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1.
芬兰北部的金矿床数量众多,大多数金矿床(点)产出于古元古界中央拉普兰绿岩带(CLGB)和库萨莫—帕拉波加片岩带内,主要分为3种类型:造山型金矿、铁氧化物铜-金(IOCG型)矿床及砂金矿。其中造山型金矿绝大部分分布于中央拉普兰绿岩带中部及库萨默地区和帕拉波加地区,最常见的矿石矿物为黄铁矿、毒砂、黄铜矿和磁黄铁矿,其次为方铅矿、闪锌矿、黝铜矿等。围岩蚀变包括钠长石化、绢云母化、黑云母化、碳酸盐化及绿泥石化。造山型金矿床主要控制因素包括构造、岩性和造山期区域变质。IOCG型矿床主要分布在CLGB的西部克拉瑞地区,容矿围岩是钠长石-直闪石石棉型岩石,矿石中富含Fe-Cu-Au±Ag、Bi、Ba、Co、Mo、Sb、Se、Te、Th、U和轻稀土元素。围岩蚀变强烈,并且有明显的分带现象。IOCG型金矿床的形成受岩浆热液活动和构造的影响较大。砂金矿床包括古砂金矿床和现代砂金矿床,主要分布在CLGB东北部。芬兰北部金矿床的研究对北极圈及邻区的找矿勘查工作具有重要意义,也为中国胶东半岛、华北克拉通北缘、小秦岭和秦岭地区及新疆北部地区进一步金矿勘查提供参考。 相似文献
2.
黔西南和黔东南是贵州的两个主要产金地区,大部分金矿都产于浊积岩中。但黔西南的金矿主要是含金蚀变岩型(或称卡林型、微细浸染型),以不可见金为主;黔东南的金矿却是含金石英脉型,以明金为主。这两种金矿都产在造山带,赋矿围岩是浊积岩,区内岩浆侵入作用不显著,成矿受背斜与断裂控制,成矿温度不高,矿石物质成分基本一致。研究表明,产生不同类型矿化的原因主要在于:黔东南地区的容矿岩石是浅变质的硅质碎屑岩,碳酸盐矿物很少;而黔西南地区是未变质的富钙硅质碎屑岩,碳酸盐矿物多。前者形成石英脉型金矿床,后者形成蚀变岩型金矿床。 相似文献
3.
Shuiyindong is one of the largest and highest grade stratabound Carlin-type gold deposits in China. This paper reports on the results of petrographic studies, electron microprobe analyses (EMPA) of arsenian pyrite, and the mass transfer during mineralization and alteration, and it presents the deposit-scale distributions of Au, As, Sb, Hg, Tl, and trace elements in a representative cross section across the Shuiyindong Carlin-type gold deposit, Guizhou Province. The main objectives were to identify the precipitation mechanisms of minerals, or elements from fluids, and the migration paths of ore-forming fluids.Petrographic and EMPA studies indicate that gold in the primary ores is mainly hosted by arsenian pyrite. Mass transfer associated with alteration and mineralization shows that Au, As, Sb, Hg, Tl, and S were significantly added to all mineralized rocks, Fe2O3 and SiO2 were immobile in the main orebodies that are hosted in bioclastic limestone, and CaO, Na2O, Sr, and Li were removed from country rocks. The relations between Fe and S indicate that the sedimentary rocks at the Shuiyindong deposit contain more iron than is needed to combine with all of their contained sulfur to form pyrite. This suggests that sulfidation and decarbonation were the principal mechanism of gold precipitation at the Shuiyindong deposit. Hg, Sb, and As commonly formed sulfide minerals, such as stibnite, realgar, and orpiment, in late-stage quartz–calcite veins, or absorbed by organic matter in argillite. Fluid cooling presumably led to depositions of stibnite, realgar, and orpiment in late-stage quartz–calcite veins. Organic matter likely served as a reductant in argillite for the ore fluids, causing the precipitation of As, Sb, Hg, and S, as well as Au.Deposit-scale distributions of gold and other relevant elements reflect the passage of fluids through the rocks. Rock strata and structures allowed the ore-forming fluids to migrate horizontally along the unconformity surface of the Middle–Upper Permian, converge on the high position of an anticline, and then ascend into the overlying strata along the anticlinal axis. The distributions of the major and trace elements show that elements that accompanied the ore-forming fluids include Au, As, Sb, Hg, Tl, and S, and that Na2O and Li were exhausted in the Longtan Formation at the anticlinal core during gold mineralization. The enrichment of Co, Cr, and Ni in the Longtan Formation at the anticlinal core might be associated with deformation that formed the anticline, or with gold mineralization. Different host rocks were preferentially mineralized by different elements. The bioclastic limestone is commonly enriched in Au, whereas the argillite is preferentially enriched in As, Hg, Sb, and Tl. The zonation of ore-forming elements in the deposit appears to be Sb–Tl–As–Hg–Au–Hg–As (from bottom to top). Enrichment of Au, As, Sb, Hg, and Tl provides useful guidance for the exploration for Carlin-type gold deposits in Guizhou. Anomalies of As and Hg in soil or stream sediment might be an important clue and these elements can be used as indicator elements. Ore-forming fluids migrated along the unconformity surface of the Middle–Upper Permian and the anticlinal axis, so these are favorable sites for exploration for Carlin-type gold deposits in Guizhou. 相似文献
4.
5.
Yunshuen Wang 《Journal of Geochemical Exploration》2010,104(1-2):61-68
Epithermal high-sulfidation gold–copper deposits at the Chinkuashih area in northeastern Taiwan occur both within Pleistocene andesite and Miocene sedimentary rocks. Spatially associated Penshan and Shumei deposits of a major gold–copper vein, the “Main Vein”, were both mineralized along an extended normal fault zone. These deposits appear to have formed from the same original hydrothermal fluids, but in different host rock types. However, the results of trace element analyses indicate that the andesite-hosted Penshan deposit has distinctly higher ore-metal and lower LREE contents than the sediment-hosted Shumei deposit. The development of higher grade ore at Penshan deposit resulted from the presence of ferrous Fe-rich minerals in andesite that caused the deposition of a larger amount of pyrite and gold during the sulfidation–reduction reactions of acidic fluid with host rocks. Moreover, the porous–permeable silicic alteration facies of the Penshan deposit provided conduits for the circulation of ore-metal bearing fluids and the trapping of metal-bearing magmatic volatile to precipitate ore minerals. On the other hand, the higher LREE contents of the Shumei open pit reflect the low pH and abundance of mainly SO42? ion in the hydrothermal fluid perhaps because sedimentary host rocks were not able to neutralize and to reduce the acidic fluid effectively through the reactions of fluid and host rocks. Moreover, the Fe-poor host rocks have lower capacity to consume H2S and precipitate pyrite and gold. In addition, the circulation of ore-metal bearing fluids and trapping of metal-bearing magmatic volatile to precipitate ore minerals could be handicapped by the low permeability and porosity of the silicified sedimentary rocks. It is apparent from these observations that physical and chemical characteristics of host rocks are important factors in controlling the ore grade of the Chinkuashih high-sulfidation gold–copper deposits. 相似文献
6.
西秦岭地区是中国最重要的金矿矿集区之一,除产出少数夕卡岩型金矿床外,几乎所有的其他金矿床都可归并为造山型、卡林型和类卡林型3种类型。研究表明,西秦岭地区中生代花岗岩主要形成于中晚三叠世,而金矿成矿主要集中在晚三叠世,它们都是华北板块与华南板块碰撞导致的秦岭造山作用的产物。西秦岭地区造山型金矿床主要赋存在泥盆系和石炭系一套复杂的构造变形和区域变质的绿片岩相岩中,主要受北西西向脆韧性剪切带控制,成矿元素组合主要为Au-Ag。矿石中含有大量显微自然金、银金矿,明金可见。成矿流体主要为变质流体。由造山作用引起的强烈构造运动为成矿流体提供了运移通道,为矿质沉淀提供了有利的场所。虽然一些造山型金矿床与中酸性岩体相邻,但矿化与岩浆活动不具直接的成因关系。西秦岭地区卡林型金矿床主要产于轻微变质的寒武系至三叠系沉积岩中,明显受地层、岩性和构造控制。金矿床中的金以超显微金和存在于含砷黄铁矿与毒砂晶格中的固溶体金为主。成矿元素组合为Au-As-Hg-Sb-Ba。成矿流体由早期形成的地层水被后期大气降水补给活化形成,也有部分岩浆水或变质水的加入。在伸展背景下大气降水通过循环演化形成了较浅层次的流体系统,导致Au等成矿元素发生沉淀而形成浸染状矿石。西秦岭地区类卡林型金矿床主要产于浅变质沉积岩建造中,受脆韧性剪切带的控制,并形成于花岗岩岩体附近。与造山型、卡林型金矿床最大的不同之处在于,类卡林型金矿床的形成与同时期的岩浆活动有密切的成因关系。矿石中存在显微自然金,载金矿物主要为黄铁矿、含砷黄铁矿和碲化物。成矿热液主要是岩浆水与变质水、建造水的混合流体。与造山型金矿床类似,流体不混溶导致类卡林型金矿床的形成。 相似文献
7.
Alteration and mineralization styles of the orogenic disseminated Zhenyuan gold deposit,southeastern Tibet: Contrast with carlin gold deposit 总被引：1，自引：0，他引：1
Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization.The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone,southeastern Tibet,was selected to clarify their difference.The alteration and mineralization from the different lithologies,including meta-quartz sandstone,carbonaceous slate,meta-(ultra)mafic rock,quartz porphyry and lamprophyre were researched.According to the mineral assemblage and replacement relationship in all types of host rocks,two reactions show general control on gold deposition:(1)replacement of earlier magnetite by pyrite and carbonaceous material;(2)alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite.Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks,it contains a large portion of Au reserve,indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure.LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks,with Au content reaching to 258.95 ppm.The diagenetic core of pyrite in meta-quartz sandstone enriched in Co,Ni,Mo,Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu,As,Sb,Au,Tl,Pb and Bi.Different host rock lithology has much impact on the alteration and mineralization features.Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration.The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu,Mo,Ag,Sb,Te,Hg,Tl,Pb and Bi,but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni.However,Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks.It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate(mainly dolomite and ankerite),sericite,pyrite and arsenopyrite develops in all types of host rocks.This is different from the Nevada Carlin type,in which alteration is mainly dissolution and silicification of carbonate host rock.On the other hand,Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits. 相似文献
8.
西秦岭金龙山卡林型金矿床地质-地球化学及矿床成因研究 总被引：1，自引：0，他引：1
金龙山金矿床位于南秦岭造山带的复理石褶冲带中,赋矿围岩为碎屑岩-碳酸盐建造,矿化明显受地层岩性与韧-脆性构造发育程度的控制。矿床稀土元素地球化学研究表明,地层岩石、矿石和热液矿物的轻重稀土分异程度和特征参数基本一致,表明成矿流体应主要来自于赋矿地层。铅同位素研究表明,地层岩石、矿石和热液矿物均具有较高的放射性成因的铅同位素组成,且均落入南秦岭造山带的泥盆系范围内,暗示铅也主要来自赋矿地层。对前人已有的碳-氧-硫-氢同位素组成和流体包裹体数据综合分析表明,碳和氧应主要来自海相碳酸盐的溶解作用,硫主要来自海相硫酸盐的热化学还原反应;从成矿早阶段到晚阶段,成矿流体的δ18O及δD值向大气降水线＂漂移＂,指示成矿流体以盆地建造水和变质水为主,在晚阶段有大气降水加入。金龙山金矿床与卡林型金矿床的矿床地质-地球化学特征相似,应属于卡林型金矿床,其形成于秦岭造山带陆内造山作用过程中,多层次陆壳叠置加厚的地球动力学背景,是陆内碰撞造山作用的产物。 相似文献
9.
《地学前缘(英文版)》2016,7(3)
It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments.For giant orogenic,intrusion-related gold systems(IRGS) and Carlin-type gold deposits and iron oxide-copper-gold(IOCG) deposits,there are common factors among all of these at the lithospheric to crustal scale.All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or,in the case of most Phanerozoic orogenic giants,define the primary suture zones between tectonic terranes.Giant provinces of IRGS,IOCG,and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province.The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids,whereas the association of such melts with Carlin-type ores is more indirect and enigmatic.Giant orogenic gold provinces show no direct relationship to such magmatism.forming from metamorphic fluids,but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.In contrast to their province scale similarities,the different giant gold deposit styles show contrasting critical controls at the district to deposit scale.For orogenic gold deposits,the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits,with resultant geometrical and lithostratigraphic complexity as a guide to their location.There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits,and those few giants are essentially preservational exceptions.Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks,enriched in syngenetic gold,to be located below an impermeable cap along antiformal "trends".Hydrocarbons probably played an important role in concentrating metal.The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock.All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources,partly due to economic factors for this relatively poorly understood,low Cu-Au grade deposit type.The supergiant Olympic Dam deposit,the most shallowly formed deposit among the larger IOCGs,probably owes its origin to eruption of volatile-rich hybrid magma at surface,with formation of a large maar and intense and widespread brecciation,alteration and Cu-Au-U deposition in a huge rock volume. 相似文献
10.
Zhou Taofa Wu Mingan Fan Yu Duan Chao Yuan Feng Zhang Lejun Liu Jun Qian Bing Franco Pirajno David R. Cooke 《Ore Geology Reviews》2011,43(1):154-169
The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling. 相似文献
11.
The northern Norrbotten area in northern Sweden, is an important mining district and hosts several deposits of Fe-oxide Cu-Au-type. One of the best examples of spatially, and possibly genetically, related apatite–iron and copper–gold deposits in the region is at Tjårrojåkka, 50 km WSW of Kiruna. The deposits are hosted by strongly sheared and metamorphosed intermediate volcanic rocks and dolerites and show a structural control. The Tjårrojåkka iron deposit is a typical apatite–iron ore of Kiruna-type and the Tjårrojåkka copper occurrence shows the same characteristics as most other epigenetic deposits in Norrbotten. The host rock has been affected by strong albite and K-feldspar alteration related to mineralisation, resulting in an enrichment of Na, K, and Ba. Fe and V were depleted in the altered zones and added in mineralised samples. REE were enriched in the system, with the greatest addition related to mineralisation. Y was also mobile associated with albite alteration and copper mineralisation. The Tjårrojåkka iron and copper deposits show comparable hydrothermal alteration minerals and paragenesis, which might be a product of common host rock and similarities in ore fluid composition, or overprinting by successive alteration stages. Mineralogy and mineral chemistry of the alteration minerals (apatite, scapolite, feldspars, amphiboles, and biotite) indicate a higher salinity and Ba/K ratio in the fluid related to the alterations in the apatite–iron occurrence than in the copper deposit, where the minerals are enriched in F and S. The presence of hematite, barite, and in SO4 in scapolite suggests more oxidising-rich conditions during the emplacement of the Tjårrojåkka-Cu deposit. From existing data it might be suggested that one evolving system created the two occurrences, with the copper mineralisation representing a slightly later product. 相似文献
12.
南天山金矿带是世界上一个重要的金矿资源地,产出数个超大型金矿。这些矿床有许多共同点:如大地构造背景、构造环境、含矿岩系、容矿岩石、控矿构造、矿体形态、矿石类型、主要金属矿物、载金矿物、围岩蚀变、成矿时代和成矿方式等相似。但是,进一步分析可以发现他们之间也存在一定差异。例如,在构造位置、物质成分、围岩蚀变等方面存在差异。对本区一些基本的成矿特征进行分析后,认为矿带的形成与南天山造山带的形成和演化关系密切,华力西期与花岗岩活动有关的热液成矿作用应是主要的成矿作用。因此,该矿带应属于细脉浸染型金矿较为合适。南天山尚有寻找此类金矿的远景。 相似文献
13.
流体是地球各圈层之间相互作用的纽带,在成岩、成矿过程中起着十分重要的作用。目前,流体的研究主要集中在流体对先存矿物岩石进行的交代作用方面,而对流体直接结晶形成的矿物领域研究较少。文中根据作者近几年的研究成果对从流体直接结晶而成的矿物——流体晶以及流体晶矿物组合、流体岩等的定义、特征进行了归纳总结。最新的研究结果显示：岩浆中可以含有大量的流体,这些流体来源既可以是岩浆演化富集、岩浆与围岩相互作用产生,亦可以是外部来源。因此,流体晶矿物、流体岩在自然界应该是普遍存在的。流体晶矿物的提出将深化人们对地质过程的理解,发展岩石学及矿床学的研究新领域,有利于矿床勘探和成矿预测。 相似文献
14.
甘肃李坝金矿围岩蚀变与金成矿关系 总被引：1，自引：0，他引：1
西秦岭地区是目前国内造山型和卡林型金矿找矿的热点地区之一,已发现的甘肃李坝造山型金矿为超大型规模。以李坝金矿6号矿带为例,系统地研究了其蚀变矿物组合、近矿围岩蚀变分带及相应的金矿化特征,总结了矿床(带)的蚀变分带模式。该模式具典型的中心式环带结构,可分为3个蚀变带,由中心向外依次为黄铁绢英岩化带、绢云母化带和绿泥石化带。蚀变矿物组合分别为黄铁矿+绢云母+石英±毒砂±白云母±电气石±方解石、绢云母+绿泥石+石英+黄铁矿±黑云母及绿泥石+黑云母±绢云母±黄铁矿;与这3个蚀变带相对应的是金的富集带、矿化带和无矿带。蚀变岩石物质组分迁移分析表明,围岩蚀变及其分带是热水流体/岩石反应时岩石化学组分发生迁移的结果,矿化伴随着蚀变发生,且金矿化与黄铁矿化和浸染状硅化关系最为密切。 相似文献
15.
青藏高原碰撞造山背景造山型金矿床:构造背景、地质及地球化学特征 总被引：2，自引：1，他引：1
青藏高原碰撞造山背景下形成了雅鲁藏布江缝合带及哀牢山造山带两条造山型金矿带。雅鲁藏布江缝合带包含马攸木、念扎、邦布及折木朗金矿等;该矿带形成于拉萨地块及特提斯喜马拉雅地层序列地壳初始缩短加厚的背景(59~44Ma),与林子宗火山岩和高压变质岩同期形成。控矿构造主要以EW向展布。金以自然金形式赋存在石英硫化物脉及石英脉两侧以绿片岩相变质为主的千枚岩及板岩中。哀牢山造山带包含镇沅、金厂、大坪及长安金矿等,主要形成于35~26Ma,成矿背景为区域发生大规模走滑剪切,矿区内分布有成矿前期的煌斑岩及富碱斑岩。控矿构造主要以NW-SE向展布,围岩变质级低于雅鲁藏布江缝合带。C-S-H-O-Pb同位素变化较大,整体雅鲁藏布江缝合带及哀牢山造山带造山型金矿成矿流体主要来源于深部地幔流体、围岩地层的变质流体及岩浆流体,成矿围岩的差异性也会导致同位素的变化性。 相似文献
16.
Li Songtao Xia Yong Liu Jianzhong Xie Zhuojun Tan Qinping Zhao Yimeng Meng Minghua Tan Lijin Nie Rong Wang Zepeng Zhou Guanghong Guo Haiyan 《中国地球化学学报》2019,38(4):587-609
The newly discovered Baogudi gold district is located in the southwestern Guizhou Province, China, where there are numerous Carlin-type gold deposits. To better understand the geological and geochemical characteristics of the Baogudi gold district, we carried out petrographic observations, elemental analyses, and fluid inclusion and isotopic composition studies. We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou. Three mineralization stages, namely, the sedimentation diagenesis, hydrothermal (main-ore and late-ore substages), and supergene stages, were identified based on field and petrographic observations. The main-ore and late-ore stages correspond to Au and Sb mineralization, respectively, which are similar to typical Carlin-type mineralization. The mass transfer associated with alteration and mineralization shows that a significant amount of Au, As, Sb, Hg, Tl, Mo, and S were added to mineralized rocks during the main-ore stage. Remarkably, arsenic, Sb, and S were added to the mineralized rocks during the late-ore stage. Element migration indicates that the sulfidation process was responsible for ore formation. Four types of fluid inclusions were identified in ore-related quartz and fluorite. The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4 ± N2 system, with medium to low temperatures (180–260 °C) and low salinity (0–9.08% NaCl equivalent). The late-ore stage fluids featured H2O–NaCl ± CO2 ± CH4, with low temperature (120–200 °C) and low salinity (0–7.48% NaCl equivalent). The temperature, salinity, and CO2 and CH4 concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage. The calculated δ13C, δD, and δ18O values of the ore-forming fluids range from − 14.3 to − 7.0‰, −76 to −55.7‰, and 4.5–15.0‰, respectively. Late-ore-stage stibnite had δ34S values ranging from − 0.6 to 1.9‰. These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids, with minor contributions from strata. Collectively, the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou. It is likely that the Baogudi gold district, together with other Carlin-type gold deposits in southwestern Guizhou, was formed in response to a single widespread metallogenic event.
相似文献17.
M. Cathelineau 《Mineralium Deposita》1983,18(1):89-97
A comprehensive study of alteration minerals, especially clays, developed around or within French hydrothermal uranium ore bodies (Vendée and Margeride), generally associated with leucogranitic rocks, using optical examinations, classical methods of clay mineralogy and electron microprobe determinations, demonstrates the general feature of potassic minerals as products of reaction between ore forming fluids and host rocks. Six stages of alteration follow the typical metallogenic sequence established for numerous deposits: early stages and uranium stages 1) 2) 3) with phengites, illite, mixed layered illite and K-montmorillonites; 4), early reworking of pitchblende 1 to pitchblende 2 with complex zoning around ores: illite, illite-K-montmorillonites; 5) then to coffinite-smectites; 6) sooty pitchblende, during supergene weathering, with smectites and kaolinite. Potassic metasomatism by fluids in desequillibrium with the minerals of the granitic host rocks, essentially albite, explains the complex alterations in K-smectites, mixed layered minerals and adularia. Variety of alteration products in each alteration zone indicate incomplete reactions of the solids and chemical potential gradients on a small scale. 相似文献
18.
黔东南金成矿区位于江南造山带金成矿省的西南端,成矿条件优越。坑头金矿床是黔东南金成矿区的一个中型矿床,在其深部找矿中,发现除石英脉型矿体外,还存在蚀变岩型矿体。然而,这种蚀变岩型矿体的构造形态、蚀变类型、与石英脉型矿体之间关系和金的赋存状态尚不清楚。本研究与当前的勘查工作紧密结合,围绕石英脉型矿体和新发现的蚀变岩型矿体为研究切入点,借助微区分析技术(扫描电镜和电子探针)进行系统的“流体- 蚀变- 成矿”研究。蚀变矿物金红石矿物化学显示为热液成因,具有典型造山型金矿床的金红石标型特征。围岩的沉积- 成岩过程(包括低级变质作用过程),主要形成了草莓状黄铁矿和含铁碳酸盐岩,为后期含金硫化物(黄铁矿和毒砂)的形成提供物质基础(如Fe)。金的成矿富集过程主要经历了绢云母+毒砂+黄铁矿+石英(Ser+Apy+Py+Qtz)阶段、黄铁矿+毒砂+石英(Py+Apy+Qtz)阶段和自然金+石英(Au0+Qtz)阶段。在Ser+Apy+Py+Qtz阶段,主要表现为含矿流体与围岩的初级交代,形成大量浸染状黄铁矿+毒砂的硫化带;Py+Apy+Qtz阶段主要为流体沿着剪切带再交代,形成蚀变岩型矿体;Au0+Qtz阶段主要表现为含金石英大脉的形成。金的赋存状态研究显示,蚀变岩矿体中Au以他形显微- 次显微自然金赋存在蚀变岩硫化物裂隙中,或以化学结合态方式赋存在黄铁矿和毒砂中(后者占主导)。在晚期Au0+Qtz阶段,自然金呈自形、粗粒(~0. 5 mm)赋存在石英脉中。综合研究认为,多期构造(流体)交代导致的溶解- 再沉淀可能是坑头金富集成矿主要原因之一。 相似文献
19.
金矿立体地球化学探测模型与深部钻探验证 总被引：1，自引：0，他引：1
深部资源地球化学探测科学问题的的焦点是元素大深度垂向迁移机理和立体地球化学探测模型的建立。本文以胶东蚀变岩型金矿和贵州水银洞卡林型金矿钻孔岩芯和地表联合取样获得的数据, 建立千米深度立体地球化学探测模型。蚀变岩型金矿立体地球化学模型显示, Au、S和Hg与金矿密切相关, 分布模式既有相似性又有差异性, Au的立体几何分布模式兼具矿化剂元素S和远程指示元素Hg的双重特征, 金异常和矿化剂元素硫与矿体倾斜方向一致, 反映了成矿过程中流体沿控矿构造的轴向运移; 金异常与类气体元素汞在垂向上一致, 而且出现从矿体到地表的连续贯通式异常, 反映了流体沿微裂隙和纳米孔的垂向迁移。卡林型金矿立体地球化学模型显示, Au、As、Sb、Hg、Tl和S在不整合面都显示高含量特征, 与深部层状主矿体分布一致; 在矿体上覆地层中都存在弱异常, 显示了明显的成矿流体沿隐伏微小断裂垂向迁移特点; 所不同的是Sb和Tl元素在不整合面附近显示了最高的元素含量, 而Sb和Hg在近地表均显示了明显高的异常特征。立体几何模型清晰地显示了矿体的展布特征和范围, 而且金及其伴生元素垂向迁移在地表形成清晰异常, 为利用金及伴生元素和矿化剂元素进行深部矿体三维预测提供了重要依据, 对指导深部金矿勘查发挥了重要作用。针对胶东蚀变岩型金矿地表完全被土壤覆盖区的穿透性地球化学微细粒级土壤采样, 金属活动态提取分析圈定的异常, 经深部钻探验证, 胶东焦家成矿带五一村3200 m钻探, 在2428.00~3234.16 m深度发现6层矿化体, 其中高品位矿体位于2854 m深度; 上宫金矿地表基岩出露, 采集断层泥或裂隙岩石样品, 可以清晰探测深部异常, 经2000 m钻探, 在1312 m处发现高品位金铅锌银矿体; 贵州水银洞采集地表细粒级土壤, 能够直接有效地揭示深部金矿体, 经500~1500 m钻探验证, 在300~1500 m深度新增金资源量203 t。 相似文献
20.
爬奔金矿位于老挝西北部琅勃拉邦构造带,是该带内迄今为止发现的唯一大型金矿床。为了解该矿床形成时的沉积环境及矿床成因,对矿区的岩石及矿石进行了微量元素、稀土元素及同位素等方面的地球化学特征研究。矿区岩石的微量元素特征表明,矿床形成时处于相对缺氧的沉积环境;矿石的硫、氢、氧、碳同位素特征证明岩浆流体参与了成矿作用; Eu异常特征说明围岩灰岩不是矿床的成矿母岩; Ce异常特征表明矿区形成于水体深度适中的氧化还原界面附近; Y/Ho特征也说明金矿床与围岩灰岩的源区不同。通过与我国滇黔桂地区的卡林型金矿进行对比研究,爬奔金矿虽然在诸多方面与卡林型金矿有着相似之处,但两者之间更多的是差异性。综合研究认为,爬奔金矿应为与岩浆有关的热液矿床。 相似文献