共查询到20条相似文献，搜索用时 31 毫秒
1.
浙西开化地区皖浙边界断裂带西侧浅变质岩系中发育了一套以流纹岩为主的酸性火山岩。两个流纹岩样品的锆石LA-ICP-MS U-Pb定年分别给出了785±5 Ma和781±10 Ma的结果,显示为南华裂谷期的产物。岩石地球化学分析显示:该流纹岩富硅偏碱,铝饱和指数A/CNK大于1.11,显示过铝质特点;稀土元素总量高,相对富集轻稀土元素,具中等Eu负异常;相对富集Rb、Th、U、Pb等强不相容元素,而相对亏损亲石元素Ba、Sr、Nb、Ta,Zr含量较高。与壳源花岗质岩浆的地球化学特征相似。在微量元素构造判别图中显示为板内火山岩。结合地质背景分析,认为其形成于大陆裂谷环境,可能与华南地幔柱活动有关。 相似文献
2.
REE Geochemical Study of the Permian—Triassic Marine Sedimentary Environment in Guizhou Province 总被引：2，自引：1，他引：2
This paper deals with the REE geochemical characteristics of Permian-Triassic marine carbonate rocks in Guizhou Province.It is found that there are two broad categories of strati-graphic units in the region studied in accordance with their ΣREE contents and REE distribu-tion patterns: one is characterized by LREE enrichment and slight Ce depletion,with the REE distribution patterns similar to those of North American shales,and the other featrures relative HREE enrichment and relatively remarkable Ce depletion,with the REE distribution patterns close to those of pelagic sediments.In terms of their different ΣREE contents,five types of stratigraphic units can be distinguished.Incorporation of detrital minerals,REE complexing ca-pability,oxidation-reduction conditions of the media are the main factors affecting the REE com-position and REE distribution patterns of marine carbonate rocks in the region studied.In the light of REE geochemical characteristics of carbonate rocks,coupled with sedimentary facies analysis,this paper discusses the characteristics of the Permian-Triassic marine sedimentary environment in Guizhou Province and its evolutional rules. 相似文献
3.
贵州老万场红土型金矿地球化学特征及其成因 总被引：4，自引：0，他引：4
对贵州西南部晴隆老万场红土型金矿与相关岩石（矿石）和喀斯特红土等进行了常量元素、微量元素和稀土元素地球化学比较研究,阐明了矿床的各类元素的地球化学特征,追溯了矿术的物质来源。研究表明,本类红土型金矿的物质来源是高硅质（石英）、富铁质（黄铁矿等）的富金矿（岩）石;具有Ａｕ－Ａｓ－Ｓｂ－Ｈｇ－Ｔｌ－Ｗ－Ａｇ－Ｂａ的微量元素组合特征,与卡林型金矿十分相似,是原始卡林型金矿风化演化的产物。常量元素和稀土元 相似文献
4.
黔东南钾镁煌斑岩岩石学特征 总被引：1，自引：0，他引：1
黔东南地区位于扬子地台东南缘与江南褶皱系西缘的过渡带。本文以黔东南马坪、麻江地区发现的钾镁煌斑岩体为主要研究对象,通过地质特征、岩石学、矿物学、地球化学等研究,认为马坪地区金云钾镁煌斑岩具基性-超基性岩的标型元素Cr、Ni、Co含量较高,不相容元素总体富集,稀土元素配分模式为右倾型且分异程度较高,与典型钾镁煌斑岩(西澳含金刚石矿钾镁煌斑岩)在岩浆来源、地球化学特征上具有较大的相似性;麻江地区钾镁煌斑岩Al_2O_3、K_2O含量低,轻稀土富集、重稀土亏损,轻稀土特高,其岩浆形成温度、地球化学成分上与典型钾镁煌斑岩有较大差异。 相似文献
5.
Rare Earth Element Patterns in the Karst Terrains of Guizhou Province, China: Implication for Water/Particle Interaction 总被引：1，自引：0，他引：1
The authors determine the concentrations of dissolved (<0.22 μm) rare earth elements (REE) and suspended particulate matter
(SPM) of typical karst rivers in Guizhou Province, China during the high-flow period. The concentrations of acid-soluble REE
extracted from SPM using diluted hydrochloric acid are also obtained to investigate water/particle interaction in the river
water. The dissolved REE contents in the river water are extremely low in the rivers of the study. The dissolved REE distribution
patterns normalized by the Post Archean Australia Shale (PAAS) in the karst rivers are not flat, show slight enrichment of
heavy REE to light REE, and also have significant negative Ce and Eu anomalies. The acid-soluble REE appears to have similar
distribution patterns as characterized by MREE enrichment and slight LREE depletion, with unremarkable Ce and Eu anomalies.
The PAAS-normalized REE distribution patterns of SPM are flat with negative Eu anomalies. The contents and distribution patterns
of REE in the SPM are closely related to the lithological character of the source rocks. The SPM contains almost all the REE
produced in the process of surficial weathering. This demonstrates that particle-hosted REE are the most important form of
REE occurrence. REE fractionation, which takes place during weathering and transport, leads to an obvious HREE enrichment
in the dissolved loads relative to the SPM. Y/Ho ratio can be used to shed light on REE behaviors during water/particle interaction. 相似文献
6.
在黔东南出露的一套新元古界下江群浅变质碎屑岩中产出众多石英脉型金矿床(点),有关该类矿床的成因问题,特别是金的物质来源一直是研究的热点,因此下江群地层岩石的含金性以及元素地球化学特征也倍受关注。本文对贵州锦屏地区新元古界下江群浅变质岩及典型矿床的微量及稀土元素进行了系统测试,通过对比分析发现:下江群剖面的每个组均富集As、Ba、Zr、Ti;亏损Cr、Rb、Sr、Ta、Sc等元素,从番召组到平略组,元素组合演化呈明显相似性和继承性。含凝灰质多的番召组和清水江组地层中金含量较高,并且含金高的层位稀土含量较低,地层中Au与壳源特征的Ag、Hg、As等低温元素关系最为密切,该区金的迁移、富集可能与地层的热液活动或区域变质作用有密切的关系。围岩、地层岩石与矿石的微量元素特征及REE组成模式体现了地球化学演化上的一致性及继承性,表明该区金矿成矿物质可能主要来自于地层,而平秋金矿部分含金石英脉矿石表现出与围岩地层不同的地球化学特征,其更接近下地壳或上地幔,说明可能有部分深部流体参与成矿。 相似文献
7.
本文对苏北地区锦屏组磷矿石及地层样品进行了岩相学及地球化学分析,研究了磷矿初始沉积环境和源区特征。磷矿类微量元素富集Ba、Pb、U、Sr,贫Th、Ta、Nb、Ti;REE配分曲线为LREE富集型,Ce负异常,表明成矿环境为陆缘海,且成矿过程受深海热水沉积和生物作用影响。Sr、Nd同位素初始值判断磷灰岩物质来源为年轻的地壳物质。绿片岩类微量元素富集Rb、Th、K,贫Th、U、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,判断其原岩为陆源碎屑岩。（混合）片麻岩类微量元素富集Pb、Th、K,亏损Ba、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,具地幔源区特征。 相似文献
8.
辽宁弓长岭铁矿二矿区条带状铁建造地球化学特征及成因探讨 总被引：1，自引：0，他引：1
本文以弓长岭铁矿二矿区磁铁石英岩、磁铁富矿和蚀变围岩样品为研究对象,进行了主量元素、微量元素、稀土元素和Fe同位素的测试。结果表明:磁铁石英岩主要由TFe2O3和SiO2组成,Al2O3和TiO2质量分数较低,微量元素质量分数和稀土元素质量分数均较低;经澳大利亚后太古界平均页岩(PAAS)标准化的稀土配分模式呈现出轻稀土亏损和重稀土富集,La、Eu和Y的正异常明显,Ce的异常不明显,Y/Ho值较高;富集Fe的重同位素,且与海底喷发热液经过氧化沉淀后的Fe同位素特征一致。磁铁富矿与磁铁石英岩的地球化学特征有很好的一致性和继承性,但磁铁富矿的REE和Eu质量分数较高,且较磁铁石英岩富集Fe的轻同位素,范围更大,与蚀变岩的Fe同位素组成相近。弓长岭铁矿的磁铁石英岩是陆源物质加入很少的古海洋化学沉积岩,为喷出的海底热液与海水的混合条件下氧化沉淀形成的。磁铁富矿推测为富Fe的轻同位素热液对磁铁石英岩进行改造,经过去硅富铁作用形成的。 相似文献
9.
黔北地区下寒武统底部黑色页岩沉积环境条件与源区构造背景分析 总被引：5，自引：2，他引：3
为了深入探讨黔北地区下寒武统底部黑色页岩的沉积环境条件和源区构造背景,对黔北地区下寒武统牛蹄塘组黑色页岩进行系统采样,对其微量元素和稀土元素地球化学特征进行了系统分析。研究表明,微量元素中高的WV/(WNi+WV)和U/Th比值等反映该区黑色页岩形成于海域开阔的还原环境。区内黑色页岩样品中Mo、Sb、U、Cd、 V、Ba、Tl、Ni、W、 Cr、Cs、Cu、Zn、Bi等元素的高富集以及正Eu异常和较低的Co/Zn比值均反映了黔北下寒武统底部黑色页岩受到深部热液活动的影响。根据主、微量和稀土元素组合及比值特征可以看出黔北地区下寒武统底部黑色页岩的源岩具有花岗岩、沉积岩和玄武岩等多成因性质。源区构造背景以被动大陆边缘为主,由于受深部热液活动的影响,也显示大陆岛弧构造背景的特征。 相似文献
10.
华南热水沉积硅质岩建造及其成矿效应 总被引：15，自引：0，他引：15
华南地区热水沉积建造发育。文中介绍该地区热水沉积建造 ,特别是震旦系顶部、泥盆系榴江组和二叠系当冲组 3个重要层位的硅质岩建造 ,分析它们的地质地球化学特征。研究表明 ,华南三层位沉积硅质岩的共同特征是TiO2 、Al2 O3 和K2 O含量一致偏低 ,大部分微量元素含量偏低 (与地壳克拉克值相比 ) ,但Ba、As、Sb富集 ,具有较为典型的热水沉积成因特点。多元统计分析显示 ,大部分微量元素在第一个主因子上均有显著因子载荷 ,与它们在基底的富集或亏损无关 ,代表了古地热系热水循环中的淋滤因子。华南三层位热水成因硅质岩具有相似的REE地球化学特征。REE总量低 ,稀土配分模式落在典型热水沉积物的上、下限之间 ,多数样品呈现δCe和δEu负异常。正常沉积的混入使部分硅质岩的REE配分模式复杂化。最后 ,讨论了与热水沉积建造相关的成矿效应 ,为金属矿床成因和评价提供约束条件 相似文献
11.
Zhi Xiachen Chen Daogong Yang JinDepartment of Earth Space Sciences University of Science andTechnology of Chin Hefei Anhui Jiang M inxi 《《地质学报》英文版》1995,69(4):406-419
The basalt terrain of the Neogene Huangguoshan and. Guiwu Formations of eastern Anhui on the east side of the Tancheng-Lujiang fault belt is one of a few Cenozoic basalt terrains in eastern China for which detailed geochemical study has not been conducted. This paper reports the abundances of major elements and more than 20 trace elements (including REE) of 22 samples and the Nd, Sr and Pb isotopic compositions of 11 samples from the eastern Anhui basalt terrain, thus more or less systematically revealing the geochemical characteristics of this continental basalt suite. The paper discusses the origin of the basalt suite and the character and process of its mantle source. The basalt suite was derived from a heterogeneous continental lithospheric mantle with end members characteristic of the EMI-type oceanic basalt mantle, which was affected by mantle metasomatism (or enrichment of trace elements) and was characterized by a multi-stage evolution under open conditions. 相似文献
12.
本文系统地研究了鄂尔多斯盆地南部延长组凝灰岩元素和同位素地球化学特征。结果表明:凝灰岩主量元素具有高K、高Al、Si中等至高、低Na的特征;REE总体特征为轻稀土富集、重稀土亏损,∑REE在48.57～402.12μg/g之间变化,Eu呈现出负异常,在0.34～0.82内变化,δCe范围在0.80～2.08之间;微量元素中U含量在3.12～144μg/g之间,Ba、U、Th、Hf和Ce呈明显正异常,Nb、P、Ti和Rb呈现负异常。详细的分析表明:U的富集和一些微量元素如Ta、Dy、Lu等相关,Th与∑REE存在明显的正相关性,这些变化可能和盆地中铀矿的富集有关;凝灰岩的硫同位素总体呈现深源特征。根据以上的研究对凝灰岩的形成原因及形成环境进行了探讨。鄂尔多斯盆地南部延长组凝灰岩来源于秦岭造山带火山作用,其中的铀元素富集是由于砂岩型铀矿中铀向凝灰岩迁移而被还原所致。本研究对盆地砂岩型铀矿的铀运移和富集机理认识具有一定指导意义。 相似文献
13.
本文对嫩江地区中生代双峰式火山岩进行了锆石LA-ICP-MSU-Pb年代学和岩石地球化学研究。测年结果显示嫩江地区中生代双峰式火山岩形成于127.5Ma的早白垩世晚期。岩石地球化学研究表明,早白垩世晚期火山岩具有双峰式组合特点,基性端员富碱,富含轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素（Nb、Ta、Ti、Y）,形成于富集的岩石圈地幔的部分熔融和分离结晶作用,形成的过程可能含有少量的陆壳混染。酸性端员显示A型流纹岩的特征,为幔源岩浆底侵,使中下地壳岩石发生部分熔融的成因。双峰式火山岩组合的存在暗示其形成于陆内拉张的构造环境。结合区域上中生代火山岩的空间展布特征,嫩江地区早白垩世晚期双峰式火山岩的形成应与太平洋板块向欧亚大陆的俯冲作用有关。 相似文献
14.
We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation. 相似文献
15.
为探讨滇西户撒盆地新近系褐煤的微量元素地球化学特征及指示意义,采集了5口验证钻孔内15层褐煤的新鲜样品,利用ICP-MS对微量元素含量进行测试。结果表明,与中国煤微量元素背景值进行比较,户撒盆地褐煤Rb、Cs、Th富集,Be、Sc、Cr、Cu、Ga、In、W、Pb、U稍富集。户撒褐煤富集的潜在有害微量元素有Be(5.32mg/kg)、Cr(39.8mg/kg)、Cu(39.7 mg/kg)、Pb(32.8 mg/kg)、Th(39.3 mg/kg)和U(7.39 mg/kg)。褐煤的REE总量为196.03~550.42 mg/kg,平均为306.71 mg/kg,远高于中国煤的REE总量均值(136 mg/kg),表现出LREE明显富集,HREE相对亏损特征。δCe值负异常与微量元素比值特征均表明户撒泥炭的沉积期主要为酸性还原环境。δE负异常与球粒陨石标准化分配模式表明户撒新近系褐煤稀土元素与盆缘酸性花岗岩的陆源供给有关。 相似文献
16.
蒙古国东南部巨斑状二长花岗岩地球化学特征与岩石成因机制探讨 总被引：1，自引：0，他引：1
巨斑状二长花岗岩是蒙古洋板块早古生代晚期重要的岩浆记录,其花岗岩年龄和地球化学特征对于揭示蒙古洋板块该时期的构造格局与演化历史有重要意义。对蒙古国东南部出露的巨斑状二长花岗岩进行锆石的LA-ICP-MS法定年,获得锆石U-Pb年龄为(454.3±3.8) Ma,表明该二长花岗岩形成于晚奥陶世。花岗岩的元素地球化学研究结果表明：该花岗岩属高钾钙碱性I型花岗岩;花岗岩具高硅特征,其SiO2质量分数为69.82%~75.16%,A12O3质量分数为12.91%~14.49%,Na2O/K2O为0.60~0.77,过铝质,其铝饱和指数为1.11~1.22,Mg#指数为39~44;稀土元素总量为(43.47~158.11)×10-6,稀土元素分布型式为具有明显负铕异常的“燕型”曲线（δEu=0.26～0.49）;在原始地幔标准化的微量元素蛛网图中,Rb、Th、U、K、Zr、Hf和轻稀土元素(如La、Ce、Nd和Sm等)富集,Ba、Sr、P和Ti等元素强烈亏损,Nb和Ta具有中等-弱亏损特点;143Nd/144Nd初始比值较高(0.512 449~0.512 507),平均为0.512 477;εNd(t)为0.2~1.3,均为正值。主量、微量元素和同位素特征表明,该巨斑花岗岩形成于同碰撞向后造山构造体制转换过渡的伸展大地构造环境背景之下。伸展构造和幔源基性岩浆的底侵,很可能是形成花岗岩的2个最主要的动力机制。 相似文献
17.
1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen… 相似文献
18.
Geochemical Characteristics and Implications of Eclogite Gravels from Mesozoic Strata at the Northern Margin of Dabie Orogenic Belt 总被引：1，自引：0，他引：1
The eclogite gravels, which were found in the Mesozoic Fenghuangtai and Maotanchang formations on the northern margin of the Dabie orogenic belt, are rich in K2O(1.21%),∑REE (278μg/g) ,and LILE(such as Rb, Ba, K, Th, etc.) , with high (La/Yb)N ratios(14.4),on the basis of the analyses of major elements, rare-earth elements (REE) and trace elements. Their enrichment in LILE, notable Nb-Ta depletion through, and depletion in HFSE relative to REE in comparison with the primitive mantle and N-MORB indicate that the protoliths of the eclogite gravels were formed in an island-arc setting. According to the Th-Hf-Ta discrimination diagram, the protoliths of the eclogite gravels are characterized by volcanic arc basalts.Trace element data indicate that the subducted marine sediments were assimilated in the magma chamber, resulting in the enrichment of LILE in the protoliths. Therefore, the protoliths of the eclogite gravels are considered to have been formed in an inland-arc setting, indicating that there had developed a paleo-inland arc before Triassic collision between the North and South China blocks in the Dabie orogenic belt. There is a marked difference between the eclogite gravels and the eclogites developed along the Dabie orngenic belt, solely based on their geochemical data,especially REE. Therefore, the eclogite gravels may not be derived from eclogite terrains preserved in the Dabie orogenic belt. 相似文献
19.
贵州省松桃县道坨超大型锰矿床的发现及其成因探讨 总被引：5，自引：0，他引：5
贵州省松桃县道坨锰矿床是新发现的一个超大型全隐伏锰碳酸盐矿床。文章阐述了该矿床的发现概况及基本的地质和地球化学特征,并应用锰矿石和含锰黑色页岩的元素和碳同位素地球化学特征对菱锰矿的形成机制提出了制约。道坨超大型锰矿床的发现是填图及对区域地质资料综合分析的结果。该矿床具有品位高、厚度大、呈层性好及展布广等特点。其锰矿石的主量元素特征为Al2O3、TiO2、Fe2O3含量较低,P2O5中等程度富集,MnO、MgO含量相对较高,Fe/Mn比值低。在微量元素方面,锰矿石显示出较为明显的Co富集,含锰黑色页岩则显示出较为明显的Co、Mo富集;在稀土元素方面,锰矿石具有较高的稀土元素总量,轻微的"帽式"稀土元素PAAS标准化配分模式及明显的Ce正异常,含锰黑色页岩的稀土元素总量与PAAS接近,其稀土元素PAAS标准化配分模式较为平坦,无Ce异常。碳同位素测试结果显示出菱锰矿富集碳的轻同位素,表明在菱锰矿形成过程中存在有机碳的参与。文章表明,道坨锰矿床内的锰是以氧化物或氢氧化物的形式沉淀,菱锰矿是在缺氧且富含有机物质的成岩环境中转化而成。 相似文献
20.
为研究兴蒙造山带-华北克拉通地球化学走廊带区域地球化学组成及其横向空间变化,统计分析不同地理单元和五万图幅单元的REE含量并绘制其空间分布折线图.内蒙古半干旱草原土壤中稀土含量较低,与其草原沙土的粘土矿物较少有关;江苏北部冲积平原区的土壤中稀土含量较高,与降雨量存在良好空间对应关系.内蒙古红格尔到河北张家口,土壤与岩石∑REE的比值绝大多数小于1,REE发生贫化;山东章丘到江苏连云港,比值基本大于1,REE发生富集.华北克拉通内蒙地块土壤稀土特征与兴蒙造山带相似,可能受其草原沙土景观的影响.在不同构造单元之间,LREE与HREE亏损与富集的空间分布存在细微差异.结果表明:地理景观,特别是黏土矿物是影响土壤REE含量的重要因素,降雨量与REE存在良好空间对应关系,REE自身的地球化学性质的差异在土壤形成过程中对轻重稀土元素分异具有重要影响. 相似文献