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1.
Results are given in the petrography of Greek coals collected from most of the major coal-bearing basins in Greece.Rank was determined by measuring reflectances on the maceral varieties eu-ulminite A and eu-ulminite B and on the maceral textinite. Reflectances obtained from these components indicate a coalification stage of brown coal for all samples. Within this group of samples there is, however, a fairly wide scatter of reflectance values indicating for some of them the transition zone from peat to brown coal and for others a coalification stage close to the transition into bituminous coals. Reflectances obtained from eu-ulminite A and eu-ulminite B were found to correlate well with chemical rank parameters such as volatile matter and calorific value.Composition was determined by maceral analysis. The coals are in general characterized by low amounts of macerals of the inertinite group, low to intermediate amounts of macerals of the liptinite group and high amounts of macerals of the huminite group. Within the latter group densinite, attrinite, eu-ulminite and textinite make up the bulk of the samples.Typical macerals observed in the coals are illustrated by two black and white and three colour plates.Cluster analysis based on maceral distribution, mineral matter and reflectance indicates that the samples studied can be divided into three major groups. The first one is dominated by eu-ulminite and densinite with relatively high reflectances. The second is dominated by attrinite, textinite and texto-ulminite with somewhat lower reflectances. The third is represented by a single sample in which textinite and resinite are the most abundant macerals. This sample also has the lowest reflectance.  相似文献   

2.
The variability in reflectance of huminite (texto-ulminite, eu-ulminite A and B, different types of corpohuminite) and liptinite groups of macerals in subbituminous coals was examined using reflected light microscopy. All macerals were selected from coal and interbedded carbonaceous shale and carbonate sediment samples from the 515-m-thick coal deposit No. 2 located in the Hat Creek valley of south-central British Columbia. The measurements obtained reveal that, in addition to burial depth, reflectance distribution depends on maceral subtypes and associated mineral matrix.Huminite in the coals and sediments (kerogen) consists mainly of humotelinite, with eu-ulminite B being the dominant maceral sub-type. Reflectance values determined on huminite in coals and Type IIIb kerogen increase from eu-ulminite A and phlobaphinite type 1 through eu-ulminite B and phlobaphinite type 2 to gelinite. The reflectance of all five huminite maceral subtypes studied increases with depth. However, the increase of phlobaphinite type 1 and gelinite reflectance with depth is irregular.A comparison of the reflectance values obtained for the same maceral subtype (eu-ulminite B) from the interbedded coal, shale and carbonate samples records consistent differences, implying some dependence of the reflectance (and perhaps rate of organic maturation) on the mineral matrix. Generally, the highest eu-ulminite B reflectance was recorded from carbonate rocks and the lowest from shale, whereas coal matrix produced intermediate values.At present, it is not known whether differences in reflectance of eu-ulminite found in the above lithologies are due to differential retention, efficiency of reaction products removal, thermal conductivity of the lithologies, or existence of a calcium carbonate catalyst.  相似文献   

3.
The mercury and maceral content of subbituminous feed coals burned at six Canadian power plants was measured and compared to the mercury and carbon content of corresponding fly ashes. The fly ashes were collected from electrostatic precipitator (ESP) pollution controls used at the power plants. Four feed coals from the Upper Cretaceous to Tertiary age Scollard Formation were deposited in freshwater depositional environment and contain 35–44% inertinite. Two feed coals from the Upper Cretaceous age Horseshoe Canyon Formation were deposited in a brackish water environment and contain 14% inertinite.The data show that abundant inertinite equates to more unburned carbon in ESP fly ash, and to enhanced capture of mercury in cold-side ESP fly ash. This indicates that the inertinite content of a coal seam may be indicative of the percentage of unburned carbon and the percentage of mercury captured by a cold-side ESP.  相似文献   

4.
通过对蔚县煤田下花园组煤中植物残体——分散角质层、半丝炭化木材等研究,结合非煤层中植物化石和孢粉组合特征分析,认为泥炭沼泽植物群落主要由松柏类、银杏类、苏铁类和蕨类组成,它们都是本区成煤的重要物质来源。这种森林体系代表了一种温暖潮湿、雨量充沛的古气候条件。煤中丝炭及半丝炭化组分含量丰富是泥炭堆积速度快于盆地基底沉降速度,并最终导致泥炭沼泽覆水浅,泥炭层多处于相对干燥、氧化环境的表现。不同煤层中丝炭及半丝炭化组分含量的差异,为煤层对比提供了新的依据。  相似文献   

5.
The coal-bearing sediments and coal seams of the Karoo Basin, Southern Africa are described and discussed. The Karoo Basin is bounded on its southern margin by the Cape Fold Belt, onlaps onto the Kaapvaal Craton in the north and is classified as a foreland basin. Coal seams are present within the Early Permian Vryheid Formation and the Triassic Molteno Formation.The peats of the Vryheid Formation accumulated within swamps in a cool temperate climatic regime. Lower and upper delta plain, back-barrier and fluvial environments were associated with peat formation. Thick, laterally extensive coal seams have preferentially accumulated in fluvial environments. The coals are in general inertinite-rich and high in ash. However, increasing vitrinite and decreasing ash contents within seams occur from west to east across the coalfields. The Triassic Molteno coal seams accumulated with aerially restricted swamps in fluvial environments. These Molteno coals are thin, laterally impersistent, vitrinite-rich and shaly, and formed under a warm temperate climatic regime.Palaeoclimate, depositional systems, differential subsidence and basin tectonics influence to varying degrees, the maceral content, thickness and lateral extent of coal seams. However, the geographic position of peat-forming swamps within a foreland basin, coupled with basin tectonics and differential subsidence are envisaged as the primary controls on coal parameters. The Permian coals are situated in proximal positions on the passive margin of the foreland basin. Here, subsidence was limited which enhanced oxidation of organic matter and hence the formation of inertinitic coals. The coals in this tectonic setting are thick and laterally extensive. The Triassci coals are situated within the tectonically active foreland basin margin. Rapid subsidence and sedimentation rates occurred during peat formation which resulted in the preservation of thin, laterally impersistent, high ash, vitrinite-rich, shaly coals.  相似文献   

6.
Most types of coal in Turkey are generally low in rank: lignite, and subbituminous. Most of the coal was formed during the Miocene, Eocene, and Pliocene ages. There are only a few thin Jurassic-age coal occurrences in Turkey. Pennsylvanian age bituminous coal is found on the Black Sea coast. General implications of the petrographic properties of Turkey's coal seams and coal deposits have not yet been taken into consideration comparatively or as a whole.For this study, about 190 channel samples were collected from different locales. The composite profile samples of the seams were taken into considerations. The content and depositional properties as well as some chemical and physical properties of the main coal seams are compared. All coal samples tend to have similar coal petrographic properties and were deposited in intermontane lacustrine basins. Later, they were affected by faulting and post-depositional volcanic activity. As a result, there are variations in the properties and rank of the coal samples. The most abundant coal maceral group is huminite and the most abundant maceral is gelinite. The liptinite and inertinite contents of the coal are low and the maceral contents of the coals show great similarity. The depositional environments of the all coals are lacustrine dominated.  相似文献   

7.
不同沉积环境成因煤显微组分的有机硫分布   总被引:2,自引:1,他引:2  
运用扫描电镜能谱微区测试对不同沉积环境成因煤的有机显微组分进行有机硫含量的系统测定,结果表明在不同类型的煤中某一类显微组分的有机硫含量存在明显差异;同一煤中不同亚显微组分的有机硫含量也不同。综合分析发现煤显微组分有机硫含量主要受聚煤环境、组分凝胶化程度、氧化程度的影响,而聚煤环境为主导影响因素。  相似文献   

8.
The Bolsovian (Middle Pennsylvanian) Peach Orchard coal bed is one of the splint coals of the Central Appalachians. Splint coal is a name for the dull, inertinite-rich lithologies typical of coals of the region. The No. 3 Split was sampled at five locations in Magoffin County, Kentucky and analyzed for petrography and major and minor elements. The No. 3 Split coals contain semifusinite-rich lithologies, up to 48% (mineral-free basis) in one case. The nature of the semifusinite varies with position in the coal bed, containing more mineral matter of detrital origin in the uppermost durain. The maceral assemblage of these terminal durains is dominated by detrital fusinite and semifusinite, suggesting reworking of the maceral assemblage coincident with the deposition of the detrital minerals. However, a durain in the middle of the coal bed, while lithologically similar to the uppermost durains, has a degraded, macrinite-rich, texture. The inertinite macerals in the middle durain have less distinct edges than semifusinites in the uppermost terminal durains, suggesting degradation as a possible path to inertinite formation. The uppermost durain has higher ash and semifusinite contents at the eastern sites than at the western sites. The difference in the microscopic petrology indicates that megascopic petrology alone can be a deceptive indicator of depositional environments and that close attention must be paid to the individual macerals and their implications for the depositional setting, especially within the inertinite group.  相似文献   

9.
内蒙古乌达矿区煤的显微特征与沉积环境关系的研究   总被引:6,自引:0,他引:6  
代世峰  张建华 《沉积学报》1998,16(3):141-146
通过对研究区主采煤层显微特征和沉积环境的分析,并利用三角图解(在三角图解中,考虑了煤中矿物特别是自生矿物对指示煤相的意义)和组分含量平面图,论述了显微煤岩特征与沉积环境的关系。研究发现,潮控下三角洲平原形成的煤层其活性组分和硫分含量较之河控下三角洲平原含量高,并且三角图解三端元的离散率小;在潮坪沉积基础上形成的煤层其惰性组分含量高并分布稳定;相同沉积环境形成的不同煤层显微组成相似,但它们的显微组成由于聚煤环境的变迁而在平面分布上有差异。  相似文献   

10.
Palynological and petrological studies have been undertaken on the Gondwana coal and associated lithologies encountered in borehole EBM-2 of East Bokaro coalfield of Damodar Basin, India. The palynological investigation resulted in the recognition of Assemblage–III (Densipollenites, 27.9 m–214.30 m), Assemblage–II (Striatopodocarpites + Faunipollenites, 225.00 m–297.60 m) and Assemblage–I (Faunipollenites + Scheuringipollenites, 307.00m–433.00 m). Lithofacies study was also done for better understanding of the preservation and abundance/paucity of the spores and pollen in different lithologies as the current borehole has significant thickness of mudstones, shales and siltstone. Palynofacies study and Petrographical studies of coal samples encountered in the borehole were used to determine the depositional environment of the coal precursor peat swamp. Palynological data has revealed the presence of younger Raniganj palynoflora between 27.00-214.30 m depth that is lithologically defined as Barren Measures Formation. This spore pollen study has proved that these sediments were deposited during late early Permian to late Permian period. Further the maceral analysis of organic sediments as well as the Thermal Alteration Index (TAI) has revealed that the coaly shale at 336.5 m depth has hydrocarbon generation potential.  相似文献   

11.
The South Sumatra basin is among the most important coal producing basins in Indonesia. Results of an organic petrography study on coals from Tanjung Enim, South Sumatra Basin are reported. The studied low rank coals have a mean random huminite reflectance between 0.35% and 0.46% and are dominated by huminite (34.6–94.6 vol.%). Less abundant are liptinite (4.0–61.4 vol.%) and inertinite (0.2–43.9 vol.%). Minerals are found only in small amounts (0–2 vol.%); mostly as iron sulfide.Based on maceral assemblages, the coals can be grouped into five classes: (1) humotelinite-rich group, (2) humodetrinite-rich group, (3) humocollinite-rich group, (4) inertinite-rich group and (5) humodetrinite–liptinite-rich group. Comparing the distribution of maceral assemblages to the maceral or pre-maceral assemblages in modern tropical domed peat in Indonesia reveals many similarities. The basal section of the studied coal seams is represented typically by the humodetrinite–liptinite-rich group. This section might be derived from sapric or fine hemic peat often occurring at the base of modern peats. The middle section of the seams is characterized by humotelinite-rich and humocollinite-rich groups. The precursors of these groups were hemic and fine hemic peats. The top section of the coal seams is typically represented by the humodetrinite-rich or inertinite-rich group. These groups are the counterparts of fibric peat at the top of the modern peats. The sequence of maceral assemblages thus represents the change of topogenous to ombrogenous peat and the development of a raised peat bog.A comparison between the result of detailed maceral assemblage analysis and the paleodepositional environment as established from coal maceral ratio calculation indicates that the use of coal maceral ratio diagrams developed for other coal deposits fails to deduce paleo-peat development for these young tropical coals. In particular, mineral distribution and composition should not be neglected in coal facies interpretations.  相似文献   

12.
在收集和整理大量山西省煤岩资料的基础上,分析了该省太原组和山西组煤的显微煤岩组分,并对各煤田太原组和山西组煤的R0,max的变化规律进行了研究。研究表明:山西省太原组和山西组煤中显微组分一般以镜质组为主,并且有从北向南有不断增加的趋势,惰质组次之,其趋势与镜质组相反,壳质组最少;太原组反射率值在0.6%~3.9%,整体上呈北低南高、西低东高的趋势,煤级从中煤级煤Ⅰ到高煤级煤Ⅱ都有赋存;山西组反射率值在0.6%~4.2%,其反射率变化趋势和煤级赋存特征与山西组类似。研究结果为评价和利用山西省的煤炭资源提供了依据。  相似文献   

13.
The coal seam No. 207 was a subject of palynological and petrographic studies. According to the results of the vitrinite random reflectance measurements supplemented by moisture and calorific value determinations, the rank of this coal is matching the boundary between sub-bituminous and bituminous coals. The aim was to reconstruct the environmental conditions during the biochemical stage of seam formation, as well as the facies development throughout the seam profile. The maceral (incident and fluorescence mode) and microlithotype compositions (incident light) supplemented by palynological analyses, show that there were two main facies developments. In the authors opinion, they correspond with a phase of ombrogenous, raised bog marked by the presence of crassidurite with Densosporites variabilis and a wet-forest swamp phase represented by vitrite and clarite with more diverse spore assemblage including densospores. Other minor but distinctive sediments, a cannel layer and a reeds facies, both occurring in the lower part of the seam. Above the tonstein horizon, a dry forest type of sedimentation is recognized.  相似文献   

14.
晋东南沁水盆地是目前我国进行煤层气勘探开发的主要地区之一,煤层气储层主要分布在石炭系和二叠系,其厚度明显受沉积古地理控制。本文通过对露头及钻井剖面的岩石学和沉积相研究,对该区主要含煤岩系-山西组和太原组进行了岩相古地理和煤储层聚集控制因素分析。太原组以石灰岩、铝土质泥岩、粉砂岩、粉砂质泥岩及砂岩为主,厚度44.90~193.48 m,含多层可采煤层,总厚度0~16.89 m,平均7.19 m。在太原组沉积期,研究区北部发育下三角洲平原相,煤层相对较厚,中部和南部为泻湖相,煤层相对较薄,东南角主要为滨外碳酸盐陆棚相,在晋城一带障壁砂坝相分布区,煤层亦较厚;山西组以砂岩、粉砂岩、泥岩为主,石灰岩仅在局部地区见到,该组厚18.60~213.25 m,含可采煤层1~2层,总厚度0~10.0 m,平均4.20 m,在山西组沉积期,北部以下三角洲平原分流河道相为主,中部和南部以分流间湾相为主,东南部则以河口砂坝相为主,厚煤带都位于中部和南部的三角洲分流间湾地区。总之,太原组富煤地带多与砂岩富集带相吻合,位于北部下三角洲平原和南部障壁砂坝地区,而山西组厚煤带大都位于南部三角洲分流间湾地区。  相似文献   

15.
This work presents the results from evaluating the gases sorbed by coal samples extracted from the Paleocene Guasare Coalfield (Marcelina Formation, northwestern Venezuela), as well as by their distinct maceral concentrates. The aim of this work has been to obtain an initial experimental main value of the gas content per unit weight of high volatile bituminous A coal samples from the open-pit Paso Diablo mine. An additional goal was to study differences in the CH4 storage ability of the distinct maceral groups forming part of the coal matrix. Both the coal samples and the maceral concentrates were studied by thermogravimetric analysis (TGA) in order to determine the temperature to be used in subsequent experiments. On-line analyses of hydrocarbons (C1, C2, C3) and CO2 yielded gas concentrations, plus δ13C values. Thermogenic gas is prevalent in the Guasare coals with vitrinite reflectance (%Ro) values from 0.65% to 0.88%. The amount of gas retained in the coals and maceral concentrates was measured with a special device that allows determination of the volume of gas sorbed by a solid sample subjected to controlled thermal treatment. The average coalbed gas concentration obtained was 0.51 cm3/g. The following list of maceral concentrates shows the relative capacity for the volume of sorbed gas per unit weight: inertinite > low-density vitrinite > liptinite ≈ high-density vitrinite. It is concluded that the gas volumes retained in the distinct maceral concentrates are not controlled by porosity but rather by their microscopic morphology.  相似文献   

16.
A detailed study of maceral composition and vitrinite reflectance of the coal deposits from Marki-Jhari-Jamni area, situated in the northwestern extremity of Wardha valley coalfield, Yeotmal district, Maharashtra has been carried out with special reference to their depositional set up. These coals have two distinct types of maceral organization, one having significantly high distribution of the vitrinite group of macerals (35–41%) and the other containing the dominance of inertinite (26–49%). Liptinite maceral group is recorded between 14 and 24%, barring a few coal bands having liptinite maceral group as high as 33–37%. The vitrinite reflectivity ranges from 0.38–0.43%. Thus, they have attained sub-bituminous C rank. Mineral matter in these coals varies between 15 and 22%. The present study suggests that the basin primarily experienced cold climate having intermittent brackish water influx with alternating dry oxidizing spells.  相似文献   

17.
An integrated analysis in this study of paleogeographic, paleontologic, seismic and sedimentologic data has been used to explain the effect of the Pangaean megamonsoon on the whole Triassic (especially the Middle–Late Triassic Mungaroo Formation) in the North Carnarvon Basin, Northwest Shelf of Australia. Our results show that the three Triassic formations from bottom to top (Locker Shale, Mungaroo Formation and Brigadier Formation) comprise a complete depositional cycle and correspond to an undeveloped, strong, and weak monsoon periods, respectively. During the strong monsoon period of the Mungaroo Formation, the palynological evidences exhibited mixture spore-pollen characteristics of the hygrophytic assemblage (spore-pollen from the pteridophyte spores, seed ferns and cycads pollen in humid environment of lowlands and coastal plain) and the xerophytic assemblage (pollen from the drought tolerant plants of the interior mountainous areas). The sedimentary evidences of the Mungaroo Formation show low-angle shingled progradational seismic reflection configuration. The highly seasonal variations in precipitation during deposition of the Mungaroo Formation exhibited typical “sandwiched” depositional characteristics of coarse channels sandstone (fining-upward fluvial aggradational cycles (FACs) with poor to moderately sorting and angular to subangular roundness), organic mudstone and coal seam interbedded. Finally, in contrast to today's typical examples of Poyang Lake Delta, a shallow-water braided delta conceptual depositional model of the Mungaroo Formation is formed with a large proximal and distal delta plain, and small delta front. The model results serve mainly to indicate the importance of various climate-forming factors (climate, topography, eustatic), whereas tectonic activity unlikely played any significant role in this process.  相似文献   

18.
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

19.
A detailed study of maceral composition and vitrinite reflectance of the coal deposits from Marki-Jhari-Jamni area, situated in the northwestern extremity of Wardha valley coalfield, Yeotmal district, Maharashtra has been carried out with special reference to their depositional set up. These coals have two distinct types of maceral organization, one having significantly high distribution of the vitrinite group of macerals (35–41%) and the other containing the dominance of inertinite (26–49%). Liptinite maceral group is recorded between 14 and 24%, barring a few coal bands having liptinite maceral group as high as 33–37%. The vitrinite reflectivity ranges from 0.38–0.43%. Thus, they have attained sub-bituminous C rank. Mineral matter in these coals varies between 15 and 22%. The present study suggests that the basin primarily experienced cold climate having intermittent brackish water influx with alternating dry oxidizing spells.  相似文献   

20.
Detailed stratigraphic and sedimentological studies of the Tertiary Tongue River Member of the Fort Union Formation in the Powder River Basin, Wyoming, and the Cretaceous Blackhawk Formation and Star Point Sandstone in the Wasatch Plateau, Utah, indicate that the depositional environments of coal played a major role in controlling coal thickness, lateral continuity, potential minability, and type of floor and roof rocks.The potentially minable, thick coal beds of the Tongue River Member were primarily formed in long-lived floodbasin backswamps of upper alluvial plain environment. Avulsion of meandering fluvial channels contributed to the erratic lateral extent of coals in this environment. Laterally extensive coals formed in floodbasin backswamps of a lower alluvial plain environment; however, interruption by overbank and crevasse-splay sedimentation produced highly split and merging coal beds. Lacustrine sedimentation common to the lower alluvial plain, similar to the lake-covered lower alluvial valley of the Atchafalaya River Basin, is related to a high-constructive delta. In contrast to these alluvial coals are the deltaic coal deposits of the Blackhawk Formation. The formation consists of three coal populations: upper delta plain, lower delta plain, and ‘back-barrier’. Coals of the lower delta plain are thick and laterally extensive, in contrast to those of the upper delta plain and ‘back-barrier’, which contain abundant, very thin and laterally discontinuous carbonaceous shale partings. The reworking of the delta-front sediments of the Star Point Sandstone suggests that the Blackhawk-Star Point delta was a high-destructive system.  相似文献   

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