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1.
《Precambrian Research》2001,105(2-4):371-383
It has been well established that fluids played an important part in determining chemical characteristics in many crustal terranes. Studies of fluid inclusions in eclogites have established that brines coexisted with the primary mineral assemblages during their metamorphic crystallization. These brines are currently multiply saturated in halide salts, carbonates, oxides, and sulfides. As a first step in quantitatively bounding the composition of the brines during metamorphism, the equilibrium compositions of the brines at room temperature were computed using the aqueous speciation codes EQ3/6. The results demonstrate that the brines are high density solutions (ca. 1.4 g/cm3) that have ionic strengths of approximately 8 mol, and are approximately 40% dissolved solids, by weight. These are predominately Na- and K-rich brines, with subordinate Ca and Mg. The approximate Na:K:Ca:Mg molar ratios are 4:2:0.5:0.2, but are sensitive to the assumed HCO3− concentrations. Charge balance is primarily maintained by the very high Cl concentrations. These brines bear resemblance to brines analyzed from fluid inclusions in metamorphic rocks reported by Roedder (Roedder, E., 1972. Composition of fluid inclusions. US Geol. Surv. Prof. Paper 440JJ, p. 164). Although these fluids have the potential of acting as significant metasomatic agents in subduction zones and deep crustal environments, their impact will be mineralogically discernible only if the fluid release and movement is channelized.  相似文献   

2.
沉积物的元素地球化学特征是对沉积盆地水体环境以及古气候条件变化的响应。本文根据元素（Al、Fe、Mg、Ca、K、Na、P、V、Ni、Co、Cr、Cu、Zn、Sr、Ba、Cd、Li、Mn、Pb、Ti）的含量及其比值（Al/Ti、Fe/Mn、Sr/Ba、Mg/Ca、Sr/Ca、Na/Ca、V/Cr、Ni/Co、Ni/V）的变化，对三水盆地古近系心组红岗段生油层的沉积条件进行了系统分析。心组红岗段下部（亚段A）表现为较稳定的地球化学特征。各元素丰度及其比值指示这一时期陆源输入持续较高、且物源组成变化不大。由于海水入侵的影响，湖盆水体盐度相对较高，底部水体以弱氧化条件为主，O2-H2S界面位于水/沉积物界面附近。红岗段中上部（亚段B、C）的元素地球化学特征变化较为频繁且幅度很大，反映古气候和湖盆沉积条件的迅速变迁。在潮湿气候条件下，沉积物的地球化学特征表现为以Al、Ti为代表的外源元素含量及其比值较高，而Mg、Ca等盆内化学沉积元素含量较低。古氧气指标指示底部水体为还原环境，有利于有机质保存。因而，相应于较高的有机碳含量。在间歇性干旱时期，陆源输入减少，外源元素含量及其比值显著降低。随着蒸发作用的加强，水体盐度加大，内源元素丰度以及Mg/Ca、Sr/Ba、Sr/Ca和Na/Ca比值大幅度上升。底部水体为氧化环境，O2-H2S界面多位于水/沉积物界面或沉积物中。上述两种气候条件在红岗段中上部沉积时期交替出现。红岗段沉积后期由于淡水的长期输入，湖水出现逐渐淡化趋势。  相似文献   

3.
川西同德和沙坝麻粒岩及其退变质岩石之间的元素迁移   总被引：6，自引：0，他引：6  
利用川西麻粒岩的全岩化学组成与岩石中特征矿物的化学性质,研究了麻粒岩退变质作用的元素迁移。对紫苏辉石、普通辉石和普通角闪石的电子探针分析表明,随着麻粒岩退变质作用程度的加深,矿物的化学组成与全岩的元素迁移同步变化。由于矿物组合和岩相的转变以及地壳流体的作用,同德二辉麻粒岩在退变质至黑云角闪斜长片麻岩过程中,K,Rb,Cs,K／Na,Fe^3+和Fe3+／Fe^2+增加,Fe^2+,V,Co,Ba,Sr和Pb降低;在沙坝二辉麻粒岩退变质为含绿帘石角闪斜长片麻岩过程中,Na,Ca,Fe^3+,Zr,Hf,Nb,Ta,Rb,U,Th,REE和Fe^3+／Fe^2+增加,Fe^2+,Mg,K,Co,Zn,Cs,Pb和K／Na降低。麻粒岩退变质过程中制约不同元素迁移的主要矿物相是普通角闪石等退变质新生矿物。同德和沙坝两个麻粒岩块退变质作用中,个别元素迁移性状并不相同,这可能与原岩的性质和变质流体的成分等环境地质条件有关。  相似文献   

4.
Twenty-four brine samples from the Heletz-Kokhav oilfield, Israel, have been analyzed for chemical composition and Li isotope ratios. The chemical composition of the brines, together with geological evidence, suggests derivation from (Messinian) seawater by evaporation that proceeded well into the gypsum stability field but failed to reach the stage of halite crystallization. The present salinity of the samples (18-47 g Cl/L) was achieved by dilution of the original evaporitic brine by local fresh waters. Like brines from other sedimentary basins, the Li/Cl ratios in the Heletz-Kokhav samples show a prominent Li enrichment (five-fold to eight-fold) relative to modern seawater. The isotopic ratios of Li, expressed in the δ 6Li notation, vary from −26.3 to −17.9‰, all values being significantly higher than that of modern seawater (−32‰) irrespective of their corresponding Li concentration (1.0-2.3 mg/L). The isotopic composition of Li and the Li/Cl ratio in the oilfield brines were acquired in two stages: (a) The original evaporated seawater gained isotopically light Li during the diagenetic interaction between the interstitial Messinian brine and the basin sediments. A parent brine with an elevated Li/Cl ratio was formed. The brine was later diluted in the oilfields. (b) The δ 6Li values of the final brines were determined during epigenetic interaction with the Heletz-Kokhav aquifer rocks. At the same time, the Li/Cl ratio inherited from stage (a) remained largely unchanged. This work represents the first use of lithium isotopic composition to elucidate the origin and evolution of formation waters in sedimentary basins.  相似文献   

5.
The c. 1.9 Ga old Stollberg sulphide and Mnrich skarn iron ores and sulphide ores in Bergslagen, south-central Sweden are hosted by hydrothermally altered and metamorphosed felsic volcanic and volcaniclastic rocks. The ores are underlain by comformable alteration zones characterized by albite-gedrite-quartz and biotite-muscovite-plagioclase-K-feldspar-quartz +/– garnet assemblages. The present mineralogies are interpreted as medium-grade metamorphic equivalents to the original alteration mineral assemblages. PT-conditions during prograde regional metamorphism are semiquantatively determined to be 510 to 560 °C at approximately 3 kbar. With increasing modal content of gedrite and biotite in the alteration zones, the Mg/Fe ratios and XMg's in octahedral positions of these minerals also increase. In the gedrite-bearing strata, whole-rock Mg/Fe ratios remain constant, whereas in the biotite-rich unit the wholerock Mg/Fe trend is parallel to that of the biotites.The trends in the metamorphic mineral composition are interpreted to be a product of original changes in fluid composition during the evolution of a sub-seafloor hydrothermal system. During the initial stage of alteration, Fe-Mn-rich fluids altered the rocks, and during a later stage, the fluids became more Mg-rich, possibly due to entrainment of fresh seawater, and the alteration zones became relatively more Mg-rich. Sulphide precipitation was contemperaneous with Mg metasomatism, suggesting base metal precipitation was a function of the mixing of cool seawater with hydrothermal fluid. It is proposed that early hydrothermal alteration was associated with the deposition of areally extensive Fe-oxide formation, and that Mg metasomatism defines a second stage of hydrothermal activity during which sulphide mineralization overprinted the earlier formed Fe-oxide deposit.  相似文献   

6.
The mineralogy and petrochemistry of the garnet-amphibolites from the highgrade part of the Abukuma metamorphic belt have been studied, using five analyses of rocks, five of hornblendes, three of garnets and one analysis of cummingtonite, Garnetiferous amphibolites are rich in Fe, whereas non-garnetiferous ones are rich in Mg, especially in cummingtonite-amphibolite. The chemical composition of hornblendes associated with garnet is pargasitic and rich in FeO and poor in CaO, but that of non-garnetiferous rocks is rich in MgO. The garnets are rich in almandine molecule. Mg/Mg + Fe2+ ratios of both hornblendes and garnets correspond with those of the host rocks. The development of garnet in the Adirondack metabasites belonging to the upper almandine-amphibolite and granulite facies is observed in Mg-rich rocks as well as in Fe-rich rocks, in which both garnet and hornblende are rich in Mg respectively. However, under the conditions of the andalusite-sillimanite type metamorphism as shown in the Abukuma Plateau, Fe-rich garnet occurs in Fe-rich basic rocks, but cummingtonite occurs in Mg-rich ones instead of Mg-rich garnet. Finally, the problem of polymetamorphism is discussed. The cummingtonite-amphibolite may be the product of polymetamorphism, and Mg-rich garnet which had been present previously was decomposed to cummingtonite and plagioclase by the subsequent regional metamorphism of andalusite-sillimanite type.  相似文献   

7.
The Palaeo-Mesoproterozoic metasiliciclastic rocks of the southern Serra do Espinhaço, Minas Gerais, Brazil, are host to historically important alluvial deposits of diamonds and gold. Detrital gold grains often comprise Au–Pd–Pt intermetallic compounds, with low Ag contents, which contain inclusions of tourmaline and titaniferous hematite (up to ~ 6 wt.% TiO2). The latter minerals connect the alluvial mineralisation to the rutile–hematite–quartz veins and tourmalinisation observed in the quartzitic country rocks of the alluvial gravel. The quartzite (Sopa-Brumadinho Formation of lacustrine to fan-deltaic origin) is affected by pervasive B metasomatism with F-bearing tourmaline replacing the recrystallised quartz fabric. The tourmaline belongs to the alkali group, with Mg/(Mg + Fe) and X/(X + Na) ratios in the ranges from 0.5 to 0.7 and 0.18 to 0.29, respectively, where X represents vacancies in the X site. Boron-isotopic values of tourmaline vary from ~ 1 to − 10.4‰ δ11B. The B-isotope range, in conjunction with the Na–Mg-rich tourmaline composition, and the widespread occurrence of tourmalinite in the Sopa-Brumadinho Formation suggest a derivation from non-marine evaporitic brines. Brines are capable of transporting otherwise immobile Ti and explain, under oxidising conditions, the fractionation of Ag from Pd to precipitate palladiferous gold with extremely high Pd/Ag ratios. Zirconium-in-rutile and Ti-in-quartz temperatures for a variety of hematite-rich veins suggest episodic vein emplacement over a temperature range from around 500 °C to ~ 350 °C. Cross-cutting relationships and episodic vein emplacement indicate a late-Brasiliano age.  相似文献   

8.
Abstract Cordierite-anthophyllite rocks and related cordierite-rich, talc-rich and chlorite-rich rocks occur in the Rosebud Syncline, north-west Queensland, Australia, as part of a Proterozoic metasedimentary sequence. Field relations and rock compositions attest the sedimentary origin of these rather unusual metamorphic rocks. Their chemical composition is comparable to that of unmetamorphosed, alkali- and Ca-poor pelites, which are associated with some evaporite deposits. Other occurrences of cordierite-anthophyllite rocks have commonly been interpreted as metamorphosed chloritic alteration products derived from mafic or felsic volcanics. A comparative chemical study, using analyses of cordierite-anthophyllite rocks from such alteration zones and analyses of unmetamorphosed magnesian pelites, demonstrates the general chemical similarity between these two rock groups of entirely different origin. However, distinct differences in major element relations help to distinguish these two genetic groups. Particularly useful are Al2O3–FeO–MgO plots, in which evaporitic pelites occupy the Fe-poor side. The highly magnesian metamorphic rocks from the Rosebud Syncline fall entirely into the compositional field of evaporitic clays and shales. Furthermore, analyses of relatively immobile trace elements give supporting evidence for the sedimentary origin of these cordierite-anthophyllite rocks. The correlation with trace element ranges of clays and shales is very good. However, the correlation with trace element ranges of mafic and felsic volcanics is poor, and major discrepancies occur with Cr, Ni, Co, Nb, Sc, Th and Ti. Thus, the magnesian metamorphics of the Rosebud Syncline appear to be derived from evaporitic clays rich in magnesian clay minerals, such as palygorskite, sepiolite, chlorite or corrensite. The complete metamorphic rock assemblage of interlayered calcareous, aluminous and magnesian rocks is interpreted as a metamorphosed carbonate-evaporite-pelite sequence.  相似文献   

9.
During Tertiary regional metamorphism in the Western Hohe Tauern, reaching maximum P, T conditions around 6 kb, 550° C in calcareous metasediments, reaction of pyrite to pyrrhotite is suggested by regional distribution and textural relations. In rocks without graphite pyrite is common at all metamorphic grades. In graphite bearing rocks, however, the dominant Fe-sulfide is pyrite at lower grade and pyrrhotite at higher grade. Furthermore, in graphite bearing high grade rocks, pyrite is restricted to assemblages with Mg-rich silicates. Several factors control pyrite-pyrrhotite relations. Increase of temperature is most effective by increase of pyrrhotite vs. pyrite stability field, shift of silicate-sulfide reactions toward the stability field of pyrrhotite, creation of sulfur free fluids from devolatilization reactions, and increase in the proportions of sulfur bearing fluid species. Presence of graphite also favours progress of pyrite to pyrrhotite reaction, as shown by different -stabilities and changes in the amount of minerals and fluid during metamorphic heating of graphite bearing and graphite free assemblages. An opposite effect is shown by assemblages with low Fe-contents in Fe-Mg silicates, due to the enlarged stability field of such minerals with increasing Mg (and F) content. Another inhibition of pyrite to pyrrhotite reaction is suggested to be due to relatively high sulfur contents of H2O rich infiltrating fluids.  相似文献   

10.
Skarns composed predominantly of Ca pyroxene, Ca amphibole, and biotite occur locally in the Grenville metamorphic terrain of the Canadian pre-Cambrian Shield. The enclosing rocks are Grenville gneisses and limestones, gabbroic rocks, veined gneisses, and granitic rocks. The metamorphic grade of the skarns is identical to that of the enclosing rocks, namely the upper region of the amphibolite facies.

Twelve skarn specimens were selected for chemical study. An investigation is made of the concentrations of Al, Fe, Mg, Mn, Ti, Ca, Na, K, Ba, V, Cr, Zr, Y, and Sc in eleven Ca pyroxenes, ten Ca amphiboles, and eleven biotites.

Consideration is given to the distribution of elements among coexisting minerals. Regular relationships appear when

1. (1) the concentration of an element in a mineral is related to the concentration of the element in a coexisting mineral by a linear or non-linear function

2. (2) the linear or non-linear function is itself a function of the concentration of another element in one or both of the coexisting minerals. These relationships indicate that, for the most part, minerals within each skarn specimen closely approached a state of chemical equilibrium.

A preliminary attempt is made to explain the distribution relationships in terms of crystal chemistry.  相似文献   


11.
Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO4 content.  相似文献   

12.
In natural resource exploration, Ca–Cl basinal brines are important for understanding the origin and spatial and temporal distribution of hydrocarbons and sedimentary ore deposits. Little attention has been paid to the possible connection between fossil basinal brines and paleo-seawaters and to the implications for reconstructing paleo-seawater compositions. Secular variations of Ca/Mg and Ca/Sr ratios in seawater have been documented mainly using fluid inclusions in halite, calcareous fossils and mineral analyses. However, brines and other sedimentary records connected to paleo-seawater or its evaporated residues may be chemically affected by burial diagenesis or the effects of continental waters of meteoric origin, thus complicating interpretations of the analytical results. To investigate these effects on fluids and minerals related to the Messinian salinity crisis of the Mediterranean basin, we re-evaluate published data from: (1) brackish-to-brine waters from onshore (Northern Apennine foredeep; Levantine basin) and offshore (porewaters from the Deep Sea Drilling Project); (2) Messinian parental seawater deduced from calcareous fossils, fluid inclusions and sulfate minerals; (3) meteoric waters dissolving evaporites. The compositional trends related to seawater evaporation, diagenesis and mixing that affect the Ca/Mg and Ca/Sr molar ratios of the basinal brines are effectively discriminated on a binary plot depicting the proper fields for seawater and meteoric-derived fluids. Brines showing stronger dolomitization start from Ca/Mg and Ca/Sr molar ratios of Messinian seawater deduced from the published analysis of fluid inclusions and open ocean fossils, that are therefore here validated ex post.  相似文献   

13.
The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton(NCC) remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite(TiO_2 ~0.1 wt%) and serpentine(Mg#=92.42–96.55), as well as residual olivine(Fo=89–90), orthopyroxene(En=89–90) and hornblende. Magnetite in the iron ores shows lower Al, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine(Fo=83–87), orthopyroxene(En=82–86), humite(Mg#=82–84) and hornblende [XMg=0.87–0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite(Th-rich oxide) and monazite(LREE-rich phosphate) are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO_2(4.77–25.23 wt%), Fe_2O_3 T(32.9–80.39 wt%) and MgO(5.72–27.17 wt%) and uniformly, those of the wall rocks are also SiO_2(16.34–48.72 wt%), Mg O(16.71–33.97 wt%) and Fe_2O_3 T(6.98–30.92 wt%). The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of Al, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates(BIF) suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification.  相似文献   

14.
Whiteschists appear in numerous high- and ultrahigh-pressure rock suites and are characterized by the mineral assemblage kyanite + talc (+-quartz or coesite). We demonstrate that whiteschist mineral assemblages are well stable up to pressures of more than 4 GPa but may already form at pressures of 0.5 GPa. The formation of whiteschists largely depends on the composition of the protolith, which requires elevated contents of Al and Mg as well as low Fe, Ca, and Na contents, as otherwise chloritoid, amphibole, feldspar, or omphacite are formed instead of kyanite or talc. Furthermore, the stability field of the whiteschist mineral assemblage strongly depends on XCO2 and fO2: already at low values of XCO2, CO2 binds Mg to carbonates strongly reducing the whiteschist stability field, whereas high fO2 enlarges the stability field and stabilizes yoderite. Thus, the scarcity of whiteschist is not necessarily due to unusual P–T conditions, but to the restricted range of suitable protolith compositions and the spatial distribution of these protoliths: (1) continental sedimentary rocks and (2) hydrothermally and metasomatically altered felsic to mafic rocks. The continental sedimentary rocks that may produce whiteschist mineral assemblages typically have been deposited under arid climatic conditions in closed evaporitic basins and may be restricted to relatively low latitudes. These rocks often contain large amounts of the clay minerals palygorskite and sepiolite. Marine sediments generally do not yield whiteschist mineral assemblages as marine shales commonly have too high iron contents. Sabkha deposits may have too high CO2 contents. Protoliths of appropriate geochemical composition occur in and on continental crust. Therefore, whiteschist assemblages typically are only found in settings of continental collision or where continental fragments were involved in subduction. Our calculations demonstrate that whiteschists can form by closed-system metamorphism, which implies that the chemical and isotopic composition of these rocks provide constraints on the development of the protoliths.  相似文献   

15.
粘土矿物在安宁盆地含盐系中分布很广。其矿物学、结晶学及地球化学特征与成盐环境和成盐作用密切相关。石盐层序中主要含伊利石;硫酸盐层序中,除伊利石外尚有绿泥石及绿/蒙混层矿物。这是由于不同盐类沉积阶段,卤水浓度、成分及pH值不同所致。在结构上,粘土矿物以三八面体型组合为特征（伊利石除外）,反映了成盐盆地中相对富Mg2+的特点。此外,粘土矿物中硼和钾的含量远高于非盐系地层,因为这些元素在盐盆地中均得到了蒸发浓集。显然,粘土矿物的上述特征,很好地反映了蒸发环境的具体特点,具有良好的指相意义。  相似文献   

16.
《Applied Geochemistry》2004,19(9):1355-1365
Hydrogeochemical assessment of 40 saline waters and brines from 20 locations within the lower (southern) and middle regions of the Benue-Trough, Nigeria are presented and discussed in terms of genesis of the primary salinity and subsequent hydrochemical evolution. The total dissolved ions range from 5263 to 88,800 mg/L and 5148 to 47,145 mg/L in the lower and middle region, respectively.The saline waters and brines are characteristically Na–Cl type enriched in Ca and Sr on the one hand and depleted in Mg and SO4 on the other, relative to the seawater evaporation trend. Ionic ratios, Na–Cl–Br systematic and divalent cations suggest two likely sources of primary salinity: a fossil seawater source and dissolution of halite. However, water–rock interaction involving Mg uptake by clay minerals and possibly dolomitization during diagenesis appear to be responsible for further modification of the primary chemistry. A conceptualized hydrogeological/flow model for the brines is presented.  相似文献   

17.
Siderite (FeCO3) is a widespread minor diagenetic mineral in clastic sedimentary basins. Although eodiagenetic authigenesis of siderite is well-known, siderite formed during burial diagenesis shows habits and chemical compositions that are poorly understood. This study tests the hypothesis that diagenetic siderite cements in sandstones in the Scotian Basin, offshore eastern Canada, show systematic variability in chemistry and habit that is a response to recrystallization and changing composition of basinal fluids. Mineral textures were determined from backscattered electron images, and chemistry mostly from electron microprobe analyses. Five chemical types of siderite are identified using k-means cluster analysis, based on the amount of substitution of Ca, Mg and Mn for Fe. Eodiagenetic microcrystalline coated grains, concretions and intraclasts in sandstones are principally Fe-rich siderite and locally have recrystallised to blocky equant crystals. Mesodiagenetic Mg-rich siderite partly replaced these equant crystals and also framework mica and K-feldspar grains, showing textural evidence for coupled dissolution–reprecipitation. Slender Mg-rich siderite rhombs (lozenges, bladed or wheat-seed siderite) have precipitated before and after the formation of quartz overgrowths in geochemical microenvironments. Magnesium substitution reflects Mg-rich formation waters resulting from smectite to illite conversion. Equivalent Ca-rich siderite occurs where sandstones overlie a Jurassic carbonate bank. Late Mn-rich siderite has complex textures resembling those of Mississippi-Valley type ores, with spheroidal rims, a honeycomb-like mesh and concentric infill around secondary pores. It also occurs in veins or replacing intraclasts, post-dating late ferroan-calcite cements in sandstones that show strong dissolution by hot basinal brines. The Ca, Mg and Mn content of diagenetic siderite, coupled with textural evidence for recrystallization, can thus be used to track changes in ambient formation fluids. Siderite habits and chemistry described from the Scotian Basin are found in many clastic basins, suggesting that the observed recrystallization textures and variation in chemical type are of broad application.  相似文献   

18.
Ninety-seven mineral phases consisting of ten chloritoids, fifteen epidotes, sixteen garnets, four sphenes, seven rutiles, seven pyroxenes, thirteen blue amphiboles, two green amphiboles, eleven phengites, two paragonites, a mariposite, seven chlorites, and two specimens of albite were obtained from the metamorphic rocks of Île de Groix, and their chemical, physical, optical and X-ray properties determined. The chloritoids are all optically positive, monoclinic polymorphs with large 2V, moderate refractive indices and characterized by high densities. Their fluorine contents have been used to propose a new upper limit for OHF substitution in the chloritoid structure, suggesting that partial pressure of fluorine might modify the stability of chloritoids from that determined in pure H2O. The epidotes belong to the Al-Fe epidote series and are epidote sensu stricto. The almandine-rich garnets and the chloromelanites are metastable relics in the glaucophane schists. The grossular contents of the calcareous schist garnets are believed to have become depressed under high CO2 pressure and the low Tschermak's contents of the pyroxenes are to be explained by equilibria involving epidote at high and low temperature when the Tschermak's components will break down to epidote group minerals. The sphenes contain appreciable amounts of combined water, fluorine substituting for oxygen and aluminium substituting for silicon and titanium. The presence of H3O+ is suspected in a specimen of blue amphibole. The barroisite has a composition between glaucophane and hornblende. On account of its high Fe3+ content it is believed to have formed under higher P O 2 than the blue amphiboles. The paragonites which occur in the ohloritoid veins are unstable in the potassium-rich aluminous schists. The phengites show a tendency towards sericitic composition due to post-glaucophanisation readjustments under the lower pressure conditions of the greenschist facies. Some of the Fe3+ contents of the chlorites are interpreted as due to oxidation of ferrous iron, e.g. 2 [Fe(OH)2]2FeOOH + H2. The minerals show strong chemical control of the host rock and their Mn contents are directly related to those of the minerals from which they have evolved through retrogression.Chloritoids and epidotes that are not associated with garnets contain higher amounts of manganese; similarly, the two blue amphiboles with the highest FeMg ratios were obtained from rocks in which garnet has not appeared. It is therefore believed that ottrelite and piemontite would be stable only at the lowest subfacies of the greenschist facies. Also, the ironrich amphiboles must have evolved from low-grade iron-aluminium chlorites, since on the appearance of garnet in a schist iron-aluminium chlorites react with quartz to give almandine and Mg-rich chlorites. The Fe2+Mg ratios of the blue amphiboles therefore reflect the grade of the original schist in which the minerals formed.  相似文献   

19.
This paper attempts to illustrate the chemical variations of metamorphic hornblendes regarding host rocks and prograde variations. Changes related to bulk chemistry (orthoamphibolites) mainly concern Si, Al, Mg, Fetot and Ca. The Mg, Fe2+ and Fe3+ contents of hornblendes are, however, not strictly related to host rook compositions and Mg enrichments are correlated with increasing Fe3+ contents in the amphiboles. Thus, variations of oxygen fugacity may control the Mg contents of the Ca amphiboles studied but this does not show clear relations with the prograde metamorphism. The most sensitive but irregular variation related to the metamorphic conditions is the prograde enrichment of the alkalis into the A vacant position and an increase of the (Na+K)tot/Na+K+Ca ratios of the amphiboles. Increasing Ti and AlIV contents as well as decreasing AlVI concentrations are also, but much less evidently, related to increasing T and P. A variation trend from tschermakitic to edenitic hornblendes may be drawn using Shido's end members calculation; this tendency and the relative deficiency of AlVI contents in the low-grade members suggests that the amphiboles studied were subjected to conditions of a low-pressure metamorphism type. Such a conclusion is in agreement with the occurrence of andalusite-cordierite/sillimanite-cordierite associations in the metapelitic rocks, and the absence of Fe-rich garnet and epidote from the orthoamphibolites of the amphibolite facies at Aracena. Comparisons with Ca amphiboles from other metamorphic areas show, in agreement with various authors, that Abukuma hornblendes are similar to those encountered in high-grade thermal aureoles and tonalitic intrusives but different from the hornblendes of Barrovian metamorphism types.  相似文献   

20.
A Permo-Triassic pelite-carbonate rock series (with interacalated metabasitic rocks) in the Cordilleras Béticas, Spain, was metamorphosed during the Alpine metamorphism at high pressures (P min near 18 kbar). The rocks show well preserved sedimentary features of evaporites such as pseudomorphs of talc, of kyanite-phengitetalc-biotite, and of quartz after sulfate minerals, and relicts of baryte, anhydrite, NaCl, and KCl, indicating a salt-clay mixture of illite, chlorite, talc, and halite as the original rock. The evaporitic metapelites have a whole rock composition characterized by high Mg/(Mg+Ca) ratios>0.7, variable alkaline and Sr, Ba, contents, but are mostly K2O rich (<8.8 wt%). The F (<2600 ppm), Cl (<3600 ppm), and P2O5 (<0.24 wt%) contents are also high. The pelitic member of this series is a fine grained biotite rock. Kyanite-phengite-talc-biotite aggregates in pseudomorphs developed in the high pressure stage. Albite-rich plagioclase was formed when the rocks crossed the albite stability curve in the early stages of the uplift. Scapolite, rich in NaCl (Ca/(Ca+Na) mol% 24–40) and poor in SO4, with Cl/(Cl+CO3) ratios between 0.6 and 0.8, formed as porphyroblasts, sometimes replacing up to 60% of the rock in a late stage of metamorphism (between 10 and 5 kbar, near 600°C). No reaction with albite is observed, and the scapolite formed from biotite by: $$\begin{gathered} Al - biotite + CaCO_3 + NaCl + SiO_2 \hfill \\ = Al - poor biotite + scapolite + MgCO_3 + KCl \hfill \\ + MgCl_2 + H_2 O \hfill \\ \end{gathered}$$ Calculated fluid composition in equilibrium with scapolite indicates varying salt concentrations in the fluid. Distribution of Cl and F in biotite and apatite also indicates varying fluid compositions.  相似文献   

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