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为了深入分析油页岩发育特征对古环境的指示作用,为油页岩资源评价提供理论指导,选取沁水盆地中部新近系张村组油页岩为研究对象,采用岩石热解、有机碳测定、X射线荧光光谱仪（XRF）测试等方法分析油页岩有机地球学和元素地球化学特征,探讨沉积期的古气候和古地理环境。结果表明,张村组油页岩含油率较低,为4.15%;干酪根类型为标准腐泥型（I1）,埋藏较浅,生烃潜力较高;样品的微量元素富集指数和地球化学参数特征显示,张村组油页岩有机质为混合来源,湖泊自身生产力提供主要物质基础;沉积期气候温暖湿润,盆地内水体由盐湖逐渐淡化,油页岩形成于水体分层不强的厌氧、深湖环境。油页岩的地球化学特征与沉积期的古气候、古地理环境具有较好耦合性。 相似文献
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The hydrocarbon potential of the sub-surface Tertiary sedimentary rock sequences of the Lokichar basin system (NW-Kenya) has been interpreted using some selective geochemical analysis of rock samples in Loperot-1 Well (denoted as LT-1 Well) for their total organic carbon (TOC) which forms the premise of this study. Understanding the sub-surface structures and depositional environments conducive for hydrocarbon generation and trapping is essential as it forms the basis for exploration. The organic matter richness and degree of thermal alteration and/or maturation are factors useful in evaluating the potential source rocks. Rock-Eval pyrolysis has been employed on selected rock samples with high TOC for quantification of data and this would help in precise identification of phases of hydrocarbon generation. 相似文献
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North Carnarvon盆地是澳大利亚最主要的产油气盆地,也是世界上主要的富气盆地之一.三叠纪North Carnarvon盆地属于克拉通边缘坳陷,地层厚度巨大且平面分布广.中三叠世晚期澳大利亚西北陆架发生强制性海退,造成North Carnarvon盆地沉积格局发生转变,沉积环境由滨浅海突变为海陆过渡环境,从而沉积了两套差异性明显的地层,即Locker shale 和Mungaroo组.本文从宏观和微观、有机与无机入手,阐述了Locker shale 和Mungaroo组的古地理背景、沉积充填演化及其相关的烃源岩与有机质显微组分发育特征.宏观上,Mungaroo组发育大型三角洲,中粗粒分支流水道砂岩与暗色泥岩频繁互层,其中近端三角洲平原泥岩厚度较薄,薄煤层只局部发育,陆源有机质含量较高,平均TOC含量为1.59%;远端三角洲平原泥岩厚度较大,薄煤层广泛发育,陆源有机质含量高,TOC含量最高,达4.11%;三角洲前缘泥岩厚度较大,陆源有机质含量低,TOC含量低,为1.05%.Locker Shale以滨浅海相沉积为主,局部发育小型三角洲,其中开阔浅海亚相烃源岩厚度较大,前三角洲、滨浅海、开阔浅海三个亚相TOC含量相当,平均值为1.16%.微观上,Mungaroo组由近端平原亚相—远端平原亚相—前缘亚相壳质组含量逐渐增多,镜质组先增加后下降,惰质组先减少后增加;远端三角洲平原镜质组含量最高.Locker shale由前三角洲相—浅海相壳质组增加,镜质组和惰质组均减少.研究区三叠系烃源岩及有机质显微组分的分布规律与特提斯南缘特殊的古地理、季风洪水的古气候背景密切相关,Mungaroo组的远端三角洲平原为最有利的烃源岩发育环境. North Carnarvon 盆地三叠系岩相古地理格局与沉积充填演化规律体现了温室气候效应下阵发性水流主导的沉积特色,为类似地质背景下油气资源评价提供了新的思路. 相似文献
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鄂尔多斯盆地延长期湖盆充填类型与优质烃源岩的发育 总被引：1，自引：0，他引：1
湖盆充填类型是盆地构造及古气候的综合反映,对优质烃源岩的发育有重要控制作用。在综合分析延长组优质烃源岩沉积环境的基础上,认为长91、长73、长72—长71烃源岩发育期湖盆都表现为平衡充填类型,但有机质丰度及规模有较大差别,因此进一步细分长91期为平衡充填三角洲前缘-深湖相组合沉积体系,长73期为平衡充填深湖相沉积体系,长72—长71期为平衡充填浊流-深湖相组合沉积体系,并指出长73期湖盆充填类型发育最优质烃源岩,进而重点探讨了其形成环境。本文认为盆地沉降过程与古气候变化主要控制优质烃源岩的沉积和保存条件,而湖盆原始生产力则与火山灰沉积和深部流体关系密切。综合长73期盆山耦合关系、湖盆充填类型、沉积岩相组合等,指出强水动力体系(浊流沉积、三角洲)对有机质起稀释作用,重点强调了火山灰沉积和深部流体带来的营养物质有利于提高湖盆原始生产力,进而初步揭示了长73优质烃源岩的发育模式。这一认识为进一步研究陆相坳陷湖盆优质烃源岩的充填类型及发育规律提供了可借鉴的研究实例。 相似文献
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《Chemie der Erde / Geochemistry》2016,76(1):117-131
Elemental and organic geochemical studies have been carried out on the Gondwana sediments, collected from the outcrops of Permian and Jurassic–Cretaceous rocks in the Krishna–Godavari basin on the eastern coast of India, to understand their paleo and depositional environment and its implications for hydrocarbon generation in the basin. Amongst the studied formations, the Raghavapuram, Gollapalli and Tirupati form a dominant Cretaceous Petroleum System in the west of the basin. Raghavapuram shales and its stratigraphic equivalents are the source rock and Gollapalli and Tirupati sandstones form the reservoirs, along with basaltic Razole formation as the caprock. Major element systematics and X-ray diffraction study of the sandstones indicate them to be variably enriched with SiO2 relative to Al2O3 and CaO, which is associated, inherently with the deposition and diagenesis of the Gondwana sediments. Post-Archean Average Shale normalized rare earth elements in shales show enrichment in most of the samples due to the increasing clay mineral and organic matter assemblage. A negative europium and cerium anomaly is exhibited by the REE's in majority of rocks. Composed primarily of quartz grains and silica cement, the Gollapalli and Tirupati sandstones have characteristics of high quality reservoirs. The shales show a significant increase in the concentration of redox sensitive trace elements, Ni, V, Cr, Ba and Zn. The total organic carbon content of the shales ranges between 0.1 and 0.5 wt%. Programmed pyrolysis of selected samples show the Tmax values to range between 352–497 °C and that of hydrogen index to be between 57–460 mgHC/gTOC. The organic matter is characterized by, mainly, gas prone Type III kerogen. The n-alkane composition is dominated by n-C11–C18 and acyclic isoprenoid, phytane. The aromatic fraction shows the presence of naphthalene, anthracene, phenanthrene, chrysene and their derivatives, resulting largely from the diagenetic alteration of precursor terpenoids. The organic geochemical proxies indicate the input of organic matter from near-shore terrestrial sources and its deposition in strongly reducing, low oxygen conditions. The organic matter richness and maturity derived from a favorable depositional setting has its bearing upon the Gondwana sediments globally, and also provides promising exploration opportunities, particularly in the Raghavapuram sequence of the KG basin. 相似文献
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甘肃-内蒙古交界处的北山盆地群侏罗系是我国西北地区潜在的油气勘探新领域。为加深对该盆地群资源潜力的认识,以有机地球化学分析数据为基础,探讨了其中煤系烃源岩的沉积环境、有机质来源,建立了该烃源岩生烃潜力评价标准。研究结果表明,中口子盆地侏罗系烃源岩干酪根类型以Ⅱ1-Ⅱ2型为主,生烃母质主要是陆生植物,含少量的藻类和水生生物,主要形成于三角洲平原沼泽或湖侵期的间湾湖泊等氧气量适中的弱氧化-弱还原沉积环境。生烃潜量和氢指数是衡量煤系源岩有机质丰度、生烃潜力和生油潜力最有效的指标,根据生烃潜力评价标准：黑帐房凹陷侏罗系暗色泥岩多属于中-差烃源岩,南泉凹陷暗色泥岩生烃潜力级别优于黑帐房凹陷,主要为中-好烃源岩;南泉凹陷炭质泥岩大多数属于中等-好油源岩,煤岩大多属于差油源岩。 相似文献
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阐述了近五年有机地球化学领域的重要研究进展和未来有可能出现新突破的领域。在沉积有机质的性质和结构的认识上有重要进展,由于分子和分子同位素测试技术的进步,发现对有机质参与的地球化学全过程能够进行定性研究。阐述了与烃源岩发育相关的环境与控制因素,但具体形成机制的推断还没有得到沉积记录的验证。生物—有机地球化学在定量环境变化与古生态系统重建研究等方面作出了独特的贡献。未来关于过度型有机质和石油天然气成藏过程定量化重建研究将是有机地球化学有可能出现新突破的领域。新的成份与同位素测定新技术的引入将促进有机地球化学相关研究领域的发展。 相似文献
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基于地质类比方法,综合运用地质、地球物理、地球化学等资料及盆地模拟技术恢复了西湖凹陷中部地区油气成藏动力学过程.结果表明:研究区内沉积充填和构造沉降具有幕式演化特征,并以始新世地层沉积厚度最大、沉积-沉降速率最高;烃源岩有机质热演化具有成熟时间短、生油窗窄、生气窗宽的特点;主力烃源岩平湖组进入成熟生烃门限的时间早,生排烃能力强,且生排烃过程发生在晚渐新世至早-中中新世期间;研究区油气运移和油气聚集主要受控于古构造面,保俶斜坡带和天屏断裂陡坡带以平行流为主,中央背斜带以汇聚流为主,存在多个有利油气聚集区,油气聚集作用主要发生在龙井运动(7 Ma)以来. 相似文献
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海相烃源岩的正反演对比分析 总被引：4，自引：0，他引：4
海相优质烃源岩有效的评价体系是海相地层油气勘探开发中的关键问题之一.沉积盆地内保存的残余有机质从生物物质到烃源岩的演化过程经历了两个阶段, 即从生物物质到沉积有机质的形成阶段和从沉积有机质到残余有机质的烃源岩形成阶段, 后者包括沉积有机质在未熟阶段经历生物化学作用成为埋藏有机质和在成熟-过成熟阶段经历热解作用成为残余或风化残余有机质两个亚阶段.烃源岩反演分析是利用残余或风化残余有机质的量来推断埋藏有机质的量或者原始生烃潜力.而正演分析则是根据沉积物沉积环境、生物物质及其介质物理化学条件特征运用地球生态学、地球微生物学、分子地球生物学和生物地球化学方法推断沉积有机质的量, 甚至推断埋藏有机质的量, 进而评估烃源岩的原始生烃潜力, 也就是利用生物生产力和保存环境等综合分析沉积有机质的量.正反演对比分析相互验证和相互补充, 更好地揭示了烃源岩基本特征, 为海相优质烃源岩的预测和评价提供了有效的研究方法. 相似文献
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The organic matter-rich Toolebuc Formation of eastern Australia was deposited in a Lower Cretaceous epicontinental sea. Parameters from biological marker studies indicate that the organic matter is immature to marginally mature for hydrocarbon generation. The occurrence of abundant coccoliths and the distribution of alkane biomarkers suggest that the organic matter (Type II) is largely of planktonic origin and only in the southeastern part of the depositional area can a terrestrial influence be discerned. Variations in kerogen composition can be attributed to the extent of the oxidation of the source materials and the degree of incorporation of sulphur. The atomic H/C ratios (c. 1.1) are remarkably constant for most of the Toolebuc Formation. Atomic O/C ratios vary from 0.1 and 0.4 and can be related both to depth and paleogeographic position. Kerogen sulphur contents range up to 7%, and the highest values occur in the most carbonate-rich sediments. Total sulphur (inorganic + organic) to carbon ratios in the sediments vary from 1 to <0.2 and are a function of paleogeographic position and lithology. Most of the sulphur in the sediments is in the form of pyrite, but the proportion of sulphur in organic form increases as the total sulphur content decreases. The evidence for oxidation of the organic matter and incorporation of sulphur into it during deposition suggests that bituminite, which is the dominant organic maceral in the Toolebuc Formation, was formed from an organic gel derived by decay of predominantly algal material. These data support a modified gyttja model (Kauffman, 1981) for the deposition of organic matter in the Toolebuc Formation. 相似文献
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Archana Devi Shivananda Boruah G. B. Gilfellon 《Journal of the Geological Society of India》2017,89(4):429-434
The study area is confined to a part of upper Assam basin, north of river Brahmaputra (north bank). Seven exploratory wells have been drilled in this part of the basin in order to probe the hydrocarbon prospects of the area. The exploratory efforts did not indicate significant hydrocarbon prospects in the north bank. Since the presence of source rock is an important component of the petroleum system, a detailed systematic study of source rock potential was carried out by analysing known source rock intervals in these seven wells. In the present study, Rock-Eval pyrolysis combined with specific geochemical analyses like GC and TLCFID has been used to characterise the source rocks, their distribution and thermal maturity of the organic matter. The source rocks in the area show mainly Type III, land-plant derived organic matter along with some Type II organic matter. They are predominantly gas prone in nature, although mixed and oil-prone source rocks are occasionally present. Although source rock intervals have been identified in the Langpar, Sylhet limestone and Kopili formations, the Barail Group and the Tipam sandstone Formation, the bulk of the source rock occurs within the Kopili Formation. Geochemical analyses of the cores indicate oil signatures at certain depths, although no commercial oil was discovered. The hydrocarbon generation potential of these source rocks are constrained by low maturity at the presently drilled depths. 相似文献
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Maria Letizia Amadori Habib Belayouni Francesco Guerrera Manuel Martín-Martín Iván Martin-Rojas Crina Micl?u? Giuliana Raffaelli 《International Journal of Earth Sciences》2012,101(6):1599-1623
A study has been performed on the Cretaceous to Early Miocene succession of the Vrancea Nappe (Outer Carpathians, Romania), based on field reconstruction of the stratigraphic record, mineralogical-petrographic and geochemical analyses. Extra-basinal clastic supply and intra-basinal autochthonous deposits have been differentiated, appearing laterally inter-fingered and/or interbedded. The main clastic petrofacies consist of calcarenites, sub-litharenites, quartzarenites, sub-arkoses, and polygenic conglomerates derived from extra-basinal margins. An alternate internal and external provenance of the different supplies is the result of the paleogeographic re-organization of the basin/margins system due to tectonic activation and exhumation of rising areas. The intra-basinal deposits consist of black shales and siliceous sediments (silexites and cherty beds), evidencing major environmental changes in the Moldavidian Basin. Organic-matter-rich black shales were deposited during anoxic episodes related to sediment starvation and high nutrient influx due to paleogeographic isolation of the basin caused by plate drifting. The black shales display relatively high contents in sub-mature to mature, Type II lipidic organic matter (good oil and gas-prone source rocks) constituting a potentially active petroleum system. The intra-basinal siliceous sediments are related to oxic pelagic or hemipelagic environments under tectonic quiescence conditions although its increase in the Oligocene part of the succession can be correlated with volcanic supplies. The integration of all the data in the “progressive reorientation of convergence direction” Carpathian model, and their consideration in the framework of a foreland basin, led to propose some constrains on the paleogeographic-geodynamic evolutionary model of the Moldavidian Basin from the Late Cretaceous to the Burdigalian. 相似文献
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The study area is the southern depocenter (depth > 4200 m) of the Mesohellenic Basin which extends between Kipourio and Grevena, central Greece. The Mesohellenic Basin is a Middle-Tertiary intramontane basin developed within the Hellenide orogen. Previous studies have focused on the depositional environments, configuration and hydrocarbon potential of the basin. In this paper we present additional geochemical and petrographic data from outcrop samples of the basin's southern depocenter, which is considered the most promising area, in terms of hydrocarbon prospectivity. A total number of thirty six samples were analysed: Rock-Eval pyrolysis, maceral analysis, vitrinite reflectance and thermal alteration index, bitumens extraction, liquid chromatography, and GC-MS. The samples were collected from deltaic deposits and submarine fan sediments of Late Eocene to Late Oligocene age. The TOC values of the analysed samples range between rich and very rich and the organic matter consists mainly of type III kerogen and the organic matter consider to be predominately gas prone. The thermal maturity assessed from Tmax and vitrinite reflectance shows an immature stage of the organic matter along with the presence of layers having reached the very early mature stage. Vitrinite reflectance measurements and maturity calculations (applying the Lopatin modeling), reveal that the lower part of the depocenter sediments falls within the ‘oil window’. The extractable organic matter (EOM) (mg bitumens/g TOC) indicate the existence of samples (from deltaic deposits) with high ratio of transformation (EOM) (> 100 mg bitumen/g TOC). The GC and GC-MS analyses of the biomarkers indicate mainly the occurrence of terrestrial organic matter reflecting oxidizing conditions and both immature and very early mature stages. The results of the Rock-Eval pyrolysis and the distribution of the isoprenoids support the assumption of the input of an organic matter mixture. 相似文献
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烃源岩的沉积环境、母源输入与有机质性质有着密切联系,吐哈盆地台北凹陷不同层系、不同地区侏罗系煤系烃源岩由于其沉积环境、母源输入的不同,导致其地球化学指标差异;通过对源岩地球化学指标相关性分析表明,姥植比（Pr/Ph）是反映源岩沉积氧化还原环境和水体盐度的重要指标;C29ααα20R在C27～C29规则甾烷ααα20R中的相对含量也是反映沉积水体盐度的重要指标。同时发现源岩类型划分的主控指标是族组成中芳烃、沥青质组分含量及饱芳比、非沥比等四项指标,姥植比、伽马蜡烷指数为源岩类型划分的次控指标,据此将台北凹陷侏罗系煤系烃源岩划分为三类。 相似文献
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通过区域地质背景分析,认为东北地区处于活动大陆边缘构造背景下,形成了石炭纪—二叠纪泛盆地,松辽盆地是在残留的石炭系—二叠系盆地之上形成和演化的,石炭系—二叠系分布面积达7.2×104km2。地球化学分析表明,二叠系以极低变质岩为主,泥岩的有机质成熟度和丰度较高,剩余生烃潜力普遍较低。盆地东部地区的二叠系泥岩厚度超过1000m,而成熟度低于北部和西部地区,处于过成熟阶段,至今仍具备生烃能力。上覆中生代地层沉积后,东部地区的二叠系泥岩有机质成熟度增幅较大,发生了二次生烃,生烃量巨大并得到有效保存,形成原生和次生油气藏,具有较好的勘探前景。 相似文献