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1.
空气扰动技术对地下水中氯苯污染晕的控制及去除效果 总被引：3，自引：0，他引：3
原位空气扰动技术(air sparging,AS)是去除饱和土壤和地下水中挥发性有机物的最有效方法之一。首先利用二维砂槽研究曝气量与空气饱和度、影响半径的关系。结果表明:提高曝气量可以增大地下水中的空气饱和度以及曝气影响半径,但二者的增幅与曝气量的增幅不成比例,随着曝气量的增加,二者增幅减缓。又利用砂槽研究了在水力梯度一定的情况下,不同曝气量对氯苯迁移和去除效果的影响。空气的注入降低了影响区域的渗透系数,减缓了地下水的流动,有效地控制了污染物的迁移。未曝气时,130 h以后,氯苯随地下水流迁移出砂箱的比例为19.7%,而曝气量为0.1、0.2 m3/h时,此比例仅为3.6%和0.9%;与此同时,AS对氯苯的去除率分别为68.2%和78.6%。这说明AS可以有效控制污染物的迁移和去除,曝气量较大时效果更为明显。 相似文献
2.
Air sparging is an emerging method used to remediate saturated soils and groundwater that have been contaminated with volatile organic compounds (VOCs). During air sparging, air is injected into the subsurface below the lowest known depth of contamination. Due to buoyancy, the injected air will rise through the zone of contamination. Through a variety of mechanisms, including volatilization and biodegradation, the air will serve to remove or help degrade the contaminants. The contaminant-laden air will continue to rise towards the ground surface, eventually reaching the vadose zone, where the vapours are collected and treated using a soil vapour extraction (SVE) system.Air sparging performance and ultimately contaminant removal efficiency is highly dependent on the pattern and type of subsurface air flow. This paper presents the results of a laboratory experimental study which investigated the injected air flow pattern development within an aquifer simulation apparatus. The test apparatus consisted of a tank measuring 61 cm long by 25.4 cm wide by 38.1 cm high. The apparatus was equipped with one air injection well and two vapour extracton wells. Three different soils were used to simulate different aquifer conditions, including a sand, a fine gravel and a medium gravel. Experiments were performed with different injected air pressures combined with different vacuum and groundwater flow conditions. Experiments were also conducted by injecting air into simulated shallow aquifers with different thicknesses. The air flow patterns observed were found to depend significantly on the soil type, groundwater flow conditions and system controls, including injected air pressure, flow rate and applied vacuum. © Rapid Science Ltd. 1998 相似文献
3.
Air sparging (AS) is an in situ soil/groundwater remediation technology, which involves the injection of pressurized air/oxygen through an air sparging well below the zone of contamination. Characterizing the mechanisms governing movement of air through saturated porous media is critical for the design of an effective cleanup treatment system. In this research, micromechanical investigation was performed to understand the physics of air migration and subsequent spatial distribution of air at pore scale during air sparging. The void space in the porous medium was first characterized by pore network consisting of connected pore bodies and bonds. The biconical abscissa asymmetric concentric bond was used to describe the connection between two adjacent pore bodies. Then a rule‐based dynamic two‐phase flow model was developed and applied to the pore network model. A forward integration of time was performed using the Euler scheme. For each time step, the effective viscosity of the fluid was calculated based on fractions of two phases in each bond, and capillary pressures across the menisci was considered to compute the pressure field. The developed dynamic model was used to study the rate‐dependent drainage during air sparging. The effect of the capillary number and geometrical properties of the network on the dynamic flow properties of two‐phase flow including residual saturation, spatial distribution of air and water, dynamic phase transitions, and relative permeability‐capillary pressure curves were systematically investigated. Results showed that all the above information for describing the air water two‐phase flow are not intrinsic properties of the porous medium but are affected by the two‐phase flow dynamics and spatial distribution of each phase, providing new insight to air sparging. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
4.
Air sparging is an effective technique for the remediation of soil and groundwater polluted by volatile organic compounds. In this paper, this technique was investigated by conducting air-sparging test in the laboratory on the Shanghai sandy silt that was artificially contaminated with p-xylene. A test tank was designed for this purpose. During the air-sparging process, aqueous p-xylene solutions were extracted from the observation holes, and their concentrations were quantified by the spectrophotometric detection method. The mechanism of mass transfer process of p-xylene in the vicinity of sparging well and the remediation of the contaminated groundwater by air sparging were explored. The results showed that the removal zone of the p-xylene was mainly located within a radius of about 20?cm around the air injection well, with 90?% p-xylene removed after 20-day air sparging. Within the initial 5-day sparging, the concentration of p-xylene decreased rapidly in the mass transfer zone. By contrast, in the area far from the injection well, the p-xylene concentration decreased evenly and slowly. Thus, the remediation of contaminated soil and groundwater by air sparging is space?Ctime dependent. For further analysis, the adsorption of silt was taken into account, and the distribution coefficient, K d , was introduced to the modified Shackleford??s mass transfer model. The comparison between the simulated and measured results indicates that the modified model can satisfactorily describe the p-xylene mass transfer observed in this study. 相似文献
5.
Based on laboratory and theoretical modeling results, we present the thermal and hydrodynamical structure of the plume conduit during plume ascent and eruption on the Earth’s surface. The modeling results show that a mushroom-shaped plume head forms after melt eruption on the surface for 1.9 < Ka < 10. Such plumes can be responsible for the formation of large intrusive bodies, including batholiths. The results of laboratory modeling of plumes with mushroom-shaped heads are presented for Ka = 8.7 for a constant viscosity and uniform melt composition. Images of flow patterns are obtained, as well as flow velocity profiles in the melt of the conduit and the head of the model plume. Based on the laboratory modeling data, we present a scheme of a thermochemical plume with a mushroom-shaped head responsible for the formation of a large intrusive body (batholith). After plume eruption to the surface, melting occurs along the base of the massif above the plume head, resulting in a mushroom-shaped plume head. A possible mechanism for the formation of localized surface manifestations of batholiths is presented. The parameters of some plumes with mushroom-shaped heads (plumes of the Altay-Sayan and Barguzin-Vitim large-igneous provinces, and Khangai and Khentei plumes) are estimated using geological data, including age intervals and volumes of magma melts. 相似文献
6.
Effect of sediment size on area of influence during groundwater remediation by air sparging: a laboratory approach 总被引：2，自引：0，他引：2
Air sparging is a groundwater remediation technique, in which organic contaminants volatilize into air as it rises from the
saturated to vadose zone. An unknown has been the relationship between sediment size and area affected by air. Laboratory
experiments were performed on sediments to determine the area affected by air as a function of grain size. For average grain
sizes of 1.1 and 1.3-mm diameter, air flow occurs in discrete meandering channels, with a maximum area of sediment column
affected of 13%/m2 for 1.1-mm and 14%/m2 for 1.3-mm sediments. For average grain sizes of 1.84, 2.61 and 4.38-mm diameter, air flow is pervasive, forming a symmetrical
cone of influence around the injection point. Maximum areas affected are15%/m2 for 1.84-mm, 25%/m2 for 2.61-mm, and 9%/m2 for 4.38-mm sediments. Optimal sites for air sparging, may be those with grain diameters between about 2–3 mm.
Received: 26 June 1998 · Accepted: 27 July 1998 相似文献
7.
In situ air sparging involves injecting atmospheric air, under pressure, into the saturated zone to remove those volatile and semi-volatile organic groundwater contaminants and to promote their biodegradation by increasing subsurface oxygen concentrations. Due to the advantages of low cost, high efficiency and in situ constructability, groundwater Air Sparging (AS) technology has been quickly developed in the world recently. Based on the explanation of its remediation principle, literature review is done on the research advancement of air sparging technology mainly from three aspects. First, various methods for determination of the zone of influence and visualization techniques of air flow forms during air sparging are summarized. Then the influence of environmental geological conditions and construction technology parameters on the remediation effect of air sparging is systematically analyzed. Thereafter, two main types of air sparging theoretical models including lumped-parameter model and multiphase fluid flow model are discussed respectively in detail. Finally, based on the problems and difficulties existing in present research and engineering practice, several future tasks such as the enhancement remediation techniques in complex geological sites, microscopic intrinsic mechanisms, and establishment of related design and construction standards which require to be done are briefly analyzed. 相似文献
8.
《Russian Geology and Geophysics》2016,57(6):858-867
Laboratory and numerical experiments simulating the heat transfer and flow structure of thermochemical mantle plumes provide insights into the mechanisms of plume eruption onto the surface depending on the relative thermal power of plumes Ka = N/N1, where N and N1 are the heat transferred from the plume base to the plume conduit and the heat transferred from the plume conduit to the surrounding mantle, respectively, under steady thermal conduction. There are three main types of plumes according to the Ka criterion: (i) plumes with low thermal power (Ka < 1.15), which fail to reach the surface, (ii) plumes with intermediate thermal power (1.15 < Ka < 1.9), which occur beneath cratons and transport melts from depths below 150 km, where diamond is stable (diamondiferous plumes), and (iii) plumes with a mushroom-shaped head (1.9 < Ka < 10), which are responsible for large intrusive bodies, including batholiths. The volume of erupted melt and the depth from which the melt is transported to the surface are estimated for plumes of types (ii) and (iii). The relationship between the plume head area (along with the plume head diameter) and the relative thermal power is obtained. The relationship between the thickness of the block above the plume head and the relative thermal power is derived. On the basis of the results obtained, the geodynamic-regime diagram of thermochemical mantle plumes, including the plumes with Ka > 10, has been constructed. 相似文献
9.
地下水曝气工程技术研究——以德州胜利油田地下水石油污染治理为例 总被引：5，自引：0，他引：5
为了研究地下水石油污染现场曝气治理效果,在胜利油田石油开采区进行了地下水现场曝气治理技术研究。采用溶解氧浓度法研究了曝气操作条件(曝气深度、曝气压力和曝气流量)对地下水石油污染曝气治理技术的影响。实验结果表明:在相同曝气压力和流量下,曝气深度越大,影响半径越大,但影响区内的气流分布越稀疏;相反,曝气深度越小,则曝气影响半径越小,但在影响区内空气流线分布越密。气流分布密度和曝气影响半径随曝气压力和流量增大而增大,但存在一个最佳限值;现场曝气存在气流分布不对称现象,是由于土壤介质的渗透性不均匀所致。地下水曝气技术对地下水石油污染治理效果显著,但曝气操作条件对该技术影响较大,需根据地质条件通过现场曝气试验确定。 相似文献
10.
Naichao Feng Shiqing Cheng Haiyang Yu Wenyang Shi Xin Liu Qicheng Liu 《Arabian Journal of Geosciences》2018,11(17):519
High-pressure air injection (HPAI) is a significant enhanced oil recovery (EOR) technology of light oils especially in deep, thin, low-permeability reservoirs. The flow and heat transfer behaviors of compressed air in wellbore is essential to maximize performance of air in EOR. Due to strong compressibility of air and high injection pressure, wellbore temperature and pressure are greatly affected by friction and gas compression. However, the available models of wellbore flow and heat transfer are only accurate for thermal fluid, such as saturated steam and superheated steam, injected at relatively low pressure and high temperature. In this paper, a novel model is proposed to characterize wellbore pressure and temperature distribution for HPAI wells with consideration of dynamic behaviors of injected air. Flow and heat transfer in depth direction are coupled with air properties by iterative technique, and heat transfer in radial direction is treated as steady state in wellbore and transient state in formation. The mathematical model is solved by employing finite difference method and it is validated by field data. Then, integrated analyses of flowing pressure, heat transfer mechanism, and interaction between pressure and temperature are conducted. Results indicate that (1) as well depth increases, temperature difference between formation and air tends to become constant, and the radial heat transfer tends to reach an equilibrium state. The higher the flow rate is, the deeper the equilibrium depth is. (2) Air temperature is dominated by heat transmission from formation at low flow rates and dominated by frictional heat and gas compression effect at high flow rates. Fictional heat begins to affect air temperature at an injection rate beyond the critical value, while gas compression effect can increase air temperature in the whole calculated injection rate range. (3) Interaction between wellbore temperature and pressure is mainly achieved by altering air density. The effect of injection pressure on air temperature can be negligible, while the influence of injection temperature shows strong dependency on injection rate. 相似文献
11.
On thermochemical mantle plumes with an intermediate thermal power that erupt on the Earth’s surface
The relative plume thermal power Ka = N/N1 is used (N is the thermal power transferred from the plume base to its conduit and N1 is the thermal power transferred from the plume conduit into the surrounding mantle in the steady-state heat conduction regime). Thermochemical mantle plumes with small (Ka < 1.15) and intermediate (1.15 < Ka < 1.9) thermal powers are formed at the core–mantle boundary beneath cratons in the absence of horizontal free-convection mantle flows beneath them, or in the presence of weak horizontal mantle flows. Thermochemical plumes reach the Earth’s surface when their relative thermal power is Ka > 1.15. The thermal and hydrodynamical structure of the plume conduit ascending from the core–mantle interface to the level from which the magmatic melt erupts on the Earth’s surface is presented. The model of two-stage eruption of the melt from the plume conduit to the surface is considered. The critical height of the massif above the plume roof, at which the eruption conduit supplying magmatic melt to the surface forms, is determined. The volume of melt erupting through the eruption conduit to the surface is estimated. The dependence of depth Δx from which the melt is transported to the surface on the plume diameter for a kinematic viscosity of ν = 0.5–2 m2/s is presented. In the case when the value Δx is larger than the depth starting from which diamond is stable (150 km), the melt from the plume conduit can transport diamonds to the Earth’s surface. The melt flow in the eruption conduit is considered as a turbulent flow in a cylindrical duct. The velocity of the melt flow in the eruption conduit and the time for the melt to be transported to the surface from a depth of Δx = 150 km for a kinematic viscosity of the melt in the eruption conduit νv = 0.01–1 m2/s are determined. Tangential stress on the eruption conduit sidewall is estimated in cases of melt flow both in smooth and rough conduits. 相似文献
12.
通过一维砂柱实验研究了阴离子表面活性剂十二烷基苯磺酸钠(SDBS)对空气扰动技术(air sparging,AS)修复氯苯污染地下水的强化效果.结果表明,SDBS的加入降低了地下水的表面张力,减小了水气两相毛细压力,从而提高了地下水中的空气饱和度.当曝气量为100 mL/min,地下水的表面张力由72.2 mN/m降至49.5 mN/m时,地下水中空气饱和度由13.2%提高至50.1%,而后随着表面张力的进一步降低,空气饱和度不再提高,反而有小幅下降.通过污染物的去除实验发现,SDBS的加入大大提高了氯苯的去除率,且去除率的变化与空气饱和度的变化趋势基本相符.因此,表面活性剂的加入可以作为空气扰动技术一种十分有效的强化手段. 相似文献
13.
为了提高空气扰动技术（air sparging,AS）的效果,做了一系列的实验,研究了表面活性剂强化空气扰动技术（surfactant-enhanced air sparging, SEAS）中表面活性剂的选择方法。结果表明：在气流运行方式以鼓泡为主要机制时,表面活性剂的加入强化了气泡的起泡性和稳泡性,使空气饱和度增加;在气流运行方式以微孔道为主要机制时,表面活性剂的加入因减小了表面张力而减小了空气驱替水所需的毛细压力,使空气饱和度增加。比较Tween-80、TritonX-100、SDS和SDBS在介质上的吸附损失,确定出在中砂中TritonX-100为优,在砾石中SDBS为优。 相似文献
14.
Rashid S. Al-Maamari Akihiko Hirayama Tsuyoshi Shiga Mark N. Sueyoshi Mahfoodh Al-Shuely Osman A. E. Abdalla Anvar R. Kacimov 《Environmental Earth Sciences》2011,63(6):1189-1198
Water table dynamics, dissolved oxygen (DO) content, electrical resistivity (ER) in monitoring wells and air pressure in the vadose zone are monitored in air sparging (AS) accompanied by soil vapor extraction (SVE) at a hydrocarbon-contaminated groundwater site in Oman, where a diesel spillover affected a heterogeneous unconfined aquifer. The formation of a groundwater mound at the early stage of air injection and potential lateral migration of contaminants from the mound apex called for an additional hydrodynamic barrier constructed as a pair of pump-and-treat (P&T) wells whose recirculation zone encompassed the AS and SVE wells. In all monitored piezometers the phreatic surface showed a rapid and distinct peak, which is attributed to the time of air breakthrough from the injection point to the vadose zone and a relatively mild recession limb interpreted as a decay of the mound. Tracer tests showed a layer of a relatively low hydraulic conductivity at an intermediate depth of the screened interval of the wells. Increased levels of DO and borehole air pressure that have been observed (as far as 50 m away) are likely mitigated by SVE and P&T. Radius of influence can be indirectly inferred from ER and DO changes in the AS operation zone. Salt tracer tests have shown that groundwater velocity within the AS zone decreases with the increase of air injection rate. 相似文献
15.
We present a thermophysical model for interaction between the conduit of a thermochemical plume and horizontal free convection flows in the mantle: The mantle flow incident on the plume conduit melts at the conduit boundary (front part) and crystallizes at its back. Geological data on the intensity of plume magmatism over the last 150 Myr are used to estimate the total thermal power of mantle plumes. A possible scenario for plume-related mantle recrystallization is proposed. Over the lifespan of a thermochemical plume, mantle melts and recrystallizes owing to the motion of the plume source and interaction between the plume conduit and horizontal free convection flows. The plume conduits can melt and recrystallize the entire mantle over a certain period of time. The model for the interaction of drifting plume conduits with mantle flows and the estimated total thermal power of mantle plumes are used to estimate the duration of plume-related melting and recrystallization of the entire mantle. The influence of mantle plumes on the convective structure of the mantle through melting is judged from the model for plume interaction with horizontal mantle flows. 相似文献
16.
减饱和法是一种通过减小砂土地基的饱和度,从而提高地基抗液化强度的新方法。基于减饱和砂土中流体模量同步更新的改进算法对减饱和砂土离心机振动台试验进行了数值分析,并与单一流体模量的简化算法进行了对比分析。结果表明：由于改进算法中考虑了因孔压变化引起的等效流体模量的变化,其计算结果更接近试验结果,而简化算法低估了减饱和砂土的孔压积累。基于改进算法开展了不同饱和度、倾斜角度的缓倾场地上液化变形的数值模拟研究,分析发现超孔隙水压力增长的速度及其峰值随着饱和度的增加而增大,饱和度从100%降低至96.4%,同一深度处的超孔压峰值降低约20%～65%,加速度响应的峰值也有明显的降低;沿地基深度0.75 m到9.00 m,侧向位移减少约20%～50%,表明饱和度的降低对抑制倾斜场地上可液化砂土层的侧向变形有显著效果,随着地基深度的减小,饱和度对于侧向位移的影响越来越明显。 相似文献
17.
气泡对流动注射峰形的影响及其干扰消除 总被引：2，自引：0，他引：2
研究了流动注射分析中气泡产生的原因、气泡形成吸收峰的原因及其峰的形状，并给出了气泡在不同温度下的吸收峰。讨论了消除流路体系中气泡的方法，指出用反压圈增大流路体系的压强是消除气泡干扰最简便的方法，并列举了用反压圈消除气泡的实例。 相似文献
18.
19.
The PT-phase relations of a Hawaiian tholeiite with 18.2% MgO has olivine–orthopyroxene multiple saturation at 20.5 kbar and 1,550°C. This pressure is less than the pressure at the lithosphere/asthenosphere transition, and it is suggested that tholeiites with this and lesser MgO contents are fractionated. Assuming a harzburgitic residuum it is shown that Hawaiian primary tholeiites contain about 23% MgO, and are generated at 36±5 kbar and 1,680±50°C. This pressure is equivalent to a depth of 112 km, which is consistent with the thickness of the lithosphere and thermal plume modeling. The minimal MgO content of primary Hawaiian tholeiites is suggested as 19% MgO. 相似文献
20.
利用高压压汞、恒速压汞、核磁共振、铸体薄片、物性等分析测试手段及试油资料,对姬塬地区长6段储层进行了流动单元的划分,同时分析不同流动单元微观孔隙结构特征及其对可动流体饱和度的影响,进而研究其生产动态的差异。结果表明:研究区四类流动单元微观孔隙结构差异明显,是造成其可动流体饱和度差异的主要因素。其中,喉道半径分布形态及主流喉道半径大小起了决定性作用。在油气田开发阶段中,应该根据不同流动单元的微观孔隙结构差异性特征,实施合理有效的开发方案。 相似文献