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1.
夏杖子金矿床中矿物包裹体水的氢、氧同位素分别为：δD=-91.7‰——73.1‰,δ18OH2o=5.68‰-6.23‰,说明读矿床的成矿溶液是来源于岩浆水和大气降水;矿物的硫同位素组成基本上全是负值,且变化范田较小,同位素平衡温度平均为208-240℃,成矿溶液总硫平均同位素组成-19.70‰——20.64‰,证明成矿热液中H2S原子团占优势,其硫源可能为本区结晶基底;石英中流体包裹体Rb-Sr同位素等时年龄为105±7.2Ma,说明其成矿时代为燕山晚期。综合分析认为,该矿床为与岩浆热液有关的中-低温热液脉型金矿床。 相似文献
2.
辽宁小佟家堡子金矿床成矿流体特征及来源讨论 总被引：1，自引：0，他引：1
小佟家堡子金矿床地处辽宁青城子矿田东南部,为一大型蚀变岩型矿床。矿床产于辽河群大石桥组三段白云石大理岩中,矿体呈层状、似层状产出。矿床由热液叠加改造作用形成,历经石英-黄铁矿、石英-碳酸盐两个阶段。流体包裹体研究表明,该矿床成矿流体属中低温、低盐Na Cl-H2O型体系热液。碳氢氧同位素地球化学的研究表明,石英-黄铁矿阶段成矿流体氧同位素δ18O组成在15.2‰~18.4‰,碳同位素δ13CV-PDB组成在-7.4‰~-13.2‰,氢同位素δD组成为-89.3‰~-92.2‰,反应该阶段成矿流体主要来自岩浆水并伴有少量的大气降水。石英-碳酸盐阶段成矿流体氧同位素δ18O组成在17‰~17.8‰,碳同位素δ13CV-PDB组成在-12.3‰~-13.5‰,氢同位素组成δD为-87.7‰~-90.4‰,表明该阶段成矿流体主要来自大气降水。 相似文献
3.
牟乳成矿带是胶东半岛金矿集区三大金成矿带之一，但带内金矿床的成矿流体来源仍存在着较大分歧。范家庄金矿床是近年在该成矿带内新发现的金矿床，其成矿流体的研究较为薄弱。鉴于此，本文从流体包裹体和H-O同位素研究入手，结合矿床地质特征，对范家庄金矿床的成矿流体和矿床成因进行探讨。金矿体主要产于侏罗纪弱片麻状黑云母二长花岗岩内，呈脉状、透镜状，受断裂构造控制明显。该矿床热液成矿期可分为3个成矿阶段：石英-粗粒黄铁矿阶段（成矿早阶段）、石英-金-多金属硫化物阶段（主成矿阶段）、石英-碳酸盐阶段（成矿晚阶段）。流体包裹体岩相学特征显示，矿床中的原生包裹体以气液两相包裹体和纯液相水溶液包裹体为主，另有少量含CO2三相包裹体。显微测温结果显示，成矿早阶段和主成矿阶段的均一温度分别为167.2~297.5℃和168.4~253.6℃，盐度（w（NaCl））分别为3.55%~22.65%和2.58%~12.05%，密度分别为0.77~1.06 g/cm3和0.84~1.02 g/cm3，具有中低温、中低盐度、低密度的特征，与中温热液成矿系统流体特征相一致。对成矿压力和深度的估算表明，主成矿阶段的成矿压力为45.8~68.7 MPa （平均为52.8 MPa），成矿深度为5.38~6.71 km （平均为5.93 km），显示出中浅成成矿的特点。成矿流体H-O同位素示踪显示，成矿早阶段流体的δDH2O-SMOW值介于-96.9‰~-89.0‰之间，δ18OH2O-SMOW值介于-4.3‰~4.5‰之间；主成矿阶段的δDH2O-SMOW值介于-90.7‰~-85.3‰之间，δ18OH2O-SMOW值介于-5.4‰~-0.2‰之间。由此认为，范家庄金矿床的成矿流体来源于岩浆水与大气降水的混合，且随着成矿流体的演化，大气降水的混入比例增加。综合矿床地质特征和成矿流体研究，认为范家庄金矿床应属中温热液脉型金矿床。 相似文献
4.
中国西南部哀牢山成矿带南段长安金矿床成因机制仍然有待研究,为了解其成矿物质与流体来源,掌握其矿床成因类型,给矿山找矿增储工作提供依据,本文以长安金矿床作为研究对象,通过详细的地质特征描述、流体包裹体测温学和矿石H-O-S-Pb同位素测试来研究成矿物质和流体来源、演化,进而制约矿床成因,建立成矿模式。研究结果表明：前人认为的近南北向构造F6并非断裂构造,而是隐爆角砾岩筒,其为长安金矿床的主容矿构造;主成矿阶段包裹体冰点温度绝大部分为-2.9~-0.7 ℃ ,对应盐度（w(NaCl)）为1.22%～4.79%,均一温度为162～226 ℃,属于低温低盐度流体体系。长安金矿床成矿主阶段石英的δ18OH2O介于4.4‰～5.2‰之间,δD为-93.9‰～-85.9‰,落入岩浆水与大气水演化线之间,说明成矿流体为岩浆流体与大气水的混合物。长安金矿床黄铁矿的δ34S平均值为2.1‰（n=32）,绝大多数介于0.0~3.6‰之间,具有明显的岩浆硫的特点,认为硫来源于岩浆岩;黄铁矿的铅同位素组成特点明显具有二元性,反映了岩浆铅和上地壳围岩铅的双重贡献。综上,认为成矿物质和流体主要来源于岩浆,后期大气水和围岩也对成矿流体物质有一定贡献;长安金矿床受隐爆角砾岩控制,与低硫化型浅成低温热液型金矿的特征相似,尽管其围岩并非传统的火山岩。 相似文献
5.
为确定中国三江成矿带北段尕龙格玛VMS(volcanogenic massive sulfide)型矿床的成矿物理化学条件、成矿物质来源、成矿流体来源,探讨成矿机制,对矿体特征、流体包裹体显微测温和激光拉曼光谱分析以及S、Pb、H、O同位素进行了系统研究.矿体赋存于晚三叠世巴塘群英安质火山岩中,具有VMS型矿床的双层结构,由下部热液流体补给通道相的脉状-网脉状矿化系统和上部海底盆地卤水池喷气-化学沉积系统组成.通道相中流体包裹体可分为富气相包裹体和水溶液包裹体,均一温度为175.6~263.3 ℃,盐度为1.05%~6.29% NaCl eqv.,密度为0.820~0.935 g/cm3,激光拉曼光谱分析包裹体气相成分为H2O、CO2和少量N2;沉积相重晶石中仅发育水溶液包裹体,均一温度为105.2~157.1 ℃,盐度为0.18%~5.55% NaCl eqv.,密度为0.735~1.173 g/cm3,显示了流体由通道相向沉积相温度显著降低,盐度保持不变,密度变大的趋势,与典型VMS型矿床流体特征相似.氢氧同位素(δ18OH2O:0.25‰~1.75‰,δD:-103.2‰~-65.3‰)研究表明,成矿流体主要来源于岩浆水和海水的混合.综合分析前人硫同位素研究结果(δ34S:1.13‰~2.45‰,12.36‰~12.37‰)及本次获得硫同位素结果(δ34S:-22.9‰~-14.7‰)表明硫来源于岩浆和细菌还原的海水硫酸盐或基底岩石.硫化物方铅矿的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为18.449~18.519、15.699~15.777和38.875~39.141,具有高放射性铅的特征,μ值为9.65~9.80,结果显示Pb等成矿物质主要来自于上地壳,并有岩浆物质参与成矿.成矿流体与海水的混合作用是尕龙格玛矿床形成的主要机制. 相似文献
6.
藏南扎西康铅锌多金属矿床是特提斯喜马拉雅构造带（TH）东段发现的首个大型铅锌矿床，但其成因备受争议。本文在详细研究矿床地质特征的基础上，对矿硐内具有"同心环带"或"热水蛋"构造的铅锌矿石中的黄铁矿、方铅矿和闪锌矿进行了原位微区硫同位素分析。结果显示：铅锌矿石硫同位素组成变化范围在8.88‰~11.83‰之间，平均为10.50‰，总硫同位素组成（δ34S∑S）约为10.07‰。其中：7个黄铁矿（Py）测点的δ34SPy值为10.29‰~11.14‰，平均为10.70‰；6个闪锌矿（Sp）测点的δ34SSp值为10.78‰~11.83‰，平均为11.49‰；5个方铅矿（Gn）测点的δ34SGn值为8.88‰~9.18‰，平均为9.04‰。总体表现为δ34SSp > δ34SPy > δ34SGn，指示硫同位素未达到分馏平衡。利用方铅矿与闪锌矿矿物对硫同位素温度计计算可得，铅锌成矿温度介于224~280℃之间，平均值为259℃。结合前人研究成果，进一步得出扎西康铅锌多金属矿床主成矿期硫源主要来自日当组（J1r）围岩地层，并可能有少量岩浆硫的混入，属受控于地层-构造-岩浆热液作用的中温热液矿床。 相似文献
7.
1017高地银多金属矿床位于内蒙古自治区东乌珠穆沁旗,矿区大地构造位置处于西伯利亚板块东南缘查干敖包-奥尤特-朝不楞早古生代构造-岩浆岩带东段。石英脉型矿石中流体包裹体研究显示,从成矿早期到主成矿期,流体温度逐渐降低(从404℃~134℃到236℃~121℃),盐度都为中低盐度,由此表明该矿床具有浅成、中低温、中低盐度热液成矿特征。激光拉曼光谱分析显示包裹体气液相成分主要为H2O。矿石硫同位素组成相对均一,δ34S介于3.4‰~8.0‰之间,均值5.35‰,与幔源S的δ34S值(介于-3‰~3.0‰之间)比较,有向沉积硫的明显漂移,表明矿石中硫来源于沉积硫与岩浆硫的混合、平衡作用;矿石硫化物铅同位素比值没有明显的差别,206Pb/204Pb值为18.274 0~18.399 6,207Pb/204Pb值为15.539 9~15.561 6,208Pb/204Pb值为38.036 3~38.177 2,具有钍铅微弱亏损特征,指示矿石中硫化物的铅源主要来自地壳深部的岩浆源区,伴随岩浆及其热液作用,不可避免地混入了部分富放射成因铅的地壳物质。矿石氢氧同位素组成为:δDV-SMOW值介于-103‰~-125‰之间,δ18 OV-SMOW值在6.9‰~13.9‰之间,显示成矿流体中的水来源于岩浆水与大气降水的混合。综合1017高地银多金属矿床的地质特征和流体包裹体、S,Pb,H,O同位素研究认为,该矿床成矿物质来源于深源岩浆和上地壳的混合,成矿流体主要来自岩浆期后热液和大气降水,其成因类型可归于中低温度、中低盐度的岩浆期后热液型银多金属矿床。 相似文献
8.
老挝班康姆矿床是近年来在琅勃拉邦-黎府成矿带新发现的一个大型铜金矿床。该矿床矽卡岩与矿体主要赋存在安山岩中且缺乏矽卡岩分带,与典型矽卡岩矿床的地质特征存在一定的差别。因此,厘清班康姆铜金矿床的成矿流体、成矿物质来源及矿床成因机制是后续开展琅勃拉邦-黎府成矿带大型铜金矿床找矿勘探的基础。该矿床矿化阶段石英流体包裹体δD分布于-110‰~-90‰,δ18O分布于-1.5‰~7.1‰,其中低δD的样品具有相对高的δ18O值;黄铁矿流体包裹体的3He/4He为0.41~3.43Ra(大部分<1Ra),40Ar/36Ar为314.8~362.4。H-O及He-Ar同位素结果表明,班康姆矿床成矿流体来源于岩浆流体(至少部分来自地幔)与低δD的大气雨水的混合,雨水占更大的比例,且某些矿化流体的雨水端元在混合前经历了明显的水岩作用。除一件样品(BK64)的黄铁矿具有高的δ34S(8.1‰)外,其余硫化物的δ34S分布于-0.9‰~1.5‰,位于地幔硫的范围。共生硫化物对的硫同位素平衡分馏计算以及动力学分馏不支持高δ34S(8.1‰)黄铁矿的硫来自从热液流体,可能来自围岩。热液方解石的δ13C范围为-3.1‰~2.5‰,δ18O变化于26.0‰~28.4‰,指示其碳来自矿区灰岩,而灰岩的溶解为热液摄取围岩的重硫提供了可能。矿石黄铁矿Pb同位素组成(206Pb/204Pb:17.9284~18.7756;207Pb/204Pb:15.5336~15.6651;208Pb/204Pb:37.9125~38.8090)位于黎府褶皱带和长山褶皱带晚二叠世—中三叠世大陆弧岩浆岩的Pb同位素范围,介于印支地块玄武岩和泰国-老挝S-型花岗岩及相关矿床的Pb同位素组成之间,指示班康姆矿床的Pb来自壳幔混合源。本文S-Pb-He-Ar同位素结果及区域Cu-Au成矿过程的岩石地化研究,表明班康姆矿床Cu、Au主要来自地幔。与典型矽卡岩Cu-Au矿床的S-Pb-H-O同位素及矽卡岩矿物流体包裹体盐度特征的对比,结合前人的火山气热液交代火山岩形成矽卡岩的实验结果,认为班康姆矽卡岩型Cu-Au矿床的形成机制为深部出溶的气相为主的含矿岩浆流体沿断裂上升到浅部交代安山岩或大理岩并经历了流体混合、沸腾及矿石沉淀等过程。 相似文献
9.
在前人研究成果的基础上,对江西新余良山钼矿床的地质特征进行了详细研究,系统测试了矿床中石英脉型钼矿石样品的氢、氧、硫和铅同位素组成,进而探讨钼矿床的成矿流体性质以及成矿物质来源。良山钼矿床δD值变化范围-61‰~ -57.9‰,平均值-59.1‰;δ18OV-SMOW值变化于7.1‰~10.5‰,平均值9.2‰,流体的δ18OH2O值变化于-3.32‰~-0.52‰,平均值-1.52‰,表明成矿流体具有岩浆水和大气降水混合流体特征。硫化物的δ34SV-CDT值为-1.8‰~2.6‰,极差4.4‰,平均值1.12‰,其中黄铁矿δ34SV-CDT值为-1.8‰~2.6‰,辉钼矿δ34SV-CDT值为0.8‰~2.3‰,硫同位素表现为较小的正值特征,具有典型的岩浆硫组成特点。良山钼矿石中的矿石铅同位素206Pb/204Pb值为17.555~19.474,207Pb/204Pb值15.486~15.768,208Pb/204Pb值37.942~39.943,μ值9.35~9.7,ω值37.06~38.31,Th/U值3.8~3.96,矿石铅为混合铅,表明成矿物质为混合来源。良山钼矿床应为岩浆热液型-石英脉型钼矿床,是中生代华南板块板内构造演化区域金属成矿作用大爆发的产物。 相似文献
10.
甘肃武都金坑子金矿床位于碧口地块北缘西秦岭南成矿亚带。本文为探讨金坑子金矿床成因，对矿床野外地质特征，H、O、S同位素组成及流体包裹体特征进行了系统的研究。研究结果表明：矿体产于千枚岩与灰岩岩性不整合面及其附近的断裂破碎带中，主要受断裂构造控制；不同成矿阶段石英的δDH2O-VSMOW值范围为-81.4‰~-67.5‰，δ18OH2O-VSMOW值范围为7.51‰~10.55‰，显示成矿流体早期主要来源于深源岩浆水，晚期有大气降水的加入；黄铁矿δ34S值变化范围为-0.7‰~0.6‰，显示成矿物质主要来源于深部岩浆，并有地层物质加入；流体包裹体的均一温度为155.6~304.0℃，盐度（w（NaCl））为0.53%~13.29%，显示成矿流体具中温、中低盐度和富含CO2的特点。结合区域研究资料，认为金坑子金矿床成因类型为印支晚期的中温热液脉型金矿床。 相似文献
11.
古利库金(银)矿床地质特征和成因 总被引：2，自引：0，他引：2
古利库金(银)矿床为冰长石-绢云母型,产出与燕山中期"减压-剪切"环境下中心式火山喷发活动有关;矿床(体)受火山穹隆和爆破角砾岩筒及北西向、北东向断裂构造控制;容矿岩石为早白垩世龙江组、光华组安山岩、英安岩和新元古界-下寒武统落马湖群糜棱岩化的长英质片岩、片麻岩;矿床划分出矿化早期、主期和晚期3个矿化期,6个成矿阶段,3类组分矿体(Au型、Au-Ag型和Ag型)和脉状、网脉状两种形态矿体;围岩蚀变主要有硅化、冰长石化、绢云母化、白云石化、黄铁矿化等,硅化和冰长石化与矿化关系最密切;成矿温度185~255℃;成矿压力13.5 MPa (平均);成矿溶液盐度0.564% NaCl (平均);成矿深度500~600m.文中对成矿作用、矿床成因和成矿模式亦进行了探索和阐述. 相似文献
12.
广东长坑金、银矿床成矿模式 总被引：2，自引：0，他引：2
广东省长坑金、银矿床共存于同一层间蚀变构造破碎带,上金、下银分别构成独立的金、银矿床.金矿床具有沉积岩围岩型金矿床的全部特征,银矿床则有石英-硫化物脉型矿床的特征.在系统归纳金、银矿石及围岩的化学组成,微量元素、稀土元素、稳定同位素地球化学特征及同位素年代学,矿石矿物包裹体的温度、压力、成分,以及对三水裂谷盆地演化特征分析的基础上,提出金矿床是沉积盆地中的流体在大规模迁移过程中萃取地层中的金而形成的浅成低温热液交代型矿床,银矿床属于构造-岩浆叠加改造热液交代型矿床,金矿床形成在先,银矿床形成于后并改造了金矿床,金、银矿床均不是热水沉积型矿床或海底喷流-沉积型矿床. 相似文献
13.
14.
长坑矿田金,银矿床地球化学特征及形成差异分析 总被引：10，自引：0，他引：10
长坑矿田金、银矿体主要产于下石炭统与上三叠统不整合面之下的硅质岩中,金、银矿体分离。金矿体主要为浸染状,富集As、Sb、Hg;银矿体主要为脉状,富集Cu、Pb、Zn。金矿体铅同位素组成与寒武纪—石炭纪地层及硅质岩的相同,银矿体铅同位素组成与金矿体的不同。金、银矿体的氢、氧、碳同位素组成也明显不同。银矿体Rb-Sr等时线年龄为70.4Ma。据上述特征,笔者认为长坑金、银矿床是不同成矿作用形成的,金矿主要是热水沉积形成,银矿主要是燕山期晚期改造形成。 相似文献
15.
黑龙潭-汪家塆金矿床受控于区内北西向断裂带。矿体呈透镜状、脉状和似层状产出。围岩蚀变主要为石英化、绢云母化及黄铁矿化。矿石类型可分为蚀变岩型、蚀变碎裂岩型及石英脉型三种。根据矿石包裹体成分、同位素特征及稀土元素组成的研究,认为该矿床成矿物质系来自围岩和七尖峰花岗岩体,属地下热（卤）水混合热液成因。 相似文献
16.
Geology and D-O-C Isotope Systematics of the Tieluping Silver Deposit,Henan, China: Implications for Ore Genesis 总被引：22，自引：0，他引：22
Franco PIRAJNO 《《地质学报》英文版》2005,79(1):106-119
The Tieluping silver deposit, which is sited along NE-trending faults within the high-grade metamorphic basement of the Xiong‘er terrane, is part of an important Mesozoic orogenic-type Ag-Pb and Au belt recently discovered. Ore formation includes three stages: Early (E), Middle (M) and Late (L), which include quartz-pyrite (E),polymetallic sulfides (M) and carbonates (L), respectively. The E-stage fluids are characterized by δD=-90%c,δ^13CCO2=2.0‰ and δ^18O=9‰ at 373℃, and are deeply sourced; the L-stage fluids, with δD=-70‰, δ^13C CO2=-1.3%c and δ^18O=-2‰, are shallow-sourced meteoric water; whereas the M-stage fluids, with δD=-109‰, δ^13C CO2=0.1%c and δ^18O2‰, are a mix of deep-sourced and shallow-sourced fluids. Comparisons of the D-O-C isotopic systematics of the Estage ore-forming fluids with the fluids derived from Mesozoic granites, Archean-Paleoproterozoic metamorphic basement and Paleo-Mesoproterozoic Xiong‘er Group, show that these units cannot generate fluids with the measured isotopic composition (high δ^180 and δ^13C ratios and low δD ratios) characteristic of the ore-forming fluids. This suggests that the E-stage ore-forming fluids originated from metamorphic devolatilization of a carbonate-shale-chert lithological association, locally rich in organic matter, which could correspond to the Meso-Neoproterozoic Guandaokou and Luanchuan Groups, rather than to geologic units in the Xiong‘er terrane, the lower crust and the mantle. This supports the view that the rocks of the Guandaokou and Luanchuan Groups south of the Machaoying fault might be the favorable sources. A tectonic model that combines collisional orogeny, metallogeny and hydrothermal fluid flow is proposed to explain the formation of the Tieluping silver deposit. During the Mesozoic collision between the South and North China paleocontinents, a crustal slab containing a lithological association consisting of carbonate-shale-chert, locally rich in organic matter (carbonaceous shale) was thrust northwards beneath the Xiong‘er terrane along the Machaoying fault.Metamorphic devolatilization of this underthrust slab provided the ore-forming fluids to develop the Au-Ag-(Pb-Zn) ore belt, which includes the Tieluping silver deposit. 相似文献
17.
银洞坡金矿位于桐柏县围山城金银矿带的中部,为一超大型金矿床,伴生银、铅锌。对金矿石中主要成矿阶段流体包裹体进行了详细的岩相学、显微测温及激光拉曼光谱成分研究,结果表明：金矿石中发育气液两相包裹体、富气相包裹体和含CO2三相包裹体,流体成分为H2O NaCl CO2体系,含少量N2、CH4、H2S和H2。流体不混溶是导致矿质沉淀的主要因素。3类包裹体的均一温度为1692～3992 ℃,流体盐度为18%～122%,其中含CO2三相包裹体的盐度明显小于气液两相包裹体的盐度。利用不混溶体系估算得到包裹体的捕获压力为62～1263 MPa,成矿深度为52 km左右。矿石中黄铁矿的δ34S为16‰~33‰,围岩中纹层状黄铁矿的δ34S为33‰～62‰,矿石中的δ34S小于围岩中δ34S值,表明成矿物质中的硫可能来源于地幔硫和围岩硫的混合。 相似文献
18.
Lithologic controls on mineralization at the Lagunas Norte high-sulfidation epithermal gold deposit, northern Peru 总被引：1，自引：0，他引：1
Luis M. Cerpa Thomas Bissig Kurt Kyser Craig McEwan Arturo Macassi Hugo W. Rios 《Mineralium Deposita》2013,48(5):653-673
The 13.1-Moz high-sulfidation epithermal gold deposit of Lagunas Norte, Alto Chicama District, northern Peru, is hosted in weakly metamorphosed quartzites of the Upper Jurassic to Lower Cretaceous Chimú Formation and in overlying Miocene volcanic rocks of dacitic to rhyolitic composition. The Dafne and Josefa diatremes crosscut the quartzites and are interpreted to be sources of the pyroclastic volcanic rocks. Hydrothermal activity was centered on the diatremes and four hydrothermal stages have been defined, three of which introduced Au ± Ag mineralization. The first hydrothermal stage is restricted to the quartzites of the Chimú Formation and is characterized by silice parda, a tan-colored aggregate of quartz-auriferous pyrite–rutile ± digenite infilling fractures and faults, partially replacing silty beds and forming cement of small hydraulic breccia bodies. The δ34S values for pyrite (1.7–2.2?‰) and digenite (2.1?‰) indicate a magmatic source for the sulfur. The second hydrothermal stage resulted in the emplacement of diatremes and the related volcanic rocks. The Dafne diatreme features a relatively impermeable core dominated by milled slate from the Chicama Formation, whereas the Josefa diatreme only contains Chimú Formation quartzite clasts. The third hydrothermal stage introduced the bulk of the mineralization and affected the volcanic rocks, the diatremes, and the Chimú Formation. In the volcanic rocks, classic high-sulfidation epithermal alteration zonation exhibiting vuggy quartz surrounded by a quartz–alunite and a quartz–alunite–kaolinite zone is observed. Company data suggest that gold is present in solid solution or micro inclusions in pyrite. In the quartzite, the alteration is subtle and is manifested by the presence of pyrophyllite or kaolinite in the silty beds, the former resulting from relatively high silica activities in the fluid. In the quartzite, gold mineralization is hosted in a fracture network filled with coarse alunite, auriferous pyrite, and enargite. Alteration and mineralization in the breccias were controlled by permeability, which depends on the type and composition of the matrix, cement, and clast abundance. Coarse alunite from the main mineralization stage in textural equilibrium with pyrite and enargite has δ34S values of 24.8–29.4?‰ and $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ values of 6.8–13.9?‰, consistent with H2S as the dominant sulfur species in the mostly magmatic fluid and constraining the fluid composition to low pH (0–2) and logfO2 of ?28 to ?30. Alunite–pyrite sulfur isotope thermometry records temperatures of 190–260 °C; the highest temperatures corresponding to samples from near the diatremes. Alunite of the third hydrothermal stage has been dated by 40Ar/39Ar at 17.0?±?0.22 Ma. The fourth hydrothermal stage introduced only modest amounts of gold and is characterized by the presence of massive alunite–pyrite in fractures, whereas barite, drusy quartz, and native sulfur were deposited in the volcanic rocks. The $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ values of stage IV alunite vary between 11.5 and 11.7?‰ and indicate that the fluid was magmatic, an interpretation also supported by the isotopic composition of barite (δ34S?=?27.1 to 33.8?‰ and $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ ?=?8.1 to 12.7?‰). The Δ34Spy–alu isotope thermometry records temperatures of 210 to 280 °C with the highest values concentrated around the Josefa diatreme. The Lagunas Norte deposit was oxidized to a depth of about 80 m below the current surface making exploitation by heap leach methods viable. 相似文献
19.
哈西金矿床位于哈萨克斯坦―准噶尔板块(Ⅰ级)唐巴勒―卡拉麦里沟弧带(Ⅱ级)西准南部扎依尔推覆体(Ⅲ级)玛依勒―哈图构造块体(Ⅳ)。通过矿床流体包裹体岩相学、显微测温学和包裹体激光拉曼光谱分析研究成矿流体性质,探讨矿床成因类型。研究结果表明,流体包裹体有气液两相、含纯液相和纯气相包裹体3种类型。气相成分以CO_2为主,其次是H_2O,总体属于CH_4-H_2O-CO_2体系;结合氢氧同位素地球化学特征(δD值为-60‰~-67.4‰;δ~(18)O值为14.3‰~16.8‰),以及稀土配分和同位素定年证据,确定本区成矿物质来于深部,成矿流体主要来源于火山-次火山岩浆热液,矿床形成于海西期具两阶段成矿特点,属中低温热液矿床。 相似文献
20.
JIANG Biao WANG Chenghui CHEN Yuchuan WU Baogui LIAO Peng CHEN Zhengle HAN Fengbin 《《地质学报》英文版》2016,90(4):1321-1340
The Gaoshan gold-silver deposit, located between the Yuyao-Lishui Fault and JiangshanShaoxing fault in Longquan Area, occurs in the Suichang-Longquan gold-silver polymetallic metallogenic belt. This study conducted an investigation for ore-forming fluids using microthermometry, D-O isotope and trace element. The results show that two types of fluid inclusions involved into the formation of the deposit are pure liquid phase and gas-liquid phase aqueous inclusions. The homogenization temperature and salinity of major mineralization phase ranges from 156°C to 236°C(average 200°C) and 0.35% to 8.68%(NaCleqv)(average 3.68%), respectively, indicating that the ore-forming fluid is characteristic of low temperature and low salinity. The oreforming pressure ranges between in 118.02 to 232.13'105 pa, and it is estabmiated that the oreforming depth ranges from 0.39 to 0.77 km, indicating it is a hypabyssal deposit in genesis. The low rare earth elements content in pyrites, widely developed fluorite in late ore-forming stage and lack of chlorargyrite(Ag Cl), indicates that the ore-forming fluid is rich in F rather than Cl. The ratios of Y/Ho, Zr/Hf and Nb/Ta of between different samples have little difference, indicating that the later hydrothermal activities had no effects on the former hydrothermal fluid. The chondrite-normalized REE patterns of pyrites from country rocks and ore veins are basically identical, with the characteristics of light REE enrichment and negative Eu anomalies, implying that the ore-forming fluid was oxidative and derived partly from the country rocks. The δD and δ18O of fluid inclusions in quartz formed during the main metallogenic stage range from -105‰ to -69 ‰ and -6.01‰ to -3.81‰, respectively. The D-O isotopic diagram shows that the metallogenic fluid is characterized by the mixing of formation water and meteoric water, without involvement of magmatic water. The geological and geochemical characteristics of the Gaoshan gold-silver deposit are similar to those of continental volcanic hydrothermal deposit, and could be assigned to the continental volcanic hydrothermal gold-silver deposit type. 相似文献