共查询到20条相似文献，搜索用时 734 毫秒
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We studied the particle growth in a protoplanetary disk in a high-ionization environment and found that icy planet formation is inactive for a disk with an ionization rate 100 times higher than that of the present Solar System. In particular, in the case of M 10~(-7.4)M_☉yr~(-1), only rocky planet formation occurs. In such a case, all the solid materials in the disk drift inward, eventually reach the inner MRI front,and accumulate there. They form a dense, thin sub-disk of solid particles, which undergoes gravitational instability to form rocky planetesimals. The planetesimals rapidly grow into a planet through pebble accretion. Consequently, rocky planets tend to be much larger than planets formed through other regimes(tandem planet formation regime and dispersed planet formation regime), in which icy planet formation actively takes place. These rocky planets may evolve into hot Jupiters if they grow fast enough to the critical core mass of the runaway gas accretion before the dispersal of the disk gas, or they may evolve into super-Earths if the gas dispersed sufficiently early. 相似文献
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Previous paleoenvironmental studies reported the δD values of a mixture of coeluting alkenones. Here, we present a semi-preparative normal-phase high-performance liquid chromatography–mass spectrometry (NP-HPLC–MS) method for purifying long chain (C37 and C38) unsaturated methyl and ethyl ketones (alkenones) on the basis of chain length and degree of unsaturation.The method was applied to purify alkenones in suspended particles and surface sediments from a site in Chesapeake Bay, eastern USA. The hydrogen isotopic composition of di- and triunsaturated C37 and C38 alkenones differed significantly on the basis of chain length and the degree of unsaturation, demonstrating the importance of gas chromatography–isotope ratio-mass spectrometry (GC–irMS) analysis of individual alkenones for accurate paleoenvironmental reconstruction. Constant fractionation factors between alkenones with different chain length but the same degree of unsaturation () and those with the same chain length but different degree of unsaturation () in all samples suggest that the values may represent hydrogen isotope fractionation associated with elongation and desaturation during alkenone biosynthesis. 相似文献
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Frédéric Béjina Misha Bystricky Nicolas Tercé Matthew L. Whitaker Haiyan Chen 《Comptes Rendus Geoscience》2019,351(2-3):86-94
In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (KT0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: GPa, GPa, GPa and GPa. These values combined with data available in the literature show that the KT0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend. 相似文献
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Fabrice Fraysse Oleg S. Pokrovsky Jacques Schott Jean-Dominique Meunier 《Chemical Geology》2009,258(3-4):197-206
In order to better understand the reactivity of plant phytoliths in soil solutions, we determined the solubility, surface properties (electrophoretic mobilities and surface charge) and dissolution kinetics of phytoliths extracted from fresh biomass of representative plant species (larch tree and elm, horsetail, fern, and four grasses) containing significant amount of biogenic silica. The solubility product of larch, horsetail, elm and fern phytoliths is close to that of amorphous silica and soil bamboo phytoliths. Electrophoretic measurements yield isoelectric point pHIEP = 0.9, 1.1, 2.0 and 2.2 for four grasses, elm, larch and horsetail phytoliths respectively, which is very close to that of quartz or amorphous silica. Surface acid–base titrations allowed generation of a 2-pK surface complexation model (SCM) for larch, elm and horsetail phytoliths. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 1 ≤ pH ≤ 8, were found to be very similar among the species, and close to those of soil bamboo phytoliths. Mechanistic treatment of all plant phytoliths dissolution rates provided three-parameters equation sufficient to describe phytoliths reactivity in aqueous solutions:Alternatively, the dissolution rate dependence on pH can be modeled within the concept of surface coordination theory assuming the rate proportional to concentration of > SiOH2+, > SiOH0 and > SiO? species. In the range of Al concentration from 20 to 5000 ppm in the phytoliths, we have not observed any correlation between their Al content and solubility, surface acid–base properties and dissolution kinetics.It follows from the results of this study that phytoliths dissolution rates exhibit a minimum at pH ～ 3. Mass-normalized dissolution rates are similar among all four types of plant species studied and these rates are an order of magnitude higher than those of typical soil clay minerals. The minimal half life time of larch and horsetail phytoliths in the interstitial soil solution ranges from 10–12 years at pH = 2–3 to < 1 year at pH above 6, comparable with mean residence time of phytoliths in soil from natural observations. 相似文献
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《Applied Geochemistry》2006,21(6):887-903
The chemical compositions of the surface/ground water of Guiyang, the capital city of Guizhou Province, China are dominated by Ca2+, Mg2+, , which have been derived largely from chemical weathering of carbonate rocks (limestone and dolomite). The production of has multiple origins, mainly from dissolution of sulfate evaporites, oxidation of sulfide minerals and organic S in the strata, and anthropogenic sources. Most ground water is exposed to soil CO2 and, therefore, the H2CO3 which attacks minerals contains much soil C. In addition, the H2SO4 produced as a result of the oxidation of sulfides in S-rich coal seams and/or organic S, is believed to be associated with the chemical weathering of rocks. The major anthropogenic components in the surface and ground water include K+, Na+, Cl−, , with Cl− and being the main contributors to ground water pollution in Guiyang and its adjacent areas. The seasonal variations in concentrations of anthropogenic components demonstrate that the karst ground water system is liable to pollution by human activities. The higher content of in ground water compared to surface water during the summer and winter seasons, indicates that the karstic ground water system is not capable of denitrification and therefore does not easily recover once contaminated with nitrates. 相似文献
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《Applied Geochemistry》2006,21(4):632-642
Acid volatile sulfide (AVS) is an operationally defined sulfide fraction, which is considered important for trace metal fate in reduced sediments. Understanding AVS formation rates is important for the management of metal polluted sediment. However, little is known about the fate and dynamics of AVS in spatially and seasonally variable freshwater environments. The authors monitored in situ AVS formation and degradation and simultaneously extracted metals (SEM) in two floodplain lakes and compared this to AVS formation rates in laboratory experiments with the same sediment. In the laboratory experiments, the formation rates of AVS were studied at 20 °C for initially oxidized sediments that were: (a) untreated; (b) enriched with extra ; and (c) treated with sodium-azide (biocide). In the field, AVS concentrations were highly variable and were significantly correlated to surface water temperature and O2 concentrations as well as to sediment composition. Between February and August, AVS formation was approximately linear at a rate of 0.07 μmol g−1 d−1. Degradation rates differed drastically between the lakes due to different degradation mechanisms. In one lake AVS removal was caused by reworking and oxygenation of the sediments by bream (Abrami brama), at a rate of 0.25 μmol g−1 d−1. In the other lake AVS removal was caused by desiccation, at a rate of ±2.6 μmol g−1 d−1. This illustrates the large differences that can be found between similar lakes, and the importance of biological processes. In the laboratory, concentrations of AVS with and without addition were similar during the first weeks, and increased at a rate of 0.15 μmol g−1 d−1. However, addition increased the AVS concentration at the end of the experiment, whereas sodium-azide eliminated AVS formation, as expected. This suggests that AVS formation was -limited in the laboratory as well as in these shallow freshwater lakes. 相似文献