内蒙古索伦山地区三叠纪侵入岩锆石U-Pb年龄、岩石地球化学特征及地质意义          下载免费PDF全文

连琛芹  李钢柱  于洋  姚佛军  张思源  王丕军  崔舜铫 《地球科学》2021,46(1):87-100

内蒙古索伦山地区朱恩道欧恩呼尔新识别出一套早中生代侵入岩,主要由角闪二长岩和二长闪长岩组成.通过LA-ICP-MS锆石U-Pb定年确定,角闪二长岩的结晶年龄为248±1 Ma(MSWD=1.1),表明该岩体形成于早三叠世.它们的SiO₂含量介于51.82%~60.17%之间,具有高镁(Mg#=53.17~59.03)、富碱(K₂O+Na₂O=7.36%~9.83%)、富钠(K₂O/Na₂O=0.25~0.53)特征,属于准铝质碱性岩.样品稀土总量变化范围为117.52×10-6~160.89×10-6,表现出一致的稀土元素和微量元素配分型式,即呈现出轻稀土元素相对于重稀土元素富集((La/Yb)_N=9.57~15.42)的右倾曲线,且无明显Eu异常(δEu=0.76~1.00),并富集Ba、Sr等大离子亲石元素,亏损Nb、Ta、Ti、Y等高场强元素,高Sr、低Y、高Sr/Y比值,具有高镁埃达克质闪长岩的地球化学特征.综合岩石地球化学特征及区域构造背景,朱恩道欧恩呼尔早中生代高镁埃达克质闪长岩类是由残余俯冲洋壳部分熔融形成的熔体与地幔橄榄岩相互作用而形成.朱恩道欧恩呼尔富碱侵入岩的形成与华北板块与西伯利亚板块碰撞后的伸展作用有关,这些新的年龄和岩石地球化学数据表明古亚洲洋闭合早于248 Ma.   相似文献   

大别—苏鲁超高压地体中面理化含榴花岗岩的成因研究   总被引：7，自引：1，他引：6  

杨启军  钟增球 《地球科学》2004,29(2):169-176

大别—苏鲁超高压地体中的面理化花岗岩因为常含石榴石而被简称为含榴花岗岩, 其岩石类型主要为二长花岗岩、花岗岩和微斜长石花岗岩, 岩石具有花岗结构和片麻状构造.详细的野外地质研究表明, 超高压片麻岩作为超高压榴辉岩的围岩与含榴花岗岩呈渐变过渡关系, 或在含榴花岗岩中呈与面理平行的残留条带, 体现超高压片麻岩通过构造置换和部分熔融向含榴花岗岩转化.含榴花岗岩在常量元素的总体组成上, w(SiO₂)为71.73%~79.15%;A/CNK为0.83~1.09, 平均0.98, 为准铝质; w(K₂O+Na₂O)为6.15%~9.00%, w(K₂O)/w(Na₂O)为0.16~1.54(绝大多数集中在0.9~1.1), 具有相对弱富钠-弱富钾特征.从标准矿物组成上看, 大别含榴花岗岩主要相当于奥长花岗岩; 山东含榴花岗岩主要相当于花岗岩; 东海含榴花岗岩主要相当于钾质花岗岩.在微量元素特征上, 含榴花岗岩的∑REE、∑LREE明显富集, δEu具有明显的负异常, 在原始地幔标准化蛛网图上, 相对亏损Nb、Ta、P、Zr、Ti等高场强元素及大离子亲石元素Sr, 富集Ba、La、Nd、Y、K等大离子亲石元素, 结合其贫w(Al)(平均11.6%)富w(Ga)(> 17×10-6)、(Fe/Mg)_M(1.087~20.330)等特征, 表明其地球化学特征相当于非造山的A型花岗岩.结合前人超高压变质作用和构造演化等研究成果, 可以推断含榴花岗岩是超高压地体折返到中下地壳, 在底侵、构造体制转换等因素作用下, 由高压片麻岩的部分熔融形成的.含榴花岗岩在大别—苏鲁不同区域上的规律变化, 表明东海含榴花岗岩的出露相对于大别更低位.   相似文献   

Petrology and geochemistry of potassic and ultrapotassic volcanism in central Italy: petrogenesis and inferences on the evolution of the mantle sources   总被引：15，自引：0，他引：15  

Sandro Conticelli  Angelo Peccerillo 《Lithos》1992,28(3-6):221-240

Major, trace element, Sr isotopic and mineral chemical data are reported for mafic volcanic rocks (Mg-value 65) from the northern-central sector of the potassic volcanic belt of Central Italy. The rocks investigated range from potassic series (KS) and high-K series (HKS) to lamproitic (LMP) and kamafugitic (KAM) through a transitional series (TRANS), thus covering the entire compositional spectrum of potassic and ultrapotassic magmas. KAM rocks are strongly silica undersaturated and, compared with the other rock series, have low SiO₂, Al₂O₃, Na₂O, Sc and V and high CaO, K/Na, (Na + K)/Al. KS and HKS have high Al₂O₃, CaO and variable enrichment in K₂O and incompatible elements. LMP rocks are saturated in silica and have high SiO₂, K₂O, K₂O/Na₂, MgO, Ni and Cr and low Al₂O₃, CaO, Na₂O, Sc and V. TRANS rocks display intermediate compositional characteristics between LMP and KS.

All the rocks under study have fractionated hygromagmaphile element patterns with high LIL/HFS element values and negative anomalies of Ti, Ta, Nb and Ba. Negative Sr anomalies are observed in the LMP and TRANS rocks. LIL elements show overall positive correlations with K₂O, whereas different trends of Sr and HFSE vs. K₂O are defined by LMP-TRANS and KS-HKS-KAM. ⁸⁷Sr/⁸⁶Sr range from about 0.710 to 0.716. KS, HKS and KAM rocks have similar ⁸⁷Sr/⁸⁶Sr values clustering around 0.710. LMP and TRANS rocks have the highest ⁸⁷Sr/⁸⁶Sr values.

Geochemical and isotopic data reported for the most primitive Italian potassic and ultrapotassic rocks support the hypothesis that the interaction between crustal and mantle reservoirs was a main process in the genesis of Italian potassic magmatism. Simple mass balance calculations exclude, however, an important role of crustal assimilation during ascent of subcrustal magmas to the surface and indicate that the sources of Central Italy volcanics underwent contamination with fluids and/or melts released by upper crustal material previously brought into the mantle by subduction processes.

Different trends of incompatible elements vs. K₂O observed in the studied rocks suggest distinct metasomatic processes for the sources of the investigated magmas. Liquids derived by bulk melting of pelitic sediments are believed to be the most likely contaminants of the source of LMP rocks. Fluids or melts rich in Ca, Sr and with high LILE/HFSE value and Sr isotopic composition around 0.710 are the most likely contaminant of the source region of KS, HKS and KAM volcanics. Variations in CaO, Na₂O and ferromagnesian element abundances and ratios suggest that, in some zones, the mantle source of potassic magmas experienced partial melting with extraction of basaltic liquids prior to metasomatism.  相似文献   

武当隆起西段牌楼新元古代A₁型花岗岩的发现及其地质意义     

张维峰  徐大良  彭练红  邓新  刘浩  金鑫镖  谭靖 《地球科学》2018,43(7):2389-2403

牌楼似斑状二长花岗岩出露于武当隆起的西部,是南秦岭地区新元古代岩浆活动的典型代表.锆石LA-ICP-MS年代学研究获得其成岩年龄为667.2±3.5 Ma.岩体Na₂O+K₂O含量和A/CNK分别介于8.31%~8.47%和0.89~0.94,显示出亚碱性、准铝质特征;同时样品富集大离子亲石元素Rb、K、U、Pb及高场强元素Nb、Ta,亏损Sr、P、Ti和重稀土元素,具有较高的Zr+Nb+Y+Ce含量以及10 000 Ga/Al、FeOT/（FeOT+MgO）比值,出现特征矿物铁韭闪石和富铁钠闪石,属于A₁型花岗岩.牌楼岩体ε_Hf（t）主要集中于-1.8~+1.5,来源于软流圈交代岩石圈地幔类似于OIB熔体,并伴随有一定的地壳混染作用.微量元素模拟显示,母岩浆在成岩之前发生了大规模的斜长石和辉石的分离结晶.综合区域研究资料、地质年代学、地球化学及同位素特征,结果表明武当隆起在新元古代成冰纪处于板片断裂的弧后伸展环境.   相似文献   

内蒙古阿拉善地块北缘查干敖包一带二长花岗岩锆石定年、地球化学特征及其构造意义     

李杰  丛殿阁  古艳春  田颖 《现代地质》2021,35(2):514-522

查干敖包二长花岗岩位于阿拉善左旗诺尔公苏木查干敖包一带。该岩体是阿拉善地块北缘诺尔公—狼山构造带诺尔公大型复式岩基的主要组成部分。通过LA-ICP-MS锆石U-Pb同位素测年,确定其形成年龄为(278±1)Ma,属早二叠世晚期。二长花岗岩SiO₂含量为72.88%~75.44%,全碱(K₂O+Na₂O)含量平均为8.16%,K₂O/Na₂O主要介于0.87~1.41之间,Al₂O₃含量为12.38%~13.98%,铝饱和指数(A/CNK)介于0.88~1.02之间,在AR-SiO₂图上落入碱性系列区域。上述特征表明查干敖包二长花岗岩为高硅、富钾、准铝质碱性花岗岩。稀土元素球粒陨石标准化曲线明显右倾,轻稀土元素相对富集(LREE/HREE=4.70~14.66),δEu= 0.18~0.87,平均为0.37,呈中等-较强烈负铕异常。明显亏损Nb、Ta、Ti、P等高场强元素,Sr平均值为94.44×10^-6,Yb为3.10×10^-6,呈现非常低Sr、高Yb的特征。岩石地球化学特征表明查干敖包二长花岗岩体形成于后碰撞环境,地幔物质底侵作用下的伸展机制可能启动了这次岩浆侵入事件。结合区域资料推断阿拉善地块所代表的华北板块西北缘在早二叠世晚期已经进入后碰撞演化阶段。  相似文献   

新疆西昆仑东南部泉水沟岩体的年龄、成因及构造意义          下载免费PDF全文

乔耿彪  伍跃中 《地球科学》2018,43(12):4283-4299

泉水沟岩体位于西昆仑造山带和巴彦喀拉褶断带夹持区域,对追溯西昆仑地区的区域发展演化具有重要指示意义.通过高精度同位素年代学、岩石矿物学与地球化学等手段,准确限定岩体的形成时代并查明其地球化学特征.LA-ICP-MS锆石U-Pb定年获得该岩体中花岗闪长岩的年龄为217.6±0.9 Ma,其中的暗色包体黑云母石英闪长岩年龄为217.4±0.7 Ma,均属晚三叠世（T₃）.花岗闪长岩具有富硅（SiO₂=67.21%~68.85%）、富碱（全碱变化于6.36%~6.76%,里特曼指数δ=1.56~1.86）、富钾（K₂O=3.50%~3.96%,K₂O/Na₂O=1.20~1.41）,而贫TiO₂、MnO和P₂O₅（< 1%）的特点;岩体的铝饱和指数A/CNK为0.88~1.05;总体上属高钾钙碱性准铝质-弱过铝质I型花岗岩.岩石富集轻稀土,轻重稀土元素分馏明显（（La/Yb）_N为1.03~11.05）,具有铕负异常（δEu为0.42~0.73）;富集Rb、Th、K和LREE等大离子亲石元素,而贫Ba、Sr、Ti、P等元素.岩石微量元素地球化学特征显示,泉水沟花岗闪长岩及其包体为下地壳变质玄武岩熔融的产物,在岩浆演化过程中岩体的分离结晶作用以斜长石、辉石和磷灰石为主,而角闪石分离结晶不明显.区域构造环境演化表明,晚三叠世时随着古特提斯洋向北消减至最终闭合,在康西瓦断裂带两侧发生大规模陆块碰撞挤压,致使地壳垂向增生加厚引起了强烈的岩浆活动,从而在下地壳发生重熔作用形成了泉水沟岩体,也表明该区当时已处于洋陆拼合后的碰撞造山新阶段.   相似文献   

草桃背矿床白垩纪橄榄玄粗岩与铀成矿关系   总被引：1，自引：0，他引：1  

张运涛  裴荣富  于波  陈永飞  杨东生  邱小平 《吉林大学学报(地球科学版)》2013,43(5):1423-1435

赣南会昌断陷盆地沿石城-寻乌深断裂分布一条白垩纪橄榄玄粗岩系列的火山岩带。草桃背大型铀矿床内出露大富足岩体中-粗粒黑云母花岗岩及早白垩世晚期到晚白垩世早期橄榄玄粗岩系列火山岩。大富足花岗岩体岩石w(SiO₂)平均为74.67％,碱总量(w（K₂O+Na₂O）)平均为7.99％,w(K₂O)>w(Na₂O),w(CaO)平均为0.54％,w(Al₂O₃)>w(CaO+Na₂O+K₂O),属高钾钙碱性岩石系列。橄榄玄粗系列火山岩岩石w(SiO₂)为45.78 %~59.78 %,w(K₂O+Na₂O)平均为7.37%,K₂O/Na₂O平均为1.02,w(TiO₂)平均为0.86%, 全铁质量分数平均为7.09%,属偏碱性橄榄玄粗质火山岩类。草桃背铀矿床赋矿岩性为橄榄玄粗岩、碎裂花岗岩及隐爆角砾岩。赋存于碎裂花岗岩及隐爆角砾岩中铀矿石化学成分,与围岩花岗岩成分相似;赋存于橄榄玄粗岩中铀矿石,Fe₂O₃+Fe₂O、CaO、MgO不同程度地带出,w(SiO₂)明显增高,表明橄榄玄粗岩在成矿过程中,通过输出大量Fe、Mg、Ca等阳离子而促进铀离子从含矿溶液中沉淀。草桃背矿床的铀矿化与充填在草桃背火山口的橄榄玄粗岩关系密切,在时间上相近、在空间上相伴、在成生上相关,受橄榄玄粗岩岩浆系列热动力的影响,铀元素发生活化、转移或物质交换而成矿,成岩成矿时代属早白垩世晚期到晚白垩世早期。从草桃背铀矿床岩石学、地球化学及赋矿特征入手,总结了铀成矿是富铀矿的花岗岩基底、北东向构造及火山作用结合的产物,橄榄玄粗岩提供热源,并指出半岭、上寮、小富足等地段是寻找草桃背式铀矿床的极有利地区。  相似文献   

广东文光岭铅锌铜多金属矿花岗闪长岩LA-ICP-MS锆石U-Pb定年、地球化学特征及其成因          下载免费PDF全文

欧阳志侠  楚克磊  陈友良  吴晓东  杨胜虎  汪汝澎  刘东宏  汪礼明 《地球科学》2019,44(4):1327-1337

广东省文光岭矿床是云开地区近年来新发现的铅锌铜多金属矿.以文光岭花岗闪长岩作为研究对象,对其开展了LA-ICP-MS锆石U-Pb同位素定年和地球化学特征研究.获得其锆石206Pb/238U同位素加权平均年龄为165.7±1.9 Ma（n=18,MSWD=3.1）.花岗闪长岩属于准铝质Ⅰ型花岗岩,SiO₂含量在64.11%~66.64%之间,Al₂O₃含量为14.9%~15.57%,MgO含量在1.39%~1.61%之间,K₂O+Na₂O含量介于6.5%~7.21%,K₂O/Na₂O=1.25~2.74,铝饱和指数A/CNK=0.93~1.11.轻、重稀土元素分馏作用明显,（La/Yb）_N=13.03~17.83,具有弱的负铕异常（δEu为0.70~0.88）,HFSE和LILE分异明显,富集Rb、Th、U、K等元素,亏损Nb、Ta、P和Ti等元素.结合区内已有资料,认为文光岭铅锌铜多金属矿床的形成与古太平洋板块的俯冲作用密切相关.   相似文献   

Boundary lines within petrologic diagrams which use oxides of major and minor elements   总被引：165，自引：0，他引：165  

Peter C. Rickwood 《Lithos》1989,22(4):247-263

Use of some petrologic diagrams applied to analyses of volcanic rocks is unnecessarily difficult due to lack of data for construction of discriminant lines between rock series. Coordinates are provided for sufficient points to enable accurate plotting of the boundary lines within seven diagrams, viz.: (1) TAS - total alkalies (Na₂O+K₂O) vs. SiO₂; (2) K₂O vs. SiO₂; (3) AFM; (4) Jensen; (5) KTP - K₂O---TiO₂---P₂O₅; (6) FMS - (FeO^*/MgO) vs. SiO₂; and (7) TAKTIP - K₂O/(Na₂O+K₂O) vs. TiO₂/P₂O₅. Different versions of these boundaries are collated to indicate their variable position, and it is demonstrated that inter-laboratory analytical precision suffices to account for almost all of their spread on the TAS and K₂O vs. SiO₂ diagrams.  相似文献   

Thermodynamic Calculation of Solubility of Na2SO4/K2SO4 in Hydrothermal Fluids     

Wei Zhang  Li Zhou  Hongfeng Tang  Heping Li  Li Wang 《地球科学进展》2019,34(4):414-423

Sulfate fluids are common fluids in nature, and their salinity studies can provide important information for the evolution of ore-forming fluids, migration and enrichment of ore-forming elements, and the classification of deposit types. Considerable research has been carried out to investigate the solubility of Na₂SO₄ and K₂SO₄ in hydrothermal fluids, however most of the literature reported experimental data were under saturated vapor pressure or the water supercritical region. A few data have been reported for the low temperature hydrothermal mineralization region. Thermodynamic model is a useful method to study the properties of hydrothermal geofluids, especially for mineral solubility. Pitzer interaction model is one of the most widely used model to calculate the thermodynamic properties of hydrothermal fluids, but few work have ever been carried out to calculate the solubility of sulfate at high temperature and pressure. With Pitzer specific interaction model, using the literature reported density data of Na₂SO₄ and K₂SO₄ solutions at high temperature and pressure, the pressure effect on Pitzer activity coefficient of sulfate and the standard partial molar volume change during sulfate dissolution process were evaluated and related parameters were obtained. The standard partial molar volumes of Na₂SO₄ and K₂SO₄ calculated with these parameters agreed well with those reported in the literature. Combined with the relevant parameters in the literature under saturated vapor pressure, a thermodynamic model for Na₂SO₄ and K₂SO₄ solubility calculation with temperature up to 250 ℃ and pressure up to 40 MPa was developed. The model gave very good agreement with the experimental solubility data. With this model, Na₂SO₄ and K₂SO₄ solubility was calculated at high temperature and pressure. The calculation results showed that pressure had a positive effect on both the average activity coefficient and solubility product of Na₂SO₄ and K₂SO₄, but the solubility of Na₂SO₄ and K₂SO₄ decreased with pressure due to the larger change of the average activity coefficient with pressure. And as the temperature increased, the degree of such reduction became larger. The results herein can provide instructions for the compositional analysis of sulfate fluid inclusions.  相似文献   

青海玉树县南洞卡组粗面安山岩地球化学特征：岩石成因与构造背景探讨          下载免费PDF全文

辜平阳  何世平  计文化  董增产  时超  陈奋宁 《地质科学》2013,48(4):1069-1082

青海玉树县南洞卡组粗面安山岩的SiO₂含量为55.92%～57.85%,高Na₂O、MgO和Al₂O₃,低K₂O、TiO₂和 P₂O₅,铝饱和指数A/CNK=0.98～1.08,具有准铝-弱过铝质的特点。岩石K₂O含量低,Na₂O/K₂O=12.60～15.97,显示出钠质粗面安山岩特征。SiO₂-K₂O图解和里特曼指数(2.89～3.25),说明岩石属于钙碱性系列。稀土配分模式为轻稀土弱富集右倾型,铕弱负异常(σEu=0.90～0.96)。微量元素蛛网图显示,岩石富集Rb、Th和U等元素,亏损高场强元素Nb、Ta和大离子亲石元素Ba,样品Ce/Pb、Nb/U 并未随着MgO含量的升高而升高,样品的La/Nb、Zr/Nb、Ba/Nb比值均表现出良好的稳定性,表明岩浆在上升过程中遭受地壳物质混染的可能性不大,可能是其源区特征的反映。研究表明岩浆经历了橄榄石和单斜辉石的结晶分异,且受到俯冲板片熔体对源区的改造作用。结合234 Ma的形成年龄,说明该粗面安山岩是金沙江洋盆向西俯冲消减和斜向碰撞的地质记录,其形成时代和地球化学特征也为江达-维西火山弧的形成演化及成矿作用研究提供依据。  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111001150     

Jinyang Zhang  Changqian Ma  Zhenbing She 《地学前缘(英文版)》2012,3(5):635-646

The Erlangmiao granite intrusion is located in the eastern part of the East Qinling Orogen.The granite contains almost 99 vol.％ felsic minerals with accessory garnet,muscovite,biotite,zircon,and Fe-Ti ...  相似文献   

江西相山矿田主要铀矿化类型及其地球化学特征对比研究   总被引：1，自引：0，他引：1  

李子颖  张万良 《现代地质》2016,30(1):1-16

江西相山矿田发现近30个铀矿床,矿化与浅成超浅成侵入岩(次火山岩)关系密切,不管是划归火山岩型还是斑岩型矿床类型,均属于热液型矿床。从热液矿床的成矿构造特点分析,相山矿田铀矿化主要有隐爆碎屑岩型和蚀变岩型两大类,后者主要有水云母化蚀变岩型和钠长石化蚀变岩型。通过收集资料,结合笔者完成的有关课题成果数据,对各铀矿化类型进行了地球化学的对比研究,结果表明：隐爆碎屑岩型矿石品位较高,U含量大多大于1%,SiO₂、Na₂O含量较低,P₂O₅含量较高,K₂O/Na₂O比值平均11.51,主要伴生元素有Hf、Sb、Cu、Pb、Zn、Zr等;水云母化蚀变岩型矿化的K₂O/Na₂O比值平均4.83,伴生元素有W、Pb、Mo、Th、Sb等;钠长石化蚀变岩型矿化的K₂O/Na₂O比值平均0.19,U与CaO、P₂O₅关系密切,伴生元素有Sr、Zr、Hf、Sc、W等。从钠长石化蚀变岩型,到水云母化蚀变岩型,到隐爆碎屑岩型,即随矿化岩石U品位的增高,稀土配分曲线呈现出从右倾向左倾有规律的变化。  相似文献   

黑龙江滨东地区唐家屯组火山岩时代的U-Pb年代学证据     

王兴  郑涛  谷华娟  牛延宏  梁城喆 《地质与资源》2016,25(3):237-243

黑龙江省滨东地区广泛发育唐家屯组火山岩,其以强片理化酸性、中酸性火山岩为主,夹少量中性火山岩及片理化变质的正常沉积岩.唐家屯组火山岩SiO₂含量为61.50%~68.96%,TiO₂、Fe₂O₃、MgO和CaO的含量分别为0.61%~0.88%、1.21%~4.24%、0.30%~2.08%和0.77%~4.57%.Mg^#为4~25,Al₂O₃=15.12%~16.99%,K₂O=2.68%~5.2%,Na₂O/K₂O=0.94~2.18,Na₂O+K₂O=7.05%~9.99%,较富碱.稀土元素总量（∑REE）为140.81×10^-6~276.36×10^-6,LREE/HREE比值为7.72~9.70,明显富轻稀土元素,贫重稀土元素.δEu=0.77~1.03,具有负异常-弱的正异常,稀土元素配分曲线为右倾性.微量元素总体上富集大离子亲石元素（LILE）Zr、Ba,亏损Nb、Ta、Ti等高场强元素和Sr、P,具有双峰式火山岩的特点.该火山岩LA-ICP-MS U-Pb定年的结果显示,其加权平均年龄分别为300±1 Ma,形成时代为晚石炭世,其形成于引张环境.  相似文献   

青海省赛支寺花岗闪长岩及其暗色包体成因:锆石U-Pb年代学、岩石地球化学和Sr-Nd-Hf同位素制约          下载免费PDF全文

崔加伟  郑有业  孙祥  吴松  高顺宝  田立明  孙君一  杨超 《地球科学》2016,41(7):1156-1170

祁连造山带分为南祁连、中祁连和北祁连构造带.赛支寺岩体位于中祁连与南祁连构造带的结合部位.首次发现了赛支寺花岗闪长岩及其暗色包体,然而对于暗色包体的成因机理以及与寄主岩石之间的成因联系仍存在很多争议.并对其进行了系统的锆石U-Pb年代学、Lu-Hf同位素、岩石地球化学以及Sr-Nd同位素地球化学研究,探讨赛支寺岩体及其暗色包体的成因及动力学背景.LA-ICP-MS锆石U-Pb年代学表明,赛支寺花岗闪长岩形成于446.1±1.3 Ma,包体形成于446.0±1.0 Ma,两者在误差范围内一致,排除了包体为捕虏体成因.暗色包体具较低的SiO₂含量、较高的Na₂O/K₂O比值,低Sr/Y、La/Yb比值,与寄主岩稀土配分曲线基本一致,但LREE相对较低;86Sr/87Sr=0.706 4~0.706 7,ε_Nd(t)=-7.38~-7.97;发育针状磷灰石,形成于岩浆混合作用.寄主岩SiO₂=66.45%~68.12%,Na₂O/K₂O=0.80~0.97,A/CNK=0.91~1.03,显示准铝质-弱过铝质岩浆特点;富集大离子亲石元素Rb、Th、U、K,亏损Nb、Ta等元素,高Sr/Y、La/Yb比值,轻稀土富集,弱负Eu异常;86Sr/87Sr=0.709 3~0.709 5,ε_Nd(t)=-1.75~-1.03,与祁连造山带I型花岗岩相似;锆石ε_Hf(t)=1.7~6.8,T_DM2=995~1 750 Ma.综上所述认为,寄主花岗闪长岩形成于壳幔岩浆混合.结合区域地质背景,赛支寺花岗闪长岩形成于俯冲背景下,幔源岩浆上涌,侵入到下地壳中,造成下地壳物质熔融,由这种既有幔源物质又有古老地壳物质的花岗岩岩浆形成.   相似文献   

滇西北普朗铜矿床高钾中-酸性侵入岩年代学及其地质意义     

石洪召  范文玉  胡志中  董涛  余海军  尹光侯 《地球科学》2018,43(8):2600-2613

普朗铜矿床是格咱岛弧产出的超大型斑岩型铜矿床,以往较多关注于含矿的石英二长斑岩,而对矿区出露的闪长岩、花岗闪长斑岩研究相对薄弱.对普朗矿区的闪长岩和花岗闪长斑岩开展了地球化学和锆石年代学分析,结果显示,闪长岩SiO₂含量为62.46%~62.25%,K₂O含量为5.53%~6.27%,MgO含量为3.58%~3.69%,（Na₂O+K₂O）总碱含量为7.93%~8.72%,K₂O/Na₂O>2,属中性超钾质碱性岩;花岗闪长斑岩SiO₂含量为66.00%~66.98%,K₂O含量为4.06%~4.19%,MgO含量为2.04%~2.17%,（Na₂O+K₂O）总碱含量为7.60%~7.81%,K₂O/Na₂O>1,属酸性钾质碱性岩.花岗闪长斑岩与中甸地区火山岩具有一致的Sr-Nd同位素特征,而闪长岩ε_Nd（t）值变化范围大,二阶段模式年龄分散（369 Ma、913 Ma、1 138 Ma）,指示有富集组分的混入.闪长岩LA-ICPMS锆石U-Pb年龄为227.0±2.9 Ma;花岗闪长斑岩LA-ICPMS锆石U-Pb年龄为211.5±3.7 Ma.结合岩石主量、微量元素、全岩Sr-Nd同位素及锆石U-Pb年龄,提出甘孜-理塘洋在长时期的西向俯冲（约25 Ma）过程中,普朗矿区（局部）可能发生过由挤压向伸展构造体制的转换,激发幔源的岩浆活动,导致钾质碱性小岩体侵位,该过程对该超大型斑岩铜多金属矿的形成具有重要意义.   相似文献   

Solution mechanisms of H₂O in depolymerized peralkaline melts     

Bjorn O. Mysen  George D. Cody 《Geochimica et cosmochimica acta》2005,69(23):5557-5566

Solubility mechanisms of water in depolymerized silicate melts quenched from high temperature (1000°-1300°C) at high pressure (0.8-2.0 GPa) have been examined in peralkaline melts in the system Na₂O-SiO₂-H₂O with Raman and NMR spectroscopy. The Na/Si ratio of the melts ranged from 0.25 to 1. Water contents were varied from ∼3 mol% and ∼40 mol% (based on O = 1). Solution of water results in melt depolymerization where the rate of depolymerization with water content, ∂(NBO/Si)/∂X_H2O, decreases with increasing total water content. At low water contents, the influence of H₂O on the melt structure resembles that of adding alkali oxide. In water-rich melts, alkali oxides are more efficient melt depolymerizers than water. In highly polymerized melts, Si-OH bonds are formed by water reacting with bridging oxygen in Q⁴-species to form Q³ and Q² species. In less polymerized melts, Si-OH bonds are formed when bridging oxygen in Q³-species react with water to form Q²-species. In addition, the presence of Na-OH complexes is inferred. Their importance appears to increase with Na/Si. This apparent increase in importance of Na-OH complexes with increasing Na/Si (which causes increasing degree of depolymerization of the anhydrous silicate melt) suggests that water is a less efficient depolymerizer of silicate melts, the more depolymerized the melt. This conclusion is consistent with recently published ¹H and ²⁹Si MAS NMR and ¹H-²⁹Si cross polarization NMR data.  相似文献   

内蒙古固阳地区新太古代变质侵入岩地球化学特征及意义          下载免费PDF全文

张莉莉  代芳华  崔加伟  吴松  郑海涛  郑有业 《地球科学》2014,39(3):271-282

内蒙古固阳地区新太古代变质侵入岩具明显TTG岩系特征, 符合钙碱性系列岩石的演化趋势, 且具有由早期富钙向晚期富钠演化的趋势.其SiO₂含量介于49.99%~76.08%(绝大多数为51%~67%之间), 全碱含量高(Na₂O+K₂O＞7%), 富钠(Na₂O＞3%), Na₂O/K₂O＞1, 铝含量高(Al₂O₃含量通常在13%~18%之间), Mg#值较高(Mg#变化范围为33~50, 均值为45).微量元素显示岩石较低的Rb/Sr比值(0.02＜Rb/Sr＜0.22, 均值为0.08), 具有明显的Nb、P和Ti负异常以及Sr正异常.稀土元素配分曲线为右倾型, 岩石强烈富集LREE, 亏损HREE, 具弱Eu正异常.利用激光等离子体质谱(LA-ICP-MS)对其锆石进行了U-Pb定年, 测得其年龄在2 500~2 520 Ma之间, 属新太古代晚期.另外, 二长花岗岩的不一致线下交点年龄为410~576 Ma, 代表着引起Pb从矿物中丢失的热事件的时间, 即可以作为"早古生代华北地台应祁连山褶皱带的闭合而向南增生"这一事件在该区的时间响应.   相似文献   

川西地区热达门石英闪长岩锆石U-Pb年龄和岩石地球化学特征:岩石成因与构造意义     

岳相元  杨波  周雄  龚大兴  叶亚康  谭红旗  周玉  朱志敏 《现代地质》2019,33(5):1015-1024

川西地区热达门石英闪长岩体位于松潘-甘孜造山带北东侧。岩体的LA-ICP MS锆石U-Pb年龄为(206.4±1.4)Ma,侵位于晚三叠世。岩石Si O2含量为50.62%~56.66%,K2O/Na2O为0.32~1.20。铝饱和指数介于0.59~0.86之间,里特曼指数(σ)介于0.40~1.20之间,属于亚碱性准铝质系列岩石。岩体稀土总量∑REE介于81.45×10-6~222.39×10-6,LREE/HREE介于5.38~10.45之间,(La/Yb)N范围为5.98~12.99,δEu为0.66~1.01,δCe为0.81~0.93。岩石地球化学特征显示热达门岩石英闪长岩是在碰撞造山环境下,由岩浆上涌诱发下地壳物质部分熔融而形成的I型花岗岩。  相似文献   

Origin of potassic (C-type) adakite magmas: Experimental and field constraints   总被引：16，自引：0，他引：16  

L. Xiao  J.D. Clemens   《Lithos》2007,95(3-4):399-414

The postcollisional, Mesozoic, C-type or high-K adakitic intrusions (K-adakites) of China lack either temporal or spatial association with subduction and have K₂O/Na₂O around unity. Otherwise, their geochemistry is very similar to ordinary adakites. New experimental data, geological observations and theoretical considerations lead us to suggest that these K-adakites were high-T (> 1050 and probably > 1075 °C), rather hydrous magmas ( 6 wt.% H₂O) produced by fluid-absent partial melting of metatonalites, meta-andesites, or possibly potassic metabasalts at pressures exceeding 2 GPa. Their peculiar chemistry is a consequence of both the elevated K₂O/Na₂O in the protolith and the very high pressure of partial melting. The most likely tectonic setting is one of extreme crustal thickening followed by delamination of the eclogitic keel and partial melting of this continental crustal material at mantle depths, with high mantle heat flow, during orogenic collapse.  相似文献