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1.
对淡水水体沉积物磷的环境生态效应的国内外研究热点和领域进行了综述、评价;提出了尽快开展真正内源磷——地质成因磷自然释放的水环境生态效应研究,特别是天然条件下（如人为干扰少的源头河流）,富磷河流水体主要初级生产者——藻类生态响应研究的建议。  相似文献   

2.
磷是生命体的必需元素,也是粮食生产的重要限制因素。磷的生物地球化学循环不仅调控着海洋的初级生产力,而且影响着全球气候系统,并决定着磷矿资源的形成和分布,与地球上生命的生存繁衍息息相关。当前“地球系统科学”理论将大气圈、水圈、岩石圈（地壳和上地幔）和生物圈等子系统有机整合,为研究磷的生物地球化学循环提供了更加广阔的视野。基于已有研究,结合“地球系统科学”理论观点,针对磷的生物化学循环获得了以下重要认识： 磷在地质历史时期的演化决定了现今磷在全球范围内（陆地生态系统与海洋生态系统）的循环模式;人类的工业和农业活动作为重要的地质营力,改变了磷的生物地球化学循环过程,造成了磷矿枯竭的资源危机及水体富营养化的环境问题;解决磷短缺的资源危机问题和磷过剩的环境污染问题的关键在于调控引起这些问题的生物地球化学循环过程。  相似文献   

3.
A large environmental restoration project designed to improve the hydrological conditions of the Florida Everglades and increase freshwater flow to Florida Bay is underway. Here we explore how changing freshwater inflow to the southern Everglades is likely to change the input of nutrients to Florida Bay. We calculated annual inputs of water, total phosphorus (TP), total nitrogen (TN), and dissolved inorganic nitrogen (DIN) to Everglades National Park (ENP) since the early 1980s. We also examined changes in these nutrient concentrations along transects through the wetland to Florida Bay and the Gulf of Mexico. We found that the interannual variability of the water discharge into ENP greatly exceeded the interannual variability of flow-weighted mean nutrient concentrations in this water. Nutrient inputs to ENP were largely determined by discharge volume. These inputs were high in TN and low in TP; for two ENP watersheds TN averaged 1.5 mg l?1 (0.11 mM) and 0.9 mg l?1 (0.06 mM) and TP averaged 15 μg l?1 (0.47 μM) and 9 μg l?1 (0.28 μM). Both TP and DIN that flowed into ENP wetlands were rapidly removed from the water. Over a 3-km section of Taylor Slough, TP decreased from a flow-weighted mean of 11.6 μg l?1 (0.37 μM) (0.20 μM) and DIN decreased from 240 μg l?1 (17μM) to 36 μ l?1 (2.6 μM). In contrast, TN, which was generally 95% organic N, changed little as it passed through the wetland. This resulted in molar TN:TP ratios exceeding 400 in the wetland. Decreases in TN concentrations only occurred in areas with relatively high P availability, such as the wetlands to the north of ENP and in the mangrove streams of western ENP. Increasing freshwater flow to Florida Bay in an effort to restore the Everglades and Florida Bay ecosystems is thus not likely to increase P inputs from the freshwater Everglades but is likely to increase TN inputs. Based on a nutrient budget of Florida Bay, both N and P inputs from the Gulf of Mexico greatly exceed inputs from the Everglades, as well as inputs from the atmosphere and the Florida Keys. We estimate that the freshwater Everglades contribute <3% of all P inputs and <12% of all N inputs to the bay. Evaluating the effect of ecosystem restoration efforts on Florida Bay requires greater understanding of the interactions of the bay with the Gulf of Mexico and adjacent mangrove ecosystems.  相似文献   

4.

Aspects of riverbed evolution including bank erosion in the Ural River basin have been considered in this paper. The natural morphodynamic types of riverbeds have been described. The spatial features of their genesis have been characterized within the Ural River basin. To study the riverbed processes, decoding of remote sensing data of the water surface has been used. The risks for the infrastructure facilities and for the residential districts have been analyzed in terms of the bank erosion in the Ural River basin. The issues concerning the border between the Russian Federation and the Republic of Kazakhstan due to riverbed reconfiguration of the Ural River have been outlined. Maps of the development of bank erosion in the Ural River basin have been created. A way to solve the problem of riverbed evolution along the border area has been proposed by organizing an Intergovernmental Specially Protected Natural Zone.

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5.
Benthic fluxes of soluble reactive phosphorus (SRP) and dissolved inorganic carbon (DIC) were measured in situ using autonomous landers in the Gulf of Finland in the Baltic Sea, on four expeditions between 2002 and 2005. These measurements together with model estimates of bottom water oxygen conditions were used to compute the magnitude of the yearly integrated benthic SRP flux (also called internal phosphorus load). The yearly integrated benthic SRP flux was found to be almost 10 times larger than the external (river and land sources) phosphorus load. The average SRP flux was 1.25?±?0.56?mmol?m?2?d?1 on anoxic bottoms, and ?0.01?±?0.08?mmol?m?2?d?1 on oxic bottoms. The bottom water oxygen conditions determined whether the SRP flux was in a high or low regime, and degradation of organic matter (as estimated from benthic DIC fluxes) correlated positively with SRP fluxes on anoxic bottoms. From this correlation, we estimated a potential increase in phosphorus flux of 0.69?±?0.26?mmol?m?2?d?1 from presently oxic bottoms, if they would turn anoxic. An almost full annual data set of in situ bottom water oxygen measurements showed high variability of oxygen concentration. Because of this, an estimate of the time which the sediments were exposed to oxygenated overlying bottom water was computed using a coupled thermohydrodynamic ocean?Csea and ecosystem model. Total phosphorus burial rates were calculated from vertical profiles of total phosphorus in sediment and sediment accumulation rates. Recycling and burial efficiencies for phosphorus of 97 and 3%, respectively, were estimated for anoxic accumulation bottoms from a benthic mass balance, which was based on the measured effluxes and burial rates.  相似文献   

6.
The war in Chechnia has few purely military targets and virtually no safe quarters for the population of the republic. The full scale of environmental devastation caused by the Russian invasion of Chechnia will probably be never properly quantified. Reports by independents paint a picture of an immense destruction of the country by the invading Russian army including whole towns and villages. In Chechnia Russia has been up against a national war of liberation and not as the Russian political and military establishment claims a few illegal armed bandits. The social structure of the Chechen society reinforces the long history of Chechen resistance to continuous attempts to subjugate the Chechen people and their integration into Russian political and economic structures.The current tragedy of Chechnia, the latest in series since the incorporation of the Caucasus into the Tsarist Empire, is to a large extend due to thematrioshka effect and the inability of the current Russian authorities to develop a viable nationality policy which would allow genuine devolution of power to the constituent parts of the Russian Federation. The dominant view of the current Russian leadership is that the constitutional principle of preserving the state on its historical and geo-political basis overrides the right of ethnic people to their own clearly defined sovereign political and economic entities. To many Russian and outside observers the Russian Federation appears to be a corpse without a head. Unless Russia's policy changes substantially there must be substantial doubts whether the Federation can survive in its present form. The prolonged guerilla war which is bound to follow the December 1994 invasion of Chechnia, rather than preserving the integrity of the Russian Federation would surely add to its progressive disintegration.  相似文献   

7.
There is a mistaken perception of a growing trade with Russia and an increase in the amount of investment available for Western businessmen in the Federation. This article argues that in fact, there is no room for real investment in the Russian Federation, as defined in Western terms and that the nature of Russian industrial organisation is such that the military dictates the nature of all meaningful industrial production, as well as having the pick of the raw materials and the workforce. There is a growing disillusion with Western methods of management and also this has spread to treaty commitments (such as the Conventional Forces Europe (CFE)) and any attempt to exercise military restraint, because of the mockery of the Western press when such measures have been taken, as in Chechnia. Overall, the need the West has to make itself believe that the Russian Federation is rapidly becoming a new trading partner in a safer international system is fundamentally mistaken. Russia and America have the ability, should they wish or have to, to marginalise a newly united Europe. Furthermore, Russia has the ability to dominate such a European federation and to claim the status of a Regional Superpower. Without America there would be no security organisation that could resist such a claim. Russia is not as far along the road to democracy as hard-pressed Western governments need to claim, so that they may cut defence expenditure and it is dangerous to pretend that the Russian Federation is capable of exporting much more than aggression. The West may well be spending money which it claims is part of planned investment in Russia, to simply buy off the aggressor state Russia has rapidly become, for another few months.  相似文献   

8.
The dominant phosphorus compound classes were characterized in marine samples using a new, high recovery method for isolating and concentrating bulk dissolved organic matter (DOM) called combined electrodialysis + reverse osmosis (ED/RO). In contrast to earlier studies that use ultrafiltration (UF) to recover only the high molecular weight DOM, ED/RO is capable of isolating both low molecular weight (LMW) and high molecular weight (HMW) DOM. Samples were collected from a broad range of marine environments: along a transect incorporating coastal and offshore waters off the Southeastern United States, in Effingham Inlet, a Pacific fjord located on Vancouver Island, British Columbia and in the Amundsen Sea, Antarctica. Results from phosphorus nuclear magnetic resonance (31P NMR) analysis reveal a similar abundance of P compound classes among samples, phosphate esters (80–85%), phosphonates (5–10%) and polyphosphates (8–13%). These samples contain significantly higher proportions of polyphosphate P and P esters and lower proportions of phosphonates than measured in previous studies using the UF method. The much higher levels of polyphosphate detected in our samples suggests that polyphosphate is present mainly in the LMW dissolved matter fraction. Polyphosphates in dissolved matter may be present as (or derived from) dissolved nucleotides or organismal polyphosphate bodies, or both. Low molecular weight P esters are possibly composed of phosphoamino acids and small carbohydrates, like simple sugar phosphates and/or dissolved nucleotides. Phosphonates in DOM are more prevalent as HMW phosphonate compounds, which suggests that LMW phosphonates are more readily utilized in marine ecosystems. Overall, the investigation of DOM across a size spectrum that includes both the HMW and the LMW fractions reveals a new picture of phosphorus distribution, cycling and bioavailability.  相似文献   

9.
The availability of reactive phosphorus (P) may promote cyanobacterial blooms, a worldwide increasing phenomenon. Cyanobacteria may also regulate benthic P cycling through labile organic input to sediments, favouring reduced conditions and P release, ultimately acting as self-sustainment mechanism for the phytoplankton blooms. To analyse P–cyanobacteria feedbacks and compare external versus internal loads, we investigated P cycling in the Curonian Lagoon, a freshwater estuary with recurrent summer blooms. At two sites representing the dominant sediment types, we characterised P pools and mobility, via combined pore water analysis, calculation of diffusive exchanges and flux measurements via sediment core incubations. Annual P budgets were also calculated, to analyse the whole lagoon role as net sink or source. Muddy sediments, representing nearly 50 % of the lagoon surface, displayed higher P content if compared with sandy sediments, and most of this pool was reactive. The muddy site had consequently higher pore water dissolved inorganic phosphorus (DIP) concentrations maintaining high diffusive gradients. However, measured fluxes suggested that both sediment types were mostly P sinks except for a large DIP regeneration (nearly 30 μmol m?2 h?1) recorded at the muddy site during an intense cyanobacteria bloom. Such internal regeneration had the same order of magnitude as the annual external P load and may offset the net annual DIP sink role of the estuary. It may also prolong the duration of the bloom. Our results suggest that positive feedbacks can regulate N-fixing cyanobacteria blooms and internal P recycling, through either diffusive fluxes or sediment settling and resuspension.  相似文献   

10.
文章介绍了甘肃龙首山地区绿草泉沟磷矿的地质特征、矿床成因、找矿标志等,对该地区的含磷岩系进行了详细的剖析。绿草泉沟磷矿赋存于震旦系草大板组底部碎屑岩中,呈层状展布于复式背斜两翼;通过普查工作共圈定磷矿体17条,矿体呈层状、似层状,长度40～1840m,厚度1.08～7.01m,控制矿体斜深为40～240m,品位w(P_2O_5)=12.04%～24.08%;矿石自然类型属砂质磷块岩,工业类型为硅质型磷矿。通过矿床地质特征、沉积环境分析,认为绿草泉沟磷矿属沉积-变质型磷矿床。  相似文献   

11.
A nutrient mass balance for the tidal freshwater segment of the James River was used to assess sources of nutrients supporting phytoplankton production and the importance of the tidal freshwater zone in mitigating nutrient transport to marine waters. Monthly mass balances for 2007–2010 were based on riverine inputs, local point sources (including sewer overflow events), ungauged inputs, riverine outputs, and tidal exchange. The tidal freshwater James River received exceptionally high areal loads (446 mg TN m?2 day?1 and 55 mg TP m?2 day?1) compared to other estuaries in the region and elsewhere. P inputs were principally from riverine sources (84 %) whereas point sources contributed appreciably (54 %) to high N loads. Despite high loading rates and short water residence time, areal mass retention was high (143 mg TN m?2 day?1 and 33 mg TP m?2 day?1). Retention of particulate fractions occurred during high discharge, whereas dissolved inorganic fractions were retained during low discharge when chlorophyll-a concentrations were high. On an annualized basis, P was retained more effectively (59 %) than N (32 %). P was retained by abiotic mechanisms via trapping of particulate forms, whereas N was retained through biological assimilation of dissolved inorganic forms. Results from a limited suite of stable isotope determinations suggest that DIN from point sources was preferentially retained. Combined inputs from diffuse and point sources accounted for only 20 % and 36 % (respectively) of estimated algal N and P demand, indicating that internal nutrient recycling was important to sustaining high rates of phytoplankton production in the tidal freshwater zone.  相似文献   

12.
We used a sequential extraction technique and 210Pb dating to determine the chemical form and amount of particulate phosphorus (PP) that is retained during burial in 1-m-long sediment cores collected along a salinity gradient from tidal freshwater to the mesohaline waters of the Patuxent River, a subestuary of the Chesapeake Bay. PP buried in the study sites with salinity values ≤3 was similar in concentration and form to PP entering the Patuxent from the watershed, suggesting efficient sequestration by the sediments at these low-salinity sites. PP extracted with citrate–dithionite–bicarbonate was the dominant form of PP at all salinities and all depths, and organic-P was the second most abundant fraction. We estimated that 81% of PP entering from the watershed is trapped in the sediments of the upper Patuxent subestuary and that the subtidal sediments retain three times as much PP as the marshes adjacent to the study sites.  相似文献   

13.
The paper reports monitoring results (obtained in 2000–2001) of the seasonal variations in the quality of lower atmospheric air in the coastal zone of the northern Caspian Sea due to the occurrence of aerosols with submicrometer-sized particles and soot in the lower atmosphere. The contributions of natural and anthropogenic factors to the ecological risk for the local human population are evaluated, along with the contribution of the premature mortality of the human population in the coastal zone in 2005 to its overall average death rate for the Russian Federation (approximately 24%). The authors’ estimates are consistent with those made by the World Health Organization at the United Nations (WHO) for the Russian Federation as a whole (approximately 21%). The information presented in this publication is important for evidence-based recommendations on preventive environment-protective measures to be taken with regard for the development of oil and gas fields on- and offshore the northern Caspian Sea.  相似文献   

14.
A survey of the interactions between phosphorus (P) species and the components of calcareous soils shows that both surface reactions and precipitation take place, especially in the presence of calcite and limestone. The principal products of these reactions are dicalcium phosphate and octacalcium phosphate, which may interconvert after formation. The role of calcium carbonate in P retention by calcareous soils is, however, significant only at relatively high P concentrations – non-carbonate clays play a more important part at lower concentrations. In the presence of iron oxide particles, occlusion of P frequently occurs in these bodies, especially with forms of the element that are pedogenic in origin. Progressive mineralization and immobilization, often biological in nature, are generally observed when P is added as a fertilizer.  相似文献   

15.
The behavior of phosphorus is considered at major stages of the sedimentary cycle beginning with supply sources for its delivery into the ocean to precipitation and its sedimentation, localization and subsequent diagenetic redistribution in bottom sediments. River runoff represents the main phosphorus source in the ocean. It delivers annually about 1.5 Mt of dissolved phosphorus and more than 20 Mt of suspended phosphorus into the ocean. Up to 80% of the suspended phosphorus incorporated in the lithogenic material precipitates within submarine continental margins. Phosphorus dissolved in seawater repeatedly participates in biogeochemical processes owing to its assimilation by phytoplankton that annually consumes from 1.5 to 2.5 Gt of phosphorus. Dissolved phosphorus is incorporated in organic remains and precipitates from seawater by a biogenic mechanism, too. Only a part of phosphorus settled onto the bottom is buried in sediments. Due to reducing diagenetic processes, up to 30–40% of the primarily precipitated phosphorus diffuses from the upper layer of sediments into bottom water. Diffusion flux into the ocean significantly exceeds the supply of dissolved phosphorus from river runoff. The absolute mass phosphorus dispersed in sediments is several orders of magnitude greater than the mass concentrated in phosphorite deposits. However, the majority of phosphorite formation epochs coincide with the intensification of total phosphorus accumulation in marine sediments in conditions of humid climate, intense chemical weathering of rocks on continents, and considerable expansion of the oceanic shelf area.  相似文献   

16.
沉积物中磷的赋存形态及磷形态顺序提取分析方法   总被引：11，自引：1，他引：10  
阐述了当前我国水体富营养化的现状,水体的富营养化与水体中磷、氮的浓度以及二者的浓度比值有着密切的关系。水体富营养化时氮和磷的浓度均很高,但没有一个固定的值,是在一个较宽泛的富营养范围内,氮和磷的浓度比值大多在10∶1～20∶1。湖泊沉积物作为湖泊水体中磷的重要蓄积库,是湖泊流域磷循环的重要归属,也是湖泊水体内源性磷的主要来源,沉积物中极少量的稳定磷转化为活性磷就会造成湖泊水体富营养化。文中介绍了沉积物中无机磷形态的分类,评述了欧盟标准局在研制湖泊沉积物磷形态标准物质时比对采用的4种提取方法(Willimas法、Hieltjes-Lijklema法、Ruttenberg法、Golterman法),总结了国内外学者所应用的沉积物中磷的各种形态提取方法和磷各形态的分析测定方法,国内学者应用的方法是在国外学者方法的基础上提出的,阐述了顺序提取方法及其地球化学意义。简要评述了湖泊沉积物中磷的生物释放、物理释放和化学释放三种释放机制,这三种释放机制相辅相成,在一特定的环境条件下某一过程可能占主导地位来控制沉积物磷的释放。最后提出应该加强对沉积物中磷的各种形态的专属提取剂及其提取有效性的分子表征和检测,更加细化对于沉积物中磷形态的分类和创新各种磷形态的分析方法,建立沉积物-水体磷的迁移、循环和转化模型,这对于从根本上解决富营养化问题具有重要意义。  相似文献   

17.
Utilizing a sequential extraction technique this study provides the first quantitative analysis on the abundance of sedimentary phosphorus and its partitioning between chemically distinguishable phases in sediments of the Bering Sea, the Chukchi Sea and the Mackenzie River Delta in the western Arctic Ocean. Total sedimentary phosphorus (TSP) was fractionated into five operationally defined phases: (1) adsorbed inorganic and exchangeable organic phosphorus, (2) Fe-bound inorganic phosphorus, (3) authigenic carbonate fluorapatite, biogenic apatite and calcium carbonate-bound inorganic and organic phosphorus, (4) detrital apatite, and (5) refractory organic phosphorus. TSP concentrations in surface sediments increased from the Chukchi Sea (18 μmol g−1 of dried sediments) to the Bering Sea (22 μmol g−1) and to the Mackenzie River Delta (29 μmol g−1). Among the five pools, detrital apatite phosphorus of igneous or metamorphic origin represents the largest fraction (~43%) of TSP. The second largest pool is the authigenic carbonate fluorapatite, biogenic apatite as well as CaCO3 associated phosphorus (~24% of TSP), followed by the Fe-bound inorganic phosphorus, representing ~20% of TSP. The refractory organic P accounts for ~10% of TSP and the readily exchangeable adsorbed P accounts for only 3.5% of TSP. Inorganic phosphorus dominates all of phosphorus pools, accounting for an average of 87% of the TSP. Relatively high sedimentary organic carbon and total nitrogen contents and low δ13C values in the Mackenzie River Delta together with the dominance of detrital apatite in the TSP demonstrate the importance of riverine inputs in governing the abundance and speciation of sedimentary phosphorus in the Arctic coastal sediments.  相似文献   

18.
Abstract Phosphorite, or guano, or insular phosphorite, commonly containing 10-35% P2O5, is one of the sources of phosphatic fertilizer. Taking the modern insular phosphorite on the Xisha Islands as an example, this paper discusses the ore-forming mechanism of phosphate and the important contribution made by animals to this process. The phosphorite occurs in the middle part of carbonate sand cays of coral reef surrounded by longshore sandbanks, which assumes a dish-shape. The surface of the cays is covered by unconsolidated guano. The phosphorite, yellowish brown to dark brown, is made up of thick-bedded sand and gravel cemented by collophanite; and partly replaced by carbonate apatite. The mechanism of mineralization is as follows: The average content of phosphorus in the sea water is only 0. 07 ppm, but through the sea food. chain concentration, phosphorus content may become higher. The phytoplanktons, as producers, suck up phosphorus out of sea water. The primary consumers, zooplanktons, obtain phosphorus by eating phytoplanktons, then they are followed by the second and third consumers. Sea birds living on fish, as the third consumers, concentrate and transport the phosphorus to the carbonate sand cays. Finally layers of guano are deposited under the arbores. Under the tropical climatic conditions with high temperature and plentiful rainfall, soluble matters are leached out of the guano and infiltrated into deeper horizon. In alkaline groundwater with pH greater than 7. 0, the phosphoritization takes place, bioclastics are cemented and replaced by collophanite or carbonate apatite. Finally, the phosphorus is fixed and phosphate formed.  相似文献   

19.
Concentrations of phosphorus have been determined in 130 specimens o regionally metamorphosed skarn rocks, including their enclosing rocks Average P2O5-values found were 0.11% in the pyroxene skarns from the Core of the Bohemian Massif and 0.07% in those of the Kruné hory Mountains, which correspond to those commonly present in primary, i.e. contact metamorphic skarns, but are quite different from the high P2O5-values usually found in sedimentary iron ores. The P-contents of the rocks from the cores of the skarn bodies studied equal those determined in relic carbonate rocks, from which they probably originated, whereas the P-contents of the rocks from the outer parts of the skarn bodies correspond to those found in the enclosing rocks. The distribution of P in migmatites surrounding the skarn bodies suggests that P did not migrate during the regional metamorphism, so that the P-contents in the skarns may be considered as primary (premetamorphic). Thus, a study of P-percentages in regionally metamorphosed skarns may be useful in the investigation of skarn genesis.
Zusammenfassung Die Phosphorgehalte von 130 Proben regionalmetamorpher Skarne, sowie ihrer Hüll- und Begleitgesteine wurden ermittelt. Der P-Durchschnittsgehalt der Pyroxenskarne beträgt im Kern der Böhmischen Masse 0,11%, im Erzgebirge 0,07%. Diese Gehalte entsprechen denjenigen kontaktmetamorpher Skarne, sind aber von den großen gewöhnlich in sedimentogenen Eisenerzen vorkommenden P-Gehalten verschieden. Die Phosphor-Gehalte der Skarngesteine aus den Kernpartien der Skarnkörper entsprechen denjenigen der reliktischen Carbonatgesteine, die die Skarne begleiten und auf deren Kosten sich die Pyroxenskarne wahrscheinlich entwickelt haben. Demgegenüber entsprechen die P-Gehalte der Gesteine aus den äußeren Partien der Skarnkörper denen der Hüllgesteine. Die Verteilung des Phosphors zwischen Metatekt und Paläosom in Migmatiten, die die Skarnkörper umhüllen, zeigt, daß Phosphor während der Regionalmetamorphose kaum migrierte. Seine Gehalte in Gesteinen lassen sich also für primär, d.h. prämetamorph halten. Wie ersichtlich, können Kenntnisse über die P-Verteilung zur Lösung der Fragen der Skarngenese beitragen.
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20.
Doklady Earth Sciences - The Central bauxite deposit on the territory of the Russian Federation is a unique geological object. It hosts both primary lateritic bauxites and products of their...  相似文献   

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