the trace element concentrations in livers and the fish trophic preferences, some trends have been observed among trophic groups: Ag, Cu, Fe, Hg, and Zn concentrations were generally higher in liver of fish with the highest trophic position whereas Cd concentrations were lower in these groups. The use of the leopard coral grouper Plectropomus leopardus as a resident top predator allowed determining the geographical variations in contamination levels with significant differences for six out of the fourteen elements investigated. The sampling sites influenced by anthropogenic inputs were revealed by high Ag, Cd, Cu, Hg, and Pb concentrations. Such geographic differences also applied to Zn but surprisingly not for the typical elements associated with Ni mining, i.e., Co, Cr, Mn and Ni. 相似文献
5.
Rob F. Nolting Wim Helder Hein J. W. de Baar Loes J. A. Gerringa 《Journal of Sea Research》1999,42(4):2393
Dissolved and particulate trace metals (Cu, Cd, Pb, Zn, Ni, Fe and Mn) measured at six stations along the Scheldt estuary in October/November 1978 are compared with more recent data. Based on Ca content in the suspended matter, three distinct geochemical regions could be distinguished: the upper estuary (salinity 1–7) dominated by fluvial mud, mid-estuary (salinity 7–17) where the composition of the suspended matter remained relatively constant, and the lower estuary where marine mud prevailed. Re-suspension of sediments is the major factor controlling the composition of the particles in the upstream region. Anoxic conditions prevailed in the upper part of the estuary extending to a salinity of 15 in 1978, while at present the seaward boundary of the anoxic water body is located at less saline waters. Furthermore, the present-day metal load is much lower than in 1978. As a consequence of the changed situation, maxima in dissolved concentrations of redox-sensitive metals in the mid/lower estuary have moved as well, which affects the trace metal re-distribution pattern. In the anoxic zone, exchange processes between dissolved and particulate metal fractions were strongly redox regulated, with Fe and Mn as excellent examples. Iron was removed from the dissolved phase in the early stages of mixing resulting in an increase in the suspended particulate matter of the leachable ‘non-residual' Fe fraction from 2 to 3.5%. Due to its slower kinetics, removal of Mn from solution occurred in mid-estuary where oxygen concentrations increased. Cu, Cd and Zn on the contrary were mobilised from the suspended particles during estuarine mixing. External inputs of Pb, and to a lesser extent of Cu, in the lower estuary resulted in the increase of their particulate and the dissolved concentrations. Calculated Kd (distribution coefficient) values were used to assess the redistribution between the dissolved and particulate phase of the investigated metals. Due to the existence of the anoxic water body in the upper estuary, the importance of redox processes in determining the Kd values could be demonstrated. The sequence of Kd values in the upper estuary (Fe, Cd, Zn, Pb > Cu > Ni, Mn) is significantly different from that in the lower estuary (Fe > Mn > Pb, Ni, Zn, Cu, Cd). Thus, in such a dynamic estuary single metal-specific Kd values cannot be used to describe redistribution processes. 相似文献
6.
Lutz Brügmann 《Marine Chemistry》1988,23(3-4)
Between 1980 and 1984 extensive studies were carried out in the Baltic Sea on trace metals (Cd, Co, Cu, Fe, Hg, Mn, Ni, Pb and Zn) in water, suspended matter and sediments. The results enabled the influence of different factors on metal distribution patterns to be considered. The vertical profiles of dissolved and particulate metals in waters of the central deep basins reflect influences caused by oxygen deficiency and anoxic conditions in near-bottom water layers. Peculiarities at Station BY15 in the Gotland Deep included high dissolved Fe, Mn and Co concentrations and remarkable enrichment of Zn (0.64%), Cd (51 μg g−1) and Cu (0.15%) in particulate matter from the anoxic zone. Manganese-rich particles were accumulated above this layer.In fine-grained soft sediments below anoxic deep waters, maximum contents of Cd, Cu and Zn were observed, relative to other coring sites, between Bothnian Bay and Lübeck Bight. The Hg content in sediments probably reflects the joint flocculation with organic matter. Land-based sources seem to play the leading part for maximum lead contents. 相似文献
7.
Some fish and crustacea caught near the northeastern Mediterranean coast of Turkey between 1977 and 1980 have been analysed by the AAS technique for their H Hg, Cd, Pb, Zn, Cu, Fe, Ni, Cr and Mn contents. In the crustacea Portunus pelagicus (crab) and Penaeus keratherus (shrimp), the two essential elements Zn and Cu, showed a linear correlation. Among the bony fish, Upeneus moluccensis (gold band goat fish), a member of the Mullidae family, and Portunus pelagicus showed a much greater tendency to accumulate Hg than other species. Although Cr concentrations in the sediments of the area studied were high, Cr levels in the organisms studied were found to be relatively low. The highly toxic metals Hg, Cd and Pb were found to be present in concentrations lower than those reported from other areas of the Mediterranean. 相似文献
8.
辽东湾表层沉积物的重金属污染特征与质量评价 总被引：1，自引：1，他引：0
本文研究了辽东湾表层沉积物中重金属的分布及污染特征，评价其生态风险及环境质量。对辽东湾表层沉积物8种重金属（As、Cu、Cd、Cr、Hg、Ni、Pb、Zn）的空间分布进行了研究，采用Hankanson法和Igeo（地累积指数）分析了该海域重金属潜在生态风险，并评价了该海域的环境质量。在辽东湾葫芦岛附近海域、西南部六股河口东南部海域以及西部近岸海域表层沉积物中As、Cu、Cd、Cr、Hg、Ni、Pb和Zn含量偏高。地累积指数法及生态风险指数法对重金属污染程度评价结果一致，辽东湾生态环境具有潜在危害的重金属主要是Cd、Hg和As，8种重金属潜在生态风险系数由高到低依次为Cd、Hg、Cu、Pb、As、Zn、Ni和Cr，各站位重金属综合潜在生态风险指数均大于150，生态风险总体上处于中等生态风险等级。Cd和Hg是该海域沉积物重金属中主要污染物，局部区域达到中、中-强污染程度。环境质量评价表明，辽东湾表层沉积物重金属引发有害生物效应的可能性不大，但Cd和Hg显著富集，应予以重视。 相似文献
9.
In different samples of Mytilus galloprovincialis Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb and Zn were determined by AAS. The mussels were taken from 11 sites in the Port of La Spezia. Typical concentration ranges (μ/g dry weight) were as follows: Cd, 2.0–6.8; Co, 0.8–3.2; Cr, 5.8–19.5; Cu, 6.9–33.7; Hg, 0.15–0.38; Mn, 11.8–37.8; Ni, 1.3–10.9; Pb, 13.9–44.6 and Zn, 203–379.Other samples were collected at 4 sites on the Promontory of Portofino and the following values were obtained: Cd, 0.8–1.1; Co, 2.6–2.9; Cu, 3.3–4.2; Hg, 0.09–0.15; Mn, 6.3–9.1; Ni, 1.2–2.4; Zn, 120–140. 相似文献
10.
厚壳贻贝对重金属的生物积累及释放规律研究 总被引：2，自引：0，他引：2
应用实验生态方法研究了厚壳贻贝对8种常见的重金属生物积累和释放情况，得出了厚壳贻贝对重金属的生物富集系数、生物半衰期及生物富集曲线．结果表明：到积累实验结束时，厚壳贻贝对Pb、Zn、Cd、Cr、Ni、As和Hg的生物富集系数分别是45．01、79．65、71．67、15．21、7．91、2．45和44．65．以积累实验结束时的生物富集系数为基准，厚壳贻贝对这几种重金属的富集能力为Zn〉Cd〉Pb〉Hg〉Ni〉Cr〉As．到释放实验结束时，厚壳贻贝对Cu、Pb、Zn、Cd、Cr、Ni、As和Hg的生物半衰期分别是43．6、29．1、38．1、31．0、26．5、35．6、127．6、36．1d．以释放实验结束时的生物半衰期为基准，厚壳贻贝对这几种重金属的释放速度呈Cr〉Pb〉Cd〉Hg〉Ni〉Zn〉Cu〉As，而且厚壳贻贝是Hg、Pb、Zn和Cd的净积累者．因此，厚壳贻贝是比较理想的重金属Hg、Pb、Zn和Cd污染的指示生物． 相似文献
11.
Concentrations of Cd, Cu, Cr, Co, Ni, Zn, Fe, Mn, Pb, As, and Sb were determined in sediment trap and bottom sediment samples collected seasonally from a station on the eastern Turkish coast of the Black Sea. Cd, Pb and Mn concentrations were highest in the sediment trap samples except during the summer period, whereas Co, Ni, Zn and Fe levels were much lower than corresponding levels found in the surface sediments. Cu, Cr, As and Sb levels showed no definite trend with sediment type. In general, with the exception of Cr, relatively lower metal concentrations in the sediment trap material were determined in the summer period. The highest mass flux, 56.5 g m−2 day−1, was measured during autumn. The highest flux of heavy metals also occurred during autumn and was strongly dependent on particle mass flux. Based on these results, we suggest that the downward vertical transport of particulate heavy metals in this region is related to the high degree of land erosion and the resultant particulate flux dynamics, which occur here. It was noteworthy that the highest concentrations of Cd, Cu, Co, Zn, Fe and Sb in particles were measured during winter a finding which suggests that enhanced fossil fuel combustion, which occurs during this period in adjacent urban and industrial areas plays an important role in the metal composition of sinking particles in nearshore waters. 相似文献
12.
邻近城市土壤重金属对九龙江口沉积土壤的影响 总被引：2，自引：0，他引：2
在研究建立于漳州地区生态地球化学调查基础上，对河口湾沉积物的重金属与人口高度集中的城市地区土壤重金属的分布特征进行了对比，分析了人为活动对河口的影响，结果表明，城区与河口湾表层样品都舍有相对区域基准值较高的Hg、Cd，而且Hg富集系数要远高于Cd的富集系数。分析两种元素来源与迁移方式可知，Hg由于可通过气态形式迁移而对河口影响更大。城区与河口湾样品的重金属进行聚类分析与主因子分析结果表明：城区土壤的As、Zn、Mo、Ni、Cr和Mn主要来自基岩来源。Pb、Se、Cd可以作为人为污染的指示元素，Hg、Sn显示与其他元素具有相对独立的行为。河口湾的元素组合与城区重金属基本相似，但Pb、Cu、Se、Mo、Cd显示出两种因素都有较大影响，可以指示人为影响与基岩源的双重作用。 相似文献
13.
14.
用原子吸收光谱法(AAS)和原子荧光光度法(AFS)测定了采集于北海银滩镇、厦门海门岛、宁德漳湾镇、乐清西门岛、温岭坞根镇、三门花桥镇等地区自然滩涂以及温岭坞根镇养殖区的可口革囊星虫(Phascolosoma esculentas)及其栖息地的底泥样品中Zn、Cu、Mn、Fe、Cd、Pb、Hg 和As 等8 种重金属含量, 并对检测结果进行了含量特征、生物体与栖息地底泥中重金属含量相关性分析、生物体重金属富集系数分析。结果表明: 不同栖息地可口革囊星虫间的重金属含量差异性显著(P<0.05), 各群体中Pb 含量均超过标准, 厦门海门岛群体中Cd 含量超标; 厦门海门岛、乐清西门岛自然滩涂栖息地和温岭坞根镇养殖区等底泥中重金属含量相对较高, 所有采样点底泥中Cu 含量以及乐清西门岛自然滩涂底泥中Cd 含量达到沉积物质量标准Ⅱ类; 可口革囊星虫对Zn、Cu、Fe 的富集系数均小于1, 对Mn、Cd、Pb、Hg 和As 的富集系数均大于1。Zn、Cu、Fe、Pb 和As 的富集系数在大部分群体间差异性较小; 可口革囊星虫中的Fe 和As 含量与底泥中的Fe 和As 含量高度正相关, Zn 和Hg 含量的相关性次之, 其余重金属元素含量的相关性较差。 相似文献
15.
Spatial and seasonal variations of the macrobenthic community and metal contamination in the Douro estuary (Portugal) 总被引：3，自引：0，他引：3
The macrobenthic community structure and characteristics of sediments were studied in samples collected seasonally at five stations in the lower mesotidal Douro estuary, Portugal. Sediment characterisation included grain size distribution, total-recoverable metals (Al, Fe, Mn, Zn, Cu, Cr, Pb, Ni and Cd), acid-volatile sulphides (AVS) and simultaneously extracted metals (SEM) and total organic matter contents. Spatial variation surpassed temporal variation both in terms of environmental parameters and community structure. Clear anthropogenic contamination in terms of Zn, Cr, Cu and Pb, and a positive SEM-AVS, indicating the potential bioavailability of these metals, were detected on the north bank of the estuary. Multivariate analysis revealed that in addition to natural sediment characteristics, the anthropogenic metal contamination was influencing the macrobenthic community structure. In fact, greater concentrations of Zn, Cr, Cu and Pb were associated with lower number of species and/or diversity. Finally, the dry weight-normalised metal concentrations appeared as a more useful tool than the SEM-AVS model in predicting disturbance of the macrobenthic community in the studied area. 相似文献
16.
Marine colloidal material (1 kDa–0.2 μm) was isolated by cross-flow ultrafiltration followed by diafiltration and freeze-drying from surface waters of the Gulf of Mexico and the Middle Atlantic Bight (MAB), as well as from estuarine waters of Galveston Bay. Elemental characterization of isolated colloidal material included organic carbon (OC) and selected trace metal (Cu, Pb, Zn, Cd, Co, Ni, Cr, Be, Fe, Al, Mn, V, Ba, and Ti) determinations. It was found that levels of these metals in marine colloids ranged from <0.1 to 50 μg/g colloidal matter, except for Fe which generally had a concentration >120 μg/g. Most metals (Cu, Pb, Zn, Ni, Al, Mn, V, and Ti) had an average concentration >1 μg/g while concentrations of Cd, Co and Be were usually <1 μg/g. Metal concentrations (μg/g) in isolated colloids were, in general, higher in Galveston Bay than in the Gulf of Mexico, suggesting either high abundance of trace metals in estuarine waters or differences in organic matter composition. Higher colloidal metal concentrations in the MAB than in the Gulf of Mexico might be due to higher terrestrial inputs in the MAB. Colloidal metal concentrations (μg/g) were generally lower than those in average soils, continental crust and suspended particles. However, metal/aluminum ratios (Me/Al) in isolated marine colloids were significantly higher than those for average soils and continental crust. Most importantly, colloids had a metal composition and metal/OC ratio (Me/C) similar to humic substances and marine plankton, suggesting that marine colloids largely originate from planktonic sources and are composed of predominately organic components. The Me/C ratios of Galveston Bay colloids followed the sequence of Cu>Ni, Cr, Zn>Mn>Co>Pb, Cd, which is similar to the Irving–Williams order except for Mn, suggesting that the interaction of metals with marine colloids is determined by the affinity of metals for specific organic ligands. 相似文献
17.
九龙江口表层沉积物重金属分布及潜在生态风险评价 总被引：5，自引：0，他引：5
对九龙江口表层沉积物中的TOC,Cu,Pb,Cd,Cr,Hg,As的含量进行了分析,TOC,Cu,Cd,Hg和As的质量分数均符合一类海洋沉积物质量标准;Pb和Cd在个别站位超标.相关性分析表明,九龙江口表层沉积物中大多数重金属呈现相近的来源特征,有机质是影响沉积物中重金属分布的重要因素.采用潜在生态风险指数法对九龙江口表层沉积物重金属污染的潜在生态风险进行了评价,结果表明,九龙江口存在一定程度的生态风险,重金属的生态风险依次为Cd>Hg>As>Pb>Cu>Cr,除Cd达到重的生态风险外,其余元素均为低生态风险. 相似文献
18.
Sediments collected from 3 onshore-offshore transects (12 stations total) in the Eastern Mississippi Bight at 5 different times during 1987–1988 have been analyzed for total Ag, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sn, Th and Zn. The data show considerable variation both spatially and temporally, largely as a result of natural variability in grain size and mineralogy. Clay-rich samples from deep water were always more metal-rich than sandy samples from shallow areas. Many samples from near the Mississippi River Delta appeared to be enriched in Ba by about a factor of two, probably as a result of contamination from oil well drilling mud, but there were few other indications of pollution influences. Many samples from throughout the area gave Mn/Fe and Cd/Fe ratios a factor of two or more lower than their Mississippi River source material. This shows that biochemical activity in the sediment is capable of solubilizing reducible and adsorbed metals. 相似文献
19.
Bustamante P González AF Rocha F Miramand P Guerra A 《Marine environmental research》2008,66(2):278-287
This study investigated 14 trace elements (Ag, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, V and Zn) in the tissues of the giant squid Architeuthis dux from the Mediterranean and Atlantic Spanish waters. As for other families of cephalopods, the digestive gland and the branchial hearts of Architeuthis showed the highest concentrations of Ag, Cd, Co, Cu, Fe, Ni, Se, V and Zn, highlighting their major role in the bioaccumulation and detoxification processes. With the exception of Hg, the muscles showed relatively low trace element concentrations. Nevertheless, this tissue contained the main proportion of the total As, Cr, Hg, Mn, Ni, and Zn body burden because muscles represent the main proportion of the squid mass. These findings suggest that the metal metabolism is overall the same as other cephalopod families from neritic waters. In females, Zn concentrations increased in the digestive gland with the squid's weight likely reflecting physiological changes during sexual maturation. Comparing the trace element concentrations in the tissues of Architeuthis, higher Ag, Cu, Hg and Zn concentrations in the squid from the Mediterranean reflected different exposure conditions. In comparison to other meso-pelagic squids from the Bay of Biscay, Cd concentrations recorded in the digestive gland suggest that Architeuthis might feed on more contaminated prey or that it displays a longer life span that other cephalopods. 相似文献
20.
为了解辽东湾西北部海域沉积物重金属的分布特征及污染程度,文章基于2017年3月辽东湾西北部12个采样站位表层沉积物7种重金属含量(Hg、Cu、Pb、Cd、Zn、Cr、As)的测定,对辽东湾西北部海洋沉积物中的重金属进行了研究。SPSS用于沉积物中重金属含量统计分析并通过地累积指数和潜在生态风险指数的方法评估重金属污染和生态危害的程度。结果显示:(1)辽东湾西北部沉积物重金属含量平均值只有Cd符合海洋沉积物一类标准,变异程度由高到低依次为Hg、Cd、As、Zn、Pb、Cu,汞和镉受人为来源控制最高;(2)地累积指数法评价结果表明重金属元素污染程度由大到小依次为Hg、Cd、Zn、As、Cu、Pb;(3)潜在生态风险指数法评价结果表明,单因子潜在生态风险系数由高到低依次为Hg、Cd、As、Cu、Pb、Zn、Cr,Hg具有很强的生态风险,综合生态风险指数在233.77~4785.15,平均1224.12,处于很强的生态风险水平。文章揭示了辽东湾西北部海域沉积物重金属的分布特征,为该海域的生态环境建设提供依据。 相似文献