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1.
巨鲕是指那些直径超过2mm、海相成因的大型鲕粒,它们在结构上与鲕粒相似,但却远没有鲕粒分布广泛,成因也与鲕粒不尽相同。豫西渑池地区寒武系第三统张夏组发育了大量的巨鲕,其核心由粒径小于2mm的放射状鲕粒或泥晶球粒组成,形成于弱搅动的水体环境中;圈层以泥晶或由Girvanella丝状体组成的暗色纹层与由微亮晶方解石组成的浅色纹层交替发育为特征。巨鲕是在低、中等能量交替的滩间海环境中由Girvanella丝状体的生长、微生物诱导的钙化作用和无机碳酸钙沉淀而成的。Girvanella丝状体在巨鲕的内、外圈层均有分布,尤以外圈层分布更为密集,显示了微生物在巨鲕形成过程中具有重要作用,这为探讨巨鲕的成因提供了一个重要的实例。 相似文献
2.
北京下苇甸剖面张夏组鲕粒特征及其白云化机制 总被引：1，自引：0，他引：1
北京下苇甸剖面张夏组作为华北寒武系的标准剖面之一,鲜有人对其中的鲕粒类型及其成岩作用进行细致研究。在充分调研前人研究的基础上,通过野外观察、实测,并结合室内薄片鉴定、XRD测试等技术,对下苇甸剖面张夏组的鲕粒类型进行总结,并对鲕粒白云化机制进行分析。结果显示：(1)下苇甸张夏组鲕粒类型主要为放射鲕、同心放射鲕及单晶鲕/多晶鲕,还有少量同心鲕、复鲕及藻鲕;(2)鲕粒发生白云化,填隙物未见白云化,且放射圈层白云化程度高于同心圈层,并且放射圈层白云石颗粒围绕核心呈放射状分布,同心圈层围绕核心呈同心状分布;(3)鲕粒内部白云石颗粒多为中细晶,自形-半自形,回流渗透白云化是造成鲕粒白云化的主要成因,因此造成亮晶鲕粒石灰岩白云化程度高于灰泥鲕粒石灰岩。 相似文献
3.
依据鲕粒的形态、结构及方解石组成,将豫西宜阳地区寒武系馒头组鲕粒灰岩中的鲕粒分为4种类型:不规则放射状泥晶鲕粒、泥晶套亮晶表皮鲕粒、同心放射状泥晶鲕粒和规则放射状微亮晶鲕粒。这些鲕粒多由泥晶方解石组成,且泥晶方解石可出现在鲕粒的不同部位,从而与研究区张夏组的鲕粒明显不同,后者由亮晶方解石组成。在电子显微镜下,鲕粒中的泥晶方解石表现为六边形蜂格和片状壁,而这种结构被认为是细菌或蓝细菌的细胞结构,是由附着的微小晶粒呈切向围绕细菌或蓝细菌排列所致。构成蜂格结构的矿物主要为碳酸钙,其被认为是蓝细菌死亡后灰泥化的结果。由此可见,鲕粒中泥晶方解石的形成与微生物的生命活动密切相关,这对于阐明鲕粒在其形成过程中受到微生物的影响具有重要意义。 相似文献
4.
5.
本文应用显微镜和扫描电镜对下石炭统马角坝组顶部的铁质鲕粒的研究发现:铁质鲕粒由核心和同心圈层组成,核心成分主要是赤铁矿碎屑和石英颗粒,圈层厚度较小,整体呈胶状形态,由赤铁矿围绕核心呈致密板状平行排列,整体上结构一致;铁质鲕粒是在适合的pH、Eh条件下,大量铁质围绕石英碎屑或矿物碎屑转动时胶体沉积形成的,沉积环境为潮间-潮下的浅水动荡环境,是大规模海退暴露后海平面初始上升期的产物。 相似文献
6.
在雪宝顶北麓的黄龙地区新发现的鲕状钙华包壳粒,是高寒区钙华形成环境中产出的一类典型陆相包覆颗粒构造。通过系统采样鲕状包壳粒沉积剖面,并借助常规显微镜、扫描电镜与能谱分析等,揭示出鲕状钙华包壳粒的矿物组分、微观结构等特征。结果表明:研究区的鲕状钙华包壳粒分为同心圆状、同心圆—放射状、薄壁同心圆状3种基本类型,包壳粒核部是由异地的钙华碎屑构成,外壳层是由泥晶与微亮晶方解石纹层围绕核部逐层形成的圈层构造;微观特征显示泥晶层无明显微生物成因发育特征。鲕状钙华包壳粒的微观形态与组构特征反映出壳体中的泥晶圈层可能形成于相对深的静水环境,亮晶圈层可能形成于浅水高能环境,鲕状钙华包壳粒的成因偏于鲕类而非核形石类。 相似文献
7.
瓦西乡产出的南红玉中的红色点状及火焰纹典型包裹体分别是石英中的红色球粒与红色管状包裹体。鏡下及扫描电镜(SEM)研究,红色球粒分布在"三色"层水晶的菱面体单形晶面的间歇层面中,由红色核、黑色壳和红色表层组成;火焰纹管状包裹体主要出现在条带水晶中,管的方向垂直水晶的菱面体晶面,管的内壁呈黑色,外壳为红色。其球粒表层或管外壳的颜色、厚度及透光性则直接影响南红的颜色质量与润泽性。研究表明,球粒状和火焰状包裹体主要由片状、鳞片状或板片状赤铁矿组成;球粒圈层中的赤铁矿晶体c轴取向呈规律变化,可能与其V2O5含量有关。据水晶晶体中的球粒、管及共生矿物绿帘石、黄铜矿包裹体的红外光谱(IR)及流体包裹体均一法测温与激光拉曼(LRS)分析,球或管的赤铁矿属含有机质的低温热液(约160℃)成因,成矿溶液中的有机质也是促使铁氧化物凝聚形成具不同圈层结构的红色球粒与管的主要原因。有机质可能来自下二叠统茅口组碳酸盐。 相似文献
8.
鲕粒是恢复古海水性质和古环境的重要载体。通过对巫溪鱼鳞剖面震旦系地层的实测,发现该剖面鲕粒发育于灯影组二段上部,且可以划分为两个鲕粒层。底部鲕粒层(鲕粒层A)厚约5.5 m,顶部鲕粒层(鲕粒层B)厚约1.4 m,两个鲕粒层之间为厚约2.4 m的泥—粉晶云岩。显微特征表明,鲕粒虽然完全白云石化,但纹层特征保存良好。鲕粒类型以泥—微晶鲕为主,同心鲕和同心—放射鲕次之,其余类型鲕粒发育较少。研究区灯二段鲕粒云岩为台地浅水鲕粒滩沉积,同心鲕和同心—放射鲕指示较强的水动力条件,泥—微晶鲕发育于水体相对较为安静的环境,而破碎再生鲕则可能与风暴事件相关。保存清晰的纹层可能表明鲕粒云岩是早期拟晶白云石化后的产物,因此灯影二段上部鲕粒白云岩是研究前寒武海水性质的良好载体。鲕粒纹层以同心状和同心—放射状主,指示灯影期海水性质可能为文石海。 相似文献
9.
鲕粒灰岩的溶解动力学特征和微观形貌的发育演化 总被引：1，自引：0，他引：1
鲕粒灰岩是重要的碳酸盐岩油气储层。通过常温常压下,北京西山鲕粒灰岩的溶解动力学实验发现,鲕粒灰岩的溶解主要受岩石和矿物的结构和化学成分控制。结构上表现为构造裂缝、鲕粒结合纹、颗粒晶体结合带等结构薄弱带优先发生溶蚀。成分上表现为白云岩化组分不仅自身较易溶蚀,而且能促进鲕粒灰岩的整体溶解;粘土矿物、石英等杂质组分常与鲕粒和白云岩化颗粒伴生,其对两者的阻溶效应更大。溶解过程中,鲕粒灰岩的构造裂隙、鲕粒放射结合纹和同心圈层等首先发生溶蚀,产生溶隙、粒内溶孔和粒间溶孔;其次为白云质组分以及白云质组分与方解石结合处而产生晶间溶孔、粒内溶孔;随着溶蚀强度的加强,围绕鲕粒形成环状溶蚀沟,在鲕粒溶蚀脱落后而形成鲕模孔。 相似文献
10.
在现代和古代碳酸盐沉积物中,碳酸盐鲕粒的包壳结构类型均较多,因其常被用于恢复古海洋的化学、物理性质演化而备受关注。对碳酸盐鲕粒包壳的研究始于 1879年,此后现代和古代鲕粒包壳的原生和次生结构特征和成因均得到了详细描述和深入探讨;然而,目前仍存在对现代鲕粒包壳原生结构的部分术语定义不明确、对古代鲕粒包壳原生结构的特征识别和分类不尽准确等问题。文中归纳了现代鲕粒包壳的原生结构类型及其主要特征,指出鲕粒包壳结构组合的常见类型包括放射状、同心状、同心—放射状等,且对包壳结构组合类型的识别是鲕粒包壳结构研究的关键。古代鲕粒受成岩作用影响,包壳原生结构保存程度可能不尽相同,甚至完全被次生结构所替代,但其原生结构类型与现代鲕粒类似,以放射状和同心状结构为主,只是同心状结构中的切线状纹层难以识别。中国的古代鲕粒研究虽已取得大量成果,但在对包壳原生结构的识别和应用方面尚存在一些误区,故在借鉴现代鲕粒包壳结构研究成果的基础上,笔者以华南下奥陶统鲕粒为例,论述了对古代鲕粒包壳结构如何进行特征描述、如何识别出保存较好的原生结构及如何利用包壳结构组合类型进行鲕粒分类等问题,展示了古代鲕粒包壳原生结构研究的重要科学意义。 相似文献
11.
菱铁矿很好地记录了过去地质流体的信息,能够用于示踪生物地球化学反应相关的成岩作用带。台湾国姓地区中新世海相泥页岩中发育自生的菱铁矿结核,其成因尚未厘清。野外观察发现菱铁矿以不连续透镜体平行散布于泥页岩中,主要由自生碳酸盐菱铁矿（78.63%）等矿物组成。菱铁矿的稀土元素配分模式为轻稀土亏损、中稀土富集,无Ce异常,指示菱铁矿形成于弱氧化的沉积环境,弱氧化的环境促进了菱铁矿在次氧化带的沉淀。菱铁矿的δ13CVPDB和δ18OVPDB值分别为-3.69‰~+0.08‰和-1.09‰~+0.25‰,指示菱铁矿形成于次氧化带,碳源很可能是海水和有机质降解混合产生。研究表明自生菱铁矿能够被用于识别沉积物中的生物地球化学过程和指示成岩作用带。 相似文献
12.
Siderite was precipitated from NaHCO3 and Fe(ClO4)2 solutions under anaerobic conditions at 25°C and 1 atm total pressure using a modified version of the chemo-stat technique and the free-drift technique. Samples of solution and solid were withdrawn at different time intervals during time course experiments to determine the bulk and isotope composition of the solution and solid, and the morphology and mineralogy of the solid. A series of metastable precursors precipitated and dissolved sequentially, culminating in well-crystallized siderite rhombohedra having an average edge of ∼ 2 μm and a limited size distribution. Siderite precipitation rate ranged from 100.23 to 102.44 μmol•m−2•h−1 for saturation states (with respect to siderite) ranging from near equilibrium to 103.53. Calculated carbon isotope fractionation factors (103lnα) averaged 8.5 ± 0.2 (1σ n = 4) for the siderite-CO2(g) system and 0.5 ± 0.2 (1σ n = 4) for the siderite-HCO3−(aq) system. 相似文献
13.
Siderite (FeCO3) is a widespread minor diagenetic mineral in clastic sedimentary basins. Although eodiagenetic authigenesis of siderite is well-known, siderite formed during burial diagenesis shows habits and chemical compositions that are poorly understood. This study tests the hypothesis that diagenetic siderite cements in sandstones in the Scotian Basin, offshore eastern Canada, show systematic variability in chemistry and habit that is a response to recrystallization and changing composition of basinal fluids. Mineral textures were determined from backscattered electron images, and chemistry mostly from electron microprobe analyses. Five chemical types of siderite are identified using k-means cluster analysis, based on the amount of substitution of Ca, Mg and Mn for Fe. Eodiagenetic microcrystalline coated grains, concretions and intraclasts in sandstones are principally Fe-rich siderite and locally have recrystallised to blocky equant crystals. Mesodiagenetic Mg-rich siderite partly replaced these equant crystals and also framework mica and K-feldspar grains, showing textural evidence for coupled dissolution–reprecipitation. Slender Mg-rich siderite rhombs (lozenges, bladed or wheat-seed siderite) have precipitated before and after the formation of quartz overgrowths in geochemical microenvironments. Magnesium substitution reflects Mg-rich formation waters resulting from smectite to illite conversion. Equivalent Ca-rich siderite occurs where sandstones overlie a Jurassic carbonate bank. Late Mn-rich siderite has complex textures resembling those of Mississippi-Valley type ores, with spheroidal rims, a honeycomb-like mesh and concentric infill around secondary pores. It also occurs in veins or replacing intraclasts, post-dating late ferroan-calcite cements in sandstones that show strong dissolution by hot basinal brines. The Ca, Mg and Mn content of diagenetic siderite, coupled with textural evidence for recrystallization, can thus be used to track changes in ambient formation fluids. Siderite habits and chemistry described from the Scotian Basin are found in many clastic basins, suggesting that the observed recrystallization textures and variation in chemical type are of broad application. 相似文献
14.
DAVID B. LOOPE RICHARD M. KETTLER KARRIE A. WEBER NATHAN L. HINRICHS DEREK T. BURGESS 《Sedimentology》2012,59(6):1769-1781
Iron‐bearing concretions are valuable records of oxidation states of subsurface waters, but the first concretions to form can be altered drastically during later diagenetic events. Distinctive concretions composed of heavy rinds of iron oxide that surround iron‐poor, mud‐rich cores are common along bases of fluvial cross‐bed sets of the Cretaceous Dakota Formation, Nebraska, USA. Concretion rinds thicken inward and cores contain 46 to 89% void space. Millimetre‐scale spherosiderites are abundant in palaeosols that developed in floodplain facies. Evolution of rinded concretions began when intraformational clasts were eroded from sideritic soils, transported, abraded and deposited in river channels. Alteration of siderite and formation of rinds occurred much later, perhaps in the Quaternary when sandstone pore waters became oxic. Dakota concretions are analogous to ‘rattlestones’ in Pleistocene fluvial channels of The Netherlands, and their rinded structure is analogous to that of iron‐rich concretions in the aeolian Navajo Sandstone of Utah. In all three deposits, rinded concretions formed when pre‐existing, siderite‐cemented concretions were oxidized within a sand matrix. Unlike fluvial examples, siderite in the Navajo Sandstone was autochthonous and of late diagenetic origin, having precipitated from carbon dioxide and methane‐enriched waters moving through folded and jointed strata. Iron‐rich rinds formed in all these strata because concretion interiors remained anaerobic, even as oxygen accumulated in the pore waters of their surrounding, permeable matrix. Iron oxide first precipitated at redox boundaries at concretion perimeters and formed an inward‐thickening rind. Acid generated by the oxidation reaction drove siderite dissolution to completion, creating the iron‐poor core. Iron‐oxide rinds are indicators of the former presence of siderite, a mineral that forms only under reducing conditions, during either early or late diagenesis. Siderite is vulnerable to complete oxidation upon exposure, so the distinctive rinded concretions are valuable clues that aid in deciphering diagenetic histories and for recognizing methanic floodplain palaeoenvironments and wet palaeoclimate. 相似文献
15.
自然界中碳酸盐的氧和碳同位素组成取决于形成这种碳酸盐的水体同位素组成,水体的氧、碳同位素组成又直接反映了成岩或含矿流体的性质和来源。菱铁矿是仅次于方解石和白云石的常见碳酸盐矿物,它作为成岩成矿的多相作用产物,在地层中广泛发育。本文试图通过它们的氧、碳同位素组成,探讨我国不同时代地层内层状和层控菱铁矿的成因问题,着重研究菱铁矿的形成环境和成矿作用。 相似文献
16.
Mike J. Pearson 《Geochimica et cosmochimica acta》1979,43(6):927-941
The major element geochemistry of a mudstone sequence of Westphalian age has been studied in detail and mineralogical distributions calculated. Quartz and zircon trends indicate the energy of the depositional environment and this is closely reflected in the clay mineralogical composition. Of the detrital clays kaolinite is concentrated in the finer-grained sediments relative to illite. Chlorite and interstratified illite-smectite probably underwent diagenetic modification and small amounts of authigenic clays may have formed.Siderite, which occurs in both concretionary and disseminated form, and pyrite developed during diagenesis under reducing conditions and account for most of the iron present. Pyrite grew first deriving its iron partly from detrital clays. Carbon isotopic evidence suggests that early siderite precipitated in pore space as nodules and later in dispersed form. A second concretionary phase, pistomesite, grew during late dewatering. Siderite iron was derived mainly from Mn-rich oxidate phases.Titanium occurs as anatase uniformly distributed through the sequence. Phosphorus is mainly in diagenetic apatite and the ratio is controlled by the micas. Adsorbed water is closely related to grain size and clay content. 相似文献
17.
本文探讨了次生萤石的成因。由于成矿后的断裂活动,使原生萤石脉受压破碎,形成了空洞。细末状萤石在地下水作用下形成胶体溶液搬运、沉淀和再结晶。另外,随着成矿后构造断裂而来的热液,引起萤石的新的溶解和结晶。 相似文献
18.
Thomas M. McCollom 《Geochimica et cosmochimica acta》2003,67(2):311-317
Thermal decomposition of siderite has been proposed as a source of magnetite in martian meteorites. Laboratory experiments were conducted to evaluate the possibility that this process might also result in abiotic synthesis of organic compounds. Siderite decomposition in the presence of water vapor at 300°C generated a variety of organic products dominated by alkylated and hydroxylated aromatic compounds. The results suggest that formation of magnetite by thermal decomposition of siderite on the precursor rock of the martian meteorite ALH84001 would have been accompanied by formation of organic compounds and may represent a source of extraterrestrial organic matter in the meteorite and on Mars. The results also suggest that thermal decomposition of siderite during metamorphism could account for some of the reduced carbon observed in metasedimentary rocks from the early Earth. 相似文献
19.
Michael Holcomb Anne L. Cohen Jeffrey L. Hutter 《Geochimica et cosmochimica acta》2009,73(14):4166-78
The morphology and composition of abiogenic (synthetic) aragonites precipitated experimentally from seawater and the aragonite accreted by scleractinian corals were characterized at the micron and nano scale. The synthetic aragonites precipitated from supersaturated seawater solutions as spherulites, typically 20-100 μm in diameter, with aggregates of sub-micron granular materials occupying their centers and elongate (fibrous) needles radiating out to the edge. Using Sr isotope spikes, the formation of the central granular material was shown to be associated with high fluid pH and saturation state whereas needle growth occurred at lower pH and saturation state. The granular aggregates have significantly higher Mg/Ca and Ba/Ca ratios than the surrounding fibers.Two types of crystals are identified in the coral skeleton: aggregates of sub-micron granular material and bundles of elongate (fibrous) crystals that radiate out from the aggregates. The granular materials are found in “centers of calcification” and in fine bands that transect the fiber bundles. They have significantly higher Mg/Ca and Ba/Ca ratios than the surrounding fibers.The observed relationship between seawater saturation state and crystal morphology and composition in the synthetic aragonites was used as a framework to interpret observations of the coral skeleton. We propose that coral skeletal growth can be viewed as a cyclical process driven by changes in the saturation state of the coral’s calcifying fluids. When saturation state is high, granular crystals precipitate at the tips of the existing skeletal elements forming the centers of calcification. As the saturation state decreases, aragonitic fibres grow in bundles that radiate out from the centers of calcification. 相似文献
20.
The crystallographic fabric and texture of siderite in concretions: implications for siderite nucleation and growth processes 总被引：3，自引：0，他引：3
Mark W. Hounslow 《Sedimentology》2001,48(3):533-557
The crystallographic fabric of siderite in siderite concretions has been determined for upper Carboniferous (Westphalian‐A) non‐marine concretions and lower Jurassic (Pliensbachian) marine concretions. Compositional zoning indicates that individual siderite crystals grew over a period of changing pore water chemistry, consistent with the concretions being initially a diffuse patch of cement, which grew progressively. The siderite crystallographic fabric was analysed using the anisotropy of magnetic susceptibility, which is carried by paramagnetic siderite. The siderite concretions from marine and non‐marine formations exhibit differences in fabric style, although both display increases in the degree of preferred siderite c‐axis orientation towards the concretion margins. The Westphalian non‐marine siderites show a preferred orientation of siderite c‐axes in the bedding plane, whereas the Pliensbachian marine siderites have a preferred orientation of c‐axes perpendicular to the bedding. In addition, a single marine concretion shows evidence of earlier formed, inclined girdle‐type fabrics, which are intergrown with later formed vertical c‐axis siderite fabrics. The marine and non‐marine fabrics are both apparently controlled by substrate processes at the site of nucleation, which was probably clay mineral surfaces. Siderite nucleation processes on the substrate were most probably controlled by the (bio?) chemistry of the pore waters, which altered the morphology and crystallographic orientation of the forming carbonate. The preferred crystallographic orientation of siderite results from the orientation of the nucleation substrate. Fabric changes across the concretions partially mimic the progressive compaction‐induced alignment of the clay substrates, while the concretion grew during burial. 相似文献