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1.
东秦岭花岗伟晶岩的基本地质矿化特征 总被引：6，自引：0，他引：6
伟晶岩是一种特殊的火成岩类,东秦岭是我国重要的花岗伟晶岩分布区和稀有金属成矿区之一,这里广泛发育各种类型花岗伟晶岩,并形成4个大的花岗伟晶岩脉密集区。岩石化学、稀土配分和氧同位素研究结果显示,东秦岭的花岗岩与伟晶岩具有一致或相似的特点。其粗大的矿物组成,表明伟晶岩中富含挥发份并且是在封闭条件较好的地壳中深部形成的,是地壳深部过程的记录和区域侵蚀深度较大的标志。各种类型的花岗伟晶岩具特征的结构、成分和矿化分带现象,反映出深部透岩浆流体的成矿作用。东秦岭花岗伟晶岩受秦岭造山带主造山阶段的加里东期板块俯冲碰撞的影响,是同一板块俯冲碰撞构造体制下由花岗岩母岩浆分异、演化的结果。东秦岭花岗伟晶岩分布面积大、类型全、分异演化强烈、矿化普遍,是我国寻找花岗伟晶岩型稀有元素矿产、铀矿和部分宝石资源的有利地区。 相似文献
2.
陕西丹凤三角地区花岗伟晶岩铀-稀有元素矿化特征及成矿作用分析 总被引：1，自引：0，他引：1
重点对北秦岭丹凤三角地带花岗伟晶岩的地质矿化特征及铀-稀有元素成矿作用进行了研究分析,认为花岗伟晶岩是在岩浆演化晚期,富含挥发分的残余岩浆进一步分异演化的结果,花岗伟晶岩主要侵位于加里东中晚期花岗岩体的内外接触带及秦岭岩群中,多沿背斜轴部和断裂、裂隙分布,多平行于区域构造线延伸方向。花岗伟晶岩的岩石类型有:黑云母伟晶岩、二云母伟晶岩、白云母伟晶岩、白云母钠长石伟晶岩、锂云母钠长石伟晶岩,是由交代分异作用引起的。花岗伟晶岩的成岩、成矿作用可划分为后岩浆、伟晶作用、气成作用和热水溶液4个阶段。花岗伟晶岩具明显的多元素矿化特征,富含U、Th、Nb、Ta、L等稀有金属和绿柱石、云母、钾长石等非金属矿产。 相似文献
3.
秦岭伟晶岩中电气石比磁化率的研究 总被引：3，自引：0，他引：3
秦岭稀有元素花岗伟晶岩中电气石产出普遍,亚种繁多,计有黑电气石、锂电气石、镁电气石。测得各类电气石的比磁化率值从-0.37～20.93×10~(-6)cm~3/g电气石比磁化率大多数为顺磁性的个别县抗磁性.电气石比磁化率的大小和它们的化学成分、晶体构造密切相关。其比磁化率与铁含量成正的线性关系,电气石比磁化率与比重、折射率等亦成正线性相关。本文根据电气石比磁化率对秦岭伟晶岩中的电气石进行了初步分类.并探讨了电气石比磁化率变化规律与伟晶岩类型和矿化的关系。 相似文献
4.
东秦岭伟晶岩区是秦岭造山带规模最大、稀有金属矿化最丰富的伟晶岩区.该区稀有金属矿化种类齐全,产出贫矿、铀矿化、铍矿化、锂矿化和复杂稀有金属矿化伟晶岩,以锂矿化和铀矿化伟晶岩为主.稀有金属伟晶岩类型丰富,包括绿柱石-铌铁矿亚型、锂辉石亚型、锂云母亚型和钠长石-锂辉石型.伟晶岩内部结构分带型式多样,包括对称分带、分层和均一结构.铀矿化伟晶岩分带简单,铍矿化和复杂稀有金属矿化伟晶岩以对称分带结构为主,锂矿化伟晶岩具有多种内部结构分带型式.伟晶岩分异演化程度跨度大.结晶分异影响着复杂稀有金属矿化伟晶岩的成矿过程.该区主要产出古生代伟晶岩,形成于晚志留世—中泥盆世,集中于两期,处于晚造山-造山后阶段.伟晶岩形成时代与伟晶岩空间分布、岩浆岩分异演化程度、稀有金属矿化类型等关联不大.东秦岭地区中大面积不同时代花岗岩体的侵位、变质沉积岩地层的发育以及长期复杂的造山演化历史,包括地壳加厚和抬升,是形成高度分异演化的伟晶岩岩浆的有利地质条件.该区具有寻找铍矿和复杂稀有金属矿的潜力,且需要关注长石、石英和云母等矿物的综合利用.稀有金属伟晶岩的岩浆成因是未来研究的重要方向. 相似文献
5.
Gatumba花岗伟晶岩矿区位于卢旺达西部,在约150 km~2的范围内出露130多条大型伟晶岩脉,它是卢旺达目前最重要的稀有金属矿产地。该地区的花岗伟晶岩具有完整的区域分带,从内到外(以Gitarama岩基为中心)依次为:黑云母伟晶岩、二云母伟晶岩、白云母伟晶岩及矿化伟晶岩,其中矿化伟晶岩属于LCT(Lithium-Caesium-Tantalum)型伟晶岩。从区域上看,这些花岗伟晶岩与强过铝质的G4花岗岩(Generation 4~(th),时代约为986±10 Ma)在时空上密切相关,其形成时代约为950～980 Ma,普遍认为G4花岗岩是Gatumba地区花岗伟晶岩的母岩。不同分带伟晶岩中的单矿物(如:黑云母、钾长石、电气石)化学成分分析的结果显示,从靠近岩体的贫矿伟晶岩到远端的矿化伟晶岩呈现出一种岩浆连续分离结晶演化的趋势。此外,利用瑞利分离结晶模型进行岩浆演化过程模拟的结果表明(以G4花岗岩为起始点),从黑云母伟晶岩到矿化伟晶岩演化程度越来越高,它们分别代表G4花岗岩母岩浆发生0～69%(F=0～69)、69%～92%(F=69～92)、92%～98%(F=92～98)及98%(F≥98)分离结晶作用的产物。综合现有认识可知,花岗岩结晶分异成因模式是Gatumba地区花岗伟晶岩出现不同区域分带的最合理解释。 相似文献
6.
河南省卢氏县蔡家花岗伟晶岩型锂矿地质特征及矿床成因分析 总被引：1，自引：0，他引：1
为进一步研究东秦岭地区稀有金属矿产特征,指导河南省卢氏县蔡家锂矿的勘查工作,本文通过对蔡家锂矿野外地质调查、岩心及薄片观察和地球化学分析,结合区域花岗伟晶岩成矿作用规律,对蔡家锂矿的地质特征和矿床成因进行了分析。结果表明,该矿床成因类型属于花岗伟晶岩型;矿石类型为微斜长石-钠长石型、锂辉石-钠长石型、锂云母-钠长石型;矿石矿物以锂辉石、锂云母为主,其次为磷锂铝石、铌锰矿、钽锰矿、铌钽铁矿、绿柱石等。在此基础上,对该区花岗伟晶岩矿脉的母岩和花岗伟晶岩密集区的形成机理进行探讨,表明研究区花岗伟晶岩母岩为桃坪花岗岩体,具有高级分异特征,主要赋存在背斜带次级构造内。 相似文献
7.
福建南平花岗伟晶岩中的电气石研究 总被引：2，自引：0，他引：2
电气石是南平伟晶岩和围岩中分布广泛的一种副矿物,根据化学成分,它们属于镁铁锂电气石亚族,其端员为铁(黑)电气石、镁电气石和锂电气石,其间还有一系列过渡矿物。南平伟晶岩中除未发现端员锂电气石外,其他端员及过渡系列电气石均十分发育,这在国内外同类伟晶岩中十分少见。不同成分电气石分布于不同类型伟晶岩及同一伟晶岩分异演化的不同阶段。本文在对电气石的化学成分、物理性质、产状等较详阐述基础上,对它们的演变规律及形成环境进行了讨论,这对于探讨南平伟晶岩的形成及寻找稀有金属伟晶岩有重要意义。 相似文献
8.
东秦岭稀有金属伟晶岩的类型、内部结构、矿化及远景——兼与阿尔泰地区对比 总被引：2，自引：1，他引：1
东秦岭地区和阿尔泰造山带均产出大量稀有金属伟晶岩,是中国重要的稀有金属产地。前者工作程度低,远景尚不明朗;后者规模巨大。开展成矿条件对比研究十分必要。东秦岭地区产出铍矿、锂矿和复杂稀有金属矿,以锂矿化为主,伟晶岩类型复杂,包括绿柱石-铌铁矿型、复杂型锂辉石亚型、复杂型锂云母亚型和钠长石-锂辉石型。阿尔泰稀有金属伟晶岩发育多种稀有金属矿化组合,伟晶岩类型为绿柱石-铌铁矿型、复杂型锂辉石亚型和钠长石-锂辉石型。东秦岭稀有金属伟晶岩的内部结构分带型式包括对称分带结构、均一结构和分层结构,阿尔泰稀有金属伟晶岩以对称分带结构为主,也见均一结构。东秦岭与阿尔泰稀有金属矿石矿物相近,东秦岭产出更多含锂磷酸盐矿物。东秦岭稀有金属伟晶岩分异演化程度相对集中且高,阿尔泰稀有金属伟晶岩分异演化程度跨度大。东秦岭和阿尔泰锂矿的锂矿化主要发生于岩浆就位前,复杂稀有金属矿稀有金属富集作用发生在岩浆就位前和就位后,但阿尔泰复杂稀有金属矿经历了更为复杂和极度的分异演化过程。东秦岭稀有金属伟晶岩可能与同期花岗岩为同一熔融事件的产物,与早期花岗岩来自同一物质来源。阿尔泰稀有金属伟晶岩与花岗岩关系复杂,但大量早期花岗岩的形成提高了地壳成熟度,有利于形成晚期稀有金属伟晶岩。东秦岭稀有金属伟晶岩产出于北秦岭单元中,形成于晚造山和造山后阶段,集中于造山后阶段,稀有金属矿化呈多期断续叠加特征。阿尔泰稀有金属伟晶岩主要产出于琼库尔-阿巴宫地体和中阿尔泰山地体内,集中于造山后和非造山阶段。伟晶岩岩浆活动受控于物质来源和造山作用。储存稀有金属的岩石在造山作用中熔融,发生多期的大规模花岗质岩浆活动,稀有金属通过长期复杂的分异演化过程在残余熔体中不断富集。这种富挥发分和稀有金属的过铝质硅酸盐岩浆随后上升就位,可经后续冷却结晶和不混溶作用进一步富集稀有金属,从而形成稀有金属伟晶岩。东秦岭具有形成含稀有金属高度分异演化岩浆的有利条件,该区具有寻找铍矿和复杂稀有金属矿的潜力。 相似文献
9.
中国花岗伟晶岩型锂矿特征和研究进展 总被引：2，自引：0，他引：2
花岗伟晶岩型锂矿是中国锂资源的重要类型之一。本文基于全国87处花岗伟晶岩型锂矿研究资料,通过与全球典型伟晶岩型锂矿的对比分析,梳理总结中国花岗伟晶岩型锂矿的时空分布规律、矿石矿物组合特征、成矿成岩温压条件、演化历史和锂同位素分馏特征,以期为今后找矿工作提供理论依据。研究表明中国花岗伟晶岩锂矿空间分布相对集中,主要分布在8个锂成矿带,主成矿期为三叠纪;含锂矿物相与花岗岩-伟晶岩体系中的H_2O、P、F和Li等挥发性元素密切相关;与国外典型花岗伟晶岩锂矿相比,中国大型-超大型伟晶岩锂矿具有成矿温度相似和成矿压力较大的特征;不同于以Harding伟晶岩为代表的侵位后P-T两阶段演化轨迹,中国花岗伟晶岩锂矿存在以川西扎乌龙为代表的单阶段快速降温降压型演化轨迹;结晶分异是花岗伟晶岩最可能的岩石成因,该地质过程中锂元素和重锂同位素富集于花岗伟晶岩;未矿化伟晶岩全岩比锂辉石矿化伟晶岩全岩更富轻锂同位素的特征表明锂成矿过程发生在流体出溶之后。 相似文献
10.
福建南平花岗伟晶岩型钽铌矿床地质特征与成因 总被引：2，自引：0，他引：2
福建南平钽铌矿是亚洲最大的花岗伟晶岩型钽铌矿床,也是中国钽铌金属矿的重要产地。南平钽铌矿在构造上位于闽西北隆起带东南缘,矿区内广泛发育有中—新元古界变质岩系。钽铌矿多呈脉体,沿变质岩系的片理或层理侵入,矿脉与围岩的关系清晰。这些脉体是在与加里东期花岗岩有成因联系的4类花岗伟晶岩分异—演化的基础上形成的。矿化伟晶岩中分带和交代蚀变作用均十分发育,稀土元素的矿化与伟晶熔体的结晶分异及后期热液蚀变作用有较密切的关系。稀土元素和磷酸盐矿物含量很多,这在国内外同类型伟晶岩中不常见。同时该地区也是新矿物——南平石的唯一产地。钽铌矿物是矿化伟晶岩中Ta和Nb元素的最主要载体,Ta含量大于Nb,还有其他可综合利用的稀土元素。闽西北地区具有进一步寻找此类型矿化伟晶岩的广阔前景。 相似文献
11.
The most important source of yellow gem elbaite is the Canary mining area in the Lundazi District of eastern Zambia. The tourmaline has been mined since 1983 from both pegmatite and eluvial/alluvial deposits, in colors typically ranging from yellow-green to yellow to orange and brown; much of the orange-to-brown material is heated to attain a ‘golden’ or ‘canary’ yellow color. The elbaite is Mn-rich (up to 9.18 wt% MnO documented in the literature) and contains small amounts of Ti and little or no Fe. The distinctive composition of this tourmaline is probably the result of the early crystallization of abundant schorl from an unusual B-rich, Li-poor pegmatite melt, which depleted Fe while conserving Mn until the late-stage crystallization of gem pockets. The simple mineralogy of the pegmatite consists of feldspars, quartz, and tourmaline; the lack of micas, phosphates, or Li minerals, and the presence of very little garnet, allowed Mn to fractionate to high levels during pegmatite crystallization. The presence of abundant gem tourmaline in a Li-poor pegmatite is highly unusual. 相似文献
12.
Encarnación Roda-Robles Romeu Vieira Alfonso Pesquera Alexandre Lima 《Mineralogy and Petrology》2010,100(1-2):23-34
Granitic pegmatites are widespread within a schist-metagreywacke complex in the Fregeneda-Almendra area (Central Iberian Zone). They intrude pre-Ordovician metasedimentary rocks and show a zonal distribution relative to the Meda-Penedono-Lumbrales granitic complex, from barren bodies to those enriched in Li, F, Sn, Nb>Ta, P and Be. Based on mineralogical criteria, these pegmatites are classified into three main categories: barren, intermediate and rare-element pegmatites, with each type including various subtypes. Phosphates are present in many pegmatites that usually occur as fine-grained accessory minerals. The most complex association of such minerals includes numerous Fe–Mn phosphates that occur in intermediate pegmatites. Al-phosphates are characteristic of Li-rich pegmatites. Electron microprobe analyses of representative phosphates reflect compositional differences depending on the pegmatite type. The Fe/(Fe+Mn) ratio of phosphates tends to decrease as the evolution degree of the pegmatites increases. 相似文献
13.
Katharina Marger Matthieu Harlaux Andrea Rielli Lukas P. Baumgartner Andrea Dini Barbara L. Dutrow Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615
Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ11B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ11B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO2 and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s). 相似文献
14.
为了对西藏错那洞电气石花岗岩源区进一步约束,利用显微镜、电子探针和激光剥蚀多接收等离子质谱仪,对错那洞电气石花岗岩中电气石的形态、成分及硼同位素组成进行了研究.结果表明,错那洞电气石花岗岩中的电气石为碱族黑/铁电气石,直接结晶自富硼熔体,与熔体之间未发生明显的硼同位素分馏.电气石δ11B值主要在-6.91‰^-9.17‰之间,与大陆地壳平均δ11B值(-10‰±3‰)相近,表明错那洞电气石花岗岩主要源自变质沉积岩的部分熔融.然而,与起源于变质沉积岩的花岗岩相比,样品的δ11B值明显偏高,而与前人报道的雅拉香波淡色花岗岩(源自石榴石角闪岩部分熔融)的δ11B值相似.因此,错那洞电气石花岗岩源区中,除了变质沉积岩外,可能还混入了少量石榴石角闪岩. 相似文献
15.
The geology of the Komu area, south-western Nigeria was investigated in order to determine the nature of occurrence, petrography and chemical composition, and to evaluate the mineral potential of granitic pegmatites. The pegmatites are hosted by para-gneisses, amphibolites and granitic rocks. These host rocks are characterized by low pressure mineral assemblages of upper greenschist to lower amphibolite facies grades. The pegmatites consist of four lithological units: alkali feldspar unit, graphic granite unit, quartz-albite-muscovite-tourmaline unit and saccharroidal albite-muscovite-tourmaline-garnet unit.
A K/Rb ratio of below 100 is indicative of a mineralization potential in most pegmatites, except for the saccharroidal albite-muscovite-tourmaline-garnet unit which has exceptionally high ratios. The discrimination diagrams Rb versus K/Rb, Zn versus K/Rb and Th versus K/Rb show a limited range of fractionation, suggesting that the pegmatites belong to the barren muscovite and rare element classes. The rare element class is moderately enriched in beryl, tourmaline and niobium–tantalum minerals. The pegmatite has affinity for beryl columbite sub-type and lithium–cesium–tantalum (LCT) family. The ores plot mainly in the field of mangano-tantalite of tantalite-columbite quadrilateral diagram. These results indicate that the pegmatites are promising hosts for Nb-Ta ores. 相似文献
A K/Rb ratio of below 100 is indicative of a mineralization potential in most pegmatites, except for the saccharroidal albite-muscovite-tourmaline-garnet unit which has exceptionally high ratios. The discrimination diagrams Rb versus K/Rb, Zn versus K/Rb and Th versus K/Rb show a limited range of fractionation, suggesting that the pegmatites belong to the barren muscovite and rare element classes. The rare element class is moderately enriched in beryl, tourmaline and niobium–tantalum minerals. The pegmatite has affinity for beryl columbite sub-type and lithium–cesium–tantalum (LCT) family. The ores plot mainly in the field of mangano-tantalite of tantalite-columbite quadrilateral diagram. These results indicate that the pegmatites are promising hosts for Nb-Ta ores. 相似文献
16.
Lukas Krmcek Milan Novak Robert B.Trumbull Jan Cempirek Stanislav Houzar 《地学前缘(英文版)》2021,12(1):219-230
Various metacarbonate and associated calc-silicate rocks form minor but genetically significant components of the lithological units in the Bohemian Massif of the Variscan orogen in Central Europe.These rocks vary in terms of their lithostratigraphy,chemical composition and mineral assemblage(dolomite/calcite ratio,silicate abundance).Tourmaline is present in five paragenetic settings within the metacarbonate and calc-silicate units.TypeⅠcomprises individual,euhedral,prismatic grains and grain aggregates in a carbonate-dominant(calcite±dolomite)matrix poor in silicates.TypeⅡis characterized by euhedral to subhedral grains and coarse-to fine-grained aggregates in silicate-rich layers/nests within metacarbonate bodies whereas typeⅢoccurs as prismatic grains and aggregates at the contact zones between carbonate and associated silicate host rocks.TypeⅣis in veins crosscutting metacarbonate bodies,and typeⅣtourmaline occurs at the exocontacts of elbaite-subtype granitic pegmatite.Tourmaline from the different settings shows distinctive compositional features.Typical for typeⅠare Mg-rich compositions,with fluor-uvite>dravite>>magnesio-lucchesiite.Tourmalines from typeⅡsilicate-rich layers/nests are highly variable,corresponding to oxy-schorl,magnesio-foitite,Al-rich dravite and fluor-uvite.Typical for typeⅢtourmalines are Ca,Ti-bearing oxy-dravite compositions.The typeⅣveins feature dravite and fluor-uvite tourmaline compositions whereas typeⅤtourmaline is Li,F-rich dravite.Tourmaline is the only Bbearing phase in paragenetic typesⅠ-Ⅳ,where it is characterised by two principal ranges of B-isotope composition(δ^11B=-13‰to-9‰and-18‰to-14‰).These ranges correspond to regionally different units of the Moldanubian Zone.Thus,the Svratka Unit(Moldanubian Zone s.l.)contains only isotopically lighter tourmaline(δ^11B=-18‰to-14‰),whereas metacarbonates in the Poli?ka unit(Teplá-Barrandian Zone)and Olesnice unit(Moravicum of the Moravo-Silesian Zone)has exclusively isotopically heavier tourmaline(δ^11B=-9‰to-13‰).Tourmalines from metacarbonates in the Variegated Unit cover both ranges of isotope composition.The isotopically light end of the B isotope range may indicate the presence of continental evaporites within individual investigated areas.On the other hand,variations in the range of~8δ-units is consistent with the reported shift in B isotopic composition of metasedimentary rocks of the Bohemian Massif due to the prograde metamorphism from very-low grade to eclogite facies.In contrast to the metacarbonate-hosted settings,tourmaline of paragenetic type V from the exocontact of granitic pegmatites displays a significantly heavier range ofδ^11B(as low as-7.7‰to-0.6‰),which is attributed to partitioning of 10 B to cogenetic axinite and/or different B-signature of the source pegmatite containing tourmaline with heavyδ^11B signature. 相似文献
17.
华南晚中生代幕阜山花岗复式岩基内部及周缘广泛发育花岗伟晶岩脉,部分岩脉富含Li-Nb-Ta等元素,形成大型－超大型稀有金属矿床.本文以幕阜山北缘断峰山地区贫锂伟晶岩类和南缘仁里地区新发现的富锂伟晶岩为主要研究对象,通过详细的岩相学和主要及特征矿物（长石、云母、电气石、石榴子石、绿柱石、铌钽铁矿）的微区原位EPMA和LA-ICP-MS主微量元素地球化学的对比分析,深入探讨了伟晶岩的分类、成因演化及成矿潜力.按照特征矿物组合将伟晶岩划分为断峰山地区电气石伟晶岩、电气石－绿柱石伟晶岩、绿柱石伟晶岩、铌钽铁矿－绿柱石伟晶岩和仁里地区的锂电气石－锂云母伟晶岩5类.5类岩脉中的长石、云母、电气石和/或石榴子石的化学成分记录了不同程度花岗伟晶岩脉的演化阶段,按岩浆演化程度由低至高依次为电气石伟晶岩→电气石－绿柱石伟晶岩→绿柱石伟晶岩→铌钽铁矿－绿柱石伟晶岩→锂电气石－锂云母伟晶岩,并分别对应伟晶岩稀有金属富集程度分类中的无矿→（含Be）→富Be→富Be、Nb、Ta→富Li、Be、Nb、Ta阶段.这一结果表明仁里地区伟晶岩已演化至晚期富集多种稀有金属元素阶段,具有Li-Nb-Ta多金属成矿潜力,而断峰山地区的伟晶岩演化程度相对较低.断峰山电气石－绿柱石伟晶岩中的色带电气石晶体发育强烈成分环带,由内向外可明显分为5环,自核部至边部,Li、Zn、Ga、Ge、Nb、Ta、Sn、Pb等不相容元素和金属元素含量逐渐升高,清晰记录了正常岩浆演化序列及稀有金属富集过程.结合前人有关幕阜山花岗岩类的研究资料,本文认为幕阜山伟晶岩为该地区晚中生代巨量花岗质岩浆经历长期结晶分异作用晚期的分异产物. 相似文献
18.
Tourmalinite and tourmaline-rich rocks associated with Fe-carbonate–graphite phyllite, strata-bound polymetallic sulphide deposits, metabasite and marble were studied, for information on the mechanism of tourmaline formation in the pre-Hercynian low-grade metamorphic sequence of the Mandanici Unit in the Peloritani Mountains of Sicily, southern Italy. The major and trace element compositions of the tourmaline rocks suggest the existence of a sedimentary protolith with pre-metamorphic black shale and bedded chert. Boron was interpreted to be accumulated in a restricted sedimentary basin, between platform carbonate formations, with abundant organic matter and Fe–Al–Ti-rich laterite–bauxite soil-derived clastic supply, under a continental volcano-tectonic extensional regime accompanied by a local convective hydrothermal system along faults. Petrographic, crystal–chemical and δ11B isotopic data are compatible with a model of marine sediment dewatering at temperatures below 200 °C, which caused the removal of boron from clay. Metamorphism led to the development of tourmaline in an Al–Ti-rich environment, in equilibrium with other minerals such as ilmenite, albite and muscovite. The upper temperature of metamorphism (almost 375 °C), estimated on the basis of δ11B, fits geothermometric results from Δ13Ccarbonate–graphite on associated rocks. The estimated value of δ11B in the tourmalinite protolith, − 7.5‰ , is also compatible with continental-derived Al-rich sediments. 相似文献
19.
四川康定甲基卡超大型锂矿是我国最大的硬岩型锂矿床之一,矿区中南部呈岩株状出露的二云母花岗岩常被认为是成矿伟晶岩的"矿源岩",对其开展Li同位素地球化学研究,对探讨矿区稀有金属的来源与演化具有重要意义.研究工作基于详细的野外地质调查,采用MC-ICP-MS方法对岩体锂同位素组成开展了研究.研究结果显示,岩体Li含量介于192×10-6~470×10-6,均值为309×10-6,δ7Li值介于-1.56‰~+0.90‰,均值为-0.24‰,与平均上地壳值基本一致,具有高Li低δ7Li的特征.δ7Li与Li、Rb、Ga、SiO2及εNd（t）不存在明显的相关性,岩体锂同位素组成反映了其形成时的源区特征,未受岩浆结晶分异作用和蚀变作用的影响.岩体岩石地球化学、同位素地球化学资料表明,岩浆来源以三叠系西康群砂泥岩的部分熔融为主,可能有部分深源物质的加入.此外,岩体Li同位素的变化规律表明伟晶岩的成矿流体来源于二云母花岗岩.岩体Li含量与Li同位素组合不仅可用来划分锂矿床类型,而且对稀有金属找矿具有一定的指导意义. 相似文献