共查询到20条相似文献，搜索用时 640 毫秒
1.
选择川北江油滚柴坡和广元上寺、杨家湾二叠系-三叠系界线剖面为研究对象,利用中子活化法分析了粘土岩样品中稀土元素的组成.通过对稀土元素丰度、标准配分模式和特征参数的比较研究,探讨了稀土元素地球化学与自然环境突变的关系.结果表明,各剖面的?Eu、?Ce、∑LREE/∑HREE-∑REE、Eu/∑REE-∑LREE/∑HREE、球粒陨石标准化曲线图解和La-Th-Sc三元图解一致反映了界线事件的存在及界线时期稀土元素的地球化学特征与环境突变的关系.同时,通过对3条剖面稀土元素地球化学特征与标准剖面的对比研究,认为P/T(二叠系/三叠系)界线事件时期环境不仅受中酸性火山作用的影响,还可能受(碱性)基性-超基性或地外溅射物的影响.研究结果为从元素地球化学的角度探讨这一重要地质时期的灾变事件提供了新的资料. 相似文献
2.
《现代地质》2020,(5)
贵州省黔西县官坝地区位于华南板块西南部,其二叠系—三叠系界线剖面出露较好,界线处出露3层黏土岩。采集贵州黔西官坝地区二叠系—三叠系地质界面黏土岩1件U-Pb年龄样品、7件地球化学样品,对其锆石进行U-Pb定年以及主量、微量和稀土元素进行测试分析。锆石LA-ICP-MS U-Pb分析结果表明,U和Th含量分别为60.26×10~(-6)～297.9×10~(-6)和46.14×10~(-6)～244.26×10~(-6),Th/U比值介于0.76～1.55之间,为典型的岩浆锆石;获得~(206)Pb/~(238)U加权平均年龄为(252.6±1.4) Ma,谐和年龄为(252.7±0.6) Ma。地球化学分析结果显示,黏土岩属于高硅、铝、钾、镁,低铁、钛的钙碱质中酸性火山物质,具有稀土元素总量相对较高、相对富集轻稀土元素和轻、重稀土元素分馏程度高的特征,负Eu异常明显,δEu=0.19～0.45。上述岩石地球化学特征表明,贵州黔西官坝地区(华南板块西南)二叠系—三叠系界线位置总体上可与浙江长兴(华南板块东南)海相二叠系—三叠系界线(金钉子)相比较。 相似文献
3.
皖北奥陶系碳酸盐岩稀土元素地球化学特征及其古岩溶意义 总被引：1，自引：0，他引：1
依据安徽北部刘桥二矿奥陶系碳酸盐岩隐伏剖面 (下奥陶统顶部 ) 17个碳酸盐岩样品的稀土元素 (15个项目 )的测试资料 ,针对不同岩性 ,分类阐述了它们的REE总量和配分模式、LREE和HREE、δEu和δCe的地球化学特征及其剖面变化特点。在此基础上 ,详细讨论了碳酸盐岩稀土地球化学特征成因机理与古岩溶发育环境的关系 ,为在岩溶岩地球化学特征与其形成环境及溶蚀程度间建立定量识别标准提供了依据。 相似文献
4.
黔北大方地区二叠纪及三叠纪地层发育,在二叠系—三叠系界线处发现12~14cm厚的界线粘土,在界线粘土层之上还发现3~4层5~18cm厚的火山事件粘土层。二叠系—三叠系界线粘土、事件粘土及松子坎段底部火山事件粘土岩(绿豆岩)均具有高的K_2O和MgO含量;二叠系—三叠系界线粘土的稀土元素特征与关岭组松子坎段底部绿豆岩相似,与沙堡湾段事件粘土岩的稀土元素特征也十分相似,Eu异常较明显,说明界线粘土及事件粘土成因均与火山活动有密切关系。界线粘土比事件粘土具更明显的Eu异常,部分界线粘土还具有Ce异常。二叠系—三叠界线粘土、事件粘土及关岭组绿豆岩的源区均属于活动大陆边缘的长英质火山岩区,为酸性的长英质火山岩喷发(火山灰)沉积的产物,而沙堡湾段及九级滩段正常沉积泥岩的源区属于被动大陆边缘的长石砂岩岩区。界线粘土中,大部分微量元素与事件粘土及关岭组绿豆岩中对应微量元素的含量相近,但其中的Th、Y、Nb、Cd、Ga、In、Ta明显高于与火山活动有关的事件粘土及绿豆岩,推测事件粘土与少量宇宙事件外来物质的加入有关。 相似文献
5.
新疆伊犁河谷沙漠沉积的稀土元素特征及其环境意义 总被引：1，自引：0，他引：1
以伊犁河谷西部塔克尔莫乎尔沙漠内的可克达拉(TKP)剖面作为研究对象开展了稀土元素特征分析,结合方解石变化特征,探讨沙漠沉积稀土元素与环境变化间的关系.研究结果表明TKP剖面的稀土元素总量(不含Y)平均为130.90 μg/g,变化范围为32.88 ～ 238.58μg/g,整个剖面分配模式相似,缓右倾斜型,轻稀土适度富集,δCe,δEu和LREE/HREE比值相近,Eu中度负异常,未见明显Ce异常,指示剖面物质来源的一致性和总体干旱、半干旱的气候环境.包括Ce在内的各稀土元素、∑REE以及LREE/HREE在垂向变化上高度相关,并与方解石含量存在较好的相关关系,表明其与气候变化密切相关,在干旱区的沙漠沉积中稀土元素对古气候变化具有良好的指示作用,并据此重建了晚全新世以来伊犁河谷的气候演变过程. 相似文献
6.
油页岩中的稀土元素（REE）研究不仅可以用于解决岩石地质成因,提供物质来源信息,而且可以对REE含量进行资源评价,有利于油页岩的综合开发利用,具有重要的理论和现实意义。本研究测试并分析了银额盆地巴格毛德凹陷中生界白垩系下统巴音戈壁组（K1b）巴格毛德油页岩REE地球化学特征,分析结果表明,油页岩中的REE总量（∑REE）为94．8×10^-6～178×10^-6,平均值为126×10^-6,低于其围岩的∑REE;轻、重稀土元素含量比值（∑LREE／∑HREE）为2．60～3．45,平均值为3．10。（La／Yb）w为0．57～1．02,平均值为0．89,表明油页岩中LREE、HREE分异不明显,LREE相对HREE富集,属于LREE低度富集型。Eu表现为明显负异常,Ce表现为微弱的正异常,表明了油页岩形成于还原的古湖泊环境。油页岩样品∑REE与其微量元素的聚类分析结果表明,油页岩中的REE主要来自陆源碎屑沉积。油页岩样品δCe与δEu、δCe与∑REE均无明显的相关关系,表明成岩作用对REE的影响十分有限,研究区油页岩的成岩阶段处于未成熟阶段。 相似文献
7.
古生代—中生代之交的生物绝灭和地质事件——四川广元上寺二叠系—三叠系界线和事件的初步研究 总被引：5，自引：1，他引：5
详细的生物地层学调查研究,揭示了四川广元上寺二叠系—三叠系界线上,古生代海生无脊椎动物大规模的绝灭,还检测到铱和微量元素的地球化学异常(Ir达2±0.5ppb)、碳和氧同位素(δ~(13)C和δ~(18)O)的剧烈变动、沉积相的显著变化(盆地相—潮间带)。(图4、5、6)这些证据表明二叠纪末期有地外事件发生,而地外事件又诱发了地内事件,包括构造上升、海水退却、火山喷发、古气候变化以及伴随的动物群大规模绝灭。古生代动物群的大规模绝灭和中生代动物群渡过萧条期才茁壮成长的迟滞、新生过程,说明了古生代与中生代间的地质事件是巨大的、深刻的,传统的二叠系—三叠系界线是一条全球灾变线。 相似文献
8.
9.
利用电感耦合等离子体质谱仪测定龙井街铅锌矿床中矿石及围岩的稀土元素含量,探讨矿床稀土元素地球化学特征及其揭示的地质意义。研究结果表明,矿石与围岩的稀土元素球粒陨石标准化配分曲线均表现出轻稀土较富集,曲线右倾的特点;矿石与围岩均显示∑REE较低,LREE较富集、HREE亏损;(La/Sm)N和(Gd/Yb)N值均反映LREE富集,LREE分馏强于HREE;矿石的δEu值介于0.67 1.28之间,均值0.88,δCe值在0.77 1.09之间,均值0.86。而围岩的δEu值在0.70 0.87范围,均值0.76,δCe值在0.80 0.89之间,均值0.85。这些特征说明矿区成矿物质和成矿流体主要来自围岩,但成矿流体中有深部热流体的加入;从早期形成的Zn S到晚期形成的Pb S,其成矿还原环境逐渐减弱,成矿温度逐渐下降。 相似文献
10.
羌塘盆地中央隆起带南侧隆额尼-昂达尔错布曲组古油藏白云岩稀土元素特征及成因意义 总被引：2，自引：0，他引：2
以系统的岩石学及沉积相分析为基础,深入探讨了隆额尼—昂达尔错古油藏白云岩及其伴生灰岩的稀土元素地球化学特征,认为该区灰岩及白云岩∑REE仍受沉积相带及沉积过程的控制,且具∑REE较低的总体特征,白云岩中HREE比LREE更具贫化的特点,这些特征均系淡水淋漓作用的结果;灰岩及白云岩在配分模式上,均为相对平坦的页岩配分模式。其中灰岩在配分模式上,在∑REE较高的情况下表现出起伏较大的特点,而白云岩在∑REE较低的情况下,表现出较为平坦的特征,白云岩化过程中稀土元素有贫化和均一的趋势;灰岩与白云岩相比,灰岩δEu值较高,而白云岩δCe较高,反映出灰岩形成于水体较深的还原环境,而白云岩形成于古地理相对高点的氧化环境。该区白云岩为混合水交代成因。 相似文献
11.
Police, politics, and the right to the city 总被引：1，自引：0，他引：1
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete. 相似文献
12.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
13.
I. M. Gorokhov M. A. Semikhatov M. M. Arakelyants E. A. Fallick N. N. Mel’nikov T. L. Turchenko T. A. Ivanovskaya T. S. Zaitseva E. P. Kutyavin 《Stratigraphy and Geological Correlation》2006,14(3):260-274
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation. 相似文献
14.
Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
15.
扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究 总被引：7，自引：3，他引：4
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。 相似文献
16.
Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean 总被引：2，自引：0，他引：2
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston
situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine
fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and
at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological
(i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates)
controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution
sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were
<20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf
of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is
lost to sediments. 相似文献
17.
18.
V. Yu. Prokof’ev L. D. Zorina V. A. Kovalenker N. N. Akinfiev I. A. Baksheev A. N. Krasnov G. A. Yurgenson N. V. Trubkin 《Geology of Ore Deposits》2007,49(1):31-68
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type. 相似文献
19.
山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义 总被引：10，自引：0，他引：10
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。 相似文献