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1.
Repetitive patterns in the records of total organic carbon (TOC), total nitrogen (TN) and δ13Corg observed in the Lake Hovsgol sediment section from HDP-04 drill core reflect past changes in productivity of Lake Hovsgol and in the isotopic composition of the lake's carbon pool. Lake Hovsgol productivity proxy signals are interpreted to represent the response of the Hovsgol lacustrine system to glacial–interglacial cycles of the Pleistocene. This interpretation is supported by the apparent orbitally-forced pattern in the TOC, TN and δ13Corg records of the past 250 ka in the BDP-96-2 drill core from neighboring Lake Baikal.The intervals with independent age control, such as the radiocarbon-dated last glacial–interglacial transition and the paleomagnetic reversals, make it evident that productivity proxy signals are reliable indicators of past cold-to-warm and warm-to-cold climate transitions, as seen from the agreement with the pattern of global climate change in marine δ18O records. The Brunhes/Matuyama reversal during the MIS 19 interglacial coincides with a distinct peak of TOC and TN in the Hovsgol record, similar to the signal during the Holocene interglacial. By contrast, the upper Jaramillo reversal in the Lake Hovsgol record occurs in a diatom-free calcareous interval characterized by minima in TOC, TN and by a ‘glacial’-type range of δ13Corg values. In both Lake Baikal and Lake Hovsgol records, peaks in TOC and TN contents help distinguishing past interglacials and interstadials, and isotopically-heaviest δ13Corg values help identify past glacial intervals.An age model for the HDP-04 drill core section is proposed based on recognizing the repetitive patterns in Lake Hovsgol productivity and lithologic records as regional paleoclimate cycles of middle to late Pleistocene. Absolute dates and diatom biostratigraphic correlation ties to the Lake Baikal record are used as key controls. In the proposed age model, the interval 81–24 m in the HDP-04 sediment section below the major unconformity is correlated to MIS 27 through late MIS 13, whereas the upper 24 m of the HDP-04 section is suggested to have recovered the sedimentary record of late MIS 7 to MIS 1.  相似文献   

2.
Three sediment cores were taken from the Pearl River estuary and adjacent northern South China Sea (SCS). These sediment cores span the time interval 1900–2000 AD. The stratigraphy of the concentration, the ratio of total organic carbon (TOC) to total nitrogen (TN) and stable isotope (δ13Corg) of organic carbon (OC) from three high-resolution sediment cores were analyzed. The stratigraphic profiles of OC concentration, TOC/TN ratios and δ13Corg for the near past 100 yrs indicate that terrestrial organic matter decreases from 68.3% to 27.4% of the TOC in the Pearl River estuary, while Dapeng Bay (offshore east of Hong Kong) apparently had throughout little terrestrial organic matter input. The highest deposited OC occurs at the Humen River mouth and the OC concentrations are higher in the outer estuary than in the inner shelf of the northern SCS. The deposited OC at the River mouth increased with time, which could be caused by the high precipitation of land-derived organic matter and the high input of terrestrial organic matter, which is likely related to the rapid urbanization and industrial development in the Pearl River Delta since the 1970s. The OC concentrations did not exhibit an obvious increase with time in most areas of the Pear River estuary and adjacent inner shelf of the SCS, but the algal-derived OC concentration inferred from the δ13Corg values increased with time especially from 1980 to 2000 in the outer Pearl River estuary and Dapeng Bay. This increase is presumably caused by enhanced primary marine productivity supported by higher anthropogenic nutrient inputs.  相似文献   

3.
Lignin is preserved in the fine silt fraction of an arable Luvisol   总被引：1，自引：0，他引：1  
Knowledge about the fate of individual biomolecules during the decomposition process in soil is limited. We used the natural isotopic label introduced by 23 years of continuous maize cropping, together with compound specific 13C isotope analysis, to study lignin monomers in particle size fractions of a Luvisol. Isotope data indicated apparent decadal turnover times for lignin. A kinetic model suggests the existence of a fast and a slow decomposing lignin pool in the soil, reconciling a low stock-to-input ratio with decadal turnover times. We found new, maize-derived lignin primarily in the 63–2000 μm fraction, whereas old, C3-derived lignin from the pre-maize vegetation had accumulated mainly in the silt (2–20 μm) fraction. This distribution of lignin differed from that of total organic carbon, which was concentrated in the <2 μm fraction. Old, C3-derived carbon in all the soil fractions was depleted in lignin compared to new, maize-derived carbon. The observation that the 2–20 μm fraction was less depleted than the others indicates that lignin preservation is particle size specific, but the underlying mechanism controlling its preservation is not clear.  相似文献   

4.
A sediment core from the Pearl River Estuary (PRE) was analyzed for grain size and organic geochemistry parameters (TOC and δ13Corg). The results showed that high mean grain-size value and increased sand content were correlated with the high TOC and negative δ13Corg. These results indicated high river runoff in the PRE area. Peak river discharge occurred during the periods 1900–1750, 1500–1600, 1400–1200, 1000–900 and 750–600 cal yr BP. The main changes recorded in grain-size distributions, TOC contents, and δ13Corg variations appear to be directly related to monsoon precipitation in the sediment source area. An increased East Asian summer monsoon rainfall (EASM) and/or an enhanced East Asian winter monsoon rainfall could result in the increasing of monsoon rainfall. Typhoon related rainfalls could act as positive influence on precipitation levels. The study of the correlations between the rainfall records and ENSO activities revealed a close relationship between the monsoon rainfall in the PRE and the tropical Pacific variations. The frequent occurrence of ENSO might result in the southern migration of the EASM rain belt and lead to more typhoon-derived rainfall in the PRD during the late Holocene.  相似文献   

5.
Subaerial exposure and oxidation of organic carbon (Corg)-rich rocks is believed to be a key mechanism for the recycling of buried C and S back to Earth's surface. Importantly, processes coupled to microbial Corg oxidation are expected to shift new biomass δ13Corg composition towards more negative values relative to source. However, there is scarcity of information directly relating rock chemistry to oxidative weathering and shifting δ13Corg at the rock-atmosphere interface. This is particularly pertinent to the sulfidic, Corg-rich alum shale units of the Baltoscandian Basin believed to constitute a strong source of metal contaminants to the natural environment, following subaerial exposure and weathering. Consistent with independent support, we show that atmospheric oxidation of the sulfidic, Corg-rich alum shale sequence of the Cambrian-Devonian Baltoscandian Basin induces intense acid rock drainage at the expense of progressive oxidation of Fe sulfides. Sulfide oxidation takes priority over microbial organic matter decomposition, enabling quantitative massive erosion of Corg without producing a δ13C shift between acid rock drainage precipitates and shale. Moreover, 13C enrichment in inorganic carbon of precipitates does not support microbial Corg oxidation as the predominant mechanism of rock weathering upon exposure. Instead, a Δ34S = δ34Sshale − δ34Sprecipitates ≈ 0, accompanied by elevated S levels and the ubiquitous deposition of acid rock drainage sulfate minerals in deposited efflorescent precipitates relative to shales, provide strong evidence for quantitative mass oxidation of shale sulfide minerals as the source of acidity for chemical weathering. Slight δ15N depletion in the new surface precipitates relative to shale, coincides with dramatic loss of N from shales. Collectively, the results point to pyrite oxidation as a major driver of alum black shale weathering at the rock-atmosphere interface, indicating that quantitative mass release of Corg, N, S, and key metals to the environment is a response to intense sulfide oxidation. Consequently, large-scale acidic weathering of the sulfide-rich alum shale units is suggested to influence the fate and redistribution of the isotopes of C, N, and S from shale to the immediate environment.  相似文献   

6.
The chemical composition of organic matter (Corg, Norg, δ13C, δ15N, and n-alkanes) was studied in the top layer of bottom sediments of the East Siberian Sea. Possible ways were proposed to estimate the amount of the terrigenous component in their organic matter (OM). The fraction of terrigenous OM estimated by the combined use of genetic indicators varied from 15% in the eastern part of the sea, near the Long Strait, to 95% in the estuaries of the Indigirka and Kolyma rivers, averaging 62% over the sea area.  相似文献   

7.
We compared the degradation behaviour of amino sugars (ASs) and amino acids (AAs) during sedimentation in two lakes. Concentrations of individual ASs and AAs were measured in plankton, sediment trap and sediment samples from Lake Zug (LZ; eutrophic, stratified, permanently anoxic below 170 m) and Lake Brienz (LB; oligotrophic, oxic throughout the water column). In the plankton samples AAs comprised 37–50% of the organic carbon (Corg) and 41–65% of the N. With increasing water depth the fraction of Corg and N as AAs almost halved in both lakes. At the sediment surface the contribution of AAs to the Corg pool was slightly greater, but in the sediments the proportion further decreased downwards to values of 1% of the Corg pool in LB and 8% in LZ, and 3% and 17% of the N pool, respectively. ASs contributed to a smaller extent to the planktonic organic matter (OM). Within the water column, the contribution decreased in both lakes. In contrast, in the sediments the contribution of ASs to the Corg and N pools increased slightly with depth, indicating AS accumulation. We applied degradation indices based on ASs, AAs and chlorins, which all revealed transformation with OM sedimentation. However, some indices were more sensitive to early degradation (e.g. reactivity index) and others to an intermediate level of degradation (e.g. chlorin index and non-protein AAs). Despite the different trophic status and redox conditions, the general pattern of degradation was similar in both lakes, but was more pronounced in the sediments of the eutrophic LZ.  相似文献   

8.
The thermal maturity and organofacies sensitivity of polycyclic aromatic compound (PAC) distributions was explored by examination of the aromatic fractions of solvent extracts from a diverse set of 53 shales, coals and kerogen macerals which have undergone either natural or artificial maturation and which represent all three principal sedimentary organic matter (OM) types. Systematic changes with maturation were observed in the following groups of isomers: tri- and tetramethylnaphthalenes, methyl- and dimethylphenanthrenes, methyl- and dimethyldibenzothiophenes, methylpyrenes, and methylchrysenes. The maturity differences were quantified by mathematical ratios of the relative concentrations of the more thermally stable isomers to the less stable, on the basis of theoretical considerations and empirical observations. The PAC maturity parameters, unlike those derived from saturated biomarker stereoisomers, are typically effective across the entire oil generation window. To compensate for the effects of OM type on the maturity parameters, they were combined using principal components analysis. The resulting first principal component was in good agreement with independent indicators of maturity. The relative distributions of C0–C3 alkylphenanthrenes, dibenzothiophene, methyldibenzothiophenes and methyldibenzofurans were evaluated by a separate principal components analysis. The results permitted an independent grouping of the samples by OM type and suggested additional, simple molecular ratios that allow graphical recognition of OM type, including the ratio of dibenzothiophenes to dibenzofurans and a ratio using C2-alkylphenanthrene isomers.  相似文献   

9.
Ocean Drilling Program Leg 207 recovered thick sequences of Albian to Santonian organic-carbon-rich claystones at five drill-sites on the Demerara Rise in the western equatorial Atlantic Ocean. Dark-colored, finely laminated, Cenomanian–Santonian black shale sequences contain between 2% and 15% organic carbon and encompass Oceanic Anoxic Events 2 and 3. High Rock-Eval hydrogen indices signify that the bulk of the organic matter in these sequences is marine in origin. However, δ13Corg values lie mostly between −30‰ and −27‰, and TOC/TN ratios range from 15 to 42, which both mimic the source signatures of modern C3 land plants. The contradictions in organic matter source indicators provide important implications about the depositional conditions leading to the black shale accumulations. The low δ13Corg values, which are actually common in mid-Cretaceous marine organic matter, are consequences of the greenhouse climate prevailing at that time and an associated accelerated hydrologic cycle. The elevated C/N ratios, which are also typical of black shales, indicate depressed organic matter degradation associated with low-oxygen conditions in the water column that favored preservation of carbon-rich forms of marine organic matter over nitrogen-rich components. Underlying the laminated Cenomanian–Santonian sequences are homogeneous, dark-colored, lower to middle Albian siltstones that contain between 0.2% and 9% organic carbon. The organic matter in these rocks is mostly marine in origin, but it occasionally includes large proportions of land-derived material.  相似文献   

10.
The Nickel Plate deposit, in which gold occurs as <25 μm blebs associated with arsenopyrite in garnet-pyroxene skarns, is in the subalpine zone near the southern limit of the Thompson Plateau. During the last glaciation the Cordilleran ice sheet moved south-southwest across the deposit and deposited a stony basal till. A dispersion train with anomalous concentrations of gold in tills and soils now extends 2 km down ice from the deposit.Gold contents of samples of humus (LFH horizon) and the −212 μm fraction of mineral soils (A, B and C horizons) was determined by instrumental neutron activation and fire assay-atomic absorption, respectively. Selected samples were examined in detail to determine distribution of gold between different size and density fractions.Despite erratic variability, Au contents of the −212 μm fraction generally decrease from 200–400 ppb close to the mine site to <50 ppb at distal sites. At most sites there is also a twofold increase of gold values down the soil profile. Within samples concentrations of Au in the −420 + 212 μm, −212 + 106 μm, −106 + 53 μm and −53 μm fractions are usually roughly constant. However, because of its abundance, the −53 μm fraction contains more than 70% of the gold. Amenability of gold in this fraction to cyanidation suggests that it is largely free gold. For size fractions > 53 μm the contribution of the heavy mineral (SG > 3.3) fraction to total gold content increases with decreasing grain size.Distribution of gold between size and density fractions is consistent with its release from the bedrock or pre-glacial regolith by glacial abrasion. The bulk of the gold was incorporated into the fine fractions of the till at or close to the source. However, differences between down ice dilution ratios for gold in different heavy mineral size fractions suggest that comminution of host minerals continued to transfer gold to the finer size fractions during glacial transport.For exploration purposes, B and C horizon samples provide the best anomaly contrast. Estimates of the abundance of gold particles in different size fractions indicate that the nugget effect, which causes erratic gold values in the −212 μm fraction, can be avoided by analysis of 30 g of −53 μm material.  相似文献   

11.
Two sediment cores of up to 550 cm length from an intertidal flat of the German Wadden Sea near the island of Spiekeroog were investigated for the quantity and composition of fossil organic matter (OM). The lowermost parts of the cores are dominated by grey mud of a salt marsh facies containing mainly terrestrial OM estimated to account for 60–75% of the total OM, based on δ13C values and the ratio of short to long chain n-alkanols. The terrigenous origin of the dominant fraction is indicated, among others, by high proportions of C29 sterols and long chain n-alkanes typical of plant waxes. Coarse shell beds overlying the grey mud at 2–2.5 m depth represent a flooding and erosion event possibly related to heavy storm floods in the Middle Ages. Within the intertidal sand-dominated sediments in the upper parts of the cores total organic carbon (TOC) contents are generally low, ranging from 0.1% to 0.5%, and correlate well with the amount of mud fraction (r2 0.90). At the surface, marine OM has not undergone intense diagenetic alteration and so is the dominant fraction. Eroded peat particles are common throughout most of the sequence and values of the Phragmites peat indicator (PPI) > 5 indicate an origin from reed peat due to a high relative abundance of the n-C24 alkane. Changes in the composition of microbial communities over the depth interval investigated are documented by varying compositions of unsaturated fatty acids with 16 and 18 carbons. Eicosapentaenoic acid (EPA) was detected along the entire cores and indicates the presence of EPA-producing bacterial strains.  相似文献   

12.
The organic matter of recent deltaic sediments cored in the Mahakam delta, East Kalimantan, has been studied before and after physical fractionation into sands >50 μm, silts 5–50 μm and clays <5 μm. Both the lipid and non-lipid components have been investigated.Weight, carbon and nitrogen fractionation budgets were used to define three types of samples, depending on coarse particle contributions to the total amount of organic matter: a = a first type with more than 50% of the O.M. in the coarse particles, high C/N ratios and O.M. content, b = an intermediary type with medium C/N ratios and O.M. content, each fraction having quite the same O.M. content, c = a third type with less than 5% of the whole O.M. in the sands and the lowest C/N ratios and O.M. content.Concerning the global organic characteristics of the fractions, a systematic increase of C/N ratios occurs when going from clays to sands; the finer the fraction is, the more nitrogenous the compounds are. This enrichment in nitrogen is related to a persistent high rate of hydrolysable material either for argillaceous organic matter-poor sediments or for the clay fractions of all types of samples. Conversely, the type (a) coarse sediments, in particular the sandy components were resistant to acid hydrolysis with burial.Concerning the geochemical markers signatures of granulometric fractions, the distribution patterns of n-alkanes and n-fatty acids are characterized by the predominance of high molecular weight compounds >C22. Carbon preference index (CPI) values are higher in the sands and silts, reflecting their enrichment in continentally-derived vegetation debris. For type (c), the fractionation revealed markers of microbial activity within the clay fractions. For all types of samples, we observed an increase with burial of the n-alkane and n-fatty acid concentrations, particularly in the clay fractions, suggesting possibly a better preservation and/or affinity of lipids with the finest fractions.  相似文献   

13.
By combining the carbon cycle model with the records of carbonate and organic (kerogen) carbon isotope, this paper presents the calculation of the fraction of organic carbon burial (f org) of beds 23–40 at the global boundary stratotype section and point (GSSP) of the Permian-Triassic boundary at Meishan, Zhejiang Province. The resulting calculation produces two episodes of f org maxima observed to occur at beds 23–24 and 27–29, which respectively corresponds to the two episodic anoxic events indicated by the flourish of green sulfur bacteria. Two episodic f org minima occurred at beds 25–26 and 32–34, generally coincident with the flourish of cyanobacteria (bed 26 and upper part of beds 29 to 34) as shown by the high value of 2-melthyhopnoanes. It appears that the f org is related to the redox conditions, with greater f org values observed under the reductive condition. The relationship between f org and the total organic carbon (TOC) content was complex. The f org value was low at some beds with a high TOC content (such as bed 26), while high observed at some beds with a low TOC content (e.g. bed 27). This association infers the important contribution of primary productivity to the TOC content. The original organic burial could be thus calculated through the configuration of the function of the primary productivity and f org, which can be used to correct the residual TOC measured today. This investigation indicates that compiling the organic-inorganic carbon isotopes with the carbon cycle model favors to understand the fraction of organic carbon burial, providing information for the reconstruction of the coupling among biota, environments and organic burial. Journal of China University of Geosciences, 2007, 32(6): 767–773 [译自: 地球科学—中国地质大学学报]  相似文献   

14.
The chemical structure, source(s), and formation pathway(s) of kerogen-like organic matter (KL) were investigated in recent sediments from the northwestern Black Sea, off the Danube delta. Three sections from a sediment core collected at the mouth of the Sulina branch of the delta, under an oxic water column, were examined: S0 (0–0.5 cm bsf), S10 (10–13 cm bsf), and S20 (20–25 cm bsf). The bulk geochemical features of these sediments (total organic carbon, organic C/N atomic ratio, δ13Corg) were determined. Thereafter, KL was isolated from the samples, as the insoluble residue obtained after HF/HCl treatment. KL chemical composition was investigated via spectroscopic (FTIR, solid state 13C and 15N NMR) and pyrolytic (Curie point pyrolysis–gas chromatography–mass spectrometry) methods, and the morphological features were examined by scanning and transmission electron microscopy. Similar morphological features and chemical composition were observed for the three KLs and they suggested that the selective preservation of land-plant derived material as well as of resistant aliphatic biomacromolecules (probably derived from cell walls of freshwater microalgae) was the main process involved in KL formation. Besides, some melanoidin-type macromolecules (formed via the degradation-recondensation of products mainly derived from proteinaceous material) and/or some encapsulated proteins also contributed to the KL chemical structure.  相似文献   

15.
In this study, organic matter content, type and maturity as well as some petrographic and physical characteristics of the Jurassic coals exposed in the eastern Taurus were investigated and their depositional environments were interpreted.The total organic carbon (TOC) contents of coals in the Feke–Akkaya, Kozan–Gedikli and Kozan–Kizilinc areas are 24.54, 66.78 and 49.15%, respectively. The Feke–Akkaya and Kozan–Kizilinc coals have low Hydrogen Index (HI) values while the Kozan–Gedikli coals show moderate HI values. All coal samples display very low Oxygen Index (OI) values. The Kozan–Gedikli coals contain Type II organic matter (OM), the Feke–Akkaya coals contain a mixture of type II and type III OM; and the Kozan–Kizilinc coals are composed of Type III OM. Sterane distribution was calculated as C27 > C29 > C28 from the m/z 217 mass chromatogram for all coal samples.Tmax values for the Feke–Akkaya, Kozan–Gedikli and Kozan–Kizilinc coals are 439, 412 and 427 °C. Vitrinite reflectance values (%Ro) for the Feke–Akkaya and Kozan–Kizilinc coal samples were measured as 0.65 and 0.51 and these values reveal that the Feke–Akkaya and Kozan–Kizilinc coals are at subbituminous A or high volatile C bituminous coal stage. On the basis of biomarker maturity parameters, these coals have a low maturity.The pristane/phytane (Pr/Ph) ratios for the Feke–Akkaya, Kozan–Gedikli and Kozan–Kizilinc coals are 1.53, 1.13 and 1.25, respectively. In addition, all coals show a homohopane distribution which is dominated by low carbon numbers, and C35 homohopane index is very low for all coal samples. All these features may indicate that these coals were deposited in a suboxic environment.The high sterane/hopane ratios with high concentrations of steranes, low Pr/Ph ratios and C25/C26 tricyclic ratios > 1 may indicate that these coals formed in a swamp environment were temporarily influenced by marine conditions.  相似文献   

16.
The Sylhet Basin of Bangladesh is a sub-basin of the Bengal Basin. It contains a very thick (up to 22 km) Tertiary stratigraphic succession consisting mainly of sandstones and mudstones. The Sylhet succession is divided into the Jaintia (Paleocene–late Eocene), Barail (late Eocene–early Miocene), Surma (middle–late Miocene), Tipam (late Miocene–Pliocene) and Dupitila Groups (Pliocene–Pleistocene), in ascending order. The origin of the organic matter (OM) and paleoenvironment of deposition have been evaluated on the basis of C, N, S elemental analysis, Rock-Eval pyrolysis and gas chromatography–mass spectrometry (GC–MS) analysis of 60 mudstone samples collected from drill core and surface outcrops. Total organic carbon (TOC) content ranges from 0.11% to 1.56%. Sulfur content is low in most samples. TOC content in the Sylhet succession varies systematically with sedimentation rate, with low TOC caused by clastic dilution produced by high sedimentation rates arising from rapid uplift and erosion of the Himalaya.The OM in the succession is characterized by systematic variations in pristane/phytane (Pr/Ph), oleanane/C30 hopane, n-C29/n-C19 alkane, Tm/Ts [17α(H)-22,29,30-trisnorhopane/18α(H)-22,29,30-trisnorhopane] and sterane C29/(C27 + C28 + C29) ratios during the middle Eocene to Pleistocene. Based on biomarker proxies, the depositional environment of the Sylhet succession can be divided into three phases. In the first (middle Eocene to early Miocene), deposition occurred completely in seawater-dominated oxic conditions, with abundant input of terrestrial higher plants, including angiosperms. The second phase (middle to late Miocene) consisted of mainly freshwater anoxic conditions along with a small seawater influence according to eustasic sea level change, with diluted OM derived from phytoplankton and a lesser influence from terrestrial higher plants. Oxygen-poor freshwater conditions prevailed in the third phase (post-late Miocene). Planktonic OM was relatively abundant in this stage, while a high angiosperm influx prevailed at times. Tmax values of ca. 450 °C, vitrinite reflectance (Ro) of ca. 0.66% and methylphenanthrene index (MPI 3) of ca. 1 indicate the OM to be mature. The lower part (middle Eocene to early Miocene) of the succession with moderate TOC content and predominantly terrestrial OM could have generated some condensates and oils in and around the study area.  相似文献   

17.
We studied the distribution of organic carbon in rocks of the Bazhenov horizon, a unique object of predominantly biogenic sedimentation in the West Siberian sedimentary basin. The contents of organic carbon in the rocks were determined using the data from 4094 core analyses and core-log relationships derived from 48,500 radioactive- and electrical-log measurements. For the Bazhenov and Tutleima Formations, both approaches gave the same results. The average content of organic carbon in the rocks is 7.7%. These data were used to compile a detailed map of the distribution of organic carbon contents in sedimentary rocks of the basin. It was shown that the average organic carbon content in the rocks increases from 2-4% on the periphery of the basin to 10-12% in its central, deepest part. The distribution of Corg values in the basin is highly asymmetric. The highest Corg values are observed in the southwestern part of the basin interior, where beds with > 10% Corg range in thickness from 5 to 12-15 m. In sections, the highest Corg values are observed in their middle and upper parts, composed predominantly of silicites and mixtites enriched in biogenic silica.  相似文献   

18.
The Mapocho river, which crosses downtown Santiago, is one of the most important rivers in contact with a population of about six million inhabitants. Anthropogenic activities, industrialization, farming activities, transport, urbanization, animal and human excretions, domestic wastes and copper mining have affected the river, contaminating it and its sediments with heavy metals. Concentration and distribution of Cu, Zn, Pb and Cd were studied with the purpose of determining their bioavailability and their relation with the characteristics of the sediments. Freshly deposited seasonal sediments were collected from 0–8 cm depths from 6 locations (S1 to S6) along the 30-km long channel length, in the four seasons of year on the following dates: May 2001 (D1, autumn); August 2001 (D2, winter); October 2001 (D3, spring) and January 2002 (D4, summer). The dried samples were sifted to obtain the < 63-μm sediment fraction, since it has been shown that large amounts of heavy metals are bound in the fine-grained fraction of the sediment. Cu and Zn were analyzed by atomic absorption spectrophotometry and Pb and Cd by square wave anodic stripping voltammetry. The highest concentrations of Cu (2850 μg g− 1) were found in the northern part of the river (S1, average D1–D4), near the mountains and a copper mine, and then decreased downstream to 209 μg g− 1 (S6). Total Zn showed an irregular variation, with higher values at S1 (1290 μg g− 1) and high values in some winter sampling (1384 μg g− 1 S4, S5–D2). Pb showed different trends, increasing from S1 to S6 (17 to 61 μg g− 1), with the highest values in the summer samples (83 μg g− 1, S4–S6, D4), and total Cd increased slightly from mean values of 0.2 and 0.5 μg g− 1. Partition into five fractions was made using Tessier's analytical sequential extraction technique; the residue was treated with aqua regia for recovery studies, although this step is not part of the Tessier procedure. The results show that Cu, Zn and Pb in the sediments were dependent on the sampling places along the river, and variation in two years was low (D1–D4). The highest values of total organic matter, carbonate and conductivity were found in S6, which has the smallest size particles, while at S1 the sediments were predominantly sand and contain larger amounts of silica. Cu associated with carbonate decreased gradually from 58% (1771 μg g− 1, S1) to 16% (32 μg g− 1, S6); Cu bonded to reducible fraction was almost constant (33% to 37%), and Cu associated with oxidizable fraction increased from 7% (S1) to 34% (S6), but copper content was lower (214 to 68 μg g− 1). Zn had a similar fractionation profile. However, Pb bound to oxidizable fraction did not show significant percent variation along the river (20% to 19%), but the amount bounded was 4 to 12 μg g− 1. The residual fraction increased from 24% to 41% (5 to 25 μg g− 1, S1 to S6). The distribution of Cd in the sediment was almost independent of the sampling stations and was bound to carbonate, reducible and residual fraction in similar proportion. Cu and Zn at S1 were mainly bound to carbonates and reducible phases with 91% and 73% (2779 and 965 μg g− 1, respectively), and with a change in the pH and/or the redox potential of the sediment–water system, these contaminants could easily enter the food chain. In S6 the amount of Cu and Zn in these phases was 50% and 53% (100 to 313 μg g− 1, respectively).  相似文献   

19.
Gold anomalies in drainage sediments are often erratic, reflecting both the nugget effect and hydraulic effects whereby gold is concentrated at favorable sites along a stream. This study investigates these factors in a stream in northeastern Thailand.Bulk sediment samples, consisting of approximately 40 kg of −12 mm material, were collected from bar and pavement sites along an 8 km study reach. Samples were wet sieved into eight size fractions. The five fractions between 425 μm and 53 μm were then processed to obtain heavy mineral concentrates (SG > 3.3). Gold content of all size and density fractions finer than 425 μm was determined by fire assay-atomic absorption.Concentrations of Au in the heavy mineral concentrates typically range from 10,000 to 50,000 ppb (maximum 198,000 ppb), whereas the corresponding light mineral fractions and the −53 μm fraction generally contain <5 ppb gold. Within the heavy mineral fractions concentrations of Au generally increase downstream away from their supposed source and are higher at pavement than at point bar sites. Variations in abundance of gold between point bar sites can be related to stream characteristics (such as width, velocity and bed roughness) that are indicative of changing energy conditions and of the ability of the stream to winnow light minerals from its bed.The estimated median number of gold particles in the heavy mineral concentrates increase from less than one in the 212–425 μm fraction to about three in the 53–106 μm size range. However, because of dilution by the light mineral and −53 μm fractions, the probability of a 30 g analytical sub-sample containing a particle of gold is so low that in thirteen out of sixteen −149 μm sediment samples no gold was detected. Insofar as this results from dilution by large quantities of −53 μm sediment, failure of conventional sieved sediment samples to reliably detect the anomaly is probably a consequence of increased erosion caused by deforestation and land usage.Heavy mineral concentrates from pavement and other high energy sites are more reliable than conventional sediment samples for detecting gold anomalies of the Huai Hin Laep type. A low sample density is adequate but, because anomaly contrast may increase downstream, careful interpretation is required.  相似文献   

20.
Structures and carbon isotopic compositions of biomarkers and kerogen pyrolysis products of a dolomite, a bituminous shale and an oil shale of the Kimmeridge Clay Formation (KCF) in Dorset were studied in order to gain insight into (i) the type and extent of water column anoxia and (ii) changes in the concentration and isotopic composition of dissolved inorganic carbon (DIC) in the palaeowater column. The samples studied fit into the curve of increasing δ13C of the kerogen (δ13CTOC) with increasing TOC, reported by Huc et al. (1992). Their hypothesis, that the positive correlation between TOC and δ13CTOC is the result of differing degrees of organic matter (OM) mineralisation in the water column, was tested by measuring the δ13C values of primary production markers. These δ13C values were found to differ on average by only 1‰ among the samples, implying that differences in the extent of OM mineralisation cannot fully account for the 3‰ difference in δ13CTOC. The extractable OM in the oil shale differs from that in the other sediments due to both differences in maturity, and differences in the planktonic community. These differences, however, are not likely to have significantly influenced δ13CTOC either. All three sediments contain abundant derivatives of isorenieratene, indicating that periodically euxinia was extending into the photic zone. The sediments are rich in organic sulfur, as revealed by the abundant sulfur compounds in the pyrolysates. The prominence of C1-C3 alkylated thiophenes over n-alkanes and n-alkenes is most pronounced in the pyrolysate of the sediment richest in TOC. This suggests that sulfurisation of OM may have played an important role in determining the TOC-δ13CTOC relationship reported by Huc et al. (1992).  相似文献   

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